EP0456795B1 - Procede de fabrication de non-tisses hydrophiles comportant des fibres naturelles, en particulier du coton ecru, non-tisses obtenus - Google Patents
Procede de fabrication de non-tisses hydrophiles comportant des fibres naturelles, en particulier du coton ecru, non-tisses obtenus Download PDFInfo
- Publication number
- EP0456795B1 EP0456795B1 EP91900039A EP91900039A EP0456795B1 EP 0456795 B1 EP0456795 B1 EP 0456795B1 EP 91900039 A EP91900039 A EP 91900039A EP 91900039 A EP91900039 A EP 91900039A EP 0456795 B1 EP0456795 B1 EP 0456795B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sheet
- fibres
- fibers
- hydrophilic
- woven fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H18/00—Needling machines
- D04H18/04—Needling machines with water jets
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
Definitions
- the invention relates to the manufacture by hydraulic bonding of hydrophilic nonwoven fabrics based on natural cellulosic fibers, such as unbleached cotton, linen, hemp or ramie, not chemically treated, to the products obtained according to the process, and hydrophilic nonwovens containing natural cellulose fibers not chemically treated.
- the purpose of the hydraulic tying technique is to provide a certain mechanical resistance to a sheet of fibers initially not linked to each other, independently of any addition of binder.
- the binding process consists in subjecting these fibers to the action of very fine jets of liquid - for example water - under pressure.
- these jets are arranged along ramps spaced from each other, and are directed towards the sheet of fibers which is supported by a permeable fabric traveling at a determined speed. Passing under these ramps, the fibers are entrained by the jets of fluid which pass through the sheet. These will bounce off the canvas and cause the fibers to become entangled by interaction. The connections thus created ensure the cohesion of the sheet.
- nonwoven fabrics from fibers of various origins: synthetic, natural, long or short, alone or in mixture, which one chooses according to the use for which they are intended.
- the products obtained generally have a drape, flexibility and softness of touch superior to those of nonwovens produced according to other techniques.
- European patent application EP 132028 describes a method of manufacturing nonwoven fabrics from unbleached cotton, consisting in subjecting a veil of unbleached unbleached cotton fibers to entanglement by water jets oscillating at low pressure and then finishing the treatment, before drying, by a scouring and bleaching step according to any known technique, for example by soaking in a autoclave at 120 ° C in a solution based on caustic soda and hydrogen peroxide.
- This last phase of the process is, according to this patent, made necessary, in particular, by the use of unbleached cotton. Indeed, it is raw cotton which has not undergone any other mechanical cleaning, possibly, and the fibers of which comprise a primary layer consisting of waxes and fats, which it is necessary to eliminate in order to make them hydrophilic. Thus the purpose of scouring is, in particular, to ensure the saponification of fats.
- the invention is based on the discovery that it is possible, by applying a consolidation treatment by water jets, to confer on a sheet of natural fibers such as unbleached cotton, the property of absorbing liquids, water in particular, without any chemical treatment.
- This threshold depends in particular on the nature and the origin of the fibers (new cotton or recovery fibers: cleaning, combing jacket, etc.) of the structure of the sheet (superimposed card sails, sheets obtained by pneumatic way ) the grammage and the thickness of the web.
- this threshold of energy dissipated by the injector was between 0.4 and 1.1 kwh per kilogram of treated fibers, for sheets whose grammage is between 25 and 200 g / m2 and preferably between 30 and 100 g / m2.
- the water jets have an unexpected and additional mechanical pickling effect on the fibers. Surprisingly, from a certain amount of energy absorbed the effect is sufficient to cause at least partial detachment of the hydrophobic sheath with possibly the release of fibrils, making the hydrophilic parts of the fibers accessible to liquids, water in particular. In addition, this pickling action does not cause any deterioration in the mechanical properties of the resulting nonwoven, since there is a continuous improvement in the breaking strength of the product obtained. It should be noted that this treatment does not necessarily lead to the elimination of the materials constituting the hydrophobic sheath. These can be retained between the fibers, or remain hooked by zones. There is no significant change in the chemical functions of the fibers after treatment with a water jet as shown by the infrared peaks, although the nonwoven has become hydrophilic.
