EP0539678B1 - Aufzeichnungsmaterial für das ink jet-Verfahren - Google Patents

Aufzeichnungsmaterial für das ink jet-Verfahren Download PDF

Info

Publication number
EP0539678B1
EP0539678B1 EP92114117A EP92114117A EP0539678B1 EP 0539678 B1 EP0539678 B1 EP 0539678B1 EP 92114117 A EP92114117 A EP 92114117A EP 92114117 A EP92114117 A EP 92114117A EP 0539678 B1 EP0539678 B1 EP 0539678B1
Authority
EP
European Patent Office
Prior art keywords
oxidized polyethylene
recording material
coating material
emulsified
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92114117A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0539678A1 (de
Inventor
Horst Dipl.-Ing. Westfal (Fh)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felex Schoeller Jr and GmbH and Co KG
Original Assignee
Felex Schoeller Jr and GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felex Schoeller Jr and GmbH and Co KG filed Critical Felex Schoeller Jr and GmbH and Co KG
Publication of EP0539678A1 publication Critical patent/EP0539678A1/de
Application granted granted Critical
Publication of EP0539678B1 publication Critical patent/EP0539678B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24901—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/3179—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers

Definitions

  • the invention relates to a recording material for the ink jet process and a coating composition for producing an ink receiving layer for the ink jet process.
  • droplets of a recording liquid are applied to the recording material using various techniques.
  • Hertz process which, by means of a digital electronic control of fine ink droplets which are pressed out of special nozzles, allows the printing of images with very high resolution directly from electronic data.
  • a recording material for multicolored ink jet printing generally consists of a support and an ink receiving layer arranged thereon.
  • a plastic film (polyester resin, diacetate resin) or paper and the like can be used as the carrier. be used.
  • the ink-receiving layers basically consist of a pigment / binder mixture.
  • the pigments serve to retain the dyes from the recording liquid on the surface of the sheet.
  • a high pigment concentration leads to high porosity of the layer (DE-PS 30 24 205). Although this achieves good smudge resistance, at the same time pigments from the ink are drawn into the interior of the recording material, which worsens the color density of the image.
  • DE-OS 30 167 66 claims a recording material which is intended to ensure a high density and resolution of the printed image by applying a coating of a water-soluble polymer to a paper carrier which has a defined water absorption capacity due to an internal sizing.
  • a disadvantage of this recording material is the fact that the material has to be smoothed in a separate operation in order to achieve the desired color density after application of the ink-receiving layer, e.g. B. by using a gloss or super calender.
  • JP 58-193 185 two layers are applied to a support.
  • the top layer made of polyvinyl alcohol is said to ensure fast ink absorption.
  • the lower layer, which contains synthetic silica, is said to ensure a high color density.
  • the disadvantage of this is that several steps are required to produce this recording material, namely the separate application of two layers and the smoothing with the aid of a calender.
  • EP-A-445327 describes a recording material for the ink jet printing process in which the ink receiving layer contains a mixture of gelatin and rice starch.
  • the object of the present invention is to propose a recording material for the ink jet process which does not have the disadvantages mentioned above and which is distinguished in particular by a high color density and a high resolving power with at the same time quickly achievable wiping resistance of the ink droplets.
  • an ink receiving layer which contains a hydrophilic binder and an oxidized polyethylene is applied to a polyolefin-coated base paper, the oxidized polyethylene being present in the aqueous coating composition used for the ink receiving layer as a cationically emulsified oxidized polyethylene.
  • the hydrophilic binder is a protein-containing binder, in particular gelatin.
  • the oxidized polyethylene contained in the ink receiving layer is present in the coating composition used for this in a cationically emulsified form.
  • the oxidized polyethylene with compounds from the group of fatty amines, fatty amine acetates, quaternary ammonium compounds and the like. cationically emulsified.
  • the oxidized polyethylene is an oxidized polyethylene cationically emulsified with stearyl fatty amine acetate.
  • the amount of the cationically emulsified oxidized polyethylene in the aqueous coating composition is between 0.1 and 5% by weight, in particular between 1 and 4% by weight.
