EP0535029A1 - Zustandsmeldevorrichtung zur meldung eines vorgegebenen temperaturzustands, dafür geeigneter temperatursensor und verfahren zu dessen herstellung. - Google Patents
Zustandsmeldevorrichtung zur meldung eines vorgegebenen temperaturzustands, dafür geeigneter temperatursensor und verfahren zu dessen herstellung.Info
- Publication number
- EP0535029A1 EP0535029A1 EP91910757A EP91910757A EP0535029A1 EP 0535029 A1 EP0535029 A1 EP 0535029A1 EP 91910757 A EP91910757 A EP 91910757A EP 91910757 A EP91910757 A EP 91910757A EP 0535029 A1 EP0535029 A1 EP 0535029A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- output
- sensors
- alarm
- status
- status reporting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Classifications
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B26/00—Alarm systems in which substations are interrogated in succession by a central station
Definitions
- the invention relates to a status reporting device of the type specified in the preamble of claim 1, a temperature sensor particularly suitable therefor according to the preamble of claim 16 and a method for its production according to the preamble of claim 18.
- the invention has the advantage that the sensors present in the individual case can be queried periodically and individually in succession and therefore only a single evaluation device is required.
- temperature sensors are proposed which enable the temperature of the surrounding air to be measured, but at the same time can be kept very small and yet be effectively protected against mechanical damage and are therefore particularly suitable for use in confined spaces.
- the method according to the invention creates a possibility of manufacturing temperature sensors of this type in such a way that the casting compound on the one hand does not become liquid even at temperatures to be measured of, for example, 300-900 ° C., but on the other hand does not become so hard that the decisive sensor part namely the thermistor bead, bursts as a result of internal tensions during manufacture or use and thus becomes unusable.
- the decisive sensor part namely the thermistor bead
- bursts as a result of internal tensions during manufacture or use and thus becomes unusable.
- condition reporting device in overheating or fire detection systems, such as in house installations, in the detection of tire overheating in trucks, in power plants or in shipping and automatic extinguishing systems in public and private buildings.
- the status reporting device can also be used as part of a control system. In connection with the electronics, this then results in further additional possible uses, such as, for example, in the field of air conditioning technology or heating control.
- FIG. 1 shows a temperature sensor according to the invention approximately on a scale of 1: 1 in an exploded front view;
- Fig. La the temperature sensor of Figure 1 in the assembled state and in a partially sectioned front view.
- 3 shows a sensor unit for the status reporting device
- FIG. 4 shows an evaluation device having a threshold switch and a test device connected in parallel for the status reporting device
- FIG. 6 shows a part of a display device for the test device according to FIG. 5;
- FIG. 7 shows a standardized plug-in card which can be adapted to different sensors for the status reporting device according to the invention.
- thermistor 1 shows a temperature sensor according to the invention with a thermistor 1 in the form of a pearl thermistor (eg M 812 from Siemens AG, D-8000 Kunststoff 80) there is a thermistor bead or a semiconductor bead 4 enclosed in a thin, short glass tube 2 and arranged at its tip 3, to which two connecting wires 5 are fastened, which lead out of the glass tube 2.
- a thermistor 1 in the form of a pearl thermistor (eg M 812 from Siemens AG, D-8000 Kunststoff 80)
- thermistor bead or a semiconductor bead 4 enclosed in a thin, short glass tube 2 and arranged at its tip 3, to which two connecting wires 5 are fastened, which lead out of the glass tube 2.
- a thermistor 1 available on the market usable for the purposes of the invention, it is combined with a preferably cylindrical connector housing 6, the one
- connection wires 5 are inserted into the hollow cylindrical ends of plugs 10 and through Crimping (crimping) firmly connected to the plugs 10 in order to avoid that any soldering mass or the like that is used can melt and run away during the subsequent casting of the end section 8.
- the plugs 10 are then inserted through bores which are formed in an insert (not shown) which fills the intermediate part 7 in such a way that the arrangement shown in FIG. 1 a results in which the free ends of the plugs 10 protrude into the hollow bottom 9.
- the connectors 10 are preferably snapped into the insert by means of elements acting in the manner of a snap connection.
