EP0456795B1 - Method for fabricating hydrophylic non woven material comprising natural fibers, particularly ecru cotton, non woven material obtained - Google Patents

Abstract

PCT No. PCT/FR90/00861 Sec. 371 Date Jul. 26, 1991 Sec. 102(e) Date Jul. 26, 1991 PCT Filed Nov. 28, 1990 PCT Pub. No. WO91/08333 PCT Pub. Date Jun. 13, 1991.The invention concerns a method for making a non-woven from unbleached cotton or other natural ligno-cellulose fibers comprising a surface layer of substances rendering the fiber hydrophobic and comprising the following stages: formation of a sheet of unbound fibers on a water-permeable cloth, tangling the sheet fibers by means of a plurality of water jets issuing from arrays of injectors located transversely to the direction of advance of the support, the method being characterized in that the total energy imparted to the sheet by the set of jets is at least equal to a minimum threshold corresponding to the value at which said sheet becomes hydrophilic. The invention also concerns a hydrophilic non-woven made by hydraulic binding from unbleached cotton or other natural, ligno-cellulose fibers such as flax, hemp or ramie and free of chemical treatment.

Description

The invention relates to the manufacture by hydraulic bonding of hydrophilic nonwoven fabrics based on natural cellulosic fibers, such as unbleached cotton, linen, hemp or ramie, not chemically treated, to the products obtained according to the process, and hydrophilic nonwovens containing natural cellulose fibers not chemically treated.

The purpose of the hydraulic tying technique is to provide a certain mechanical resistance to a sheet of fibers initially not linked to each other, independently of any addition of binder. The binding process consists in subjecting these fibers to the action of very fine jets of liquid - for example water - under pressure. Usually, these jets are arranged along ramps spaced from each other, and are directed towards the sheet of fibers which is supported by a permeable fabric traveling at a determined speed. Passing under these ramps, the fibers are entrained by the jets of fluid which pass through the sheet. These will bounce off the canvas and cause the fibers to become entangled by interaction. The connections thus created ensure the cohesion of the sheet.

By this process, it is possible to obtain nonwoven fabrics from fibers of various origins: synthetic, natural, long or short, alone or in mixture, which one chooses according to the use for which they are intended. The products obtained generally have a drape, flexibility and softness of touch superior to those of nonwovens produced according to other techniques.

European patent application EP 132028, in particular, describes a method of manufacturing nonwoven fabrics from unbleached cotton, consisting in subjecting a veil of unbleached unbleached cotton fibers to entanglement by water jets oscillating at low pressure and then finishing the treatment, before drying, by a scouring and bleaching step according to any known technique, for example by soaking in a autoclave at 120 ° C in a solution based on caustic soda and hydrogen peroxide.

This last phase of the process is, according to this patent, made necessary, in particular, by the use of unbleached cotton. Indeed, it is raw cotton which has not undergone any other mechanical cleaning, possibly, and the fibers of which comprise a primary layer consisting of waxes and fats, which it is necessary to eliminate in order to make them hydrophilic. Thus the purpose of scouring is, in particular, to ensure the saponification of fats.

The invention is based on the discovery that it is possible, by applying a consolidation treatment by water jets, to confer on a sheet of natural fibers such as unbleached cotton, the property of absorbing liquids, water in particular, without any chemical treatment.

• formation par tout procédé convenable d'une nappe de fibres, non liées, sur une toile support perméable à l'eau ;
• enchevêtrement des fibres de la nappe au moyen d'une pluralité de jets d'eau issus de rampes d'injecteurs, disposées transversalement par rapport au sens de déplacement du support. Il est caractérisé en ce que l'énergie totale communiquée à la nappe par l'ensemble des jets est au moins égale à un seuil minimum correspondant à la valeur à laquelle ladite nappe devient hydrophile.

The process according to the invention for manufacturing a nonwoven fabric from unbleached cotton fibers, or other natural lignocellulosic fibers comprising on the surface a layer of material rendering the fiber hydrophobic, comprises the following steps:

• formation by any suitable process of a sheet of unbound fibers on a support fabric permeable to water;
• entanglement of the fibers of the sheet by means of a plurality of water jets coming from injector ramps, arranged transversely with respect to the direction of movement of the support. It is characterized in that the total energy communicated to the sheet by all of the jets is at least equal to a minimum threshold corresponding to the value at which said sheet becomes hydrophilic.

