EP0329718B1 - Pyrotechnische mischung zur erzeugung eines tarnnebels - Google Patents
Pyrotechnische mischung zur erzeugung eines tarnnebels Download PDFInfo
- Publication number
- EP0329718B1 EP0329718B1 EP88904505A EP88904505A EP0329718B1 EP 0329718 B1 EP0329718 B1 EP 0329718B1 EP 88904505 A EP88904505 A EP 88904505A EP 88904505 A EP88904505 A EP 88904505A EP 0329718 B1 EP0329718 B1 EP 0329718B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbonate
- potassium
- composition
- mixture
- fog
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
- C06B33/14—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds at least one being an inorganic nitrogen-oxygen salt
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/04—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic nitrogen-oxygen salt
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D3/00—Generation of smoke or mist (chemical part)
Definitions
- the invention relates to a pyrotechnic mixture for producing a camouflage mist.
- Hygroscopic compounds such as metal chlorides (ZnCl2, FeCl3, AlCl3, TiCl4, SiCl4) or phosphorus oxides P2O3, P2O5) are generated and evaporated, which then hydrolyze with the air and form suitable clouds of fog.
- ZnCl2, FeCl3, AlCl3, TiCl4, SiCl4 or phosphorus oxides P2O3, P2O5 are generated and evaporated, which then hydrolyze with the air and form suitable clouds of fog.
- mist formed especially from so-called HC mist sets containing hexachloroethane, but also from phosphor mist sets, is extremely acidic due to hydrolysis in humid air, since hydrochloric acid (HG mist) and phosphoric acids are formed, and therefore toxic and plant-intolerant.
- the heavy metal zinc is introduced into the environment in the most commonly used fog mixture based on hexachloroethane (HC) and zinc or zinc oxide.
- the object of the invention is therefore to produce a camouflage mist which is particularly suitable for training purposes and which consists of a non-toxic aerosol, which therefore cannot have a toxic effect on humans and animals, and on the other hand is environmentally compatible.
- the mist mainly consists of macronutrients suitable for plants.
- a non-toxic mist of sufficient optical density is formed by the invention.
- the fog is formed in the following way:
- the components magnesium powder, potassium nitrate and potassium perchlorate already produce fog-like clouds when converted in the range of 2500 °.
- the fog density is particularly characterized by the proportion of potassium chloride and / or sodium chloride, whose sublimation point at 1500 or boiling point at 1450 ° C are far below the reaction temperature of the reaction of magnesium and potassium nitrate.
- the reaction products of the chemical conversion from magnesium with potassium nitrate, potassium perchlorate, calcium carbonate etc. form a useful training fog with the subliming potassium chloride or the evaporating sodium chloride without toxic or environmentally incompatible ingredients.
- the energy (E) released in the three basic conversions mentioned is used for sublimation / evaporation of potassium chloride and sodium chloride.
- nitrogen-releasing substances such as azodicarbonamide, oxamide or dicyandiamide are added to the mixture. This results in a continuous gas flow for better transport of the aerosol particles and a higher aerosol yield, since the permanently formed gases prevent the slag from flowing together and promote sublimation and evaporation by increasing the surface area.
- a pure white aerosol which mainly consists of the components potassium chloride, magnesium oxide, calcium hydroxide, calcium carbonate, sodium chloride and potassium carbonate. These components are environmentally friendly and non-toxic and apart from NaCl macronutrients for plants.
- the pH of the generated fog is highest at the point of origin (9).
- chemical reactions of the primary oxides K2O and CaO (equations 1, 3) with components of the air, especially H2O and CO2 to form KHCO3, K2CO3, Ca (OH) 2 and CaCO3 and by dilution it quickly decreases and reaches the pH of the ambient air ( ⁇ 6) at a distance of 5-10 m from the fog source.
- a pyrotechnic mixture with the same components as the mixture for producing the camouflage mist can be used as the ignition mixture, but in which the content of magnesium and oxidizing agent is increased to increase the sensitivity to ignition and transmission reliability.
- the primer can e.g. consist of the following proportions: 25% Mg, 35% KNO3, 10% KClO4, 20% CaCO3, 10% KCl.
- mist set and the primer are pressed into sleeves in a manner known per se and reacted with conventional igniters.
- the drawing shows an embodiment of a mist body with the new mixture.
- a sleeve 1 with bottom 3 there is the compressed mixture 4, which carries the ignition mixture 5 pressed on with it as a conclusion.