- the solution of the invention thus has the advantage of allowing, in a single step and from unbleached cotton fibers, the production of products bound by water jets having a marked absorbent character, and not requiring chemical treatment. complex aimed at imparting a hydrophilic character to the fibers such as scouring.
- the method is applicable to all lignocellulosic fibers having a hydrophobic character in the natural state due to the presence on the surface of waxy or fatty mineral materials, which are usually reduced by chemical treatment.
- unbleached cotton is the material targeted in the first place by the process, but other fibers such as linen, hemp or ramie for example are not excluded.
- Another advantage is to allow the recovery of recovered fibers such as spinning waste for example; thus the method allows the treatment of fibers made up of combing residues which are relatively short fibers, of length between 5 and 25 mm.
- thermoplastic fibers - based on polyethylene, polypropylene or other - and, after elimination of water, passing the veil in an oven heated to a sufficient temperature to melt them at least partially.
- the softened material constitutes attachment zones forming bonds between the cotton fibers after cooling to room temperature.
- the subject of the invention is also a hydrophilic nonwoven comprising mainly natural lignocellulosic fibers entangled according to a hydraulic bonding process characterized in that said fibers have not undergone any scouring treatment intended to make them hydrophilic.
- a nonwoven according to the invention comprises at least 70% of unbleached cotton and is free from any wetting agent, surfactant or other product. Despite this, it has an absorption capacity for aqueous liquids such that its immersion time, measured according to the method reported below, is less than 30 seconds. In addition, its absorption coefficient is greater than 9 g / g of nonwoven.
- the nonwoven comprises up to 30% of synthetic fibers.
- a nonwoven is produced, the wettability of which is further improved by associating a sheet of cellulose wadding with the web and subjecting the assembly to a hydraulic binding treatment.
- the cellulose wadding is an absorbent crepe paper used for washing or wiping.
- the tablecloth is made of 100% unbleached cotton.
- synthetic fibers such as thermobonding fibers can be incorporated therein which will consolidate the nonwoven obtained after an additional suitable heat treatment.
- the hydraulic tying technique allows the treatment of sheets whose grammage is between 25 g / m2 and 200 g / m2. Below 25 g / m2, the energy released by the fluid jets would cause significant displacement of the fibers and their encrustation between the meshes of the support fabric. This would cause the canvas to hang and the unwanted fluff to form on the final product. Above 200 g / m2 the thickness does not allow a deep treatment of the sheet.
- the quantity of paper cellulose fibers that is thus incorporated depends on the total grammage and the destination of the product according to the required mechanical strength.
- the paper fibers can thus constitute from 10% to 50% of the total weight without however representing less than 10 g / m2. It is possible to superimpose several sheets of cellulose wadding to achieve the desired grammage.
- the product obtained according to this process has considerably improved wettability compared to nonwovens without the addition of cellulosic fibers.
- the immersion time thus goes from around 30 seconds to less than 10 seconds.
- FIG. 1 represents a hydraulic binding installation of the type developed by the company PERFOJET. It comprises a first hydraulic tying unit (10) with an endless fabric (12) stretched between horizontal rollers (14) so as to form a loop. The fabric is driven in the direction of the arrow at a predetermined constant running speed. It comprises an upper portion at the level of which a first battery of injector ramps (16) has been placed, supplied with liquid under pressure and oriented vertically in the direction of the fabric. The ramps are arranged perpendicular to the direction of travel of the fabric, and include injection orifices distributed over the entire width of the web. The number of ramps is variable and chosen according to the desired pressure step. Preferably it will be between 3 and 10.
- suction boxes (18), communicating with a vacuum source have the function of recovering the water, coming from the injectors, which has passed through the fabric.
- the installation comprises a second hydraulic tying unit (20) with an endless cloth (22) for the treatment of the second face. It comprises a second battery of injector banks (26) supplied with pressurized liquid by pipes not shown. The ramps are associated with suction boxes (28) for the recovery of the liquid after its entanglement work.
- the sheet of fibers is deposited on the fabric (12) from a station for forming the sheet, not shown.