- the rest of the glass tube 2 is preferably arranged such that it is arranged parallel and coaxially to the axis of the connector housing 6 and the thermistor bead 4 on that of the intermediate part 7 opposite end of the end section 8 is arranged.
- the hollow end section 8 is now filled with a potting compound 11 so that the entire glass tube 2, with the exception of its tip 3, is embedded in the potting compound 11 Potting therefore only protrudes the tip 3 with the semiconductor ball 4 from the connector housing 6 or the potting compound 11, which on the one hand results in a mechanically stable sensor and on the other hand creates a very sensitive and very quickly responding temperature sensor which detects the temperature of the measures the surrounding air and the faster the temperature changes, the smaller the area of the semiconductor bead 4 to be heated is.
- response times of the order of half a second can be achieved , which is particularly important for rapid fire detection and fighting important is also the advantage, that in such thermistors 1 by means of circuits, which are described below with reference to FIG. 4, in the range from 80 ° C. and 300 ° C. the desired triggering temperature to approximately ⁇ 1 ° C. can be set.
- a preferably cylindrical protective cap 12 can be screwed onto the end section of the plug housing 6, which is either on the outside End is open and / or provided with a plurality of openings so that the air, the temperature of which is to be monitored, can flow around the tip 3 and thus the semiconductor bead 4.
- the thermistor bead 4 is arranged at a preselected location within the protective cap 12 and the sealing compound 11 is filled into the protective cap to such a height h that in turn only the tip 4 with the semiconductor bead 4 from the sealing compound 11 protrudes After encapsulation, the protective cap 12 forms an inseparable unit with the plug housing 6
- the introduction of the sealing compound 11 into the end section 8 must be done with extreme caution. Otherwise the potting compound 11 will either be too soft with the result that it will be in the temperature range to be monitored, e.g. 80 ° C to 300 ° C flowable and thereby the mechanical stability of the sensor is impaired, or becomes too hard with the risk that the tip 3 of the glass tube 2 jumps off and the sensor becomes unusable.
- Casting compounds which have been found to be useful are those which are produced from thermosetting epoxy resins and have high thermal conductivity and a coefficient of thermal expansion comparable to that of copper.
- the end section 8 must, however, be filled as follows when using this casting resin:
- the sensor is first manufactured in the manner described.
- a potting compound is then produced by mixing the sealing compound and the hardener in the mixing ratio (weight ratio) 10: 1 to 10: 1.1.
- the casting compound is then filled into the end section 8, which is preferably preheated to approximately 80 ° C., and preheated to 80 ° C. in a heating oven.
- the subsequent curing takes place in three heating levels in the heating furnace, first for 16 hours at 80 ° C, then for 3 hours at 120 ° C and finally again for 3 hours at 180 ° C.
- the heating furnace is then reset to 80 ° C and switched off when this temperature is reached.
- the ready-to-use temperature sensor with cast-in thermistor can be removed from the furnace.
- the sensor can be made of different materials.
- the connector housing is preferably made of metal and the insert is made of an electrically non-conductive plastic with the required resistance at the temperatures that may occur.
- a potting compound 11 made of a non-conductive material it also provides the necessary insulation.
- the senor manufactured according to the method described above can be used anywhere for temperature measurement or temperature monitoring in a temperature range of approximately - 60 ° C to 900 ° C and can either function as a thermometer or thermostat.
- An excellent application is described below using a fire detection system with a range of e.g. describes seven identical temperature sensors attached to different danger zones.
- FIG. 2 shows the circuit of a power supply unit for operating the circuits shown in the following figures with a constant voltage V A of, for example, + 5 V ⁇ 1% in accordance with the usual IC technology.
- the input voltage can be selected between, for example, + 8 V and + 32 V, is applied to an input line 21 provided with a fuse Si x and, in the exemplary embodiment, is + 24 V.
- a tens diode ZD X BZT 03 / D39
- Two diodes D x and D 2 connected in lines 21 and 22 (eg 1 N 4007) serve as polarity protection.
- a line 24 connected to the input line 21 and provided with a fuse Si 2 leads to an alarm and / or safety device 20 shown in FIG. 5 and to a circuit breaker T t likewise shown in FIG. 5.
- the IC modules IQ to IQ and IQ belong to the evaluation device according to FIG. 4.
