EP0471629B1 - Abnehmbare Kappe und Behälter versehen mit einem Garantieverschluss - Google Patents

Abnehmbare Kappe und Behälter versehen mit einem Garantieverschluss Download PDF

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Publication number
EP0471629B1
EP0471629B1 EP91420292A EP91420292A EP0471629B1 EP 0471629 B1 EP0471629 B1 EP 0471629B1 EP 91420292 A EP91420292 A EP 91420292A EP 91420292 A EP91420292 A EP 91420292A EP 0471629 B1 EP0471629 B1 EP 0471629B1
Authority
EP
European Patent Office
Prior art keywords
cover
neck
base
snapping
capsule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91420292A
Other languages
English (en)
French (fr)
Other versions
EP0471629A1 (de
Inventor
Bernard Schneider
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albea Tubes France SAS
Original Assignee
Cebal SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cebal SAS filed Critical Cebal SAS
Publication of EP0471629A1 publication Critical patent/EP0471629A1/de
Application granted granted Critical
Publication of EP0471629B1 publication Critical patent/EP0471629B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/18Arrangements of closures with protective outer cap-like covers or of two or more co-operating closures
    • B65D51/20Caps, lids, or covers co-operating with an inner closure arranged to be opened by piercing, cutting, or tearing
    • B65D51/22Caps, lids, or covers co-operating with an inner closure arranged to be opened by piercing, cutting, or tearing having means for piercing, cutting, or tearing the inner closure
    • B65D51/221Caps, lids, or covers co-operating with an inner closure arranged to be opened by piercing, cutting, or tearing having means for piercing, cutting, or tearing the inner closure a major part of the inner closure being left inside the container after the opening
    • B65D51/222Caps, lids, or covers co-operating with an inner closure arranged to be opened by piercing, cutting, or tearing having means for piercing, cutting, or tearing the inner closure a major part of the inner closure being left inside the container after the opening the piercing or cutting means being integral with, or fixedly attached to, the outer closure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0006Upper closure
    • B65D2251/0025Upper closure of the 47-type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0068Lower closure
    • B65D2251/0071Lower closure of the 17-type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S215/00Bottles and jars
    • Y10S215/901Tamper-resistant structure