- the cotton Before being sent to this tablecloth forming station, the cotton is first cleaned and freed of most of its impurities such as seeds, leaf debris and dust, on conventional textile material, for example opener, cleaner, etc ...
- the fiber flakes are then sent on topping material: carding machine, pneumatic coating machine, etc ...
- the number of card sails to be superimposed depends on the weight per m2 desired. For example, for a grammage of 65 g / m2, 4 card sails are superimposed.
- pneumatic means of the RANDO type can also be used, in particular for the heavier weights, up to 200 g / m2.
- the sheet thus formed is deposited on the fabric (12), moving at a predetermined speed, from where it is driven towards the battery of injector banks (16) for treatment on a first face.
- an injector whose pressure is adjusted to a low level (30 bars), without disturbing the arrangement of the fibers.
- the other injectors are adjusted to pressures varying from 40 to 250 bars, to ensure the entanglement of the fibers.
- the web having undergone a first consolidation on the first face, can be driven towards the second tying unit where it will be taken up by a fabric so as to present its second face to the battery of injectors (26).
- the second face is treated identically to the first.
- the nonwoven then passes over a last vacuum slit which allows most of the water to be removed. It is then dried, for example on a through air dryer or on drying drums, not shown. If necessary, it is subjected to a thermobonding treatment if provision has been made to incorporate thermobonding fibers in the web.
- a sheet of unbleached cotton fibers of the combing type was treated by this method.
- the average length of the fibers was 12 to 14 mm with a micron index 4.
- Each hydraulic tying unit consisted of 4 injectors whose pressures were 30, 95, 125 and 125 bars respectively. At a machine speed of 30 meters per minute, the energy released successively by the injectors and measured at level of pumps, per kilogram of nonwoven, is reported in the table below:
- FIG. 2 shows the evolution of the breaking strength of the web as a function of the energy communicated to the web by the successive injectors. It can be seen that the resistance, both in the forward and in the cross direction, increases as a function of the energy received by the sheet to reach, with regard to the cross direction resistance, a plateau after 0.9 kwh per kg of nonwoven.
- FIG. 3 shows for the example considered, the evolution of the immersion time representative of the wetting ability, as a function of this same amount of energy. It is noted that the time taken by the sample to sink into the water becomes measurable from a minimum energy threshold which is 0.7 kwh per kg of nonwoven for the example considered.
- the table below shows the immersion time values relating to the nonwoven of the example on the one hand and, for a nonwoven of the same grammage obtained by mechanical needling from the same unbleached cotton card webs on the other hand .
- Immersion times greater than 300 seconds mean that after this time, the nonwoven still floats on water and does not get wet.
- This measure of the immersion time is used in the pharmacopoeia as a measure of the wettability of cotton wool.
- the method is as follows: - using a cylindrical basket, previously dried, consisting of copper wires with a diameter of about 0.4 mm. This basket is 8.0 cm high, 5.0 cm in diameter and 1.5 to 2.0 cm wide. Its mass is 2.7 ⁇ 0.3 g.
- the absorption coefficient is determined from the previous test.
- the basket is removed from the water, it is left to drain for 30 s then it is placed in a tared container (m3) and the whole is weighed (m4).
- the photos taken with a scanning electron microscope show the pickling action of the jets on the primary layer of the fibers.
- the micrographs 4 A and B show that the fibers before treatment are smooth and intact while the micrographs 4 C and D taken after treatment reveal the presence of fibrils attached to the fibers which have not been otherwise deteriorated.
- FIG. 5 There is shown in Figure 5 a slightly modified installation for making a nonwoven according to another embodiment of the invention.
- the elements corresponding to those of FIG. 1 bear the same reference increased by 100.
- the installation comprises a first hydraulic tying unit (110) with an endless fabric (112) stretched between horizontal rollers (114) so as to form a loop. It comprises an upper portion at the level of which a first battery of injector banks (116) supplied with liquid under pressure has been placed.
- the installation comprises a second hydraulic tying unit (120) with an endless cloth (122), for the treatment of the second face. It comprises a second battery of injector banks (126) supplied with pressurized liquid by pipes not shown. The ramps are associated with suction boxes (128) for recovering the liquid after its entanglement work.