  • the amount of the binder in the ink-receiving layer is at least 50% by weight, preferably 70 to 99% by weight, based on the dry layer.
  • the ink-receiving layer can additionally contain white pigments, dyes, hardening agents, dispersing aids, wetting agents and the like. Contain auxiliaries.
  • the application amount of the ink-receiving layer is 0.5 to 10 g / m2, preferably 2 to 7 g / m2.
  • the coating composition for the ink-receiving layer can be applied to the carrier by all customary application and metering methods, such as e.g. Roller application, engraving or nipping processes as well as air brush or roller doctor metering.
  • the polyolefin used to coat the base paper is preferably low density polyethylene (LDPE) and / or high density polyethylene (HDPE). But also other polyolefins, such as. B. LLDPE or polypropylene can be used.
  • the application amount of the polyolefin coating, which may additionally contain pigments and other additives, is at least 5 g / m2.
  • the gloss of the recording material according to the invention does not require additional post-treatments, e.g. using a glossy calender.
  • the very good color density is achieved even without pigmentation of the ink receiving layer.
  • the print images also have good water resistance and abrasion resistance.
  • the front of a polyethylene-coated base paper according to Example 1 was coated with the following coating compositions: Components Composition,% by weight 2a 2 B Gelatin (220 Bloom) 20% in water 51.0 46.0 Oxidized 32% polyethylene stabilized in water with stearyl fatty amine acetate (Südranol 270, Süd Weg Emulsions-Chemie GmbH) 0.4 5.0 amphoteric silica 10.0 10.0 Wetting agent (Triton X100) 10% in water 0.5 0.5 Alcohol mixture IPA / BU / H2O 25: 25: 50 10.0 10.0 Citric acid 10% in water 0.3 0.3 Chromalun 10% in water 1.2 1.1 TAF / formaldehyde (1: 0.05) 2% in IPA / BU / H2O 1.2 1.1 Water, demineralized 25.4 26.0 Order quantity, g / m2 7 7
  • the ink-receiving layers according to V1 and V2 were applied from an aqueous medium in the following composition: Components Composition,% by weight V1 V2 Gelatin (220 Bloom) 20% in water 61.4 61.0 oxidized polyethylene 32% in water non-ionic emulsifier system (Südranol 340, Süd Weg Emulsions-Chemie GmbH) - 0.4 Wetting agent (Triton X100) 10% in water 0.5 0.5 Alcohol mixture IPA / BU / H2O 25: 25: 50 10.0 10.0 Citric acid 10% in water 0.3 0.3 Chromalun 10% in water 1.5 1.5 TAF / formaldehyde (1: 0.05) 2% in IPA / BU / H2O 1.5 1.5 Water, demineralized 24.8 24.8 Order quantity, g / m2 7 7
  • the recording material obtained according to the comparative examples was printed in a continuous ink jet process and then analyzed.
  • the results are summarized in Table 2.
  • the recording material was printed with the aid of an Excelerator 4/1120 inkjet printer from Stork X-cel, which works according to the Hertz inkjet printing principle, using the inks developed by Stork. Color density, abrasion resistance, water resistance and gloss were examined in the print images obtained.
  • the density measurements were carried out before and after a 24-hour exposure of the images using a xenon lamp.
  • the device used for this was an original reflection densitometer SOS-45.
  • the measurements were carried out in the color gradations F1 - F6 for the colors cyan, magenta, yellow and black, the values for F1 and F6 being given in the tables.
  • the smudge resistance was assessed according to the degree of so-called "knocking off” of the printing ink from the surface of the material. The test was carried out individually for all four primary colors. The designation “+” means that all colors immediately “strike away” from the leaf surface, ie penetrate into the layer interior. The designation “o” means that 3 primary colors immediately penetrate from the leaf surface into the layer interior and the fourth primary color only after a few seconds. "-” denotes a poor smudge resistance of the material, ie no or only weak penetration of almost all colors is observed.
  • the recording material sample was heated in water and rubbed with a finger at 5 ° C. intervals.
  • the temperature at which the white background of the recording material shows through was taken as a measure of the water resistance and abrasion resistance.
  • the gloss of the recording material was measured using a three-angle gloss meter according to Dr. Measured for a long time at a measuring angle of 60 ° C.
EP92114117A 1991-10-26 1992-08-19 Aufzeichnungsmaterial für das ink jet-Verfahren Expired - Lifetime EP0539678B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4135388A DE4135388A1 (de) 1991-10-26 1991-10-26 Aufzeichnungsmaterial fuer das ink jet-verfahren
DE4135388 1991-10-26