Definitions

  • the invention relates to an assembly of an opening capsule and a tamper-evident container according to the preamble of claim 1, comprising an opening capsule or strain capsule comprising a base or strain attached to the neck of a container and an opening part closing the orifice of this neck, the opening of this part being for example by rotation or by pivoting relative to said base, and the orifice of the neck being initially provided with a tamper-evident seal.
  • Plastic opening capsules are known, the base or strain of which is fixed to the plastic neck of a tube typically by snap-fastening, this base comprising a sealing means from the inside of said neck, for example a penetrating crown. with forcing inside this neck.
  • the Applicant has sought to develop an opening capsule adapted to such a container having a tamper-evident seal.
  • EP-A- 0 192 011 describes a set of closures and of a container with a plastic neck surmounted by a tamper-evident seal, said closure comprising means of axial fitting by force of said seal.
  • said closure is an opening capsule comprising a base or strain to be fixed to said neck and an opening part or cover which can open and close relative to said base when the latter is fixed to the neck, in that said cover is provided with said means of axial nesting by force of said cover and in that said base and said neck comprise on the one hand means complementary latching, the start of their latching occurring only after the start of fitting at maximum effort of said fitting means in said cover, and on the other hand, below said latching means complementary screwing, these latching and screwing means allowing the rupture of the cover and then its insertion into said neck.
  • Said means of axial fitting by force of the cover have a tightening function both anti-rotation and producing the retention of the cover in the blockage.
  • They are preferably either longitudinal fins internal to the capsule inserted between longitudinal reliefs of the cover, or again, as known from the document cited, longitudinal radial fins for notching the cover.
  • the screwing means of the neck immediately follows the screwing means of the base of the capsule in the just snapped-in position, and the base in this position is blocked or strongly braked with regard to possible rotation in the sense of unscrewing and / or the anti-unscrewing means intervene from the latched position, preventing this rotation.
  • the position just snapped in is the delivery position of the non-violated encapsulated container, which can be identified by a witness, for example a colored area of the shoulder of the container visible at this stage between this shoulder and the lower end of the skirt. outside of the base of the capsule.
  • a witness for example a colored area of the shoulder of the container visible at this stage between this shoulder and the lower end of the skirt. outside of the base of the capsule.
  • the capsule can only rotate in the direction of screwing, that is to say the usual direction of closure, and its opening part rotates the cover by its notched fins and tears the web of connection of this cover by shearing: quickly, typically after 1/10 of rotation with or without screwing.
  • the lower end of the lid enters the orifice of the neck and comes to stopper it, the opening of the container then being done by pivoting of the opening part of the capsule and the lid that remains prisoner.
  • These means can be fins and ratchet teeth carried respectively by the inner surface of the outer skirt of said capsule and by a lateral surface of the container, typically of its shoulder. These means oppose when unscrewing said base, leaving only an angular movement of less than 10 °.
  • Figure 1 shows an assembly according to the invention in the snapped-on position, in axial section.
  • Figure 2 shows the same assembly in the screwed position, also in axial section.
  • FIG. 3 represents the anti-unscrewing means of said assembly, according to a half-section seen from above marked AA in FIG. 2.