This threshold depends in particular on the nature and the origin of the fibers (new cotton or recovery fibers: cleaning, combing jacket, etc.) of the structure of the sheet (superimposed card sails, sheets obtained by pneumatic way ) the grammage and the thickness of the web.

It has in fact been found, surprisingly, that from a certain threshold of kinetic energy communicated by the water jets to the fibers, in order to ensure their entanglement, an action occurs breaking their initial hydrophobic character.

It has been found, for example, that for an unbleached cotton of the combing type, of micronaire 3 to 5, or of the new cotton type, of micronaire 3 to 8, this threshold of energy dissipated by the injector was between 0.4 and 1.1 kwh per kilogram of treated fibers, for sheets whose grammage is between 25 and 200 g / m² and preferably between 30 and 100 g / m².

So, for example, when we assess the wettability of an unbleached cotton veil by measuring the time it takes to sink into water after having deposited it on the surface, it is not measurable for a veil of untreated fibers, that is to say not bound by a jet of water, because the sheet floats on the surface. On the other hand, it becomes so when the same veil has undergone the treatment of the invention, that is to say that it has absorbed the minimum energy required.

Without wishing to be limited to an interpretation, it appears that the water jets have an unexpected and additional mechanical pickling effect on the fibers. Surprisingly, from a certain amount of energy absorbed the effect is sufficient to cause at least partial detachment of the hydrophobic sheath with possibly the release of fibrils, making the hydrophilic parts of the fibers accessible to liquids, water in particular. In addition, this pickling action does not cause any deterioration in the mechanical properties of the resulting nonwoven, since there is a continuous improvement in the breaking strength of the product obtained. It should be noted that this treatment does not necessarily lead to the elimination of the materials constituting the hydrophobic sheath. These can be retained between the fibers, or remain hooked by zones. There is no significant change in the chemical functions of the fibers after treatment with a water jet as shown by the infrared peaks, although the nonwoven has become hydrophilic.

The solution of the invention thus has the advantage of allowing, in a single step and from unbleached cotton fibers, the production of products bound by water jets having a marked absorbent character, and not requiring chemical treatment. complex aimed at imparting a hydrophilic character to the fibers such as scouring.

The method is applicable to all lignocellulosic fibers having a hydrophobic character in the natural state due to the presence on the surface of waxy or fatty mineral materials, which are usually reduced by chemical treatment. Among the raw materials, unbleached cotton is the material targeted in the first place by the process, but other fibers such as linen, hemp or ramie for example are not excluded.

Another advantage is to allow the recovery of recovered fibers such as spinning waste for example; thus the method allows the treatment of fibers made up of combing residues which are relatively short fibers, of length between 5 and 25 mm.

• de l'essuyage industriel ou domestique : chiffons, torchons, torchons à vaisselle
• de la toilette : gants, serviettes
• de la lingerie de table : nappes, serviettes
• de la literie : draps de lit, taies d'oreiller , housses de traversin, etc...
• du vêtement de protection.

The products resulting from the process of the invention find multiple applications, for example in the fields:

• industrial or household wiping: rags, tea towels, dish towels
• of the toilet: gloves, towels
• table linen: tablecloths, napkins
• bedding: bed sheets, pillow cases, bolster covers, etc ...
• protective clothing.

Although in general the product is sufficiently resistant to be handled, it is possible to continue the treatment, beyond the minimum threshold required for hydrophilicity, until the improvement of the properties of mechanical resistance to rupture reaches a plateau. However, the hydrophilic properties are not increased in the same proportion.

In accordance with another object of the invention, it is also possible to incorporate into the web a certain amount of synthetic fibers, in particular binders or hot-melt, which after an appropriate treatment - thermal and / or mechanical if necessary - increase the resistance mechanics of the nonwoven veil, especially in the wet state.

One can incorporate for example up to 30% of thermoplastic fibers - based on polyethylene, polypropylene or other - and, after elimination of water, passing the veil in an oven heated to a sufficient temperature to melt them at least partially. The softened material constitutes attachment zones forming bonds between the cotton fibers after cooling to room temperature.

The subject of the invention is also a hydrophilic nonwoven comprising mainly natural lignocellulosic fibers entangled according to a hydraulic bonding process characterized in that said fibers have not undergone any scouring treatment intended to make them hydrophilic.

