EP0408567B1 - Wasserhalt- und drainagemittel bei der papierherstellung - Google Patents

Wasserhalt- und drainagemittel bei der papierherstellung Download PDF

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Publication number
EP0408567B1
EP0408567B1 EP89901903A EP89901903A EP0408567B1 EP 0408567 B1 EP0408567 B1 EP 0408567B1 EP 89901903 A EP89901903 A EP 89901903A EP 89901903 A EP89901903 A EP 89901903A EP 0408567 B1 EP0408567 B1 EP 0408567B1
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EP
European Patent Office
Prior art keywords
stock
papermaking
component
cationic
anionic
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Expired - Lifetime
Application number
EP89901903A
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English (en)
French (fr)
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EP0408567A4 (en
EP0408567A1 (de
Inventor
John D. Rushmere
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Nouryon Pulp and Performance Chemicals LLC
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Eka Nobel Inc
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Publication of EP0408567A4 publication Critical patent/EP0408567A4/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
    • D21H23/765—Addition of all compounds to the pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
    • D21H17/43—Carboxyl groups or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/10—Retention agents or drainage improvers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06—Controlling the addition
    • D21H23/14—Controlling the addition by selecting point of addition or time of contact between components

Definitions

  • This invention is directed to an aid for use in enhancing the resistance to shear and the retention of fibrous fines and/or particulate fillers in a paper web formed by vacuum felting of a stock on a wire or the like, and enhancing the dewatering of the web in the course of its formation.
  • U. S. Patent Nos. 4,578,150 and 4,385,961 disclose the use of a two-component binder system comprising a cationic starch and an anionic colloidal silicic acid sol as a retention aid when combined with cellulose fibers in a stock from which is formed a paper web by vacuum felting on a wire or the like.
  • Finnish Published Specifications Nos. 67,735 and 67,736 refer to cationic polymeric retention agent compounds including cationic starch and polyacrylamide as useful in combination with an anionic silicon compound to improve the reception of a sizing.
  • the sizing agent is added in the furnish, whereas in Specification No. 67,736, the sizing is applied after the paper web is formed.
  • the basic mechanism by which the cationic and anionic component aids function is often stated in terms of the components forming agglomerates, either alone or in combination with the cellulose fibers, that result in retention of fiber fines and/or mineral fillers. It is well recognized in the papermaking art that a pulp slurry, i.e. stock, undergoes severe shear stress at various stages in the papermaking process. After digestion, the stock may be beaten or refined in any of the several ways well known in the papermaking industry or it may be subjected to other similar treatments prior to the deposition of the stock onto a papermaking wire or the like for dewatering and web formation.
  • the stock is subjected to shear forces associated with mixing and particularly to hydrodynamic shear associated with flow of the stock through such equipment as distribution devices, some of which divide the pulp stream and then recombine the streams at high velocities and in a manner that promotes mixing by means of high turbulence prior to the stock entering the headbox.
  • shear forces associated with mixing and particularly to hydrodynamic shear associated with flow of the stock through such equipment as distribution devices, some of which divide the pulp stream and then recombine the streams at high velocities and in a manner that promotes mixing by means of high turbulence prior to the stock entering the headbox.
  • Shear stress continues to be experienced by the stock, and in fact is more severe in many instances, as it leaves the headbox, flows onto the wire, and is dewatered.
  • the stock is discharged from the headbox through a manifold, thence a slice, onto the moving wire, there are very strong shear forces exerted upon both the liquid and the solids content of the stock.
  • the slice lips can be considered as flat plates held parallel to the main direction of flow; as the fluid travels farther along the plate, the shearing forces, due to the region of viscous action, accomplish the retardation of a continually expanding portion of the flow.
  • the velocity gradient at the boundary surface is reduced, the growth in boundary layer thickness along the plate is paralleled by a steady increase in boundary shear.
  • the stock on the wire is subjected to still further hydrodynamic, including shear, forces.
  • Paper sheet forming is predominantly a hydrodynamic process which affects all the components of the stock including fibers, fines, and filler.
  • the fibers may exist as relatively mobile individuals or they may be connected to others as part of a network, agglomerate or mat.
  • the motions of the individual fibers follow the fluid motions closely because the inertial force on a single fiber is small compared with the viscous drag on it.
  • the response of the fibers to fluid drag may be drastically modified when they are consolidated in a network or fiber mat.
  • Chemical and colloidal forces are recognized to play a significant part in determining whether the fibers assume a network or mat geometry, such being particularly true with respect to fines and fillers.
  • a papermaking stock comprising cellulose fibers in an aqueous medium at a concentration of preferably at least about 50 percent by weight of the total solids in the stock is provided with a retention and dewatering aid comprising a two-component combination of an anionic polyacrylamide and a cationic colloidal silica sol in advance of the deposition of the stock onto a papermaking wire.
  • the stock so combined has been found to exhibit good dewatering during formation of the paper web on the wire and desirably high retention of fiber fines and fillers in the paper web products under conditions of high shear stress imposed upon the stock.
  • the present invention has been found to be effective with pulps of both hardwoods or softwoods or combinations thereof. Pulps of the chemical, mechanical (stoneground), semichemical, or thermomechanical types are suitable for treatment in accordance with the present process.
  • the present invention has been found to provide shear-resistant complexed stocks where there is present in the stock substantial lignosulfates or abietic acid as might be encountered especially in unbleached mechanical pulps or in other pulps due to accumulation of these substances in recirculated white water.