  • Figure 4 shows the same assembly after screwing, the capsule being opened, also in axial section.
  • the neck 2 whose end orifice 7 has a diameter of 7.5 mm is surmounted by a tight seal 8 connected to the inside of the neck by a narrow tearable portion 9 of thickness 0.2 mm.
  • the cover successively comprises an externally curved annular skirt 10 with an outside diameter greater than 0.2 mm than the diameter of the orifice 7, then an annular cup 11 with an outside diameter 10.5 mm serving as a sealed stop for the future insertion of the cover 8 into the orifice 7, and also serving as a safety stop for mounting the cover in the cover 5, then finally a cylindrical portion 12 of height 5 mm and of 8.8 mm diameter with a slight entry chamfer 13 0.4 mm high at its upper end.
  • the neck 2 carries 4 mm below its orifice 7, at the lower end of an inclined outer surface 14 of increasing diameter, a snap-in relief 15 in the form of a rib 15 with an outside diameter of 13 mm and a horizontal annular underside 16 surmounting a recessed cylindrical portion 17 with a diameter of 12 mm and a height of 3 mm.
  • This recessed portion 17 is followed by a slightly stronger portion carrying an external thread 18 with a pitch of 1.5 mm and a total height of 5 mm.
  • This thread 18 ends on the shoulder 19 of the tube 1, the surface of which lateral 20 carries on the one hand a colored area 21 and on the other hand teeth 22 said ratchet, here inclined in the direction of screwing ( Figure 3) but can also be radial as has been shown by another test.
  • the opening part or cover 5 of the capsule 3 comprises a central tube 23 open at its two ends, its inner surface 24 of diameter 8.9 mm carrying radial fins 25 with a tapered end at an angle of 15 °, these fins 25 having a lower end 26 which gradually widens.
  • the slight diametral clearance of the surface 24 between fins relative to the cover 8 will facilitate the insertion of this cover 8 into the tube 23 despite its small notches or incision by these fins 25.
  • the base 4 of the capsule 3 comprises a central cylindrical portion 27 having an internal diameter 270 of 13 mm and 2.5 mm high with at its base a snap relief 28 having a horizontal flange 29 with an internal diameter 12.35 mm then a frustoconical engagement surface 30 with a height of 1 mm and a diameter of 13.2 mm at its base 300.
  • the central portion 27 and the relief 28 are extended by a tube 31 carrying in its upper part, just below the relief 28, an internal thread 32 of height 2.3 mm which is screwed onto the thread 18 of the neck.
  • the outer skirt 33 of the base 4 with an internal diameter of 26 mm, carries on its inner surface inclined fins 34 (FIGS. 1 and 3) anti-unscrewing, cooperating with the teeth 22 of the neck 2 from the snap-fastening of the capsule 4 and 5.
  • the rotation of the capsule 3 in the direction of screwing without screwing or else with the start of screwing makes it possible to leave this waiting position.
  • the cover 8 is rotated by the cover 5 and the insertion of its radial fins 25, its tearable connection 9 ( Figure 1) with the neck 2 being quickly chiselled. After approximately 30 ° of rotation, this connection 9 is broken, the lower end of the skirt 10 of the cover sinking into the orifice 7 during screwing (stage not shown), the connection 9 having to facilitate this depression has an outside diameter slightly smaller than the diameter of this orifice 7.
  • the cover is released from the orifice 7 by the pivoting of the cover 5 and accompanies it in its opening.
  • the closing of the cover 5 is accompanied by a sealed filling of the orifice 7 by the cover 8 trapped in this cover 5.
  • Tamper evident containers with an opening capsule in the hygiene, pharmaceutical, cosmetology, food and cleaning products industries.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Packages (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Lock And Its Accessories (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)
  • Devices For Use In Laboratory Experiments (AREA)
  • Cartons (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)