In particular, a nonwoven according to the invention comprises at least 70% of unbleached cotton and is free from any wetting agent, surfactant or other product. Despite this, it has an absorption capacity for aqueous liquids such that its immersion time, measured according to the method reported below, is less than 30 seconds. In addition, its absorption coefficient is greater than 9 g / g of nonwoven.

Finally according to a particular embodiment, the nonwoven comprises up to 30% of synthetic fibers.

In accordance with another object of the invention, a nonwoven is produced, the wettability of which is further improved by associating a sheet of cellulose wadding with the web and subjecting the assembly to a hydraulic binding treatment.

It is recalled that the cellulose wadding is an absorbent crepe paper used for washing or wiping.

• former une nappe non liée, comportant au moins 70 % de fibres de coton écru, ou d'autres fibres lignocellulosiques naturelles comportant en surface une gaine de matières hydrophobes, et la déposer sur une toile perméable;
• soumettre une première face de ladite nappe à un traitement d'enchevêtrement par jets d'eau ; l'énergie libérée étant suffisante pour rendre la nappe hydrophile ;
• déposer sur la seconde face opposée à la première au moins une feuille d'ouate de cellulose ;
• soumettre la seconde face ainsi revêtue à un traitement d'enchevêtrement par jets d'eau.

The process consists of:

• forming an unbound web, comprising at least 70% of unbleached cotton fibers, or other natural lignocellulosic fibers comprising on the surface a sheath of hydrophobic materials, and depositing it on a permeable fabric;
• subjecting a first face of said sheet to a tangle treatment by water jets; the energy released being sufficient to make the sheet hydrophilic;
• depositing on the second side opposite the first at least one sheet of cellulose wadding;
• subject the second side thus coated to a tangle treatment by water jets.

Preferably, the tablecloth is made of 100% unbleached cotton. However, up to 30% of synthetic fibers such as thermobonding fibers can be incorporated therein which will consolidate the nonwoven obtained after an additional suitable heat treatment.

The hydraulic tying technique allows the treatment of sheets whose grammage is between 25 g / m² and 200 g / m². Below 25 g / m², the energy released by the fluid jets would cause significant displacement of the fibers and their encrustation between the meshes of the support fabric. This would cause the canvas to hang and the unwanted fluff to form on the final product. Above 200 g / m² the thickness does not allow a deep treatment of the sheet.

The quantity of paper cellulose fibers that is thus incorporated depends on the total grammage and the destination of the product according to the required mechanical strength. The paper fibers can thus constitute from 10% to 50% of the total weight without however representing less than 10 g / m². It is possible to superimpose several sheets of cellulose wadding to achieve the desired grammage.

The product obtained according to this process has considerably improved wettability compared to nonwovens without the addition of cellulosic fibers. The immersion time thus goes from around 30 seconds to less than 10 seconds.

• la figure 1 représente une installation de liage hydraulique permettant la mise en oeuvre du procédé de l'invention ;
• la figure 2 est une représentation graphique de la résistance à la rupture du produit traité, en fonction de la quantité d'énergie, libérée par les injecteurs successifs, par kilogramme de produit traité ;
• la figure 3 est une représentation graphique du temps d'immersion du produit traité dans l'exemple en fonction de la quantité d'énergie, libérée par les injecteurs successifs, par kilogramme de produit traité ;
• les figures 4 A et B sont des microphotographies des fibres de coton écru avant traitement ;
• les figures 4 C et D sont des microphotographies des mêmes fibres représentées aux figures 4 A et B, après le traitement de l'invention, et extraites du nontissé;
• la figure 5 représente une installation de liage hydraulique permettant la confection d'un nontissé conforme à un deuxième mode de réalisation de l'invention.

Other characteristics and advantages of the process will appear on reading the following description of two non-limiting embodiments of the invention, accompanied by the attached drawings in which:

• FIG. 1 represents a hydraulic binding installation allowing the implementation of the method of the invention;
• FIG. 2 is a graphic representation of the breaking strength of the treated product, as a function of the amount of energy, released by the successive injectors, per kilogram of treated product;
• FIG. 3 is a graphic representation of the immersion time of the product treated in the example as a function of the amount of energy, released by the successive injectors, per kilogram of product treated;
• FIGS. 4 A and B are photomicrographs of the unbleached cotton fibers before treatment;
• Figures 4 C and D are photomicrographs of the same fibers shown in Figures 4 A and B, after the treatment of the invention, and extracted from the nonwoven;
• FIG. 5 represents a hydraulic binding installation allowing the making of a nonwoven according to a second embodiment of the invention.