  • Inorganic fillers such as clays, calcium carbonate, titanium oxide, and/or recycled broke or other cellulosic waste may suitably be incorporated in stocks processed in accordance with the present invention.
  • the cationic component supplied to the stock is of a colloidal silica sol type such as colloidal silicic acid sol and preferably such a sol which has at least one layer of aluminum atoms on the surface of the siliceous component.
  • a suitable sol is prepared according to the methods such as described in U. S. Patent No. 3,007,878; 3,620,978; 3,719,607 and 3,956,171, each of which is incorporated herein by reference. Such methods involve the addition of an aqueous colloidal silica sol to an aqueous solution of a basic aluminum salt such that the silica surface is coated with a positive aluminum species rendering the sol cationic.
  • This sol is unstable under normal conditions of storage and, therefore, is preferably stabilized with an agent such as phosphate, carbonate, borate, magnesium ion or the like as is known in the art.
  • Surface aluminum to silicon mol ratios in the sol may range from between about 1:2 to about 2:1, and preferably 1:1.25 to 1.25:1 and most preferable 1:1, the latter being desirably more stable.
  • Particle size of the sol particulates appears to exhibit a lesser effect in determining the efficacy of the sol as used in the present process than certain other properties such as aluminum/silicon mol ratio, etc. Particle sizes of between about 3 and 30 nm can be employed. The smaller size ranges are preferred because of their generally superior performance.
  • the anionic component of the present invention comprises a polyacrylamide having a molecular weight in excess of 100,000, and preferably between about 5,000,000 and 15,000,000.
  • the anionicity (degree of carboxyl fraction present) of the polyacrylamide may range between about 1 to about 40 percent, but polyacrylamides having an anionicity of less than about 10 percent, when used with the cationic colloidal silica sols, have been found to give the best all- around balance between freeness, dewatering, fines retention, good paper formation and strength, and resistance to shear.
  • Suitable anionic polyacrylamides may be obtained either by hydrolysis of a preformed polyacrylamide or by coplymerization of acrylamide with acrylic acid.
  • Anionic polyacrylamides and anionic copolymers derived from the copolymerization of acrylamide with methacrylamide also may be employed in the present invention.
  • the polymer products of either of these methods of production appear to be suitable in the practice of the present invention.
  • the lesser degrees of anionicity are preferred for all-around benefits but optimum shear resistance with acceptable accompanying retention and dewatering properties has been found to occur with those polyacrylamides having an anionicity of between about 1 and 10 percent.
  • Suitable anionic polyacrylamides are commercially available from Hi- Tek Polymers, Inc., Louisville, Kentucky, (Polyhall brand), from Hyperchem, Inc., Tampa, Florida (Hyperfloc brand), or Hercules, Inc., Wilmington, Delaware (Reton brand) as indicated in the following Table A: TABLE A Polymer Average Molecular Weight Range (MM) % Carboxyl Polyhall 650 10 5 Polyhall 540 10 15-20 Polyhall 2J 10-15 2 Polyhall 7J 10-15 7 Polyhall 21J 10-15 21 Polyhall 33J 10-15 33 Polyhall 40J 10-15 40 Polyhall CFN020 5 5 Polyhall CFN031 10 12 Hyperfloc AF302 10-15 2-5 Reten 521 15 10 Reten 523 15 30 Of these polymers, the Polyhall 650 provides a combination of good dewatering retention, and shear resistance, while minimizing floc size, and therefore is a preferred polymer for use in the present invention.
  • the anionic polymer is prepared as a relatively dilute solution containing about 0.15 percent by weight or less.
  • the cationic colloidal silica sol and the anionic polyacrylamide are added sequentially directly to the stock at or briefly before the stock reaches the headbox. Little difference in fines retention or shear resistance is noted when the order of component introduction is alternated between cationic component first or anionic component first although it is generally preferred to add the cationic component first.
  • the sol and polymer preferably are preformed as relatively dilute aqueous solutions and added to the dilute stock at or slightly ahead of the headbox in a manner that promotes good distribution, i.e. mixing, of the additive with the stock.
  • Acceptable dewatering, retention and shear resistance properties of the stock are obtained when the cationic and anionic components are added to the stock in amounts representing between about 0.01 and about 2.0 weight percent for each component, based on the solids weight percent for each component, based on the solids content of the treated stock.
  • the concentration of each component is between about 0.2 to about 0.5 weight percent.
  • the cationic component was a cationic colloidal silica sol prepared according to the teachings of U.S. 3,956,171. Specifically, in the production of the sol, conditions are selected to provide a surface aluminum/silicon mol ratio of from about 1:2 to 2:1, preferably about 1:1.25 to 1.25:1. It has been found that a sol having a surface aluminum/silicon mol ratio of 1:1 is most stable under those conditions existing in papermaking, so that sols with the 1:1 mol ratio are most suitable.
  • the anionic component used in the Examples comprised various anionic polyacrylamides, each of which is commercially available and identified hereinabove.
  • the anionic polyacrylamides were prepared as dilute solutions of 0.15 weight percent or less as noted.
  • the pH of the stock in the several Examples was chosen to be pH 4 and pH 8, it is to be recognized that the present invention is useful with stocks having a pH in the range of about pH 3 to pH 9.
  • Groundwood pulp is characterized by having a high percentage of fines and low dewatering (freeness).
  • a 0.3 wt. % stock was prepared from 100% stoneground wood (40% poplar, 60% black spruce). To the stock was added 1.5g/1 of sodium sulfate decahydrate to provide a specific conductivity of 115mS/cm similar to that of a typical papermaking process. The pH of the stock was adjusted to either pH 4 or pH 8 by means of dilute sodium hydroxide and sulfuric acid solutions and Canadian Standard Freeness Tests were then run to determine drainage in the presence of various amounts of polyacrylamide and cationic sol.
  • the polyacrylamide used was Polyhall 650 and was added in amounts up to 1.0 wt. % [8,94 kg/tonne (20 lbs./ton)] based on the pulp content of the stock.
  • the cationic sol used is described above and was used in amounts up to 1.5 wt. % of the pulp.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Claims (18)