Claims (12)

  1. Vorrichtung eines Verschlusses (3) mit einem Behälter (1) mit Hals (2) aus Kunststoff, auf dem eine Garantiekappe (8) sitzt, wobei der genannte Verschluß (3) Mittel (25) zum axialen Hineindrücken der genannten Kappe (8) aufweist, dadurch gekennzeichnet, daß der genannte Verschluß (3) eine Verschlußkapsel (3) mit einer am genannten Hals zu befestigenden Basis oder Unterteil (4) und einem zu öffnenden Teil (5) oder Deckel ist, der zu der genannten Basis geöffnet und geschlossen werden kann, wenn diese an dem Hals befestigt ist, daß der genannte Deckel (5) mit den genannten Mitteln (25) zum axialen Hineindrücken der genannten Garantiekappe (8) versehen ist und daß die genannte Basis (4) und der genannte Hals (2) einerseits komplementäre Einschnappmittel (28 und 15) aufweisen, wobei dieses Einschnappen erst beginnt, wenn das Hineindrücken mit maximalem Druck der Mittel (25) zum Hineindrücken in die genannte Garantiekappe (8) bereits begonnen hat, und andererseits unterhalb der genannten Einschnappmittel (28 und 15) komplementäre Verschraubmittel (32 und 18) aufweisen, wobei die genannten Einschnapp- und Verschraubmittel (28 und 15, 32 und 18) den Bruch der Garantiekappe (8) und sodann ihr Hineindrücken in den genannten Hals (2) ermöglichen.
  2. Vorrichtung nach Anspruch 1, bei der die genannte Kapsel (3) aus härterem Kunststoff ist als der genannte Hals (2) und die genannte Kappe (8).
  3. Vorrichtung nach Anspruch 1, bei der das Einschnappmittel (28) der genannten Basis (4) eine kegelstumpfförmige Eingriffsfläche (30) um das Einschnappmittel (15) des genannten Halses (2) herum aufweist, wodurch ein stetiges Steigern der Einschnappkraft ermöglicht wird, und bei der das Einschnappmittel (28) und Verschraubmittel (32) der genannten Basis (4) innen auf einem axialen Innenkranz (31) der genannten Basis (4) sitzen.
  4. Vorrichtung nach Anspruch 3, bei der das genannte Einschnappmittel (15) des Halses (2) eine Rippe (15) ist, die sich in einen zylindrischen Innenabschnitt (27) des genannten Kranzes (31) der genannten Basis (4) drückt, wobei der Abschnitt (27) sich in Schließstellung der genannten Kapsel (3) nach Bruch der genannten Kappe (8) über dem genannten Einschnappmittel (28) dieser Basis (4) befindet.
  5. Vorrichtung nach einem der Ansprüche 1 bis 4, bei der das Verschraubmittel (18) des Halses (2) direkt auf das Verschraubmittel (32) der Basis (4) in eingeschnappter Position folgt.
  6. Vorrichtung nach Anspruch 1, bei der die genannte Basis (4) einen Außenmantel (33) hat, in dessen Inneren Abschraub-Blockiermittel (34) sitzen, die nach Einschnappen mit komplementären Mitteln (22) zusammenwirken, die an dem Absatz (19) des genannten Behälters (1) sitzen.
  7. Vorrichtung nach Anspruch 5, bei der die genannten Abschraub-Blockiermittel (34 und 22) aus Innenrippen (34) des genannten Mantels (33) bzw. aus Sperrzähnen (22) an der Seitenfläche (20) des genannten Absatzes (19) bestehen.
  8. Vorrichtung nach Anspruch 7, bei der die genannten Innenrippen (34) und die genannten Sperrzähne (22) zusammenwirken, sobald die eingeschnappte Position erreicht ist, und dadurch eine Drehung in Einschraubrichtung verhindern.
  9. Vorrichtung nach einem der Ansprüche 6 oder 7, bei der sich das untere Ende des genannten Außenmantels (33) über dem genannten Absatz (19) des genannten Behälters (1) befindet, wenn dieser in Einschnapposition vor dem Einschrauben ist, wobei dieser Mantel (33) dann ein auf dem genannten Absatz (19) sitzendes Kontrollzeichen (20) dafür sichtbar macht, daß die genannte Kapsel (3) nicht hineingedrückt ist.
  10. Vorrichtung nach Anspruch 1, bei der die genannte Garantiekappe (8) über ihrem zertrennbaren Bereich (9) einen nach außen gewölbten ringförmigen Abschnitt (10) mit einem Außendurchmesser, der um 0,1 bis 0,4 mm größer ist als der Durchmesser der Endöffnung (7) des genannten Halses (2), und über dem genannten ringförmigen Abschnitt (10) einen ringförmigen Rand (11) aufweist, der sowohl als Anschlag beim Hineindrücken der Kapsel (3, 5) in die Kappe (8) als auch als Auflage für diese Kappe (8) am Ende des Halses (2) bei erneutem Verschließen dient.
  11. Vorrichtung nach Anspruch 1, bei der die genannten Mittel (25) zum Eindrücken der genannten Garantiekappe (8) Schneidrippen (25) sind, die in einem offenen, axialen Kanal (24) der genannten Verschlußkapsel (3 und 5) sitzen und abgeschrägte Kanten mit einer Dicke von 0,1 bis 0,3 mm haben, die einen kreisförmigen, zylindrischen Abschnitt (12) der genannten Kappe (8) einschneiden.
  12. Vorrichtung nach Anspruch 1, wobei die Kappe (8), wenn diese gebrochen und von der Kapsel (3) eingeschlossen ist, bei jedem Schließen der Kapsel (32) als Mittel zum dichten Verschließen des Behälters (1) dient.
EP91420292A 1990-08-14 1991-08-08 Abnehmbare Kappe und Behälter versehen mit einem Garantieverschluss Expired - Lifetime EP0471629B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9010605 1990-08-14
FR9010605A FR2665886B1 (fr) 1990-08-14 1990-08-14 Ensemble d'une capsule a ouverture et d'un recipient a opercule inviolable.

