EP0154367A3 - Process for phosphatizing metals - Google Patents
Process for phosphatizing metals Download PDFInfo
- Publication number
- EP0154367A3 EP0154367A3 EP85200192A EP85200192A EP0154367A3 EP 0154367 A3 EP0154367 A3 EP 0154367A3 EP 85200192 A EP85200192 A EP 85200192A EP 85200192 A EP85200192 A EP 85200192A EP 0154367 A3 EP0154367 A3 EP 0154367A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- phosphatizing
- metals
- coatings
- phosphatizing metals
- ethylenediamenetetraacetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/23—Condensed phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Electrolytic Production Of Metals (AREA)
- Paints Or Removers (AREA)
- Secondary Cells (AREA)
- Materials For Medical Uses (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Glass Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT85200192T ATE37203T1 (de) | 1984-03-09 | 1985-02-15 | Verfahren zur phosphatierung von metallen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3408577 | 1984-03-09 | ||
| DE19843408577 DE3408577A1 (de) | 1984-03-09 | 1984-03-09 | Verfahren zur phosphatierung von metallen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0154367A2 EP0154367A2 (de) | 1985-09-11 |
| EP0154367A3 true EP0154367A3 (en) | 1986-08-20 |
| EP0154367B1 EP0154367B1 (de) | 1988-09-14 |
Family
ID=6229954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP85200192A Expired EP0154367B1 (de) | 1984-03-09 | 1985-02-15 | Verfahren zur Phosphatierung von Metallen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4637838A (de) |
| EP (1) | EP0154367B1 (de) |
| CN (1) | CN85101297A (de) |
| AT (1) | ATE37203T1 (de) |
| AU (1) | AU575380B2 (de) |
| CA (1) | CA1224121A (de) |
| DE (2) | DE3408577A1 (de) |
| ES (1) | ES8602152A1 (de) |
| GB (1) | GB2155960A (de) |
| ZA (1) | ZA851761B (de) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8527833D0 (en) * | 1985-11-12 | 1985-12-18 | Pyrene Chemicals Services Ltd | Phosphate coating of metals |
| DE3630246A1 (de) * | 1986-09-05 | 1988-03-10 | Metallgesellschaft Ag | Verfahren zur erzeugung von phosphatueberzuegen sowie dessen anwendung |
| EP0304108B1 (de) * | 1987-08-19 | 1992-05-13 | Metallgesellschaft Ag | Verfahren zur Phosphatierung von Metallen |
| JPH01100281A (ja) * | 1987-10-13 | 1989-04-18 | Nippon Parkerizing Co Ltd | 金属表面の皮膜化成処理液 |
| JPH0730455B2 (ja) * | 1988-09-27 | 1995-04-05 | 日本パーカライジング株式会社 | リン酸塩化成処理液 |
| JP2781844B2 (ja) * | 1988-10-20 | 1998-07-30 | 日本ペイント株式会社 | 塗装用下地処理剤 |
| JP2636919B2 (ja) * | 1989-01-26 | 1997-08-06 | 日本パーカライジング株式会社 | 鉄鋼の冷間塑性加工用潤滑処理方法 |
| DE3916498A1 (de) * | 1989-05-20 | 1990-11-22 | Kolbenschmidt Ag | Verfahren zum aufbringen einer phosphat-laufschicht auf eine lagermetallschicht |
| US5143562A (en) * | 1991-11-01 | 1992-09-01 | Henkel Corporation | Broadly applicable phosphate conversion coating composition and process |
| DE4409306A1 (de) * | 1994-03-18 | 1995-09-21 | Basf Ag | Verfahren zur Modifizierung von Metalloberflächen |
| DE4417965A1 (de) * | 1994-05-21 | 1995-11-23 | Henkel Kgaa | Eisenphosphatierung unter Verwendung von substituierten Monocarbonsäuren |
| RU2123067C1 (ru) * | 1997-06-11 | 1998-12-10 | Акционерное общество "ФК" | Раствор для фосфатирования стальных поверхностей |
| US6716192B1 (en) * | 1997-09-30 | 2004-04-06 | Charles F. Schroeder | Medical needle having a visibly marked tip |
| RU2160324C1 (ru) * | 1999-03-11 | 2000-12-10 | Закрытое акционерное общество "Мультисервис" | Состав для защиты от коррозии металлических поверхностей из черных металлов |
| US6551417B1 (en) | 2000-09-20 | 2003-04-22 | Ge Betz, Inc. | Tri-cation zinc phosphate conversion coating and process of making the same |
| DE102005047424A1 (de) * | 2005-09-30 | 2007-04-05 | Henkel Kgaa | Phosphatierlösung mit Wasserstoffperoxid und chelatbildenden Carbonsäuren |
| CN102839374A (zh) * | 2012-09-05 | 2012-12-26 | 业纮企业股份有限公司 | 球阀用碳钢球体表面处理方法 |
| CN103668149B (zh) * | 2013-12-19 | 2016-08-24 | 湖南金裕化工有限公司 | 常温快速磷化液及其制备方法 |
| CN103695881B (zh) * | 2013-12-19 | 2016-08-24 | 湖南金裕化工有限公司 | 常温无渣快速磷化液及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1086955A (fr) * | 1952-08-28 | 1955-02-17 | Parker Ste Continentale | Perfectionnements relatifs à l'enduisage des métaux |
