EP0329718B1 - Pyrotechnische mischung zur erzeugung eines tarnnebels - Google Patents

Pyrotechnische mischung zur erzeugung eines tarnnebels Download PDF

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Publication number
EP0329718B1
EP0329718B1 EP88904505A EP88904505A EP0329718B1 EP 0329718 B1 EP0329718 B1 EP 0329718B1 EP 88904505 A EP88904505 A EP 88904505A EP 88904505 A EP88904505 A EP 88904505A EP 0329718 B1 EP0329718 B1 EP 0329718B1
Authority
EP
European Patent Office
Prior art keywords
carbonate
potassium
composition
mixture
fog
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP88904505A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0329718A1 (de
Inventor
Uwe Krone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nico Pyrotechnik Hanns Juergen Diederichs GmbH and Co KG
Original Assignee
Nico Pyrotechnik Hanns Juergen Diederichs GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nico Pyrotechnik Hanns Juergen Diederichs GmbH and Co KG filed Critical Nico Pyrotechnik Hanns Juergen Diederichs GmbH and Co KG
Priority to AT88904505T priority Critical patent/ATE71351T1/de
Publication of EP0329718A1 publication Critical patent/EP0329718A1/de
Application granted granted Critical
Publication of EP0329718B1 publication Critical patent/EP0329718B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B33/00Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
    • C06B33/12Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
    • C06B33/14Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds at least one being an inorganic nitrogen-oxygen salt
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B33/00Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
    • C06B33/04Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic nitrogen-oxygen salt
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06DMEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
    • C06D3/00Generation of smoke or mist (chemical part)

Definitions

  • the invention relates to a pyrotechnic mixture for producing a camouflage mist.
  • Hygroscopic compounds such as metal chlorides (ZnCl2, FeCl3, AlCl3, TiCl4, SiCl4) or phosphorus oxides P2O3, P2O5) are generated and evaporated, which then hydrolyze with the air and form suitable clouds of fog.
  • ZnCl2, FeCl3, AlCl3, TiCl4, SiCl4 or phosphorus oxides P2O3, P2O5 are generated and evaporated, which then hydrolyze with the air and form suitable clouds of fog.
  • mist formed especially from so-called HC mist sets containing hexachloroethane, but also from phosphor mist sets, is extremely acidic due to hydrolysis in humid air, since hydrochloric acid (HG mist) and phosphoric acids are formed, and therefore toxic and plant-intolerant.
  • the heavy metal zinc is introduced into the environment in the most commonly used fog mixture based on hexachloroethane (HC) and zinc or zinc oxide.
  • the object of the invention is therefore to produce a camouflage mist which is particularly suitable for training purposes and which consists of a non-toxic aerosol, which therefore cannot have a toxic effect on humans and animals, and on the other hand is environmentally compatible.
  • the mist mainly consists of macronutrients suitable for plants.
  • a non-toxic mist of sufficient optical density is formed by the invention.
  • the fog is formed in the following way:
  • the components magnesium powder, potassium nitrate and potassium perchlorate already produce fog-like clouds when converted in the range of 2500 °.
  • the fog density is particularly characterized by the proportion of potassium chloride and / or sodium chloride, whose sublimation point at 1500 or boiling point at 1450 ° C are far below the reaction temperature of the reaction of magnesium and potassium nitrate.
  • the reaction products of the chemical conversion from magnesium with potassium nitrate, potassium perchlorate, calcium carbonate etc. form a useful training fog with the subliming potassium chloride or the evaporating sodium chloride without toxic or environmentally incompatible ingredients.
  • the energy (E) released in the three basic conversions mentioned is used for sublimation / evaporation of potassium chloride and sodium chloride.
  • nitrogen-releasing substances such as azodicarbonamide, oxamide or dicyandiamide are added to the mixture. This results in a continuous gas flow for better transport of the aerosol particles and a higher aerosol yield, since the permanently formed gases prevent the slag from flowing together and promote sublimation and evaporation by increasing the surface area.
  • a pure white aerosol which mainly consists of the components potassium chloride, magnesium oxide, calcium hydroxide, calcium carbonate, sodium chloride and potassium carbonate. These components are environmentally friendly and non-toxic and apart from NaCl macronutrients for plants.
  • the pH of the generated fog is highest at the point of origin (9).
  • chemical reactions of the primary oxides K2O and CaO (equations 1, 3) with components of the air, especially H2O and CO2 to form KHCO3, K2CO3, Ca (OH) 2 and CaCO3 and by dilution it quickly decreases and reaches the pH of the ambient air ( ⁇ 6) at a distance of 5-10 m from the fog source.
  • a pyrotechnic mixture with the same components as the mixture for producing the camouflage mist can be used as the ignition mixture, but in which the content of magnesium and oxidizing agent is increased to increase the sensitivity to ignition and transmission reliability.
  • the primer can e.g. consist of the following proportions: 25% Mg, 35% KNO3, 10% KClO4, 20% CaCO3, 10% KCl.
  • mist set and the primer are pressed into sleeves in a manner known per se and reacted with conventional igniters.
  • the drawing shows an embodiment of a mist body with the new mixture.
  • a sleeve 1 with bottom 3 there is the compressed mixture 4, which carries the ignition mixture 5 pressed on with it as a conclusion.
  • the embodiment of the drawing has a recess 6 for the use of an igniter known per se.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Combustion & Propulsion (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Air Bags (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Road Signs Or Road Markings (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Pyridine Compounds (AREA)
  • Cosmetics (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
EP88904505A 1987-08-26 1988-05-05 Pyrotechnische mischung zur erzeugung eines tarnnebels Expired - Lifetime EP0329718B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88904505T ATE71351T1 (de) 1987-08-26 1988-05-05 Pyrotechnische mischung zur erzeugung eines tarnnebels.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3728380A DE3728380C1 (de) 1987-08-26 1987-08-26 Pyrotechnische Mischung zur Erzeugung eines Tarnnebels und Anzuendmischung hierfuer
DE3728380 1987-08-26