- the fiber sheet (101) is deposited on the fabric (112) from a sheet forming station, not shown, from where it is driven towards the battery of injector banks (116 ) for treatment on a first side.
- a sheet forming station not shown
- injector banks 116
- pre-wetting of the web it is possible, for example, to use an injector whose pressure is adjusted to a low level, without disturbing the arrangement of the fibers.
- the other injectors are adjusted to pressures varying from 40 to 250 bars, to ensure the entanglement of the fibers.
- the sheet, having undergone a first consolidation on the first face is turned over so as to present its other face upwards as shown in the figure.
- the second unit (120) receives a sheet of cellulose wadding (103) which is applied to its upper face by a pressing cylinder (123).
- the cellulose wadding sheet (103) is conventionally fed from a feed roller rotatably mounted about a horizontal axis.
- the assembly (101), (103) - wadding on the top - is driven towards the second battery of injector banks (126) whose jets of fluid which they project ensure both the binding of the fibers of the sheet (101), continue their pickling, and the attachment of the paper fibers (103) in the sheet (101).
- the latter acts as a filter and prevents the short fibers from being entrained on the underlying fabric (122).
- the nonwoven then passes over a last vacuum slit which allows most of the water to be removed. It is then dried, for example on a through air dryer or on drying drums, not shown. If necessary, it is subjected to a thermobonding treatment if provision has been made to incorporate thermobonding fibers in the web.
- a nonwoven was produced according to the method described above from a sheet of unbleached cotton fibers of the combing type.
- the average fiber length was 12-14 mm.
- Each hydraulic tying unit was composed of 4 injectors whose pressures were respectively at 60, 110, 130, 70 bars. At the running speed of 30 meters per minute, the energy released successively by the injectors and measured at the pumps per kilogram of material treated is reported in the table below:
- the overall energy released by the injectors is therefore 0.99 Kwh per kg of nonwoven complex.
- the energy released on the cotton veil alone was 0.91 kWh per kg of cotton.
- the energy released on the whole cotton wadding plus cotton was 0.49 Kwh per kg of nonwoven complex.
- the product has a very low immersion time, of the order of 4 to 6 seconds, to be compared with an immersion time of 30 seconds for products without short, hydrophilic lignocellulosic fibers, which are the fibers. paper mills.
- the immersion time was measured using the same basket method as in Example 1. The same is true for the absorption coefficient which in the present case is normally lower than in the case of the nonwoven 100 % cotton. In fact, the coefficient of cellulose wadding is itself lower, of the order of 5 to 6 g / g.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Compounds Of Unknown Constitution (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8915892A FR2655361B1 (fr) | 1989-12-01 | 1989-12-01 | Procede de fabrication de nontisses hydrophiles comportant des fibres naturelles, en particulier du coton ecru, nontisses obtenus. |
FR8915892 | 1989-12-01 | ||
FR909006838A FR2662711B2 (fr) | 1989-12-01 | 1990-06-01 | Procede de fabrication de nontisse. |
FR9006838 | 1990-06-01 | ||