- FIG. 3 shows a transmitter unit 25 which, in the exemplary embodiment, contains seven thermistor temperature sensors Rs j to Rs, (for example M 812-100 k ⁇ 10%), which, at arbitrary locations of an aircraft, truck or the like, are to be monitored arranged, preferably designed according to FIG. 1 and in the A exemplary embodiment in the range from -55 ° C. to 350 ° C.
- the ohmic resistance of the sensors Rs j to Rsy decreases with increasing temperature.
- the sensors Rs t to Rs therefore consist of resistors, the one connections of which are connected via a line 26 to the output line 23 of the power pack (FIG. 2).
- the other connections are connected via resistors R 14 to R ⁇ (for example 56 ⁇ ) to outputs 27 to 33, which emit output signals whose sizes depend on the temperatures monitored by the sensors RSi to I ⁇ .
- a tens diode ZD 2 to ZD 8 (eg ZPD 6 V 2) is placed in order to measure the voltages at the outputs of the sensors Rs x to RS Limit ⁇ to 6.2 V for securing subsequent circuits.
- the transmitter unit 25 in which the transmitter unit 25 is only shown schematically, its outputs 27 to 33 are each connected to an input of an evaluation circuit which can emit an alarm signal on an output line 35. In the exemplary embodiment, this always appears when the output signal at any output 27 to 33 of the transmitter unit 25 exceeds a preselected critical variable in the positive or negative direction as desired
- the evaluation device contains a single threshold value switch IC 51 in the form of an IC module (for example LT 1017 IN8), the output (7) of which is connected to line 35.
- This IC 51 threshold switch has two adjustable resistors R «(for example 10 k) at its inverting input (6). and R ⁇ (eg 20 k), by means of which a positive voltage can be set as a threshold at the inverting input (6).
- the non-inverting input (5) is connected to the output (3) of an interrogation device IQ in the form of a line 36, to which a resistor R 5 (for example 1.62 k) connected to its other connection is connected further IC module (z_3. HEF 4051 BP) connected, which has seven inputs (1, 2, 5, 12 - 14) connected to an output 27 to 33 each and an input (4) connected to ground
- One with line 36 connected filter capacitor Q serves to avoid voltage peaks.
- Means are assigned to the interrogation device IQ, by means of which the inputs (1, 2, 5, 12-14) mentioned can be connected to the output (3) individually in succession and periodically.
- These means preferably consist of an oscillator in the form of a further IC module (for example HEF 4060 BP) which has three outputs (4, 5, 7) which are connected to three further inputs (9-11) of the interrogation device IQ which clock signals appear with three different clock frequencies.
- the oscillator IQ is provided with an external circuit (eg R 3 , Q) according to the data sheet.
- the resistance of the sensor Rs j and the resistors R 1 , R s form a voltage divider.
- the voltages and resistances are selected so that at normal temperatures a smaller voltage appears at the non-inverting input (5) than at the inverting input (6) of the threshold switch IC 51 , which is set to + 2 ⁇ V, for example.
- An output signal of 0 V is therefore emitted from the threshold switch IC S1 .
- the setting can be selected so that the threshold is exceeded at a critical temperature of 180 ° C or any other temperature.
- the alarm signal therefore appears periodically whenever one of the sensors R ⁇ ! until Rs is exposed to a temperature which is higher than the set threshold, and this alarm signal is retained until the next sensor is placed on the threshold switch IC S1 by means of the interrogation device IQ.
- line 35 of evaluation device IQ is connected to an input (4) of a monoflop IQ (eg HFF 4538 BP), the output (10) of which is connected via a series resistor R u (eg 10 k) and an output line 37
- the evaluation device is connected to the circuit breaker T x according to FIG. 5.
- the monoflop IQ is set by the appearance of each alarm signal at its output (10) for a preselected period of time, which is triggered by external sound at other inputs (1, 2, 14, 15) can be set according to the data sheet. This ensures that a sufficiently long signal for controlling the alarm and / or security device 20 is formed in the output line 37 even at a preferably very high polling frequency.
- the line 35 is grounded via a high resistance R ⁇ (eg 1 M). This ensures that the monoflop IQ is set to zero at the output (10) in the event of an extreme disturbance situation, eg in the event of a voltage drop due to a disconnected battery and does not inadvertently emit an output signal signaling an alarm state.