- the embodiment of the drawing has a recess 6 for the use of an igniter known per se.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Combustion & Propulsion (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Air Bags (AREA)
- Fire-Extinguishing Compositions (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Road Signs Or Road Markings (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Pyridine Compounds (AREA)
- Cosmetics (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88904505T ATE71351T1 (de) | 1987-08-26 | 1988-05-05 | Pyrotechnische mischung zur erzeugung eines tarnnebels. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3728380A DE3728380C1 (de) | 1987-08-26 | 1987-08-26 | Pyrotechnische Mischung zur Erzeugung eines Tarnnebels und Anzuendmischung hierfuer |
DE3728380 | 1987-08-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0329718A1 EP0329718A1 (de) | 1989-08-30 |
EP0329718B1 true EP0329718B1 (de) | 1992-01-08 |
Family
ID=6334469
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88904505A Expired - Lifetime EP0329718B1 (de) | 1987-08-26 | 1988-05-05 | Pyrotechnische mischung zur erzeugung eines tarnnebels |
Country Status (24)
Country | Link |
---|---|
US (1) | US4968365A (es) |
EP (1) | EP0329718B1 (es) |
JP (1) | JPH02501138A (es) |
KR (1) | KR890701505A (es) |
CN (1) | CN1032778A (es) |
AR (1) | AR246937A1 (es) |
AT (1) | ATE71351T1 (es) |
AU (1) | AU600141B2 (es) |
CA (1) | CA1306112C (es) |
DE (2) | DE3728380C1 (es) |
DK (1) | DK172188B1 (es) |
ES (1) | ES2008004A6 (es) |
FI (1) | FI891759A0 (es) |
GR (1) | GR880100322A (es) |
IL (2) | IL87269A0 (es) |
IN (1) | IN168235B (es) |
JO (1) | JO1564B1 (es) |
NO (1) | NO168241C (es) |
NZ (1) | NZ225919A (es) |
PH (1) | PH23604A (es) |
PT (1) | PT88324B (es) |
SG (1) | SG85592G (es) |
WO (1) | WO1989001926A1 (es) |
ZA (1) | ZA884982B (es) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011042114A1 (de) * | 2009-10-09 | 2011-04-14 | Rheinmetall Waffe Munition Gmbh | Kunststoffgebundene pyrotechnische mischung zur erzeugung von alkalimetall-chlorid- bzw. erdalkalimetallchlorid-aerosolen als tarnnebel |
DE102012024809A1 (de) | 2012-12-19 | 2014-06-26 | Rheinmetall Waffe Munition Gmbh | Pyrotechnische Mischung zur Erzeugung eines Aerosols |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8820660D0 (en) * | 1988-09-01 | 1988-11-16 | Astra Holdings Plc | Smoke producing article |
US4997497A (en) * | 1990-04-05 | 1991-03-05 | Rockwell International Corporation | Castable smoke-producing pyrotechnic compositions |
US6051087A (en) * | 1992-01-29 | 2000-04-18 | Cordant Technologies Inc. | Low smoke rocket motor liner compositions |
AU682682B2 (en) * | 1993-02-16 | 1997-10-16 | Spectrex Inc. | Fire extinguishing methods and systems |
CN1060149C (zh) * | 1993-03-30 | 2001-01-03 | 陈锦铭 | 硝酸铵发烟罐及其制造方法 |
NL1005529C2 (nl) * | 1997-03-13 | 1998-09-15 | Tno | Samenstelling voor het genereren van rook. |
DE102008010942B4 (de) | 2008-02-25 | 2012-09-27 | Rheinmetall Waffe Munition Gmbh | Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels |
CN101624320B (zh) * | 2008-07-13 | 2012-11-14 | 周健 | 舞台快速黄色烟雾剂及其制备方法 |
RU2460711C1 (ru) * | 2011-03-29 | 2012-09-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВПО "КНИТУ") | Пиротехнический состав цветного огня |
US20120267016A1 (en) * | 2011-04-19 | 2012-10-25 | Lombardi John L | Nontoxic Obscurant Compositions and Method of Using Same |
GB201200829D0 (en) * | 2012-01-18 | 2012-02-29 | Albertelli Aldino | Fire suppression system |