FIG. 1 represents a hydraulic binding installation of the type developed by the company PERFOJET. It comprises a first hydraulic tying unit (10) with an endless fabric (12) stretched between horizontal rollers (14) so as to form a loop. The fabric is driven in the direction of the arrow at a predetermined constant running speed. It comprises an upper portion at the level of which a first battery of injector ramps (16) has been placed, supplied with liquid under pressure and oriented vertically in the direction of the fabric. The ramps are arranged perpendicular to the direction of travel of the fabric, and include injection orifices distributed over the entire width of the web. The number of ramps is variable and chosen according to the desired pressure step. Preferably it will be between 3 and 10.

Opposite the ramps, under the fabric, suction boxes (18), communicating with a vacuum source, have the function of recovering the water, coming from the injectors, which has passed through the fabric.

The installation comprises a second hydraulic tying unit (20) with an endless cloth (22) for the treatment of the second face. It comprises a second battery of injector banks (26) supplied with pressurized liquid by pipes not shown. The ramps are associated with suction boxes (28) for the recovery of the liquid after its entanglement work.

As can be seen in the figure, the sheet of fibers is deposited on the fabric (12) from a station for forming the sheet, not shown.

Before being sent to this tablecloth forming station, the cotton is first cleaned and freed of most of its impurities such as seeds, leaf debris and dust, on conventional textile material, for example opener, cleaner, etc ... The fiber flakes are then sent on topping material: carding machine, pneumatic coating machine, etc ...

We can use cards of all types. It is preferably chosen for light nonwovens, of a weight less than 100 g / m², a card with veil jammer which makes it possible to obtain good resistance ratios from direction to cross direction.

The number of card sails to be superimposed depends on the weight per m² desired. For example, for a grammage of 65 g / m², 4 card sails are superimposed.

Instead of forming the web by carding, pneumatic means of the RANDO type can also be used, in particular for the heavier weights, up to 200 g / m².

The sheet thus formed is deposited on the fabric (12), moving at a predetermined speed, from where it is driven towards the battery of injector banks (16) for treatment on a first face. To ensure the pre-wetting of the web (necessary because of the hydrophobicity of the fibers used), it is possible, for example, to use an injector whose pressure is adjusted to a low level (30 bars), without disturbing the arrangement of the fibers. The other injectors are adjusted to pressures varying from 40 to 250 bars, to ensure the entanglement of the fibers. Then, the web, having undergone a first consolidation on the first face, can be driven towards the second tying unit where it will be taken up by a fabric so as to present its second face to the battery of injectors (26). In the example, the second face is treated identically to the first. The nonwoven then passes over a last vacuum slit which allows most of the water to be removed. It is then dried, for example on a through air dryer or on drying drums, not shown. If necessary, it is subjected to a thermobonding treatment if provision has been made to incorporate thermobonding fibers in the web.

One can also provide, if desired, a hydraulic structuring station arranged before drying of course.

Example 1

A sheet of unbleached cotton fibers of the combing type was treated by this method. The average length of the fibers was 12 to 14 mm with a micron index 4. The final nonwoven, weighing 65 g / m², consisted of 4 superimposed card webs.

Each hydraulic tying unit consisted of 4 injectors whose pressures were 30, 95, 125 and 125 bars respectively. At a machine speed of 30 meters per minute, the energy released successively by the injectors and measured at level of pumps, per kilogram of nonwoven, is reported in the table below:

A nonwoven with the following characteristics was obtained:

FIG. 2 shows the evolution of the breaking strength of the web as a function of the energy communicated to the web by the successive injectors. It can be seen that the resistance, both in the forward and in the cross direction, increases as a function of the energy received by the sheet to reach, with regard to the cross direction resistance, a plateau after 0.9 kwh per kg of nonwoven.

FIG. 3 shows for the example considered, the evolution of the immersion time representative of the wetting ability, as a function of this same amount of energy. It is noted that the time taken by the sample to sink into the water becomes measurable from a minimum energy threshold which is 0.7 kwh per kg of nonwoven for the example considered.

The table below shows the immersion time values relating to the nonwoven of the example on the one hand and, for a nonwoven of the same grammage obtained by mechanical needling from the same unbleached cotton card webs on the other hand .