- a test device is connected in parallel to the interrogation device IQ, which tests the proper functioning of the interrogation device IQ, in particular the sensors Rs j to Rs ? checked and emits a further alarm signal if the function is not correct.
- This test device contains a further interrogation device IQ (for example HEF 4051 BP) corresponding to the interrogation device IQ and one connected to its output (3) further threshold switch IQ 2 (eg LT 1017 IN 8), which is preferably combined with the threshold switch IC 51 in a common housing, which has a further output (1) and two further inputs (2, 3), which the threshold switch IC ⁇ are assigned
- inputs (1, 2, 4, 5, 12, 13, 15) of the interrogation device IC 4 with the output lines 27 to 33 of the transmitter unit 25 and further inputs (9-11) with the outputs are one means corresponding to means IQ, preferably connected to the same oscillator IQ, so that inputs (1, 2, 4, 5, 12, 13, 15) are correspondingly connected to output 3.
- the output (3) of the interrogator IQ is connected to a line 38 leading to the non-inverting input (3) of the threshold switch I 5 , to which a comparatively large resistor R 5 (e.g. 46.4 k) and a filter capacitor Q are connected.
- a comparatively large resistor R 5 e.g. 46.4 k
- the voltage normally at the non-inverting input (2) of the threshold switch IQ 2 is set to a larger value than the voltage at the inverting input by means of resistors R 3 , R, and the threshold switch I 2 is more functional Sensor unit 25 and interrogation device IQ emits an output signal of, for example, + 5 V, regardless of whether the monitored temperature corresponds to the preselected room temperature or the temperature preselected with the threshold value of the threshold value switch IC S1
- the alarm signal maintained on line 37 switches through the circuit breaker T x , for example a field effect transistor, to whose input (3) the 24 V voltage of the power pack (FIG. 2) is applied, which is caused by the switching process a control line 40 arrives leads to the alarm and / or security device 20
- the alarm and / or security device 20 contains, for example, a warning lamp 1 ⁇ connected via a diode D 5 (for example IN 4007), which lights up when the alarm signal appears as long as the monoflop IQ is set at the output (10).
- a warning lamp 1 ⁇ connected via a diode D 5 (for example IN 4007), which lights up when the alarm signal appears as long as the monoflop IQ is set at the output (10).
- a third diode D g may be via a further corresponding diode D 6, a Wider ⁇ was R ⁇ (zB220 k) and "(eg Also in 4007) may be connected to a warning lamp I ⁇ to the control line 40th
- the holding circuit which contains a switch T 2 designed as a field effect transistor, the control input (2) of which is connected to the output of the diode D 6 via a resistor R jj (eg 3 k) and to the ground via a Zener diode ZD 9 and whose voltage input ( 3) is connected to the line 24 coming from the power pack via a hand switch 41.
- the output (5) of this switch T 2 is on the one hand on the warning lamp L ⁇ and on the other hand is returned to the control input (2) via the resistors R 21 and R ⁇ l ⁇ therefore lights up continuously after triggering the switch T 2 , which has the advantage, for example, that a driver who has currently left his vehicle equipped with the condition reporting device described above has se When he returns, he can determine whether an alarm signal has now appeared or not. By briefly actuating the hand switch 41 to open the holding circuit, the alarm lamp L j can be extinguished again.
- the alarm and / or security device 20 can have, for example, at least two fire extinguishing bottles HR j and H ⁇ as security elements, which are provided with trigger capsules customary in fire protection systems.
- the voltage input of the fire extinguisher bottle HR X is, for example, via a diode D 3 (e.g.
- two indicator lamps I 1 and L 4 which are connected between the voltage inputs of the fire extinguisher bottles HR j and HR 2 and a second fixed contact of the hand switch 41, serve to check the function of the alarm and / or security device 20 are, and two diodes D 4 and D 7 , which are connected between the second fixed contact of the hand switch 41 and the connection points between the diodes D 5 and D g and the associated alarm lamps L j and L j .
- the hand switch 41 is switched over from its normal position shown in FIG. 4 to the second fixed contact, the aluminum lamps I 1, 1 1 are therefore connected to the 24 V line 24 and thereby tested. In this position of the hand switch 41, the indicator lamps L are also intended to be tested j and L 4 light up.
