EP0142082B1 - Verfahren und Einrichtung zum Feuerverzinken von Rippenrohren - Google Patents
Verfahren und Einrichtung zum Feuerverzinken von Rippenrohren Download PDFInfo
- Publication number
- EP0142082B1 EP0142082B1 EP84112869A EP84112869A EP0142082B1 EP 0142082 B1 EP0142082 B1 EP 0142082B1 EP 84112869 A EP84112869 A EP 84112869A EP 84112869 A EP84112869 A EP 84112869A EP 0142082 B1 EP0142082 B1 EP 0142082B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- blow
- facility
- zinc
- galvanising
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005246 galvanizing Methods 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 23
- 239000011701 zinc Substances 0.000 claims abstract description 23
- 238000011282 treatment Methods 0.000 claims abstract description 15
- 238000002844 melting Methods 0.000 claims abstract description 11
- 230000008018 melting Effects 0.000 claims abstract description 11
- 238000005238 degreasing Methods 0.000 claims abstract description 9
- 238000004532 chromating Methods 0.000 claims abstract description 8
- 230000001681 protective effect Effects 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000005192 partition Methods 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims abstract 8
- 238000007598 dipping method Methods 0.000 claims abstract 4
- 239000000956 alloy Substances 0.000 claims abstract 2
- 229910045601 alloy Inorganic materials 0.000 claims abstract 2
- 230000004907 flux Effects 0.000 description 8
- 239000007789 gas Substances 0.000 description 6
- 238000005554 pickling Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XEPNJJFNSJKTSO-UHFFFAOYSA-N azanium;zinc;chloride Chemical compound [NH4+].[Cl-].[Zn] XEPNJJFNSJKTSO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/38—Wires; Tubes
- C23C2/385—Tubes of specific length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
- B08B3/022—Cleaning travelling work
Definitions
- the invention relates to a system for hot-dip galvanizing finned tubes with system components arranged in line one behind the other at a treatment level, which are connected via an automatically operating transport device with horizontally and vertically attached support, guide and driving rollers or with a transport chain device in the preheating area.
- US-A-3 722 463 shows a further development of the system described in US-A-3 122 114 for the continuous production and galvanizing of smooth tubes.
- the individual smooth tubes are connected to form an endless tube.
- the pretreatment of the connected smooth tubes includes a flux treatment (zinc ammonium chloride) and subsequent drying at approx. 200 ° C.
- This procedure requires considerable exhaust air volumes with a large pollutant load in the galvanizing process due to the sublimation of the flux.
- Environmental protection-related requirements can only be met with a corresponding exhaust air detection and downstream cleaning system, with the overall system being considerably less economical.
- This known method and the device for the hot-dip galvanizing of pipes is only suitable for smooth pipes with the inclusion of a classic flux treatment and all the negative aspects resulting therefrom.
- the present invention includes a system for galvanizing finned tubes without the flux treatment necessary according to the aforementioned publication.
- the system according to the invention takes into account all specific requirements for hot-dip galvanizing the finned tube with variable handling of all relevant parameters and taking into account all requirements relevant to environmental protection.
- the finned tube essentially consists of an oval base tube (or other cross-sections) on which a sheet metal fin is endlessly wound diagonally in the winding process, the finned tube being significantly different from a smooth tube, not least because of the surface area increased by a factor of 40.
- Rib and base tube have no metallic connection and have considerable differences in material thickness. The division of the rib on the base tube is approx. 3 mm.
- the state of the art in hot-dip galvanizing finned tubes is immersion in a zinc melt with upstream degreasing, rinsing, pickling, rinsing and fluxing. These upstream treatments are individual separate processes, the finned tubes each in individual immersion baths containing the corresponding degreasing, rinsing, pickling or the like. B. be immersed by means of a crane. Cooling takes place after galvanizing in a water bath. Qualified immediate treatment of the finned tube after galvanizing is not possible.
- FR-A-2 181 863 and FR-A-2 323 772 systems for the continuous production of galvanized smooth pipes or for galvanizing smooth profiles are known, the system components mentioned in claim 1 in principle in FR-A -2 181 863 are described and the core of a system of this type, working under protective gas, with a preheating furnace and a galvanizing furnace is shown in principle in FR-A-2 323 772.
- the galvanizing furnace has no separate melting and charging areas which are separated by a partition.
- the advantages of the device according to the invention are, in particular, that it makes it possible to continuously pretreat finned tubes in closed treatment stages connected in quick succession without zinc galvanizing and aftertreatment, and thus in the optimal economical control of the zinc layer thickness with optimized technology the entire system, taking into account emission-relevant factors.
