EP0326817B1 - Anlage zum Verschwelen von Abfallstoffen - Google Patents
Anlage zum Verschwelen von Abfallstoffen Download PDFInfo
- Publication number
- EP0326817B1 EP0326817B1 EP89100361A EP89100361A EP0326817B1 EP 0326817 B1 EP0326817 B1 EP 0326817B1 EP 89100361 A EP89100361 A EP 89100361A EP 89100361 A EP89100361 A EP 89100361A EP 0326817 B1 EP0326817 B1 EP 0326817B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- carbonisation
- gases
- temperature
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002699 waste material Substances 0.000 title claims description 7
- 238000009434 installation Methods 0.000 title claims 2
- 238000010000 carbonizing Methods 0.000 title 1
- 239000007789 gas Substances 0.000 claims description 45
- 238000002485 combustion reaction Methods 0.000 claims description 11
- 238000003763 carbonization Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 8
- 230000001105 regulatory effect Effects 0.000 claims 2
- 239000003344 environmental pollutant Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000571 coke Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000013502 plastic waste Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23M—CASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
- F23M5/00—Casings; Linings; Walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0273—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using indirect heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/48—Preventing corrosion
Definitions
- the invention relates to a plant for charring waste materials according to the preamble of the claim.
- Waste materials in the sense of the invention are to be understood as household and industrial waste as well as chemical residues which develop pollutants or gases, such as various types of dioxins, furans, CO etc.
- An afterburning chamber is connected downstream of a rotary kiln. In this combustion chamber there is a temperature between 1200 - 1400 ° C as well as a gas speed of 2 - 4 m / sec.
- an afterburning chamber behind a combustion furnace of a chemical waste incinerator is known. The burners of the afterburning chamber used are concentrated on a certain chamber area.
- the discharge device for residues from the smoldering drum has a stair grate provided with a combustion device with a subsequent afterburning chamber and a heat recovery system, preferably one Waste heat boiler with steam drum is connected downstream.
- the combustion or smoldering gases enter the afterburning chamber as a heat-emitting medium. This is also the case with the system according to the invention. If necessary, additional fuels from another source of the combustion chamber can also be added.
- DE-A-3 504 810 discloses a process for the thermal conversion of dioxin, in which a coke battery is connected in parallel to a pyrolysis plant and the coke battery and the plant release their gas to an afterburner (3 in the drawing), where obviously the coke gas is used to burn the dioxin above 1200 ° C.
- plastic waste is preheated in a rotary kiln for the purpose of splitting off hydrogen chloride.
- the plastic waste is then burned on the grate of an incinerator.
- the combustion gas from the furnace is then cooled with water and the fly ash is removed. The gas then escapes through a chimney.
- the air for indirect preheating of the plastic waste in the rotary kiln is heated in an air heater, which is located in the flue gas chimney of the incinerator, and is circulated to the air jacket of the rotary kiln.
- the object of the invention is to keep the heating device of the carbonization system completely or largely free of corrosion, and also to enable the conversion of environmentally harmful gases in the afterburning chamber to those with a low pollutant content, which can be done with simple design means should be achieved.
- the invention provides the features of the characterizing part of the patent claim.
- the system according to the invention ensures that the pollutant-laden gases entering the afterburner chamber at a temperature of approximately 1400 ° C. are kept at a temperature of 1200 ° C. and above for a residence time of 1.0-5.0 seconds, preferably 2 seconds , so that this conversion into a gas with a low pollutant content can take place during this time. Furthermore, there is the advantage that the heat extracted from the gas of the afterburning chamber benefits the smoldering process in that the gas heating the smoldering device is heated in the heat exchanger of the afterburning chamber, and this in a closed circuit between the smoldering device and the heat exchanger of the afterburner, so that corrosion in the parts of this circuit is avoided.
- a smoldering drum is used as the smoldering device 1, to which the material to be smoldered is fed via a screw 2, the smoldered material leaving the smoldering drum in the direction of arrow 3.
- the heating gas required for the smoldering process reaches the drum via the feed 4 and is discharged via the line 5.
