EP0349891A1 - Dispositif et procédé de décontamination de matières solides et/ou de matières en vrac et élimination des substances polluantes - Google Patents
Dispositif et procédé de décontamination de matières solides et/ou de matières en vrac et élimination des substances polluantes Download PDFInfo
- Publication number
- EP0349891A1 EP0349891A1 EP89111734A EP89111734A EP0349891A1 EP 0349891 A1 EP0349891 A1 EP 0349891A1 EP 89111734 A EP89111734 A EP 89111734A EP 89111734 A EP89111734 A EP 89111734A EP 0349891 A1 EP0349891 A1 EP 0349891A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pollutants
- continuous furnace
- moisture
- chamber
- furnace according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/10—Drying by heat
- F23G2201/101—Drying by heat using indirect heat transfer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/50—Devolatilising; from soil, objects
Definitions
- the invention relates to a device by means of which inorganic materials which are contaminated by organic pollutants, e.g. chlorinated dioxins and furans, polychlorinated biphenyls or chlorinated hydrocarbons, are contaminated, can be almost completely freed from the pollutants; it also relates to a method for decontamination and removal or decomposition of the pollutants, which can be carried out by means of the device.
- organic pollutants e.g. chlorinated dioxins and furans, polychlorinated biphenyls or chlorinated hydrocarbons
- the method according to DE-PS 27 35 913 is based on this method, in which activated carbon particles are reactivated in an elongated combustion chamber without the activated carbon particles burning.
- Infrared emitters infrared lamps are used to supplement the heat generated by combustion in this process.
- the present invention now solves the problem of creating a device in which a continuous furnace is provided, in which moisture and pollutants by indirect heating of the solid or piece goods (and corresponding desorption of the pollutants) with the help of radiation, for example infrared radiation, as a heat source the gas phase are transferred, and which has a separate reaction chamber with one or more burners, wherein the gas phase is a thermal or oxidative treatment to destroy the pollutants when the heat generated is used directly, and optionally downstream devices for aftertreatment of the exhaust gases before they are discharged to the outside.
- radiation for example infrared radiation
- the invention also relates to the method for decontamination and decomposition of the pollutants by means of the new device.
- FIG. 2 shows a variant of the device in which the removal and removal of the moisture from the contaminated material is connected upstream of the pollutant drive in a separate chamber.
- the radiator can be placed closer to the material to be treated in the part, since less cross-section is required for gas / steam discharge.
- the contaminated material is in the container 1, which is brought into the continuous furnace 3 via the feeder 2.
- the combustion chamber 6 acts as an infrared radiator.
- a transport device guides the contaminated material through the furnace, at the end of which it is released into the cooling device 10 through a lock. From there, the decontaminated material reaches the collecting container 11. The coolant from the cooling device 10 is discharged via 12.
- the gas phase in the continuous furnace 3, which contains moisture and pollutants, is conducted via line 5 into the combustion chamber 6 at one end.
- the pollutant-free exhaust gas is passed through the pipe 8, possibly for further use of the heat content via the heat exchanger 8a, into the aftertreatment device 9, from there then into the open air.
- the burners 7 are operated with conventional fuels, preferably with propane. They are expediently designed so that they can also be operated with the addition of pollutant-containing gas with a low calorific value.
- the material entry from the container 1 into the continuous furnace 3 takes place, for example, with a metering belt which removes the contaminated material directly from the container or via an inlet chute, and a downstream entry lock with a distributor element above the furnace belt.
- the entry lock takes over one of the essential separations of the (closed) furnace system from the environment.
- the continuous furnace 3 preferably consists of a sheet steel housing with an insulation made of lightweight ceramic materials, in which a conveyor belt made of thermally resilient material, e.g. a wire mesh belt, a plate belt or a trough belt is installed, which, preferably with chains on both sides or other devices, is guided exactly lengthways material containing pollutants feeds through the heating zones at an adjustable feed rate.
- the heating takes place by means of the infrared radiation emanating from the combustion chamber 6 installed in the furnace.
- the Combustion chamber 6 preferably consists of ceramic material or corrosion and heat-resistant metal alloys. It can be in one or more parts and have one or more burners 7. For example, the combustion chamber 6 can be divided into several interconnected chambers, each equipped with a separately controllable burner 7.
- Burner 7 and chambers are designed so that surface temperatures between about 700 and 1200 ° C can be reached.
- the combustion chamber itself thus acts as an infrared radiator and is used to heat the material entered in the continuous furnace 3, first for moisture removal up to about 250 ° C and then for pollutant removal at higher temperatures (up to about 850 ° C).
- the continuous furnace 3 is divided into several temperature control zones, the temperature range of each zone between about 200 ° C and about 850 ° C can be adjusted precisely. If desired, 3 further heating elements are provided in the continuous furnace.
- the elements 1 to 12 have the meaning given in Figure 1.
