EP0139142A1 - Agent et procédé de conservation de bois et de matériaux dérivés du bois - Google Patents

Agent et procédé de conservation de bois et de matériaux dérivés du bois Download PDF

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Publication number
EP0139142A1
EP0139142A1 EP84109718A EP84109718A EP0139142A1 EP 0139142 A1 EP0139142 A1 EP 0139142A1 EP 84109718 A EP84109718 A EP 84109718A EP 84109718 A EP84109718 A EP 84109718A EP 0139142 A1 EP0139142 A1 EP 0139142A1
Authority
EP
European Patent Office
Prior art keywords
wood
alkali
mixture
biocidal
chemical compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84109718A
Other languages
German (de)
English (en)
Other versions
EP0139142B1 (fr
Inventor
Wolfgang Dipl.-Chem.Dr. Metzner
Detlef Dipl.-Chem.Dr. Seepe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Desowag Materialschutz GmbH
Original Assignee
Desowag Bayer Holzschutz GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Desowag Bayer Holzschutz GmbH filed Critical Desowag Bayer Holzschutz GmbH
Priority to AT84109718T priority Critical patent/ATE25941T1/de
Publication of EP0139142A1 publication Critical patent/EP0139142A1/fr
Application granted granted Critical
Publication of EP0139142B1 publication Critical patent/EP0139142B1/fr
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16Inorganic impregnating agents
    • B27K3/163Compounds of boron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16Inorganic impregnating agents
    • B27K3/32Mixtures of different inorganic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/30Fireproofing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/02Staining or dyeing wood; Bleaching wood