| EP0015021A1 (de) * | 1979-02-23 | 1980-09-03 | Metallgesellschaft Ag | Verfahren zur Vorbereitung von Metalloberflächen für die elektrophoretische Tauchlackierung |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2884351A (en) * | 1956-01-25 | 1959-04-28 | Parker Rust Proof Co | Method of cold rolling ferrous strip stock |
| GB865497A (en) * | 1958-10-03 | 1961-04-19 | Pyrene Co Ltd | Improvements relating to the cleaning and phosphate coating of metallic surfaces |
| GB1414484A (en) * | 1972-05-03 | 1975-11-19 | Pyrene Chemical Services Ltd | Treatment of zinc surfaces |
| SU800240A1 (ru) * | 1977-03-05 | 1981-01-30 | Научно-Исследовательский Институтхимии Саратовского Государственногоордена Трудового Красного Знамениуниверситета Им.H.Г.Чернышевского | Раствор дл фосфатировани кадми |
| GB1591039A (en) * | 1977-05-03 | 1981-06-10 | Pyrene Chemical Services Ltd | Processes and compositions for coating metal surfaces |
| JPS5811513B2 (ja) * | 1979-02-13 | 1983-03-03 | 日本ペイント株式会社 | 金属表面の保護方法 |
| GB2072225B (en) * | 1980-03-21 | 1983-11-02 | Pyrene Chemical Services Ltd | Process and composition for coating metal surfaces |
| DE3016576A1 (de) * | 1980-04-30 | 1981-11-05 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur phosphatierung von metalloberflaechen sowie dessen anwendung |
| DE3118375A1 (de) * | 1981-05-09 | 1982-11-25 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur phosphatierung von metallen sowie dessen anwendung zur vorbehandlung fuer die elektrotauchlackierung |
| US4498935A (en) * | 1981-07-13 | 1985-02-12 | Parker Chemical Company | Zinc phosphate conversion coating composition |
| US4486241A (en) * | 1981-09-17 | 1984-12-04 | Amchem Products, Inc. | Composition and process for treating steel |
| DE3311738A1 (de) * | 1983-03-31 | 1984-10-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur phosphatierung von metalloberflaechen |
-
1984
- 1984-03-09 DE DE19843408577 patent/DE3408577A1/de not_active Withdrawn
-
1985
- 1985-02-15 EP EP85200192A patent/EP0154367B1/de not_active Expired
- 1985-02-15 DE DE8585200192T patent/DE3564967D1/de not_active Expired
- 1985-02-15 AT AT85200192T patent/ATE37203T1/de not_active IP Right Cessation
- 1985-03-05 US US06/708,463 patent/US4637838A/en not_active Expired - Fee Related
- 1985-03-06 AU AU39574/85A patent/AU575380B2/en not_active Ceased
- 1985-03-07 CA CA000475958A patent/CA1224121A/en not_active Expired
- 1985-03-07 ES ES541015A patent/ES8602152A1/es not_active Expired
- 1985-03-08 GB GB08506049A patent/GB2155960A/en not_active Withdrawn
- 1985-03-08 ZA ZA851761A patent/ZA851761B/xx unknown
- 1985-04-01 CN CN198585101297A patent/CN85101297A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1086955A (fr) * | 1952-08-28 | 1955-02-17 | Parker Ste Continentale | Perfectionnements relatifs à l'enduisage des métaux |
| EP0015021A1 (de) * | 1979-02-23 | 1980-09-03 | Metallgesellschaft Ag | Verfahren zur Vorbereitung von Metalloberflächen für die elektrophoretische Tauchlackierung |
Non-Patent Citations (2)
| Title |
|---|
| CHEMICAL ABSTRACTS, Band 94, Nr. 22, Juni 1981, Seite 280, Nr. 179325a, Columbus, Ohio, US; & SU - A - 800 240 (SARATOV STATE UNIVERSITY) 23-01-1981 * |
| CHEMICAL ABSTRACTS, Band 99, Nr. 26, Dezember 1983, Seite 273, Nr. 216843u, Columbus, Ohio, US; & JP - A - 58 144 477 (NIPPON PAINT CO., LTD.) 27-08-1983 * |
Also Published As
| Publication number | Publication date |
|---|---|
| AU575380B2 (en) | 1988-07-28 |
| GB8506049D0 (en) | 1985-04-11 |
| CA1224121A (en) | 1987-07-14 |
| US4637838A (en) | 1987-01-20 |
| DE3564967D1 (en) | 1988-10-20 |
| DE3408577A1 (de) | 1985-09-12 |
| ZA851761B (en) | 1985-11-27 |
| EP0154367B1 (de) | 1988-09-14 |
| ES541015A0 (es) | 1985-12-01 |
| AU3957485A (en) | 1985-09-12 |
| ES8602152A1 (es) | 1985-12-01 |
| EP0154367A2 (de) | 1985-09-11 |
| ATE37203T1 (de) | 1988-09-15 |
| CN85101297A (zh) | 1987-01-24 |
| GB2155960A (en) | 1985-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3564967D1 (en) | Process for phosphatizing metals | |
