EP0141355A1 - Procédé pour blanchir une pulpe de bois broyé - Google Patents
Procédé pour blanchir une pulpe de bois broyé Download PDFInfo
- Publication number
- EP0141355A1 EP0141355A1 EP84112648A EP84112648A EP0141355A1 EP 0141355 A1 EP0141355 A1 EP 0141355A1 EP 84112648 A EP84112648 A EP 84112648A EP 84112648 A EP84112648 A EP 84112648A EP 0141355 A1 EP0141355 A1 EP 0141355A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- salts
- acids
- bleaching
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract 6
- 229920001131 Pulp (paper) Polymers 0.000 title abstract description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims abstract description 10
- 150000002978 peroxides Chemical class 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 6
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims abstract description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 5
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000174 gluconic acid Substances 0.000 claims abstract description 5
- 235000012208 gluconic acid Nutrition 0.000 claims abstract description 5
- 150000003009 phosphonic acids Chemical class 0.000 claims abstract description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000002253 acid Substances 0.000 claims description 18
- 150000007513 acids Chemical class 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 claims description 5
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 5
- KONBRAAEGUYPQV-UHFFFAOYSA-N 2-phosphonobutane-1,1,2-tricarboxylic acid Chemical compound CCC(P(O)(O)=O)(C(O)=O)C(C(O)=O)C(O)=O KONBRAAEGUYPQV-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- QXVJRDMNUOAUNI-UHFFFAOYSA-N [1-[bis(hydroxymethyl)amino]-1-phosphonoethyl]phosphonic acid Chemical compound OP(=O)(O)C(P(O)(O)=O)(C)N(CO)CO QXVJRDMNUOAUNI-UHFFFAOYSA-N 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- VPRHJIQBWBXGNE-UHFFFAOYSA-N 3-(1,1-diphosphonoethylamino)propanoic acid Chemical compound OP(=O)(O)C(P(O)(O)=O)(C)NCCC(O)=O VPRHJIQBWBXGNE-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- -1 alkaline earth metal salts Chemical class 0.000 claims description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 235000011007 phosphoric acid Nutrition 0.000 claims 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 1
- 239000004471 Glycine Substances 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 235000019353 potassium silicate Nutrition 0.000 description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000368 destabilizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004076 pulp bleaching Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- GPCTYPSWRBUGFH-UHFFFAOYSA-N (1-amino-1-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(N)(C)P(O)(O)=O GPCTYPSWRBUGFH-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1042—Use of chelating agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
Definitions
- the present invention relates to auxiliaries.
- the present invention relates to auxiliaries for stabilizing bleaching solutions used for wood pulp bleaching, in particular when using bleaching solutions containing peroxide and / or sulfite.
- the bleaching of the wood pulp necessary for use as a raw material in paper production is generally carried out with the aid of hydrogen peroxide and / or dithionite or hydrosulfite.
- the bleaching can be carried out in one or two stages.
- the bleaching result is influenced by the type of wood and wood pretreatment, the amount of bleach, the water quality, the Dosage and the type of additives.
- the average increase in white for one-step bleaching is 8-10 points, for two-step bleaching 16-19 points.
- the aim of the present invention was therefore to develop products which allow complete replacement of the water glass in the peroxide bleaching of wood pulp and which also have a bleaching support in the case of the dithionite bleaching.
- Gluconic acid citric acid, N, N-dihydroxyethylenegycin, diethylenetriaminepentaacetic acid, ethylenediaminetetraacetic acid, nitrilotrisacetic acid or the corresponding salts of these acids.
- the corresponding alkali and alkaline earth metal salts of orthophoric acid b and polyphosphoric acids can be used as the phosphate component.
- a bleaching formulation can have the following composition:
- Example 2 as example 1, but 4% water glass was replaced by 1% of the specified compound.
- Example 3 as example 1, but instead of 4% water glass 1% of combinations of the compounds mentioned in example 2
- Example 4 Experimental procedure as in Example 1, but with a combination of three substance groups.
- the test was carried out at a consistency of 5% under inert gas.
- the pH was 6, the equilibrium temperature was 60 ° C., the residence time was 1 hour.
- the bleaching aid was metered in at 1%, as was the Na 2 S 2 O 4 .