- the system for hot-dip galvanizing finned tubes consists essentially of loading device 1, degreasing device 2 with blow-off device, rinsing device 3 with blow-off device, pickling device 4 with blow-off device, rinsing device 5 with blow-off device, preheating furnace 6, galvanizing furnace 7 with blow-off, vibrating or stripping device, cooling and Drying device 8, chromating device 9 with blow-off device, removal device 10 and from a transport device, not shown.
- the finned tubes to be treated are automatically transported by means of the transport device consisting of support, guide and drive rollers or in the area of the preheating furnace from a transport chain device.
- the transport speed is infinitely variable.
- the finned tubes are fed manually via the loading device 1.
- the treatment media are applied in the degreasing 2, rinsing 3, pickling 4, rinsing 5, cooling 8 and chromating 9 treatment stages by means of nozzles (not shown) in the spraying process.
- the applied media are blown off after each special treatment in order to avoid or minimize discharge losses.
- the indirectly gas-heated preheating furnace 6 is composed of several furnace segments which are equipped with individual controls.
- the finned tubes are thus advantageously heated in a sliding manner from room temperature to the galvanizing temperature in the zinc bath of approximately 450-560 ° C.
- the entire system works in a protective gas atmosphere, which prevents oxidation of the finned tubes in the preheating furnace 6.
- Nitrogen with a hydrogen content of approximately 10% is preferably used as the inert gas.
- the finned tubes are galvanized in the galvanizing furnace 7, also in a protective gas atmosphere in the temperature range of approx. 450 - 560 ° C, free of emissions and residues.
- the finned tubes in the galvanizing furnace 7, which is formed with a zinc charging area 20 and a melting area 18 with a galvanizing pan 12, are flooded with zinc 19 by means of a zinc pump 16.
- the arrangement of the galvanizing pan 12 over the melting area 18 in the galvanizing furnace 7 largely prevents leakage losses of the protective gas atmosphere 17 at the operating level of the zinc alloy.
- the zinc 19 discharged from the galvanizing pan 12 with the finned tube is blown off vertically by means of a blow-off device 13 or a mechanical stripping or vibrating device . away. The occurrence of bridges between the finned tube fins and the formation of a drainage edge is effectively prevented.
- the temporary corrosion protection is provided by the chromating.
- the galvanizing furnace 7 has a refractory lining 11.
- a zinc collecting container 14 is arranged below the blow-off device 13.
- the device according to the invention allows the use of any zinc alloy. Flux treatment is also possible, which can be followed by rinsing step 5.
- the flux can be applied similar to the treatment medium in the stages degreasing 2, rinsing 3, pickling 4, rinsing 5, cooling 8 and chromating 9. In order to avoid loss of discharge, the applied flux is blown off.
- the finned tubes pretreated in this way are heated in the indirectly gas-heated preheating furnace 6, which is composed of several furnace segments with individual controls.
- the heating of the finned tubes in the preheating takes place in the case of flux treatment thus advantageously slide from room temperature to about 150 0 C.
- the entire system operates in a protective gas atmosphere, which prevents oxidation of the finned tubes in the preheating zone 6.
- Nitrogen is preferably used as the inert gas.
- the finned tubes are also galvanized in a protective gas atmosphere 17 in the temperature range of approx. 450 - 560 ° C.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating With Molten Metal (AREA)
- Chemically Coating (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Fire Alarms (AREA)
- Fire-Detection Mechanisms (AREA)
- Chemical Treatment Of Metals (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT84112869T ATE43646T1 (de) | 1983-11-11 | 1984-10-25 | Verfahren und einrichtung zum feuerverzinken von rippenrohren. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3340813 | 1983-11-11 | ||
DE3340813 | 1983-11-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0142082A2 EP0142082A2 (de) | 1985-05-22 |