  1. Papierstoff zur Papierherstellung, welcher Cellulosefasern in einer Konzentration von wenigstens etwa 50 Gew.-% derartiger Fasern in einem wässrigen Medium mit einem pH-Wert zwischen etwa 3 und etwa 9 einschließt, dadurch gekennzeichnet, daß der Papierstoff einschließt
    - eine kationische Komponente, die eine kolloidale Siliciumdioxidsol-Verbindung umfaßt, die gewählt ist aus der Gruppe, die besteht aus kolloidalem Kieselsäuresol und kolloidalem Kieselsäuresol, das mit wenigstens einer Oberflächenschicht aus Aluminiumatomen modifiziert ist;
    - eine anionische Komponente, die gewählt ist aus der Gruppe, die besteht aus Polyacrylamid, das durch Hydrolyse von Polyacrylamid hergestellt wird, Polyacrylamid, das durch Copolymerisation von Acrylsäure mit Acrylamid hergestellt wird, und Polyacrylamid, das aus der Copolymerisation mit Methacrylamid abgeleitet ist;
    wobei die kationische Komponente in dem Papierstoff in einer Konzentration zwischen etwa 0,01 und etwa 2,0 Gew.-% zugegen ist, bezogen auf den Feststoffgehalt in dem Papierstoff, und wobei die anionische Komponente in dem Papierstoff in einer Konzentration von etwa 0,01 bis etwa 1,0 Gew.-% zugegen ist, bezogen auf den Feststoffgehalt in dem Papierstoff,
    wodurch der Papierstoff durch Scherkräfte, die im Verlauf der Bildung einer Papier-Bahn aus dem Papierstoff auf den Papierstoff wirken, effektiv beständig gegenüber einer Zerstörung seiner Wasserhalte- und Entwässerungseigenschaften gemacht wird.
  2. Papierstoff zur Papierherstellung nach Anspruch 1, dadurch gekennzeichnet, daß die kationische Komponente und die anionische Komponente in einem Verhältnis zwischen 1 : 100 und 100 : 1 zugegen sind.
  3. Papierstoff zur Papierherstellung nach Anspruch 2, dadurch gekennzeichnet, daß die kationische Komponente und die anionische Komponente in einem Verhältnis zwischen 1 : 10 und 10 : 1 zugegen sind.
  4. Papierstoff zur Papierherstellung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß der pH-Wert des Papierstoffs zwischen etwa 4 und etwa 9 liegt.
  5. Papierstoff zur Papierherstellung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die anionische Komponente eine Anionizität zwischen etwa 1 und etwa 40 % aufweist.
  6. Papierstoff zur Papierherstellung nach Anspruch 5, dadurch gekennzeichnet, daß die anionische Komponente eine Anionizität von weniger als etwa 10 % zeigt.
  7. Papierstoff zur Papierherstellung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß die anionische Komponente ein Molekulargewicht zwischen etwa 100.000 und 15.000.000 aufweist.
  8. Papierstoff zur Papierherstellung nach Anspruch 7, dadurch gekennzeichnet, daß die anionische Komponente ein Molekulargewicht zwischen etwa 5.000.000 und 15.000.000 aufweist.
  9. Papierstoff zur Papierherstellung nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß die kationische Komponente eine Teilchengröße zwischen etwa 3 und 30 nm aufweist.
  10. Verfahren zur Papierherstellung unter Verwendung eines Papierstoffs, der wenigstens etwa 50 Gew.-% Cellulosefasern in einem wässrigen Medium mit einem pH-Wert zwischen etwa 3 und etwa 9 umfaßt, wobei der Papierstoff aus einem Stoffumlaufkasten, der den Papierstoff enthält, auf ein sich bewegendes Papiermaschinensieb geleitet und darauf vakuum-verfilzt wird, dadurch gekennzeichnet, daß dem Papierstoff vor seinem Ablassen aus dem Stoffumlaufkasten auf das Sieb zugesetzt werden,