Publications (2)

Publication Number Publication Date
EP0539678A1 EP0539678A1 (de) 1993-05-05
EP0539678B1 true EP0539678B1 (de) 1996-03-06

Family

ID=6443502

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92114117A Expired - Lifetime EP0539678B1 (de) 1991-10-26 1992-08-19 Aufzeichnungsmaterial für das ink jet-Verfahren

Country Status (7)

Country Link
US (1) US5328748A (es)
EP (1) EP0539678B1 (es)
JP (1) JP3210097B2 (es)
AT (1) ATE134936T1 (es)
DE (2) DE4135388A1 (es)
DK (1) DK0539678T3 (es)
ES (1) ES2086031T3 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07179032A (ja) * 1993-10-27 1995-07-18 Eastman Kodak Co インキジェット記録媒体
EP0744302B1 (en) * 1995-05-26 2001-12-05 Toyo Boseki Kabushiki Kaisha Surface-treated plastic film and ink jet recording material
US6203153B1 (en) 1996-02-28 2001-03-20 Hewlett-Packard Company Method and apparatus for printing on gelatin coated media
US6270858B1 (en) 1996-11-15 2001-08-07 Fargo Electronics, Inc. Method of coating using an ink jet printable mixture
US6051306A (en) * 1996-11-15 2000-04-18 Fargo Electronics, Inc. Ink jet printable surface
US6153288A (en) * 1997-07-24 2000-11-28 Avery Dennison Corporation Ink-receptive compositions and coated products
JP4178493B2 (ja) * 1999-11-30 2008-11-12 北越製紙株式会社 インクジェット記録シート
US7037013B2 (en) * 2001-03-05 2006-05-02 Fargo Electronics, Inc. Ink-receptive card substrate
US6979141B2 (en) * 2001-03-05 2005-12-27 Fargo Electronics, Inc. Identification cards, protective coatings, films, and methods for forming the same
US6485609B1 (en) 2001-03-08 2002-11-26 Celanese International Corporation Ink jet printing paper incorporating amine functional poly(vinyl alcohol)
US6951683B2 (en) 2001-07-25 2005-10-04 Avery Dennison Corporation Synthetic paper skins, paper and labels containing the same and methods of making the same
US8956490B1 (en) 2007-06-25 2015-02-17 Assa Abloy Ab Identification card substrate surface protection using a laminated coating
JP6253243B2 (ja) * 2013-04-16 2017-12-27 キヤノン株式会社 記録装置および記録方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2234823C3 (de) * 1972-07-15 1984-06-20 Agfa-Gevaert Ag, 5090 Leverkusen Aufzeichnungsmaterial für Ink-Jet-Bilder
JPS55146786A (en) * 1979-05-02 1980-11-15 Fuji Photo Film Co Ltd Ink-jet recording sheet
DE3024205A1 (de) * 1980-06-27 1982-01-21 Felix Schoeller jr. GmbH & Co KG, 4500 Osnabrück Aufzeichnungspapier fuer tintenspritzaufzeichnunsverfahren
JPS58193185A (ja) * 1982-05-08 1983-11-10 Mitsubishi Paper Mills Ltd 記録用シ−ト
JPS60198285A (ja) * 1984-03-23 1985-10-07 Ricoh Co Ltd インクジエツト記録材
US5180624A (en) * 1987-09-21 1993-01-19 Jujo Paper Co., Ltd. Ink jet recording paper
JPH0643145B2 (ja) * 1988-03-07 1994-06-08 富士写真フイルム株式会社 インク記録用シート
DE3932419C1 (es) * 1989-09-28 1991-02-21 Felix Schoeller Jun. Gmbh & Co Kg, 4500 Osnabrueck, De
EP0445327B1 (de) * 1990-03-07 1994-07-06 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Aufzeichnungsmaterial für das Tintenstrahldruck-Verfahren