WO2014175982A1 (en) * | 2013-03-21 | 2014-10-30 | Kms Consulting, Llc | Training ammunition cartridge with a gaseous plume signature |
JP6404603B2 (ja) * | 2014-06-11 | 2018-10-10 | 株式会社ダイセル | 煙幕発生器およびその使用方法 |
JP6334298B2 (ja) * | 2014-07-04 | 2018-05-30 | 株式会社ダイセル | 煙幕発生装置 |
CN107666842A (zh) | 2015-06-03 | 2018-02-06 | 爱格升公司 | 具有隐藏提升机构的高度可调节装置 |
US10519074B2 (en) | 2016-09-20 | 2019-12-31 | Goodrich Corporation | Obscurant emission systems and methods |
CN106495971A (zh) * | 2016-10-13 | 2017-03-15 | 湖南荣晖实业有限公司 | 无硫开苞药 |
CN107021865A (zh) * | 2017-05-26 | 2017-08-08 | 北京理工大学 | 可干扰可见光、红外及毫米波的宽频段烟幕材料 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR339233A (fr) * | 1903-12-23 | 1905-01-26 | Cyanidgesellschaft Mit Beschra | Nouveau procédé pour l'obtention d'explosifs |
US1461646A (en) * | 1919-01-14 | 1923-07-10 | Nat Carbon Co Inc | Material for producing smoke screens |
DE803645C (de) * | 1949-10-11 | 1951-04-05 | Dynamit Act Ges Vormals Alfred | Schagwettersichere Sprengkapsel in Verbindung mit elektrischen Zuendern |
US2995526A (en) * | 1951-07-27 | 1961-08-08 | Ment Jack De | Composition for smoke production |
DE918196C (de) * | 1952-12-23 | 1954-09-20 | J G W Berckholtz Fa | Masse zur Erzeugung von farbigem Rauch |
US4484195A (en) * | 1960-06-10 | 1984-11-20 | The United States Of America As Represented By The Secretary Of The Army | Method of screening infra-red radiation |
US3274035A (en) * | 1964-06-15 | 1966-09-20 | Lohr A Burkardt | Metallic composition for production of hygroscopic smoke |
US3862866A (en) * | 1971-08-02 | 1975-01-28 | Specialty Products Dev Corp | Gas generator composition and method |
DE2743363C3 (de) * | 1977-09-27 | 1980-06-19 | Nico-Pyrotechnik Hanns-Juergen Diederichs Kg, 2077 Trittau | Nebelsatz und Verfahren zur Herstellung desselben |
DE2841815C2 (de) * | 1978-09-26 | 1985-02-21 | Buck Chemisch-Technische Werke GmbH & Co, 7347 Bad Überkingen | Verfahren zur Herstellung einer Geschoßfüllung |
DE3031369C2 (de) * | 1980-08-20 | 1987-01-02 | Pyrotechnische Fabrik F. Feistel GmbH + Co KG, 6719 Göllheim | Pyrotechnische Ladung aus Nebelsatz und Anzündsatz und Verfahren zur Herstellung der Nebelmischung und des Anzündsatzes |
DE3104464C2 (de) * | 1981-02-09 | 1983-01-13 | Buck Chemisch-Technische Werke GmbH & Co, 7341 Bad Überkingen | Verfahren zum Herstellen eines Nebelsatzes sowie Nebeltopf mit darin untergebrachtem Nebelsatz |
US4438700A (en) * | 1982-07-19 | 1984-03-27 | The United States Of America As Represented By The Secretary Of The Army | White smoke spotting composition for training ammunition |
FR2560186B1 (fr) * | 1982-07-27 | 1987-06-05 | France Etat Armement | Composition pyrotechnique generatrice de fumee opaque au rayonnement infrarouge et munition fumigene obtenue |
FR2560371B1 (fr) * | 1982-07-27 | 1989-03-31 | France Etat Armement | Procede d'occultation des rayonnements visible et infrarouge et munition fumigene mettant en oeuvre ce procede |
FR2583037B1 (fr) * | 1985-06-07 | 1987-11-13 | France Etat Armement | Compositions fumigenes coulables efficaces dans l'infrarouge |
USH705H (en) * | 1985-10-09 | 1989-11-07 | Process for making smoke producing composition | |
USH232H (en) * | 1986-08-26 | 1987-03-03 | The United States Of America As Represented By The Secretary Of The Army | Smoke-producing composition |
USH233H (en) * | 1986-08-29 | 1987-03-03 | The United States Of America As Represented By The Secretary Of The Army | Smoke producing composition |