    - eine kationische kolloidale Siliciumdioxidsol-Komponente, die gewählt ist aus der Gruppe, die besteht aus kolloidalem Kieselsäuresol und kolloidalem Kieselsäuresol, das mit wenigstens einer Oberflächenschicht aus Aluminiumatomen modifiziert ist, und
    - eine anionische Polyacrylamid-Komponente, die gewählt ist aus der Gruppe, die besteht aus Polyacrylamid, das durch Hydrolyse von Polyacrylamid hergestellt wird, Polyacrylamid, das durch Copolymerisation von Acrylsäure mit Acrylamid hergestellt wird, und Polyacrylamid, das aus der Copolymerisation von Acrylamid mit Methacrylamid abgeleitet ist,
    wobei die Komponenten getrennt voneinander und unter Ablaufen einer Zeit zwischen den Zeitpunkten ihrer Zugabe zugeleitet werden, die ausreichend ist, um ein gutes Durchmischen zu erlauben, wobei die kationische Komponente in dem Papierstoff in einer Konzentration von etwa 0,01 bis 2,0 Gew.-% zugegen ist, bezogen auf den Feststoffgehalt des Papierstoffs, und wobei die anionische Komponente in dem Papierstoff in einer Konzentration von etwa 0,01 bis etwa 1,0 Gew.-% zugegen ist, bezogen auf den Feststoffgehalt des Papierstoffs.
  11. Verfahren zur Papierherstellung nach Anspruch 10, dadurch gekennzeichnet, daß die kationische Komponente und die anionische Komponente in einem Verhältnis zwischen etwa 1 : 100 und 100 : 1 zugegen sind.
  12. Verfahren zur Papierherstellung nach Anspruch 11, dadurch gekennzeichnet, daß die kationische Komponente und die anionische Komponente in einem Verhältnis zwischen etwa 1 : 10 und 10 : 1 zugegen sind.
  13. Verfahren zur Papierherstellung nach einem der Ansprüche 10 bis 12, dadurch gekennzeichnet, daß der pH-Wert des Papierstoffs zwischen etwa 4 und etwa 9 liegt.
  14. Verfahren zur Papierherstellung nach einem der Ansprüche 10 bis 13, dadurch gekennzeichnet, daß die anionische Komponente eine Anionizität zwischen etwa 1 und etwa 40 % zeigt.
  15. Verfahren zur Papierherstellung nach Anspruch 14, dadurch gekennzeichnet, daß die anionische Komponente eine Anionizität von weniger als etwa 10 % zeigt.
  16. Verfahren zur Papierherstellung nach einem der Ansprüche 10 bis 15, dadurch gekennzeichnet, daß die anionische Komponente ein Molekulargewicht zwischen etwa 100.000 und 15.000.000 aufweist.
  17. Verfahren zur Papierherstellung nach Anspruch 16, dadurch gekennzeichnet, daß die anionische Komponente ein Molekulargewicht zwischen etwa 5.000.000 und 15.000.000 aufweist.
  18. Verfahren zur Papierherstellung nach einem der Ansprüche 11 bis 17, dadurch gekennzeichnet, daß die kationische Komponente eine Teilchengröße zwischen etwa 3 und 30 nm aufweist.
EP89901903A 1988-03-08 1989-01-12 Wasserhalt- und drainagemittel bei der papierherstellung Expired - Lifetime EP0408567B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/165,634 US4798653A (en) 1988-03-08 1988-03-08 Retention and drainage aid for papermaking
US165634 1988-03-08
PCT/US1989/000124 WO1989008742A1 (en) 1988-03-08 1989-01-12 Retention and drainage aid for papermaking