Publications (2)

Publication Number Publication Date
EP0329718A1 EP0329718A1 (de) 1989-08-30
EP0329718B1 true EP0329718B1 (de) 1992-01-08

Family

ID=6334469

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88904505A Expired - Lifetime EP0329718B1 (de) 1987-08-26 1988-05-05 Pyrotechnische mischung zur erzeugung eines tarnnebels

Country Status (24)

Country Link
US (1) US4968365A (es)
EP (1) EP0329718B1 (es)
JP (1) JPH02501138A (es)
KR (1) KR890701505A (es)
CN (1) CN1032778A (es)
AR (1) AR246937A1 (es)
AT (1) ATE71351T1 (es)
AU (1) AU600141B2 (es)
CA (1) CA1306112C (es)
DE (2) DE3728380C1 (es)
DK (1) DK172188B1 (es)
ES (1) ES2008004A6 (es)
FI (1) FI891759A0 (es)
GR (1) GR880100322A (es)
IL (2) IL87269A0 (es)
IN (1) IN168235B (es)
JO (1) JO1564B1 (es)
NO (1) NO168241C (es)
NZ (1) NZ225919A (es)
PH (1) PH23604A (es)
PT (1) PT88324B (es)
SG (1) SG85592G (es)
WO (1) WO1989001926A1 (es)
ZA (1) ZA884982B (es)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011042114A1 (de) * 2009-10-09 2011-04-14 Rheinmetall Waffe Munition Gmbh Kunststoffgebundene pyrotechnische mischung zur erzeugung von alkalimetall-chlorid- bzw. erdalkalimetallchlorid-aerosolen als tarnnebel
DE102012024809A1 (de) 2012-12-19 2014-06-26 Rheinmetall Waffe Munition Gmbh Pyrotechnische Mischung zur Erzeugung eines Aerosols

Families Citing this family (18)

* Cited by examiner, † Cited by third party
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GB8820660D0 (en) * 1988-09-01 1988-11-16 Astra Holdings Plc Smoke producing article
US4997497A (en) * 1990-04-05 1991-03-05 Rockwell International Corporation Castable smoke-producing pyrotechnic compositions
US6051087A (en) * 1992-01-29 2000-04-18 Cordant Technologies Inc. Low smoke rocket motor liner compositions
AU682682B2 (en) * 1993-02-16 1997-10-16 Spectrex Inc. Fire extinguishing methods and systems
CN1060149C (zh) * 1993-03-30 2001-01-03 陈锦铭 硝酸铵发烟罐及其制造方法
NL1005529C2 (nl) * 1997-03-13 1998-09-15 Tno Samenstelling voor het genereren van rook.
DE102008010942B4 (de) 2008-02-25 2012-09-27 Rheinmetall Waffe Munition Gmbh Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels
CN101624320B (zh) * 2008-07-13 2012-11-14 周健 舞台快速黄色烟雾剂及其制备方法
RU2460711C1 (ru) * 2011-03-29 2012-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВПО "КНИТУ") Пиротехнический состав цветного огня
US20120267016A1 (en) * 2011-04-19 2012-10-25 Lombardi John L Nontoxic Obscurant Compositions and Method of Using Same
GB201200829D0 (en) * 2012-01-18 2012-02-29 Albertelli Aldino Fire suppression system
WO2014175982A1 (en) * 2013-03-21 2014-10-30 Kms Consulting, Llc Training ammunition cartridge with a gaseous plume signature
JP6404603B2 (ja) * 2014-06-11 2018-10-10 株式会社ダイセル 煙幕発生器およびその使用方法
JP6334298B2 (ja) * 2014-07-04 2018-05-30 株式会社ダイセル 煙幕発生装置
CN107666842A (zh) 2015-06-03 2018-02-06 爱格升公司 具有隐藏提升机构的高度可调节装置
US10519074B2 (en) 2016-09-20 2019-12-31 Goodrich Corporation Obscurant emission systems and methods
CN106495971A (zh) * 2016-10-13 2017-03-15 湖南荣晖实业有限公司 无硫开苞药
CN107021865A (zh) * 2017-05-26 2017-08-08 北京理工大学 可干扰可见光、红外及毫米波的宽频段烟幕材料