US4841865A (en) * | 1987-06-17 | 1989-06-27 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Smoke composition and method of making same |
-
1987
- 1987-08-26 DE DE3728380A patent/DE3728380C1/de not_active Expired
-
1988
- 1988-04-29 PH PH36865A patent/PH23604A/en unknown
- 1988-05-05 WO PCT/EP1988/000378 patent/WO1989001926A1/de active IP Right Grant
- 1988-05-05 US US07/350,737 patent/US4968365A/en not_active Expired - Lifetime
- 1988-05-05 DE DE8888904505T patent/DE3867623D1/de not_active Expired - Lifetime
- 1988-05-05 EP EP88904505A patent/EP0329718B1/de not_active Expired - Lifetime
- 1988-05-05 JP JP63504291A patent/JPH02501138A/ja active Pending
- 1988-05-05 AU AU17817/88A patent/AU600141B2/en not_active Ceased
- 1988-05-05 AT AT88904505T patent/ATE71351T1/de not_active IP Right Cessation
- 1988-05-05 KR KR1019890700749A patent/KR890701505A/ko not_active Application Discontinuation
- 1988-05-17 GR GR880100322A patent/GR880100322A/el unknown
- 1988-05-23 IN IN405/CAL/88A patent/IN168235B/en unknown
- 1988-07-11 ZA ZA884982A patent/ZA884982B/xx unknown
- 1988-07-29 IL IL87269A patent/IL87269A0/xx unknown
- 1988-08-12 AR AR88311652A patent/AR246937A1/es active
- 1988-08-16 IL IL87469A patent/IL87469A0/xx unknown
- 1988-08-20 CN CN88106145A patent/CN1032778A/zh active Pending
- 1988-08-22 JO JO19881564A patent/JO1564B1/en active
- 1988-08-23 PT PT88324A patent/PT88324B/pt not_active IP Right Cessation
- 1988-08-23 ES ES8802611A patent/ES2008004A6/es not_active Expired
- 1988-08-24 NZ NZ225919A patent/NZ225919A/en unknown
- 1988-08-25 CA CA000575671A patent/CA1306112C/en not_active Expired - Lifetime
-
1989
- 1989-04-03 DK DK160989A patent/DK172188B1/da not_active IP Right Cessation
- 1989-04-13 FI FI891759A patent/FI891759A0/fi not_active IP Right Cessation
- 1989-04-26 NO NO891720A patent/NO168241C/no not_active IP Right Cessation
-
1992
- 1992-08-24 SG SG855/92A patent/SG85592G/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011042114A1 (de) * | 2009-10-09 | 2011-04-14 | Rheinmetall Waffe Munition Gmbh | Kunststoffgebundene pyrotechnische mischung zur erzeugung von alkalimetall-chlorid- bzw. erdalkalimetallchlorid-aerosolen als tarnnebel |
DE102012024809A1 (de) | 2012-12-19 | 2014-06-26 | Rheinmetall Waffe Munition Gmbh | Pyrotechnische Mischung zur Erzeugung eines Aerosols |
Also Published As
Publication number | Publication date |
---|---|
FI891759A (fi) | 1989-04-13 |
DK160989D0 (da) | 1989-04-03 |
WO1989001926A1 (en) | 1989-03-09 |
DE3728380C1 (de) | 1988-11-24 |
ATE71351T1 (de) | 1992-01-15 |
US4968365A (en) | 1990-11-06 |
NZ225919A (en) | 1991-03-26 |
NO168241C (no) | 1992-01-29 |
AU600141B2 (en) | 1990-08-02 |
EP0329718A1 (de) | 1989-08-30 |
NO168241B (no) | 1991-10-21 |
PT88324A (pt) | 1989-06-30 |
JPH02501138A (ja) | 1990-04-19 |
ES2008004A6 (es) | 1989-07-01 |
FI891759A0 (fi) | 1989-04-13 |
JO1564B1 (en) | 1989-12-16 |
AR246937A1 (es) | 1994-10-31 |
CN1032778A (zh) | 1989-05-10 |
DK172188B1 (da) | 1997-12-22 |
IL87269A0 (en) | 1989-01-31 |
ZA884982B (en) | 1989-03-29 |
IN168235B (es) | 1991-02-23 |
DE3867623D1 (de) | 1992-02-20 |
GR880100322A (el) | 1989-05-25 |
CA1306112C (en) | 1992-08-11 |
NO891720L (no) | 1989-04-26 |
NO891720D0 (no) | 1989-04-26 |
PT88324B (pt) | 1993-09-30 |
SG85592G (en) | 1992-12-24 |
AU1781788A (en) | 1989-03-31 |
IL87469A0 (en) | 1989-01-31 |
PH23604A (en) | 1989-09-11 |
KR890701505A (ko) | 1989-12-20 |
DK160989A (da) | 1989-04-24 |
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