Also Published As

Publication number Publication date
EP0539678A1 (de) 1993-05-05
DK0539678T3 (da) 1996-07-01
US5328748A (en) 1994-07-12
DE59205573D1 (de) 1996-04-11
ATE134936T1 (de) 1996-03-15
JP3210097B2 (ja) 2001-09-17
ES2086031T3 (es) 1996-06-16
JPH05212952A (ja) 1993-08-24
DE4135388A1 (de) 1993-04-29

Similar Documents

Publication Publication Date Title
EP0445327B1 (de) Aufzeichnungsmaterial für das Tintenstrahldruck-Verfahren
EP0631880B1 (de) Aufzeichnungsblatt für Ink-Jet-Druckverfahren
DE19618607C2 (de) Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren
DE19955081C1 (de) Basispapier für ein Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
EP1048480B1 (de) Ink-Jet-Aufzeichnungspapier mit Pigmentschichten
DE4322178C2 (de) Aufzeichnungsmaterial für Ink-Jet-Druckverfahren
EP0539678B1 (de) Aufzeichnungsmaterial für das ink jet-Verfahren
EP0514633B1 (de) Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren
EP0812697A1 (de) Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
DE69825509T2 (de) Aufzeichnungsmedium und Aufzeichnungsverfahren unter Verwendung desselben
DE19535072C2 (de) Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
EP1226959B2 (de) Poröses Tintenstrahlaufzeichnungsmaterial
DE10222454B4 (de) Ink-Jet-Aufzeichnungsblatt mit verbesserter Ozonresistenz
DE19720833C1 (de) Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
DE60005115T2 (de) Tintenstrahldruckverfahren
DE112018002297T5 (de) Beschichtetes Druckpapier
DE112018002292T5 (de) Druckpapier
EP0501011A1 (de) Schichtträger für ein Empfangsmaterial für thermische Farbstoffübertragungsverfahren
DE19604693A1 (de) Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

17P Request for examination filed

Effective date: 19931023

17Q First examination report despatched

Effective date: 19950322

RBV Designated contracting states (corrected)

Designated state(s): AT BE CH DE DK ES FR GB IT LI LU NL PT SE

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB IT LI LU NL PT SE

REF Corresponds to:

Ref document number: 134936

Country of ref document: AT

Date of ref document: 19960315

Kind code of ref document: T

REF Corresponds to:

Ref document number: 59205573

Country of ref document: DE

Date of ref document: 19960411

ITF It: translation for a ep patent filed

Owner name: SOCIETA' ITALIANA BREVETTI S.P.A.

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2086031

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19960606

SC4A Pt: translation is available

Free format text: 960325 AVAILABILITY OF NATIONAL TRANSLATION

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20040723

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20040806

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20040809

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20040810

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20040818

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050819

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050820

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050820

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060220

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

EUG Se: european patent has lapsed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20060814

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20060815

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20060816

Year of fee payment: 15

Ref country code: DE

Payment date: 20060816

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20060817

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20060824

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20060831

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20060914

Year of fee payment: 15

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20050820

BERE Be: lapsed

Owner name: FELIX *SCHOELLER JR. PAPIERFABRIK G.M.B.H. & CO. K

Effective date: 20070831

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20070819

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070831

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080301

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070831

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20080301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070819

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20080430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070819

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070819