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FR339233A (fr) * 1903-12-23 1905-01-26 Cyanidgesellschaft Mit Beschra Nouveau procédé pour l'obtention d'explosifs
US1461646A (en) * 1919-01-14 1923-07-10 Nat Carbon Co Inc Material for producing smoke screens
DE803645C (de) * 1949-10-11 1951-04-05 Dynamit Act Ges Vormals Alfred Schagwettersichere Sprengkapsel in Verbindung mit elektrischen Zuendern
US2995526A (en) * 1951-07-27 1961-08-08 Ment Jack De Composition for smoke production
DE918196C (de) * 1952-12-23 1954-09-20 J G W Berckholtz Fa Masse zur Erzeugung von farbigem Rauch
US4484195A (en) * 1960-06-10 1984-11-20 The United States Of America As Represented By The Secretary Of The Army Method of screening infra-red radiation
US3274035A (en) * 1964-06-15 1966-09-20 Lohr A Burkardt Metallic composition for production of hygroscopic smoke
US3862866A (en) * 1971-08-02 1975-01-28 Specialty Products Dev Corp Gas generator composition and method
DE2743363C3 (de) * 1977-09-27 1980-06-19 Nico-Pyrotechnik Hanns-Juergen Diederichs Kg, 2077 Trittau Nebelsatz und Verfahren zur Herstellung desselben
DE2841815C2 (de) * 1978-09-26 1985-02-21 Buck Chemisch-Technische Werke GmbH & Co, 7347 Bad Überkingen Verfahren zur Herstellung einer Geschoßfüllung
DE3031369C2 (de) * 1980-08-20 1987-01-02 Pyrotechnische Fabrik F. Feistel GmbH + Co KG, 6719 Göllheim Pyrotechnische Ladung aus Nebelsatz und Anzündsatz und Verfahren zur Herstellung der Nebelmischung und des Anzündsatzes
DE3104464C2 (de) * 1981-02-09 1983-01-13 Buck Chemisch-Technische Werke GmbH & Co, 7341 Bad Überkingen Verfahren zum Herstellen eines Nebelsatzes sowie Nebeltopf mit darin untergebrachtem Nebelsatz
US4438700A (en) * 1982-07-19 1984-03-27 The United States Of America As Represented By The Secretary Of The Army White smoke spotting composition for training ammunition
FR2560186B1 (fr) * 1982-07-27 1987-06-05 France Etat Armement Composition pyrotechnique generatrice de fumee opaque au rayonnement infrarouge et munition fumigene obtenue
FR2560371B1 (fr) * 1982-07-27 1989-03-31 France Etat Armement Procede d'occultation des rayonnements visible et infrarouge et munition fumigene mettant en oeuvre ce procede
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011042114A1 (de) * 2009-10-09 2011-04-14 Rheinmetall Waffe Munition Gmbh Kunststoffgebundene pyrotechnische mischung zur erzeugung von alkalimetall-chlorid- bzw. erdalkalimetallchlorid-aerosolen als tarnnebel
DE102012024809A1 (de) 2012-12-19 2014-06-26 Rheinmetall Waffe Munition Gmbh Pyrotechnische Mischung zur Erzeugung eines Aerosols

Also Published As

Publication number Publication date
FI891759A (fi) 1989-04-13
DK160989D0 (da) 1989-04-03
WO1989001926A1 (en) 1989-03-09
DE3728380C1 (de) 1988-11-24
ATE71351T1 (de) 1992-01-15
US4968365A (en) 1990-11-06
NZ225919A (en) 1991-03-26
NO168241C (no) 1992-01-29
AU600141B2 (en) 1990-08-02
EP0329718A1 (de) 1989-08-30
NO168241B (no) 1991-10-21
PT88324A (pt) 1989-06-30
JPH02501138A (ja) 1990-04-19
ES2008004A6 (es) 1989-07-01
FI891759A0 (fi) 1989-04-13
JO1564B1 (en) 1989-12-16
AR246937A1 (es) 1994-10-31
CN1032778A (zh) 1989-05-10
DK172188B1 (da) 1997-12-22
IL87269A0 (en) 1989-01-31
ZA884982B (en) 1989-03-29
IN168235B (es) 1991-02-23
DE3867623D1 (de) 1992-02-20
GR880100322A (el) 1989-05-25
CA1306112C (en) 1992-08-11
NO891720L (no) 1989-04-26
NO891720D0 (no) 1989-04-26
PT88324B (pt) 1993-09-30
SG85592G (en) 1992-12-24
AU1781788A (en) 1989-03-31
IL87469A0 (en) 1989-01-31
PH23604A (en) 1989-09-11
KR890701505A (ko) 1989-12-20
DK160989A (da) 1989-04-24

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