Publications (2)

Publication Number Publication Date
EP0471629A1 EP0471629A1 (de) 1992-02-19
EP0471629B1 true EP0471629B1 (de) 1993-12-29

Family

ID=9399819

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91420292A Expired - Lifetime EP0471629B1 (de) 1990-08-14 1991-08-08 Abnehmbare Kappe und Behälter versehen mit einem Garantieverschluss

Country Status (14)

Country Link
US (1) US5203838A (de)
EP (1) EP0471629B1 (de)
JP (1) JPH07102864B2 (de)
AT (1) ATE99255T1 (de)
CA (1) CA2049105C (de)
DE (1) DE69100886T2 (de)
DK (1) DK0471629T3 (de)
ES (1) ES2047999T3 (de)
FI (1) FI913830A (de)
FR (1) FR2665886B1 (de)
IE (1) IE69573B1 (de)
IS (1) IS3744A7 (de)
NO (1) NO913153L (de)
PT (1) PT98671B (de)

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US5687865A (en) * 1991-10-08 1997-11-18 Portola Packaging, Inc. Spill-reduction cap for fluid container
US5547091A (en) * 1991-11-27 1996-08-20 Colgate-Palmolive Company Dispensing container snap hinge closure
IT1255757B (it) * 1992-09-03 1995-11-15 Guala Spa Dispensatore a schiacciamento elastico per prodotti viscosi, particolarmente di tipo alimentare
JP2535498B2 (ja) * 1993-08-25 1996-09-18 株式会社ラッキーコーポレーション ヘアカ―ラ―及びその製造方法
EP0700645A4 (de) * 1994-03-31 1999-10-27 Lucky Corp Co Ltd Haarwickler
GB2300628B (en) * 1995-05-09 1998-10-07 Paul Stephen Nightingale Container and cap
US5690242A (en) * 1996-03-25 1997-11-25 Winfield Industries Sharps disposal container cap securement arrangement
CA2181828C (en) * 1996-07-22 2002-01-15 Richard Lamoureux One-piece cap for liquid dispenser container
GB9702056D0 (en) * 1997-01-31 1997-03-19 Wallace Cameron & Company Limi Container
US5992659A (en) * 1997-09-25 1999-11-30 Pano Cap (Canada) Limited Tamper proof flip top cap
US5971232A (en) * 1998-06-03 1999-10-26 Aptargroup, Inc. Dispensing structure which has a pressure-openable valve retained with folding elements
US6408904B1 (en) 1998-10-20 2002-06-25 Abel Unlimited, Inc. Hygienic bottle cap
US6123122A (en) * 1998-10-20 2000-09-26 Abel Unlimited, Inc. Hygenic bottle cap and liquid dispensing system
US6006960A (en) * 1998-10-28 1999-12-28 Aptargroup, Inc. Dispensing structure which has a lid with a pressure-openable valve
US6095354A (en) * 1999-03-30 2000-08-01 Kerr Group, Inc. Child resistant closure and container
DE60007718T2 (de) * 1999-06-24 2004-12-09 Tuboplast Hispania, S.A. Behälter mit originalitätsverschluss
ITMO20020204A1 (it) * 2002-07-16 2004-01-16 Lameplast Spa Recipiente per la confezione di prodotti fluidi o pastosi, particolarmente cosmetici, medicinali e simili
GB2396151B (en) * 2002-11-04 2006-03-01 Portola Packaging Ltd Integrally moulded closure system
ITMO20030283A1 (it) * 2003-10-21 2005-04-22 Lameplast Spa Flacone per prodotti fluidi, particolarmente farmaceutici,
US20080281280A1 (en) * 2007-04-05 2008-11-13 Bradley Fixtures Corporation Eyewash system
JP5801596B2 (ja) * 2011-04-20 2015-10-28 東罐興業株式会社 キャップ及び蓋付容器
US8522994B2 (en) * 2011-05-09 2013-09-03 Weiler Engineering, Inc. Hermetically sealed container
ES2803755T3 (es) * 2017-07-25 2021-01-29 Incap Int Ltd Tapa de cierre para un contenedor
DE102018001102A1 (de) 2018-02-09 2019-08-14 Holopack Verpackungstechnik Gmbh Behälter
JP7278889B2 (ja) * 2018-12-28 2023-05-22 株式会社吉野工業所 容器用キャップ
JP7266951B2 (ja) * 2019-06-28 2023-05-01 株式会社吉野工業所 ヒンジキャップ
US11059633B2 (en) 2019-10-31 2021-07-13 Cheer Pack North America Flip-top closure for container
JP7301482B2 (ja) * 2019-11-28 2023-07-03 株式会社吉野工業所 容器用キャップ
JP7391478B2 (ja) * 2020-03-31 2023-12-05 株式会社吉野工業所 容器用キャップ、及び容器用キャップの製造方法
JP7433114B2 (ja) * 2020-03-31 2024-02-19 株式会社吉野工業所 ヒンジキャップ
JP7446161B2 (ja) * 2020-05-29 2024-03-08 株式会社吉野工業所 注出キャップ

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US4234103A (en) * 1978-03-31 1980-11-18 Baxter Travenol Laboratories, Inc. Diagnostic reagent dispensing bottle
US4402415A (en) * 1980-10-17 1983-09-06 U. G. Closures & Plastics Limited Integrally sealed container with cap
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FR2574372B1 (fr) * 1984-12-11 1987-09-18 Cebal Recipient a goulot en matiere plastique surmonte d'un opercule d'inviolabilite lisse et muni d'un capuchon et procede d'ouverture
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Also Published As

Publication number Publication date
CA2049105A1 (fr) 1992-02-15
JPH07102864B2 (ja) 1995-11-08
CA2049105C (fr) 1996-09-17
NO913153L (no) 1992-02-17
JPH0516961A (ja) 1993-01-26
US5203838A (en) 1993-04-20
EP0471629A1 (de) 1992-02-19
FI913830A (fi) 1992-02-15
IE912862A1 (en) 1992-02-26
IS3744A7 (is) 1992-02-15
DE69100886T2 (de) 1994-04-28
IE69573B1 (en) 1996-10-02
FI913830A0 (fi) 1991-08-13
NO913153D0 (no) 1991-08-13
PT98671B (pt) 1999-01-29
FR2665886A1 (fr) 1992-02-21
ATE99255T1 (de) 1994-01-15
FR2665886B1 (fr) 1992-10-16
DK0471629T3 (da) 1994-01-24
DE69100886D1 (de) 1994-02-10
ES2047999T3 (es) 1994-03-01
PT98671A (pt) 1994-01-31

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