Immersion times greater than 300 seconds mean that after this time, the nonwoven still floats on water and does not get wet.

This measure of the immersion time is used in the pharmacopoeia as a measure of the wettability of cotton wool. The method is as follows:
- using a cylindrical basket, previously dried, consisting of copper wires with a diameter of about 0.4 mm. This basket is 8.0 cm high, 5.0 cm in diameter and 1.5 to 2.0 cm wide. Its mass is 2.7 ± 0.3 g.

We weigh the basket (m₁). 1 g of nonwoven is taken from 5 different places in the sample. The 5 g are introduced without packing into the basket which is weighed (m₂). On the other hand, a container 11 cm to 12 cm in diameter filled with water at about 20 ° C. is prepared over a height of 10 cm. The basket is presented in a horizontal position above the water and dropped from a height of 10 mm. We measure the time it takes to sink into the water. It is this time in seconds which is shown in Figure 3.

The absorption coefficient is determined from the previous test. The basket is removed from the water, it is left to drain for 30 s then it is placed in a tared container (m₃) and the whole is weighed (m₄). The water absorption coefficient per gram of cotton reported above in the example is given by the formula: $$\text{C =}\frac{\text{m₄ - (m₂ + m₃)}}{\text{m₂ - m₁}}$$

The photos taken with a scanning electron microscope show the pickling action of the jets on the primary layer of the fibers. The micrographs 4 A and B show that the fibers before treatment are smooth and intact while the micrographs 4 C and D taken after treatment reveal the presence of fibrils attached to the fibers which have not been otherwise deteriorated.

Infrared spectrophotometry was also carried out.

At the infrared peaks, there is an evolution between two spectra, one before treatment and the other after treatment. However, this development is not sufficient to allow conclusions to be drawn therefrom on the disappearance of the materials conferring hydrophobic properties on the fiber.

There is shown in Figure 5 a slightly modified installation for making a nonwoven according to another embodiment of the invention. The elements corresponding to those of FIG. 1 bear the same reference increased by 100.

The installation comprises a first hydraulic tying unit (110) with an endless fabric (112) stretched between horizontal rollers (114) so as to form a loop. It comprises an upper portion at the level of which a first battery of injector banks (116) supplied with liquid under pressure has been placed.

The installation comprises a second hydraulic tying unit (120) with an endless cloth (122), for the treatment of the second face. It comprises a second battery of injector banks (126) supplied with pressurized liquid by pipes not shown. The ramps are associated with suction boxes (128) for recovering the liquid after its entanglement work.

As can be seen in the figure, the fiber sheet (101) is deposited on the fabric (112) from a sheet forming station, not shown, from where it is driven towards the battery of injector banks (116 ) for treatment on a first side. To ensure pre-wetting of the web (necessary due to the hydrophobicity of the fibers used), it is possible, for example, to use an injector whose pressure is adjusted to a low level, without disturbing the arrangement of the fibers. The other injectors are adjusted to pressures varying from 40 to 250 bars, to ensure the entanglement of the fibers. Then, the sheet, having undergone a first consolidation on the first face, is turned over so as to present its other face upwards as shown in the figure. It is driven to the second unit (120) where it receives a sheet of cellulose wadding (103) which is applied to its upper face by a pressing cylinder (123). The cellulose wadding sheet (103) is conventionally fed from a feed roller rotatably mounted about a horizontal axis.

The assembly (101), (103) - wadding on the top - is driven towards the second battery of injector banks (126) whose jets of fluid which they project ensure both the binding of the fibers of the sheet (101), continue their pickling, and the attachment of the paper fibers (103) in the sheet (101). The latter acts as a filter and prevents the short fibers from being entrained on the underlying fabric (122).

The nonwoven then passes over a last vacuum slit which allows most of the water to be removed. It is then dried, for example on a through air dryer or on drying drums, not shown. If necessary, it is subjected to a thermobonding treatment if provision has been made to incorporate thermobonding fibers in the web.

One can also provide, if desired, a hydraulic structuring station arranged before drying of course.

Example 2

A nonwoven was produced according to the method described above from a sheet of unbleached cotton fibers of the combing type. The average fiber length was 12-14 mm.