EP0142082A3 EP0142082A3 (en) | 1985-08-21 |
EP0142082B1 true EP0142082B1 (de) | 1989-05-31 |
Family
ID=6214064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84112869A Expired EP0142082B1 (de) | 1983-11-11 | 1984-10-25 | Verfahren und Einrichtung zum Feuerverzinken von Rippenrohren |
Country Status (12)
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3720965A1 (de) * | 1987-06-25 | 1989-01-05 | Solms Juergen | Verfahren und vorrichtung zum kontinuierlichen feuerverzinken von langfoermigem verzinkungsgut |
DE3935146A1 (de) * | 1989-09-06 | 1991-03-21 | Wirtz Gmbh & Co | Verfahren und vorrichtung zum kontinuierlichen feuerverzinken von rippenrohren |
JPH04321895A (ja) * | 1991-04-19 | 1992-11-11 | Nichias Corp | 流体加熱管 |
DE4324924A1 (de) * | 1993-07-24 | 1995-01-26 | Leybold Durferrit Gmbh | Vorrichtung zum Reinigen und/oder zur Wärmebehandlung von Werkstücken, insbesondere von Profilbändern |
DE4325452A1 (de) * | 1993-07-29 | 1995-04-06 | Theodor Willecke | Verfahren und Vorrichtung zum Feuerverzinken von Eisenteilen |
ATE188260T1 (de) * | 1996-08-30 | 2000-01-15 | Balcke Duerr Gmbh | Verfahren zum feuerverzinken |
DE10320071A1 (de) * | 2003-05-05 | 2004-12-02 | Basf Ag | Alkoxygruppen aufweisende Ester von Phosphor-Sauerstoff-Säuren und ihre Verwendung als Korrosionsinhibitoren |
DE102016106617A1 (de) * | 2016-03-21 | 2017-09-21 | Fontaine Holdings Nv | Feuerverzinkungsanlage sowie Feuerverzinkungsverfahren |
CN112481570A (zh) * | 2019-09-12 | 2021-03-12 | 西藏中驰集团股份有限公司 | 一种新型镀锌工艺流程及其所用流水线 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2771056A (en) * | 1951-06-06 | 1956-11-20 | Selas Corp Of America | Apparatus for coating pipes |
US3639142A (en) * | 1968-06-10 | 1972-02-01 | Bethlehem Steel Corp | Method of galvanizing |
JPS5017420B1 (enrdf_load_stackoverflow) * | 1970-08-19 | 1975-06-20 | ||
US3673980A (en) * | 1970-10-30 | 1972-07-04 | Theodore H Krengel | Protective and supporting means for apparatus for continuously coating steel strip |
DE2105661A1 (en) * | 1971-02-05 | 1972-08-10 | Mandl J | Hot dip metal coating - with melt flow along workpiece surface |
US3845540A (en) * | 1972-04-28 | 1974-11-05 | Maneely Illinois | Hot galvanizing process and apparatus |
GB1433019A (en) * | 1973-06-26 | 1976-04-22 | Turner Lisle Ltd | Galvanizing plant |
DE2406939A1 (de) * | 1974-02-14 | 1975-09-04 | Friedrich Heck | Verfahren zum ueberziehen von rohren und stangen mit schmelzfluessigen metallen |
FR2323772A1 (fr) * | 1975-05-30 | 1977-04-08 | Delot Jose | Procede de revetement metallique en continu de profils metalliques rigides |
GB1532554A (en) * | 1976-02-10 | 1978-11-15 | Raymond A | Metallic coating of metal tubes and similar work pieces |
-
1984
- 1984-03-17 DE DE3409935A patent/DE3409935C1/de not_active Expired
- 1984-10-25 AT AT84112869T patent/ATE43646T1/de not_active IP Right Cessation
- 1984-10-25 DE DE8484112869T patent/DE3478474D1/de not_active Expired
- 1984-10-25 EP EP84112869A patent/EP0142082B1/de not_active Expired
- 1984-11-06 GR GR80858A patent/GR80858B/el unknown
- 1984-11-07 DD DD84269223A patent/DD231085A1/de not_active IP Right Cessation
- 1984-11-07 YU YU01874/84A patent/YU187484A/xx unknown
- 1984-11-07 IN IN774/CAL/84A patent/IN163652B/en unknown
- 1984-11-08 ES ES537521A patent/ES537521A0/es active Granted
- 1984-11-09 JP JP59235378A patent/JPS60169568A/ja active Pending
- 1984-11-09 ZA ZA848756A patent/ZA848756B/xx unknown
- 1984-11-09 BR BR8405749A patent/BR8405749A/pt not_active IP Right Cessation
- 1984-11-09 AU AU35298/84A patent/AU3529884A/en not_active Abandoned
-
1986
- 1986-08-20 YU YU01461/86A patent/YU146186A/xx unknown
-
1989
- 1989-01-06 AU AU27790/89A patent/AU2779089A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
BR8405749A (pt) | 1985-09-17 |
DE3478474D1 (en) | 1989-07-06 |
EP0142082A2 (de) | 1985-05-22 |
ES8605865A1 (es) | 1985-12-16 |
ATE43646T1 (de) | 1989-06-15 |
DE3409935C1 (de) | 1985-04-18 |
ES537521A0 (es) | 1985-12-16 |
YU146186A (en) | 1988-06-30 |
YU187484A (en) | 1988-04-30 |
AU3529884A (en) | 1985-05-16 |
EP0142082A3 (en) | 1985-08-21 |
ZA848756B (en) | 1985-07-31 |
AU2779089A (en) | 1989-04-27 |
JPS60169568A (ja) | 1985-09-03 |
IN163652B (enrdf_load_stackoverflow) | 1988-10-22 |
DD231085A1 (de) | 1985-12-18 |
GR80858B (en) | 1985-02-27 |
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