Publications (3)

Publication Number Publication Date
EP0408567A1 EP0408567A1 (de) 1991-01-23
EP0408567A4 EP0408567A4 (en) 1991-12-11
EP0408567B1 true EP0408567B1 (de) 1994-05-25

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EP89901903A Expired - Lifetime EP0408567B1 (de) 1988-03-08 1989-01-12 Wasserhalt- und drainagemittel bei der papierherstellung

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US (1) US4798653A (de)
EP (1) EP0408567B1 (de)
JP (1) JP2818677B2 (de)
KR (1) KR900700691A (de)
AT (1) ATE106107T1 (de)
AU (1) AU614327B2 (de)
CA (1) CA1324707C (de)
DE (1) DE68915542T2 (de)
ES (1) ES2009700A6 (de)
FI (1) FI92233C (de)
WO (1) WO1989008742A1 (de)

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US4798653A (en) 1989-01-17
AU614327B2 (en) 1991-08-29
ATE106107T1 (de) 1994-06-15
EP0408567A4 (en) 1991-12-11
CA1324707C (en) 1993-11-30
JP2818677B2 (ja) 1998-10-30
FI904420A0 (fi) 1990-09-07
WO1989008742A1 (en) 1989-09-21
DE68915542T2 (de) 1994-12-15
JPH03503297A (ja) 1991-07-25
EP0408567A1 (de) 1991-01-23
FI92233B (fi) 1994-06-30
DE68915542D1 (de) 1994-06-30
KR900700691A (ko) 1990-08-16
AU2941189A (en) 1989-10-05
FI92233C (fi) 1994-10-10
ES2009700A6 (es) 1989-10-01

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