- the diodes D 3 to D 8 are each polarized so that the currents only flow in the directions shown in FIG. 5 and no undesirable effects on uninvolved circuit parts can occur.
- the display device 39 is constructed, for example, as follows:
- Fig. 4 it contains on the one hand a ground switch IQ (e.g. CD 4099 BF), the
- Input (3) is connected to the output (1) of the threshold switch IQ 2 , while three further inputs (5 - 7) of the ground switch IQ are connected to the outputs (4, 5, 7) of a means which periodically and individually in succession Outputs (1, 9, 11 - 15) of the ground switch IQ activated.
- the outputs (1, 9, 11 - 15) of the ground switch IQ are each connected to an input of a keyboard 43 which is only schematically indicated in FIG. 4.
- Each of these inputs leads over a push button switch TS 1 to TS 7 to the cathode of a control device 44 with its anode connected to the operating voltage, for example a light-emitting diode. If any of the push button switches TS 1 to TS 7 is pressed, the cathode of the control device 44 is connected to the associated output of the ground switch IQ via this push button switch.
- the control device 44 would therefore always have to respond in the cycle determined by the polling frequency of the oscillator IQ, for example. light up when the output of the ground switch IQ assigned to the actuated key switch is activated. On the other hand, if the control device 44 does not react, then there is a defect, because the associated output of the ground switch IQ is not periodically connected to ground.
- the alarm and / or security device 20 and the test device with the display device 39 assigned to them result in the advantage that a functional check can be carried out continuously while the entire system is in operation.
- FIG. 7 shows a particularly preferred embodiment of the status reporting device according to the invention.
- This consists of a standardized plug-in card or circuit board, which is soldered to an IC socket and on which all IC components, cabling and circuits are permanently mounted with the exception of those parts that should be individually changeable.
- the IC components IQ to IQ, IC 51 and IC ⁇ , IQ and IQ are combined to form a single IC component IQ, which inputs (1, 4, 5, 33, 34, 39, 51, 52) Connection of the resistors R 3 and R s to R 10 and the capacitors Q to Q, further inputs (10, 20, 35 - 37) for applying the operating voltages or ground, and further inputs (13 - 19) for applying the transmitter unit 25 and outputs (54-62) for connecting the keyboard 43 or the like.
- the IC module IQ can be used for a multiple number of different status messages or monitors and can be combined with any encoder units and keyboards or other display devices. Depending on the sensors and display devices used in the individual case, it is only necessary to adapt some external switching elements shown in FIG. 7 accordingly.
- the IC module IQ shown in FIG. 7 is, moreover, preferably used for the Pour the sealant described in temperature sensors and then cure for 16 hours at 80 ° C and 3 hours at 120 ° C. The rest of the procedure can then be carried out as with the curing of the temperature sensor. Due to the universal construction of such a module, it is possible to solve a multitude of monitoring tasks with almost identical means and by means of an optimized device which takes up little space.
- the invention is not restricted to the exemplary embodiments described, which can be modified in many ways. This applies in particular to the temperature sensors used, in the place of which other temperature sensors and also sensors for completely different purposes, for example cold conductors, strain gauges, infrared and other light sensors, voltmeters or the like, can be used. It is only necessary to convert the measurement signals obtained in detail into signals usable for the electrical circuits described and to adapt the thresholds set on the threshold switches IC 51 and IQ 2 accordingly. Furthermore, it goes without saying that other alarm and / or security devices and other display devices can be provided, the design of which largely depends on the type of the monitored states. In addition to visual displays, acoustic or other displays can of course also be provided.
- sensors of different types or sensors for monitoring different types of states can be provided, although it is of course also possible to apply sensors of different types or sensors for monitoring different types of states to the described circuit, in particular the IC module IQ according to FIG , only their output signals would have to be adapted accordingly.
- the invention is not limited to the use of the individually specified IC modules, which were only mentioned for example.