PCT/FR1990/000861 WO1991008333A1 (fr) | 1989-12-01 | 1990-11-28 | Procede de fabrication de non-tisses hydrophiles comportant des fibres naturelles, en particulier du coton ecru, non-tisses obtenus |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0456795A1 EP0456795A1 (fr) | 1991-11-21 |
EP0456795B1 true EP0456795B1 (fr) | 1994-07-06 |
Family
ID=26227704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91900039A Expired - Lifetime EP0456795B1 (fr) | 1989-12-01 | 1990-11-28 | Procede de fabrication de non-tisses hydrophiles comportant des fibres naturelles, en particulier du coton ecru, non-tisses obtenus |
Country Status (12)
Country | Link |
---|---|
US (1) | US5253397A (es) |
EP (1) | EP0456795B1 (es) |
JP (1) | JP2566084B2 (es) |
AT (1) | ATE108226T1 (es) |
CA (1) | CA2046651A1 (es) |
DE (1) | DE69010490T2 (es) |
ES (1) | ES2057849T3 (es) |
FI (1) | FI110125B (es) |
FR (1) | FR2662711B2 (es) |
IE (1) | IE64858B1 (es) |
TR (1) | TR24980A (es) |
WO (1) | WO1991008333A1 (es) |
Cited By (2)
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EP1688522B2 (en) † | 2005-02-06 | 2012-03-14 | Winner Industries (Shenzhen) Co., Ltd. | Method for producing spunlace non-woven cloth, method for producing spunlace non-woven cloth with X-Ray detectable element, spunlace non-woven cloth with X-Ray detectable element |
CN103938368A (zh) * | 2014-05-07 | 2014-07-23 | 东华大学 | 一种具有单向导水功能的水刺非织造材料及其制备方法和应用 |
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FR2680670B1 (fr) * | 1991-09-02 | 1995-07-13 | Elysees Balzac Financiere | Combine assechant. |
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SE503606C2 (sv) * | 1994-10-24 | 1996-07-15 | Moelnlycke Ab | Nonwovenmaterial innehållande en blandning av massafibrer och långa hydrofila växtfibrer samt förfarande för framställning av nonwovenmaterialet |
US5766746A (en) * | 1994-11-07 | 1998-06-16 | Lenzing Aktiengesellschaft | Flame retardant non-woven textile article |
AT401656B (de) * | 1994-11-07 | 1996-11-25 | Chemiefaser Lenzing Ag | Flammfestes nicht gewebtes textiles gebilde |
FR2730248B1 (fr) * | 1995-02-03 | 1997-03-21 | Kaysersberg Sa | Procede de traitement d'une nappe de fibres cellulosiques |
JP3735784B2 (ja) * | 1995-08-16 | 2006-01-18 | ユニチカ株式会社 | 綿製不織布の製造方法、及び高圧液体流処理用油剤 |
DE19627256A1 (de) * | 1996-07-08 | 1998-01-15 | Fleissner Maschf Gmbh Co | Verfahren und Vorrichtung zum hydromechanischen Verschlingen der Fasern einer Faserbahn |
EP0947011B1 (en) * | 1996-09-20 | 2001-12-12 | Johns Manville International, Inc. | Resilient mat; a method of making the resilient mat and a battery including the resilient mat |
DE19654056C2 (de) | 1996-12-23 | 2000-05-11 | Pelz & Co Kg W | Saugfähiges Produkt für Ausscheidungen des menschlichen Körpers |
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FR2781819B1 (fr) * | 1998-08-03 | 2000-09-22 | Vetrotex France Sa | Procede de fabrication de mats de fils continus |
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DE20106096U1 (de) * | 2001-04-03 | 2001-06-21 | Vliestec AG, 39112 Magdeburg | Laminat als Wandbelag bzw. Schattierungselement |
CZ20033134A3 (cs) * | 2003-11-18 | 2005-07-13 | Rieter Cz A. S. | Způsob výroby spřadatelných rostlinných vláken ze surových vícebuněčných rostlinných vláken a výrobky z nich |
MX2008006155A (es) | 2008-05-09 | 2009-11-09 | Grupo P I Mabe Sa De C V | Articulo absorbente desechable, amigable con el medio ambiente. |
CN101775701B (zh) * | 2009-12-30 | 2011-11-16 | 稳健实业(深圳)有限公司 | 单向导湿的全棉水刺无纺布、制品及其制造方法 |
EP2366821A1 (de) * | 2010-03-19 | 2011-09-21 | Carl Freudenberg KG | Vliesstoff aus fibrillierten Naturfasern |