- the afterburning chamber 8 which is preferably arranged upright, is assigned to the smoldering device 1 via the lines 6, 7.
- the pollutant-laden burner gases pass into it from the carbonization drum in the direction of arrow 9 into the afterburning chamber through the nozzle 10 in the direction of arrow 11.
- a heat exchanger provided with the general reference number 12 is arranged in the upper region of the afterburning chamber 8.
- this line 7 opens and leads the heat exchanger from the smoldering device 1 recycle gas, preferably an inert gas or the like, and leaves this gas via line 6 again come to the smoldering drum 1, so that a closed circuit via the smoldering device, the lines 6 and 7 and the heat exchanger 12 is given.
- recycle gas preferably an inert gas or the like
- the gases of the afterburning chamber 8 enter in the direction of arrow 9 at a temperature of 1400 ° C. in the upper section 12a of the heat exchanger 12. They have a flow rate of about 2-4 m / sec, so that, taking into account the diameter of the heat exchanger 12, the gases have a residence time of 1-5 sec, preferably 2 sec, in the afterburning chamber.
- the length or height L of the exchanger 12 is chosen such that the given residence time of 1-5 seconds within the heat exchanger is ensured at the given speed of the gases in the afterburner chamber. It is immaterial whether the temperature of the gas has already dropped to 1200 ° C over a height L 1, the only important thing is that the residence time of 1.0-5.0 seconds, preferably 2 seconds, is maintained.
- the length L of the heat exchanger, on the one hand, or the flow rate of the gases in the afterburner chamber within the heat exchanger area, on the other hand, is selected so that the above-mentioned parameters (residence time and temperature) are observed. It is during this time that environmentally harmful gases are converted into gases with a low pollutant content.
- Temperature measuring devices 14 can be provided, the lowest of which Temperature measuring device 14a is arranged at the outlet of the burned gases 12b of the heat exchanger 12.
- the heat exchanger itself is designed as a cylindrical ring part with an outer wall 15 and an inner wall 16, the inner wall 16 having a lining 17. Aggressive components of the post-combustion chamber gases can run downwards there.
- a bypass line 19 with a control valve 20 is provided. This is preferably connected to the temperature measuring device 14a via a control line 21. If the temperature measuring device 14a recognizes that the temperature in the outlet of the burned gases 12b falls below 1200 ° C., the valve 20 controls a part of the approximately 750 ° C.
- the temperature in the inlet connection 22 of the heat exchanger 8 is increased, so that a temperature of 1200 ° C. is ultimately also maintained in the lower section 12b of the heat exchanger 12. It can thus be ensured by the control via the bypass 19 and the valve 20 that in any case over the length L of the heat exchanger 12 with a residence time of the temperature of 1200 ° C. and more is preferably maintained for 2 seconds in order to convert the environmentally harmful gases into low-emission gases.
- the low-pollutant gases leave the afterburning chamber via line 11 and can be used in a downstream superheater 23.
- the material and the thickness of the lining, which is preferably locked on the inner wall, must be selected accordingly.