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- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Fire-Detection Mechanisms (AREA)
- Fire Alarms (AREA)
- Alarm Systems (AREA)
- Measuring Temperature Or Quantity Of Heat (AREA)
- Selective Calling Equipment (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4019542 | 1990-06-19 | ||
DE4019542 | 1990-06-19 | ||
PCT/DE1991/000507 WO1991020065A2 (de) | 1990-06-19 | 1991-06-19 | Zustandsmeldevorrichtung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0535029A1 true EP0535029A1 (de) | 1993-04-07 |
EP0535029B1 EP0535029B1 (de) | 1994-09-14 |
Family
ID=6408676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91910757A Expired - Lifetime EP0535029B1 (de) | 1990-06-19 | 1991-06-19 | Zustandsmeldevorrichtung zur meldung eines vorgegebenen temperaturzustands, dafür geeigneter temperatursensor und verfahren zu dessen herstellung |
Country Status (10)
Country | Link |
---|---|
US (1) | US5463375A (de) |
EP (1) | EP0535029B1 (de) |
JP (1) | JPH06500873A (de) |
AT (1) | ATE111621T1 (de) |
AU (1) | AU8084291A (de) |
CA (1) | CA2085872A1 (de) |
DE (2) | DE59102963D1 (de) |
DK (1) | DK0535029T3 (de) |
ES (1) | ES2064107T3 (de) |
WO (1) | WO1991020065A2 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE9306174U1 (de) * | 1993-04-23 | 1994-05-19 | Kolter, Heinrich, 50374 Erftstadt | Meßgerät zur Bestimmung der Intensität der im Sonnenspektrum enthaltenen ultravioletten Strahlung |
US6210036B1 (en) * | 1996-09-06 | 2001-04-03 | Gerald P. Eberle | Connector thermal sensor |
GB2320681B (en) * | 1996-11-12 | 2003-05-28 | Don Henry Dawson | Fire extinguishing system |
US6083587A (en) | 1997-09-22 | 2000-07-04 | Baxter International Inc. | Multilayered polymer structure for medical products |
JP4121104B2 (ja) * | 1999-07-16 | 2008-07-23 | 松下電器産業株式会社 | 二次電池 |
US6894254B2 (en) | 2000-04-20 | 2005-05-17 | Mks Instruments, Inc. | Heater control system with combination modular and daisy chained connectivity and optimum allocation of functions between base unit and local controller modules |
JP3739084B2 (ja) * | 2001-09-28 | 2006-01-25 | ホーチキ株式会社 | 火災熱感知器 |
US6971790B2 (en) * | 2002-10-11 | 2005-12-06 | Welch Allyn, Inc. | Thermometry probe calibration method |
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- 1991-06-19 JP JP3510521A patent/JPH06500873A/ja active Pending
- 1991-06-19 US US07/962,789 patent/US5463375A/en not_active Expired - Fee Related
- 1991-06-19 CA CA002085872A patent/CA2085872A1/en not_active Abandoned
- 1991-06-19 AU AU80842/91A patent/AU8084291A/en not_active Abandoned
- 1991-06-19 DK DK91910757.3T patent/DK0535029T3/da active
- 1991-06-19 AT AT91910757T patent/ATE111621T1/de not_active IP Right Cessation
- 1991-06-19 DE DE59102963T patent/DE59102963D1/de not_active Expired - Fee Related
- 1991-06-19 EP EP91910757A patent/EP0535029B1/de not_active Expired - Lifetime
- 1991-06-19 DE DE4120126A patent/DE4120126A1/de not_active Withdrawn
- 1991-06-19 WO PCT/DE1991/000507 patent/WO1991020065A2/de active IP Right Grant
- 1991-06-19 ES ES91910757T patent/ES2064107T3/es not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
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See references of WO9120065A3 * |
Also Published As
Publication number | Publication date |
---|---|
DE59102963D1 (de) | 1994-10-20 |
EP0535029B1 (de) | 1994-09-14 |
US5463375A (en) | 1995-10-31 |
CA2085872A1 (en) | 1991-12-20 |
DE4120126A1 (de) | 1992-01-02 |
WO1991020065A3 (de) | 1992-03-05 |
DK0535029T3 (da) | 1995-01-09 |
WO1991020065A2 (de) | 1991-12-26 |
AU8084291A (en) | 1992-01-07 |
JPH06500873A (ja) | 1994-01-27 |
ATE111621T1 (de) | 1994-09-15 |
ES2064107T3 (es) | 1995-01-16 |
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