After having hydraulically treated a first face of the sheet, it was turned over, deposited on the other face two sheets of cellulose wadding of 17 g / m² each, and treated the whole hydraulically. Each hydraulic tying unit was composed of 4 injectors whose pressures were respectively at 60, 110, 130, 70 bars. At the running speed of 30 meters per minute, the energy released successively by the injectors and measured at the pumps per kilogram of material treated is reported in the table below:

The overall energy released by the injectors is therefore 0.99 Kwh per kg of nonwoven complex. On the first side, the energy released on the cotton veil alone was 0.91 kWh per kg of cotton. On the second side, the energy released on the whole cotton wadding plus cotton was 0.49 Kwh per kg of nonwoven complex.

A nonwoven with the following characteristics was obtained:

It appears that the product has a very low immersion time, of the order of 4 to 6 seconds, to be compared with an immersion time of 30 seconds for products without short, hydrophilic lignocellulosic fibers, which are the fibers. paper mills.

The immersion time was measured using the same basket method as in Example 1. The same is true for the absorption coefficient which in the present case is normally lower than in the case of the nonwoven 100 % cotton. In fact, the coefficient of cellulose wadding is itself lower, of the order of 5 to 6 g / g.

Claims (16)

1. Process for manufacturing a non-woven fabric from raw cotton or other natural lignocellulose fibres having on their surface a coating of substances making the fibre hydrophobic, comprising the following stages:

   - forming a sheet of unbound fibres on a water-permeable cloth,

   - interlocking the fibres in the sheet by means of a plurality of jets of water from injector manifolds disposed transversely with respect to the direction of travel of the support, characterised in that the total energy communicated to the sheet by all the jets is at least equal to a minimum threshold corresponding to the value at which the said sheet becomes hydrophilic.
2. Process for manufacturing a non-woven fabric from raw cotton according to Claim 1 characterised in that the energy threshold is between 0.4 and 1.1 kWh per kg of treated fibres.
3. Process according to either one of Claims 1 or 2, characterised in that the said sheet has a weight of between 25 and 200 g/m² and preferably between 30 and 100 g/m².
4. Process according to one of the preceding claims, characterised in that it consists of treating the two faces of the sheet successively.
5. Process according to the preceding claim, characterised in that the number of injectors is between 3 and 10 for each face.
6. Process according to one of Claims 4 and 5, characterised in that the first injector is at a low pressure so as to ensure the wetting of the cloth without displacing the fibres.
7. Process according to one of Claims 4 to 6, characterised in that the binding treatment is carried out by means of jets of water, the pressure of which at the outlet from the injector is set at a medium or high value, between 40 and 250 bars.
8. Manufacturing process by hydraulic binding of a non-woven fabric from raw cotton or other lignocellulose fibres, according to any one of Claims 1 to 7, consisting of:

   - forming an unbound sheet containing at least 70% of the said raw cotton fibres or other natural lignocellulose fibres having on their surface a sheath of hydrophobic substances, and depositing it on a permeable cloth;

   - subjecting a first face of the said sheet to an interlocking treatment by means of water jets;

   characterised in that the energy released is sufficient to make the cloth hydrophilic, and in that at least one layer of cellulose wadding is then deposited on the second face opposite the first and the second face thus covered is subjected to an interlocking treatment by means of jets of water.
9. Process according to the preceding claim, characterised in that the sheet of fibres has a weight of between 25 and 20 g/m² and the layer of cellulose wadding has a weight above 10 g/m².
10. Process according to the preceding claim, characterised in that the cellulose wadding represents 10% to 50% of the total weight of the non-woven fabric.
11. Hydrophilic non-woven fabric obtained according to one of the preceding Claims 9 or 10, characterised in that the immersion time of a sample is below 10 seconds.
12. Hydrophilic non-woven fabric containing a majority of cotton fibres or other natural lignocellulose fibres, obtained by hydraulic binding according to Claim 1, characterised in that the said fibres were not subjected to any boiling treatment intended to make them hydrophilic.
13. Non-woven hydrophilic fabric according to Claim 12, characterised in that it contains at least 70% raw cotton and is free of any wetting agent.
14. Hydrophilic non-woven fabric according to Claim 13, characterised in that it has a wettability such that the immersion time of a sample is below 90 seconds and preferably below 30 seconds.
15. Hydrophilic non-woven fabric according to one of Claims 13 or 14, characterised in that its absorption coefficient is above 9 g/g.
16. Non-woven fabric according to one of Claims 12 to 15, characterised in that it comprises up to 30% synthetic fibres.

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