| AU6205898A (en) | Process of treating metallic surfaces | |
| ES2116108T5 (es) | Procedimiento de produccion de un revestimiento anticorrosion, de fuerte adherencia; y piezas asi revestidas. | |
| ATE138112T1 (de) | Nickelfreie phosphatierverfahren | |
| ES8200408A2 (es) | Procedimiento para la formacion de un revestimiento de con- version de fosfato de cinc sobre una superficie metalica | |
| GB8515561D0 (en) | Anti-corrosion meal complex compositions | |
| GB1309356A (en) | Method for applying a primer paint coating | |
| IL92062A0 (en) | Continuous process for the manufacture of alkali metal perchlorate | |
| AU561151B2 (en) | Phosphating of zinc-plated metal | |
| AU581789B2 (en) | A process for phosphating electrolytically zinc-coated metal goods | |
| DE3568165D1 (en) | Adhesion promoters for metal substrates | |
| ES8606528A1 (es) | Procedimiento para el fosfatado de superficies metalicas, especialmente ferreas | |
| AU568186B2 (en) | Laidlomycin phenylcarbamate | |
| AU2671088A (en) | Method and apparatus for producing one-side electroplated steel strip with enhanced phosphatability | |
| AU548696B2 (en) | Pretreating galvanized metal | |
| ES447267A1 (es) | Procedimiento de fosfatacion de superficies metalicas. | |
| JPS55158276A (en) | Zinc electroplating method for high carbon steel | |
| YU133185A (en) | Process for obtaining sorbinyl and its intermediary | |
| UA6160A1 (uk) | Електроліт для осадження покриттів з тугоплавних металів і спосіб його приготування | |
| Rausch et al. | Process for Phosphating Metals | |
| ES430280A1 (es) | Procedimiento continuo en una sola operacion para el trata-miento de superficies metalicas de base. | |
| ES8606530A1 (es) | Un procedimiento para chapar un sustrato metalico | |
| JPS53147633A (en) | Additive for zinc electroplating | |
| RU2075227C1 (ru) | Способ фосфатирования металлической поверхности | |
| ES8302803A1 (es) | "un procedimiento para electrodepositar un revestimiento de niquel protector sobre una banda o chapa metalica". |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): AT BE CH DE FR IT LI NL SE |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE FR IT LI NL SE |
|
| 17P | Request for examination filed |
Effective date: 19861008 |
|
| 17Q | First examination report despatched |
Effective date: 19871030 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE FR IT LI NL SE |
|
| REF | Corresponds to: |
Ref document number: 37203 Country of ref document: AT Date of ref document: 19880915 Kind code of ref document: T |
|
| REF | Corresponds to: |
Ref document number: 3564967 Country of ref document: DE Date of ref document: 19881020 |
|
| ET | Fr: translation filed | ||
| ITF | It: translation for a ep patent filed | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19890228 Year of fee payment: 5 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed | ||
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Effective date: 19900901 |
|
| NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee | ||
| ITTA | It: last paid annual fee | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19910313 Year of fee payment: 7 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19911213 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19911217 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19920115 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19920226 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19920323 Year of fee payment: 8 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19921103 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Effective date: 19930215 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19930216 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Effective date: 19930228 Ref country code: CH Effective date: 19930228 Ref country code: BE Effective date: 19930228 |
|
| BERE | Be: lapsed |
Owner name: SOC. CONTINENTALE PARKER Effective date: 19930228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Effective date: 19931029 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
| EUG | Se: european patent has lapsed |
Ref document number: 85200192.4 Effective date: 19930912 |