- the bypass 19 serves with its control option.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Incineration Of Waste (AREA)
- Gasification And Melting Of Waste (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3803096 | 1988-02-03 | ||
DE3803096 | 1988-02-03 | ||
DE3804853A DE3804853A1 (de) | 1988-02-03 | 1988-02-17 | Anlage zum verschwelen von abfallstoffen |
DE3804853 | 1988-02-17 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0326817A2 EP0326817A2 (de) | 1989-08-09 |
EP0326817A3 EP0326817A3 (en) | 1990-06-27 |
EP0326817B1 true EP0326817B1 (de) | 1992-12-02 |
Family
ID=25864494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89100361A Expired - Lifetime EP0326817B1 (de) | 1988-02-03 | 1989-01-11 | Anlage zum Verschwelen von Abfallstoffen |
Country Status (4)
Country | Link |
---|---|
US (1) | US4913064A (ru) |
EP (1) | EP0326817B1 (ru) |
DE (2) | DE3804853A1 (ru) |
UA (1) | UA13104A (ru) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19528018B4 (de) * | 1995-07-31 | 2005-12-15 | Eisenmann Maschinenbau Gmbh & Co. Kg | Anlage für die thermische Behandlung von organische Bestandteile aufweisenden Materialien zur thermischen Entsorgung von Abfallstoffen, Haus-, Industrie- und/oder Sondermüll, chemischen Rückständen und/oder dergleichen |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3815187A1 (de) * | 1988-05-04 | 1989-11-16 | Siemens Ag | Temperaturgeregelte anlage zur thermischen abfallentsorgung |
CN110801724B (zh) * | 2019-11-14 | 2023-12-19 | 西安交通大学 | 一种具有腐蚀防控功能的烟气污染物脱除系统 |
CN111807671A (zh) * | 2020-06-15 | 2020-10-23 | 上海市政工程设计研究总院(集团)有限公司 | 一种污泥焚烧与碳化协同处理的系统 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2026970A1 (de) * | 1969-10-03 | 1971-04-22 | Tvtr Meissner, W , Dipl Ing , Tischer, H , Dipl Ing, Pat Anwalte, 1000 Berlin und 8000 München | Verfahren und Vorrichtung zum Verbrennen von Kunststoff Abfallen |
US3749030A (en) * | 1971-11-08 | 1973-07-31 | Wasteco Inc | Heating and exhaust emission control system and method for material dryers |
US3818869A (en) * | 1973-01-02 | 1974-06-25 | Combustion Eng | Method of operating a combined gasification-steam generating plant |
GB1562492A (en) * | 1976-08-02 | 1980-03-12 | Foster Wheeler Power Prod | Pyrolysis of waste |
DE3504810A1 (de) * | 1985-02-13 | 1986-08-14 | Hoelter Heinz | Verfahren zur thermischen umsetzung von dioxin |
US4676177A (en) * | 1985-10-09 | 1987-06-30 | A. Ahlstrom Corporation | Method of generating energy from low-grade alkaline fuels |
US4656955A (en) * | 1986-05-01 | 1987-04-14 | Kuo Tsung H | Refuse incineration system |
US4746290A (en) * | 1986-05-29 | 1988-05-24 | International Technolgy Corporation | Method and apparatus for treating waste containing organic contaminants |
DE3625397A1 (de) * | 1986-07-26 | 1988-02-04 | Gutehoffnungshuette Man | Nachbrennkammer hinter einem verbrennungsofen einer verbrennungseinrichtung fuer chemischen abfall |
DE3633212A1 (de) * | 1986-09-30 | 1988-04-14 | Kwu Umwelttechnik Gmbh | Pyrolyseanlage |
DE3730339A1 (de) * | 1987-09-10 | 1989-03-30 | Voith Gmbh J M | Mehrstufiges wechselgetriebe |
ATE68814T1 (de) * | 1988-05-04 | 1991-11-15 | Siemens Ag | Anlage zur entsorgung von abfallstoffen. |
-
1988
- 1988-02-17 DE DE3804853A patent/DE3804853A1/de active Granted
-
1989
- 1989-01-11 EP EP89100361A patent/EP0326817B1/de not_active Expired - Lifetime
- 1989-01-11 DE DE8989100361T patent/DE58902837D1/de not_active Expired - Fee Related
- 1989-01-31 UA UA4613339A patent/UA13104A/ru unknown
- 1989-02-01 US US07/305,279 patent/US4913064A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19528018B4 (de) * | 1995-07-31 | 2005-12-15 | Eisenmann Maschinenbau Gmbh & Co. Kg | Anlage für die thermische Behandlung von organische Bestandteile aufweisenden Materialien zur thermischen Entsorgung von Abfallstoffen, Haus-, Industrie- und/oder Sondermüll, chemischen Rückständen und/oder dergleichen |
Also Published As
Publication number | Publication date |
---|---|
US4913064A (en) | 1990-04-03 |
DE58902837D1 (de) | 1993-01-14 |
EP0326817A2 (de) | 1989-08-09 |
EP0326817A3 (en) | 1990-06-27 |
DE3804853A1 (de) | 1989-08-17 |
DE3804853C2 (ru) | 1990-05-03 |
UA13104A (ru) | 1997-02-28 |
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