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT84112648T ATE34790T1 (de) | 1983-10-21 | 1984-10-19 | Verfahren zum bleichen von holzschliff. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3338260 | 1983-10-21 | ||
| DE3338260A DE3338260C1 (de) | 1983-10-21 | 1983-10-21 | Verfahren und Mittel zum Bleichen von Holzschliff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0141355A1 true EP0141355A1 (fr) | 1985-05-15 |
| EP0141355B1 EP0141355B1 (fr) | 1988-06-01 |
Family
ID=6212408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84112648A Expired EP0141355B1 (fr) | 1983-10-21 | 1984-10-19 | Procédé pour blanchir une pulpe de bois broyé |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0141355B1 (fr) |
| AT (1) | ATE34790T1 (fr) |
| DE (2) | DE3338260C1 (fr) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4752354A (en) * | 1985-09-04 | 1988-06-21 | Benckiser-Knapsack Gmbh | Process and composition for bleaching wood pulp |
| EP0369711A2 (fr) * | 1988-11-11 | 1990-05-23 | Albright & Wilson Limited | Composition de phosphate et son utilisation |
| WO1995012029A1 (fr) * | 1993-10-26 | 1995-05-04 | Akzo Nobel N.V. | Acides diphosphoniques d'aminoalcanes utilises pour blanchir la pate a papier |
| WO1997006303A1 (fr) * | 1995-08-04 | 1997-02-20 | Cht R. Beitlich Gmbh | Procede de stabilisation de bains de blanchiment alcalins contenant des peroxydes pour le blanchiment de pates de cellulose et d'autres substances fibreuses |
| WO1997030210A1 (fr) * | 1996-02-19 | 1997-08-21 | Kemira Chemicals Oy | Procede de blanchiment de pate haut rendement |
| WO1997030207A1 (fr) * | 1996-02-19 | 1997-08-21 | Kemira Chemicals Oy | Procede de blanchiment de pate chimique |
| EP0845525A2 (fr) * | 1996-11-29 | 1998-06-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| EP0845526A2 (fr) * | 1996-11-29 | 1998-06-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| WO2009056893A2 (fr) | 2007-11-02 | 2009-05-07 | Innospec Limited | Procédé de blanchiment de pâte |
| US8802613B2 (en) | 2007-12-13 | 2014-08-12 | Akzo Nobel N.V. | Stabilized hydrogen peroxide solutions |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4224607A1 (de) * | 1992-07-25 | 1994-01-27 | Benckiser Knapsack Ladenburg | Verfahren zum oxidativen oder reduktiven Bleichen und Mittel zur Stabilisierung bei der Bleiche |
| US11207863B2 (en) | 2018-12-12 | 2021-12-28 | Owens Corning Intellectual Capital, Llc | Acoustic insulator |
| US11666199B2 (en) | 2018-12-12 | 2023-06-06 | Owens Corning Intellectual Capital, Llc | Appliance with cellulose-based insulator |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1052798B (de) * | 1952-09-11 | 1959-03-12 | Scott Paper Co | Verfahren zum Bleichen von Holzschliff |
| DE1052797B (de) * | 1951-08-08 | 1959-03-12 | Scott Paper Co | Verfahren zum Bleichen von Holzschliff |
| DE2226784A1 (fr) * | 1971-06-03 | 1972-12-14 | ||
| DE2209358A1 (de) * | 1972-02-27 | 1973-09-13 | Henkel & Cie Gmbh | Mittel zur herstellung von kaltbleichflotten, insbesondere von kaltbleichwirksamen waschlaugen |
| DE2500209A1 (de) * | 1975-01-03 | 1976-07-08 | Benckiser Knapsack Gmbh | Verfahren zur verhuetung von harzausscheidungen bei der papierherstellung |
| GB2072643A (en) * | 1980-04-01 | 1981-10-07 | Interox Chemicals Ltd | Aqueous H2O2 bleach compositions |
| US4294575A (en) * | 1979-01-02 | 1981-10-13 | Monsanto Company | Peroxide stabilization |
-
1983
- 1983-10-21 DE DE3338260A patent/DE3338260C1/de not_active Expired
-
1984
- 1984-10-19 DE DE8484112648T patent/DE3471705D1/de not_active Expired
- 1984-10-19 AT AT84112648T patent/ATE34790T1/de active
- 1984-10-19 EP EP84112648A patent/EP0141355B1/fr not_active Expired
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1052797B (de) * | 1951-08-08 | 1959-03-12 | Scott Paper Co | Verfahren zum Bleichen von Holzschliff |