- the continuous furnace is divided into two chambers (13 and 14), 13 for moisture removal (drying), 14 for desorption of the pollutants.
- the steam is fed via line 15 to the combustion chamber (infrared radiator) 6 and mixed with the pollutant-containing gas from chamber 14.
- a heating element is used, which is the waste heat of the Combustion chamber 6 is used.
- a vacuum is used in the method according to the invention.
- the vacuum can be reduced by conventional means, e.g. with a fan installed at a suitable point in the continuous furnace.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Processing Of Solid Wastes (AREA)
- Treating Waste Gases (AREA)
- Fire-Extinguishing Compositions (AREA)
- Drying Of Solid Materials (AREA)
- Incineration Of Waste (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89111734T ATE71202T1 (de) | 1988-07-04 | 1989-06-28 | Vorrichtung und verfahren zur dekontamination von feststoffen bzw. schuettgut und beseitigung der schadstoffe. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3822534A DE3822534A1 (de) | 1988-07-04 | 1988-07-04 | Vorrichtung und verfahren zur dekontamination von feststoffen bzw. schuettgut und beseitigung der schadstoffe |
DE3822534 | 1988-07-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0349891A1 true EP0349891A1 (fr) | 1990-01-10 |
EP0349891B1 EP0349891B1 (fr) | 1992-01-02 |
Family
ID=6357888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19890111734 Expired - Lifetime EP0349891B1 (fr) | 1988-07-04 | 1989-06-28 | Dispositif et procédé de décontamination de matières solides et/ou de matières en vrac et élimination des substances polluantes |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0349891B1 (fr) |
JP (1) | JPH04501305A (fr) |
AT (1) | ATE71202T1 (fr) |
DE (2) | DE3822534A1 (fr) |
ES (1) | ES2028418T3 (fr) |
GR (1) | GR3003781T3 (fr) |
WO (1) | WO1990000237A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4206109C2 (de) * | 1992-02-27 | 1994-09-01 | Bruker Franzen Analytik Gmbh | Verfahren und Vorrichtung zur Aufbereitung fester Proben mit Hilfe pyrolytischer Verdampfung für eine Analyse mittels eines Massenspektrometers oder eines Gaschromatographen |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3648630A (en) * | 1970-05-20 | 1972-03-14 | Shirco Inc | Incinerator |
US3780676A (en) * | 1972-05-08 | 1973-12-25 | Air Preheater | Metallic recovery system |
US4667609A (en) * | 1986-09-08 | 1987-05-26 | Robert Hardison | Apparatus and method for treatment of soil contaminated with hydrocarbons |
DE3635068A1 (de) * | 1986-10-15 | 1988-04-21 | Kloeckner Humboldt Deutz Ag | Verfahren und anlage zur kombinierten thermischen entsorgung von kontaminiertem boden, muell, sonderabfall, klaerschlamm und altoel |
-
1988
- 1988-07-04 DE DE3822534A patent/DE3822534A1/de not_active Withdrawn
-
1989
- 1989-06-28 WO PCT/EP1989/000730 patent/WO1990000237A1/fr unknown
- 1989-06-28 EP EP19890111734 patent/EP0349891B1/fr not_active Expired - Lifetime
- 1989-06-28 ES ES198989111734T patent/ES2028418T3/es not_active Expired - Lifetime
- 1989-06-28 AT AT89111734T patent/ATE71202T1/de not_active IP Right Cessation
- 1989-06-28 DE DE8989111734T patent/DE58900659D1/de not_active Revoked
- 1989-06-28 JP JP1507211A patent/JPH04501305A/ja active Pending
-
1992
- 1992-02-11 GR GR920400207T patent/GR3003781T3/el unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3648630A (en) * | 1970-05-20 | 1972-03-14 | Shirco Inc | Incinerator |
US3780676A (en) * | 1972-05-08 | 1973-12-25 | Air Preheater | Metallic recovery system |
US4667609A (en) * | 1986-09-08 | 1987-05-26 | Robert Hardison | Apparatus and method for treatment of soil contaminated with hydrocarbons |
DE3635068A1 (de) * | 1986-10-15 | 1988-04-21 | Kloeckner Humboldt Deutz Ag | Verfahren und anlage zur kombinierten thermischen entsorgung von kontaminiertem boden, muell, sonderabfall, klaerschlamm und altoel |
Also Published As
Publication number | Publication date |
---|---|
EP0349891B1 (fr) | 1992-01-02 |
WO1990000237A1 (fr) | 1990-01-11 |
ATE71202T1 (de) | 1992-01-15 |
GR3003781T3 (fr) | 1993-03-16 |
DE3822534A1 (de) | 1990-01-11 |
ES2028418T3 (es) | 1992-07-01 |
DE58900659D1 (de) | 1992-02-13 |
JPH04501305A (ja) | 1992-03-05 |
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