RU2596105C2 (ru) | 2012-05-03 | 2016-08-27 | Ска Хайджин Продактс Аб | Способ получения гидроспутанного нетканого материала |
DE102015112955A1 (de) * | 2015-04-13 | 2016-10-13 | TRüTZSCHLER GMBH & CO. KG | Anlage und Verfahren zur Verbindung bzw. Verfestigung einer Bahn von Faserstoff mit einem Vlies |
DE202021001414U1 (de) * | 2021-04-19 | 2021-05-26 | Sandler Ag | Deckblatt |
CN114717747A (zh) * | 2022-05-07 | 2022-07-08 | 江苏恒合新材料科技有限公司 | 一种复合水刺无纺布的制作工艺 |
Family Cites Families (10)
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US3620903A (en) * | 1962-07-06 | 1971-11-16 | Du Pont | Lightweight nonpatterned nonwoven fabric |
US3493462A (en) * | 1962-07-06 | 1970-02-03 | Du Pont | Nonpatterned,nonwoven fabric |
US3494821A (en) * | 1967-01-06 | 1970-02-10 | Du Pont | Patterned nonwoven fabric of hydraulically entangled textile fibers and reinforcing fibers |
US3616175A (en) * | 1969-06-16 | 1971-10-26 | Du Pont | Chamoislike nonwoven fabric |
US4024612A (en) * | 1976-04-02 | 1977-05-24 | E. I. Du Pont De Nemours And Company | Process for making an apertured nonwoven fabric |
AU2790084A (en) * | 1983-05-11 | 1984-11-15 | Chicopee | Pattern printed fabrics |
JPH0784696B2 (ja) * | 1983-05-20 | 1995-09-13 | ジヨンソン・アンド・ジヨンソン | 不織布製造方法 |
US4647490A (en) * | 1983-05-20 | 1987-03-03 | Johnson & Johnson | Cotton patterned fabric |
US4775579A (en) * | 1987-11-05 | 1988-10-04 | James River Corporation Of Virginia | Hydroentangled elastic and nonelastic filaments |
US4879170A (en) * | 1988-03-18 | 1989-11-07 | Kimberly-Clark Corporation | Nonwoven fibrous hydraulically entangled elastic coform material and method of formation thereof |
-
1990
- 1990-06-01 FR FR909006838A patent/FR2662711B2/fr not_active Expired - Lifetime
- 1990-11-28 US US07/730,828 patent/US5253397A/en not_active Expired - Lifetime
- 1990-11-28 AT AT91900039T patent/ATE108226T1/de not_active IP Right Cessation
- 1990-11-28 CA CA002046651A patent/CA2046651A1/fr not_active Abandoned
- 1990-11-28 WO PCT/FR1990/000861 patent/WO1991008333A1/fr active IP Right Grant
- 1990-11-28 JP JP3500672A patent/JP2566084B2/ja not_active Expired - Lifetime
- 1990-11-28 EP EP91900039A patent/EP0456795B1/fr not_active Expired - Lifetime
- 1990-11-28 DE DE69010490T patent/DE69010490T2/de not_active Expired - Fee Related
- 1990-11-28 ES ES91900039T patent/ES2057849T3/es not_active Expired - Lifetime
- 1990-11-29 IE IE431190A patent/IE64858B1/en not_active IP Right Cessation
- 1990-12-03 TR TR90/1090A patent/TR24980A/xx unknown
-
1991
- 1991-07-26 FI FI913598A patent/FI110125B/fi not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1688522B2 (en) † | 2005-02-06 | 2012-03-14 | Winner Industries (Shenzhen) Co., Ltd. | Method for producing spunlace non-woven cloth, method for producing spunlace non-woven cloth with X-Ray detectable element, spunlace non-woven cloth with X-Ray detectable element |
CN103938368A (zh) * | 2014-05-07 | 2014-07-23 | 东华大学 | 一种具有单向导水功能的水刺非织造材料及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CA2046651A1 (fr) | 1991-06-02 |
FI110125B (fi) | 2002-11-29 |
FR2662711B2 (fr) | 1992-08-14 |
WO1991008333A1 (fr) | 1991-06-13 |
FI913598A0 (fi) | 1991-07-26 |
JP2566084B2 (ja) | 1996-12-25 |
TR24980A (tr) | 1992-09-01 |
DE69010490T2 (de) | 1994-10-27 |
ES2057849T3 (es) | 1994-10-16 |
JPH04503231A (ja) | 1992-06-11 |
US5253397A (en) | 1993-10-19 |
IE64858B1 (en) | 1995-09-06 |
DE69010490D1 (de) | 1994-08-11 |
EP0456795A1 (fr) | 1991-11-21 |
ATE108226T1 (de) | 1994-07-15 |
FR2662711A2 (fr) | 1991-12-06 |
IE904311A1 (en) | 1991-06-05 |
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