| DE1052798B (de) * | 1952-09-11 | 1959-03-12 | Scott Paper Co | Verfahren zum Bleichen von Holzschliff |
| DE2226784A1 (fr) * | 1971-06-03 | 1972-12-14 | ||
| DE2209358A1 (de) * | 1972-02-27 | 1973-09-13 | Henkel & Cie Gmbh | Mittel zur herstellung von kaltbleichflotten, insbesondere von kaltbleichwirksamen waschlaugen |
| DE2500209A1 (de) * | 1975-01-03 | 1976-07-08 | Benckiser Knapsack Gmbh | Verfahren zur verhuetung von harzausscheidungen bei der papierherstellung |
| US4294575A (en) * | 1979-01-02 | 1981-10-13 | Monsanto Company | Peroxide stabilization |
| GB2072643A (en) * | 1980-04-01 | 1981-10-07 | Interox Chemicals Ltd | Aqueous H2O2 bleach compositions |
Non-Patent Citations (2)
| Title |
|---|
| ABSTRACTS BULLETIN OF THE INSTITUTE OF PAPER CHEMISTRY, Band 52, Nr. 7, Januar 1982, Seiten 788-789, Nr. 7374, Appleton, Wisconsin, USA; B.H. MAY: "DTPMPA - A new sequestrant for silicate-free bleaching of paper pulp with hydrogen peroxide" & EUCEPA INTERN. MECH. PULPING CONF., 16.-19. Juni 1981 * |
| AMERICAN DYESTUFF REPORTER, Band 68, Nr. 9, September 1979, Seiten 49-54, New York, USA; X. KOWALSKI: "Sequestering agents in silicate-free peroxide bleaching" * |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4752354A (en) * | 1985-09-04 | 1988-06-21 | Benckiser-Knapsack Gmbh | Process and composition for bleaching wood pulp |
| EP0369711A2 (fr) * | 1988-11-11 | 1990-05-23 | Albright & Wilson Limited | Composition de phosphate et son utilisation |
| GB2226341A (en) * | 1988-11-11 | 1990-06-27 | Albright & Wilson | Stabilising hydrogen peroxide bleach |
| EP0369711A3 (en) * | 1988-11-11 | 1990-11-22 | Albright & Wilson Limited | Phosphate composition and uses thereof |
| GB2226341B (en) * | 1988-11-11 | 1993-06-02 | Albright & Wilson | Phosphate composition and uses thereof |
| CN1054169C (zh) * | 1993-10-26 | 2000-07-05 | 阿克佐诺贝尔公司 | 漂白纸浆的方法及氨基链烷二膦酸的应用 |
| WO1995012029A1 (fr) * | 1993-10-26 | 1995-05-04 | Akzo Nobel N.V. | Acides diphosphoniques d'aminoalcanes utilises pour blanchir la pate a papier |
| AU678631B2 (en) * | 1993-10-26 | 1997-06-05 | Akzo Nobel N.V. | Aminoalkane diphosphonic acids in pulp bleaching |
| US5641386A (en) * | 1993-10-26 | 1997-06-24 | Akzo Nobel Nv | Aminoalkane diphosphonic acids in pulp bleaching |
| WO1997006303A1 (fr) * | 1995-08-04 | 1997-02-20 | Cht R. Beitlich Gmbh | Procede de stabilisation de bains de blanchiment alcalins contenant des peroxydes pour le blanchiment de pates de cellulose et d'autres substances fibreuses |
| WO1997030210A1 (fr) * | 1996-02-19 | 1997-08-21 | Kemira Chemicals Oy | Procede de blanchiment de pate haut rendement |
| WO1997030207A1 (fr) * | 1996-02-19 | 1997-08-21 | Kemira Chemicals Oy | Procede de blanchiment de pate chimique |
| EP0845525A2 (fr) * | 1996-11-29 | 1998-06-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| EP0845526A2 (fr) * | 1996-11-29 | 1998-06-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| EP0845525A3 (fr) * | 1996-11-29 | 1999-03-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| EP0845526A3 (fr) * | 1996-11-29 | 1999-03-03 | Eka Chemicals AB | Composition de nettoyage, désinfection et blanchiment |
| WO2009056893A2 (fr) | 2007-11-02 | 2009-05-07 | Innospec Limited | Procédé de blanchiment de pâte |
| WO2009056893A3 (fr) * | 2007-11-02 | 2009-07-02 | Innospec Ltd | Procédé de blanchiment de pâte |
| US8906199B2 (en) | 2007-11-02 | 2014-12-09 | Innospec Limited | Process for bleaching pulp |
| US8802613B2 (en) | 2007-12-13 | 2014-08-12 | Akzo Nobel N.V. | Stabilized hydrogen peroxide solutions |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE34790T1 (de) | 1988-06-15 |
| DE3471705D1 (en) | 1988-07-07 |
| DE3338260C1 (de) | 1985-07-25 |
| EP0141355B1 (fr) | 1988-06-01 |
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