Definitions

  • the present invention relates to an agent for preserving wood and timber materials on the basis of at least one alkali metal monofluorophosphate and / or Alkalidi- fluorp h osphates of the general formula M 2 PO 3 F and / or MPO 3 F 2, wherein M is sodium, potassium or ammonium means (as a fungicide and / or insecticide).
  • alkali fluorides in particular alkali bifluoride
  • wood preservatives against wood-destroying fungi and insects cf., inter alia, Chemistry Lexicon, Ullmann 4th edition (1Q76), pages 687-688.
  • sodium fluoride has a low solubility and is unsuitable for immersion immersion, for example, sodium, potassium and / or ammonium bifluorides are used in particular.
  • the disadvantage is however, the volatility and rejuvenation of these compounds, which, when using hydrogen fluoride, can lead, among other things, to glass etching, to the corrosion of metals associated with the wood, to reaction with calcareous building materials, etc.
  • certain protective measures must be observed when handling these agents.
  • the aim and object of the present invention was therefore to avoid or reduce these disadvantages and to find a means for preserving wood which has a good preservative effect and a reduced tendency to corrosion and whose toxicity to warm-blooded animals is relatively low.
  • a means for preserving wood and wood-based materials based on at least one alkali salt containing fluorine or fluorine ions the wood preservative as alkali salt containing fluorine or fluorine ions, alkali monofluorophosphate and / or alkali difluorophosphate of the general formula M 2 PO 3 F and / or MPO 3 F 2 , in which M means sodium, potassium and / or ammonium (as a fungicide and / or insecticide).
  • disodium fluorophosphate is used directly on the human body as a caries inhibitor and is considered to be relatively non-toxic, these compounds were suitable for
  • Wood preservation is surprising insofar as very high and other requirements must be placed on the active substances in the field of wood preservation, so that in general those active substances which are used for use on the human body are not also suitable as active substances for the wood preservatives.
  • the agent has a good preservative effect with a reduced tendency to corrode, preferably when the wood preservative consists of a mixture of alkali monofluorophosphate and / or alkali difluorophosphate, at least one biocidal and / or fire-retardant chemical compound or a compound mixture, that as at least a component contains a biocidal and / or fire-retardant chemical compound, and / or at least one wetting agent, emulsifier, dye and / or pigment.
  • the wood preservative consists of 99.95 to 95% by weight, preferably 99.8 to 97% by weight, of alkali monofluorophosphate and / or alkali difluorophosphate or a mixture of alkali mono- and / or alkali difluorophosphate with at least one biocidal and / or fire-retardant chemical compound or a prevention mixture which contains at least one component a biocidal and / or fire-retardant chemical compound and 0.05 to 5% by weight, preferably 0.2 to 3% by weight, of at least one wetting agent, emulsifier , Dye and / or pigment ..
  • the penetration depth and the distribution of the agent are improved.
  • the wetting agent or wetting agent mixture is preferably used when the compound mixture (with the exception of dye) consists of inorganic constituents. If organic constituents, organic chemical biocides and the like are also used, an emulsifier without an emulsifier mixture is used. If the wood preservative is not to be colored, the dye and / or the pigment can be omitted entirely, but not the others dung at least one wetting agent and / or an emulsifier.
  • the wood preservative consists of a mixture of 0.1 to 80% by weight, preferably 10 to 75% by weight, of alkali monofluorophosphate and / or alkali difluorophosphate, 99.85 to 15% by weight, preferably 89.8 to 22% by weight, at least one biocidal and / or fire-retardant chemical compound or a compound mixture which contains as a component a biocidal and / or fire-retardant chemical compound, and 0.05 to 5% by weight, preferably 0.2 to 3 wt .-%, at least one wetting agent, emulsifier, dye and / or pigment.
  • the wood preservative expediently contains at least one biocidal and / or fire-retarding inorganic chemical compound or an inorganic-chemical compound mixture as a biocidal and / or fire-retarding compound (except alkali monofluorophosphate or alkali difluorophosphate), which as a component contains a biocidal and / or fire-retarding inorganic chemical compound owns.
  • the wood preservative contains at least one water as a biocidal and / or fire-retardant inorganic chemical compound soluble alkali salt and / or ammonium salt of chromic acid, dichromic acid, phosphoric acid, hydrofluoric acid, boric acid, borofluorohydric acid and / or an ammonium, magnesium, copper and / or zinc silicofluoride, boric acid, phosphoric acid, borofluorohydric acid and / or a water-soluble copper salt or one or more of these compounds directly or as part of the compound mixture.
  • a water-soluble alkali, ammonium, potassium and / or magnesium salt or a mixture of two or more of these salts is present in the wood preservative as part of the compound mixture in addition to the biocidal and / or fire-retardant organic chemical compound.
  • These compounds can be in the form of water-soluble chlorides, sulfates, carbonates and the like. They support the action of the biocidal and / or fire retardant compounds.
  • ammonium, magnesium, copper and / or zinc silicofluoride care must be taken that no alkali or other alkaline earth compounds are used with the other constituents in order to avoid precipitation of poorly soluble alkali or alkaline earth silicofluorides. This can be done, for example, by using ammonium compounds such as ammonium mono- and / or ammonium difluorophosphate.
  • the wood preservative contains as a biocidal compound (except alkali monofluorophosphate or alkalidifluorophosphate) at least one biocidal organochemical compound or an organochemical compound mixture which has at least one constituent of a biocidal organochemical compound, the organochemical compound consisting of at least one water-insoluble, but in an organic chemical solvent or solvent mixture soluble organic chemical fungicide and / or insecticide, and at least one emulsifier, wetting agent, dye and / or pigment and an organic chemical solvent or solvent mixture.
  • the use of at least one emulsifier or one emulsifier mixture and / or wetting agent-emulsifier mixture is preferred, while the wetting agent is used only when the content of the organic chemical compound is low.
  • the invention further relates to a method for preserving wood using the agent for preserving wood and wood-based materials, the wood using a pressure and / or vacuum or DoDpelvakuumvon with a 1.5 to 7 wt .-%, preferably 2 to 5 wt .-% aqueous solution of the wood preservative is treated while using the dipping or spraying driving the wood with a 5 to 35 wt .-%, preferably 8 to 25 wt .-% aqueous solution of the wood preservative is treated.
  • Pine sapwoods are immersed in a 20% aqueous solution of the agent according to Example 1. Depending on the diving time, 5 - 50 g protective agent / m 2 are applied.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
EP84109718A 1983-10-07 1984-08-16 Agent et procédé de conservation de bois et de matériaux dérivés du bois Expired EP0139142B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84109718T ATE25941T1 (de) 1983-10-07 1984-08-16 Mittel und verfahren zum konservieren von holz und holzwerkstoffen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19833336557 DE3336557A1 (de) 1983-10-07 1983-10-07 Mittel und verfahren zum konservieren von holz und holzwerkstoffen
DE3336557 1983-10-07

Publications (2)

Publication Number Publication Date
EP0139142A1 true EP0139142A1 (fr) 1985-05-02
EP0139142B1 EP0139142B1 (fr) 1987-03-18

Family

ID=6211276

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84109718A Expired EP0139142B1 (fr) 1983-10-07 1984-08-16 Agent et procédé de conservation de bois et de matériaux dérivés du bois

Country Status (4)

Country Link
EP (1) EP0139142B1 (fr)
JP (1) JPH0698609B2 (fr)
AT (1) ATE25941T1 (fr)
DE (2) DE3336557A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0264488A1 (fr) * 1986-09-15 1988-04-27 DESOWAG Materialschutz GmbH Agent protecteur du bois
EP0288735A1 (fr) * 1987-04-28 1988-11-02 DESOWAG Materialschutz GmbH Agent pour la préservation du bois et des matériaux en bois
WO2003082534A2 (fr) * 2002-03-29 2003-10-09 Nijman Wood Modification Trading Company Ltd. Procede de traitement du bois, de farine de bois et analogues, equipement destine au traitement du bois, produits fabriques a partir du bois modifie et produits fabriques a partir de la farine de bois traitee et analogues
AT515644A1 (de) * 2014-03-21 2015-10-15 List Gmbh F Furnierelement

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109159228A (zh) * 2018-10-10 2019-01-08 马鞍山和春文化传媒有限公司 一种耐腐蚀户外广告牌用木板

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1046062A (fr) * 1951-11-30 1953-12-03 Produit destiné à la conservation des bois
FR1374402A (fr) * 1963-07-10 1964-10-09 Solvay Werke Gmbh Nouveaux agents de conservation des bois et procédé pour les fixer rapidement avec un degré de fixation élevé
DE3210193A1 (de) * 1981-03-20 1982-09-30 SzkoŁa GŁówna Gospodarstwa Wiejskiego, Akademia Rolnicza w Warszawie, Warszawa Holzschutzmittel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1046062A (fr) * 1951-11-30 1953-12-03 Produit destiné à la conservation des bois
FR1374402A (fr) * 1963-07-10 1964-10-09 Solvay Werke Gmbh Nouveaux agents de conservation des bois et procédé pour les fixer rapidement avec un degré de fixation élevé
DE3210193A1 (de) * 1981-03-20 1982-09-30 SzkoŁa GŁówna Gospodarstwa Wiejskiego, Akademia Rolnicza w Warszawie, Warszawa Holzschutzmittel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MAHLKE-TROSCHEL "Handbuch der Holzkonservierung", 2. Auflage, 1928 JULIUS SPRINGER, Berlin Seite V, Zeilen 41,45,46 * *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0264488A1 (fr) * 1986-09-15 1988-04-27 DESOWAG Materialschutz GmbH Agent protecteur du bois
EP0288735A1 (fr) * 1987-04-28 1988-11-02 DESOWAG Materialschutz GmbH Agent pour la préservation du bois et des matériaux en bois
WO2003082534A2 (fr) * 2002-03-29 2003-10-09 Nijman Wood Modification Trading Company Ltd. Procede de traitement du bois, de farine de bois et analogues, equipement destine au traitement du bois, produits fabriques a partir du bois modifie et produits fabriques a partir de la farine de bois traitee et analogues
NL1020280C2 (nl) * 2002-03-29 2003-10-17 Nijman Wood Modification B V Werkwijze voor het behandelen van hout, houtpoeder en dergelijke, inrichting voor het behandelen van hout, uit het gemodificeerde hout vervaardigde voortbrengselen en uit het behandelde houtpoeder vervaardigde voortbrengselen.
WO2003082534A3 (fr) * 2002-03-29 2003-12-18 Nijman Wood Modification Tradi Procede de traitement du bois, de farine de bois et analogues, equipement destine au traitement du bois, produits fabriques a partir du bois modifie et produits fabriques a partir de la farine de bois traitee et analogues
AT515644A1 (de) * 2014-03-21 2015-10-15 List Gmbh F Furnierelement

Also Published As

Publication number Publication date
JPH0698609B2 (ja) 1994-12-07
DE3336557A1 (de) 1985-04-18
EP0139142B1 (fr) 1987-03-18
DE3462669D1 (en) 1987-04-23
ATE25941T1 (de) 1987-04-15
JPS60107304A (ja) 1985-06-12

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