EP0116882A2 - Agent de séparation et de lubrification à l'état solide - Google Patents

Agent de séparation et de lubrification à l'état solide Download PDF

Info

Publication number
EP0116882A2
EP0116882A2 EP84101118A EP84101118A EP0116882A2 EP 0116882 A2 EP0116882 A2 EP 0116882A2 EP 84101118 A EP84101118 A EP 84101118A EP 84101118 A EP84101118 A EP 84101118A EP 0116882 A2 EP0116882 A2 EP 0116882A2
Authority
EP
European Patent Office
Prior art keywords
lubricant
agent
release agent
lubricant according
release
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84101118A
Other languages
German (de)
English (en)
Other versions
EP0116882A3 (en
EP0116882B1 (fr
Inventor
Jacques Dr. Périard
Alain Dr. Cron
Francis Dr. Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lonza AG
Original Assignee
Lonza AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lonza AG filed Critical Lonza AG
Priority to AT84101118T priority Critical patent/ATE49018T1/de
Publication of EP0116882A2 publication Critical patent/EP0116882A2/fr
Publication of EP0116882A3 publication Critical patent/EP0116882A3/de
Application granted granted Critical
Publication of EP0116882B1 publication Critical patent/EP0116882B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0239—Lubricating
    • B21B45/0245—Lubricating devices
    • B21B45/0263—Lubricating devices using solid lubricants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B25/00—Mandrels for metal tube rolling mills, e.g. mandrels of the types used in the methods covered by group B21B17/00; Accessories or auxiliary means therefor ; Construction of, or alloys for, mandrels or plugs
    • B21B25/04—Cooling or lubricating mandrels during operation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/081—Inorganic acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/12—Glass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/02—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/34—Lubricating-sealants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses

Definitions

  • the invention relates to a release and lubricant in solid form for hot metal deformation, in particular for hot plate or profile rolling and, for example, also as mandrel lubricant in the manufacture of seamless pipes.
  • glasses, salts and laminar lubricants based on graphite or aqueous emulsions with synthetic, surface-active emulsions with synthetic, surface-active agents as cutting and lubricants for non-cutting metal processing. Except for the laminar, graphite-based lubricants, all other means for hot plate rolling are not applicable. Glasses or vitreous lubricants cannot be used because they can hardly be removed from the surface of the processed pieces. Salts as lubricants in the form of aqueous solutions lead to high corrosion on the workpiece and machines. The use of lubricating and cooling liquids requires an additional device for their cooling and cleaning so that the liquid can be circulated.
  • the object of the invention was to propose a solid, softening at high temperatures to melting lubricant, which does not have the disadvantages mentioned and beyond the hot plate and profile rollers also for other applications, such as the lubrication of mandrels or mandrel bars in the manufacture seamless pipes can be used on, for example, continental or civil roads.
  • the release agent and lubricant according to the invention accordingly contains at least one thermoplastic polymer and / or copolymer and a lubricant for plastics.
  • additives can, according to the An Crumissen to the separation - and lubricant can be provided.
  • Such additives can be a solid lubricant and / or a wetting agent and / or an adhesion promoter and / or a surface modification agent and / or a plasticizer and / or fibers and / or clay.
  • the separating and lubricating agent expediently contains two thermoplastic polymers and / or copolymers.
  • thermoplastic polymers and / or copolymers polyolefins, vinyl resins, acrylic and methacrylic resins, polyesters, polyamides, thermoplastic polyurethanes, polyoxymethylene, polyoxyethylene, polyoxypropylene, polycarbonates, foliaretherimides, polyphenylene oxides and sulfides, thermoplastic cellulose derivatives or hydrocarbon resins in amounts of 1 to 90% by weight . - % are used.
  • thermoplastic polymers and / or copolymers can have the same molecular structure but different chain lengths.
  • examples include polyethylene, coumarone indene resins, hydrocarbon resins.
  • suitable mixtures of two different polymers and / or copolymers are, for example, polyethylene with polyisobutylene and polymethyl methacrylates with polymethacrylate. These polymers are mutually incompatible, a mixture of polymers or copolymers which are to be classified as mutually compatible, for example polystyrene, has proven to be particularly advantageous 2,6-dimethyl-1,4-phenylene oxide.
  • the release agent and lubricant contains a lubricant for plastics.
  • Fatty acids, fatty alcohols, fatty amides, soaps, waxes or polyethylene waxes or silicone oil can be used as lubricants.
  • an adhesion promoter and / or plasticizer for the polymers or copolymers is said to improve the adhesion to metal surfaces and to lower the softening temperature of the mixture.
  • They are generally rosin derivatives, terpene resins or hydrocarbon resins, coumarone-indene resins and the plasticizers commonly used in thermoplastics, as listed, for example, in "Modern Plastic Encyclopedia (1983)".
  • the separating and lubricating agent also advantageously contains a solid lubricant.
  • a solid lubricant Polytetrafluoroethylene, calcium fluoride, molybdenum disulfide, boron nitride and in particular graphite are preferred. The effect of such lubricants is known per se.
  • a wetting agent can be added to disperse the solid lubricant in the release agent and lubricant and to increase the adhesion to the metal.
  • the wetting agent causes a superficial plasticization ("Rehbinder effect", PA Rehbinder, ED Scukin, Les phenomenes de surface dans la deformation et la fracture des solides - Seminaire de Mecanique des Surfaces ISMCM - CNRS (1971)) of the metal, which is caused by friction leads to low friction coefficients and, due to the smoothing of the surface, low, even wear of the friction partners.
  • a surface modification agent preferably from the series of the silanes or titanates, can be used.
  • aminopropyltri- ethoxy silane or isopropyl triisostearyl titanate may be called.
  • plastic inorganic raw materials from the series of clay minerals, such as kaolins, clays, bentonites, talc or verminculite, it is achieved that the plasticity and the coefficient of friction of the release agent and lubricant can be influenced.
  • the mixture of the components according to the invention must result in a release agent and lubricant which has a solid form at normal temperature. If the separation and Lubricants, for example, heated and softened when they are used in hot plate rolling by contact with a hot roller or in the manufacture of seamless tubes on a hot mandrel, can be homogeneous in composition and thickness by rubbing and / or melting on the roller or on the mandrel Form a film.
  • this film is waterproof, so that the considerable amounts of cooling water which flow over the rollers or the mandrel do not impair the film.
  • the film can be easily transferred from one roller to the other.
  • the solid lubricant ensures that even under these difficult conditions, such as high pressures, high temperatures and friction between the tool and the workpiece, there are no excessive loads and tensions.
  • the separating and lubricating agent is produced by mixing the components in the heat, for example a kneader, and pressing the individual components into the desired shape. Processing can also be carried out in an extruder and using injection molding technology.
  • the finished elements are solid at normal temperature and have a softening point of 20 to 250 ° C.
  • the Shore D hardness is 20 to 50 for elements with a low softening point and 50 to 80 for elements with a high softening point.
  • the melting point is 30 to 300 ° C.
  • the cold compressive strength should be 5 to 500 kg / cm 2 .
  • the release agent and lubricant according to the invention it is achieved that due to the good separating and lubricating effect, the power to be used, for example for rolling sheets and profiles, drops considerably.
  • the quality of the surface of the processed workpieces is also improved and, for example, has a low roughness.
  • the separating and lubricating agent also leads to greater operational safety, since the lubricating effect can be controlled by the choice of additives and thus an excessively good lubricating effect, which leads to slipping sheets, can be avoided.
  • the film thickness can also be controlled well and films of 50 to 200 microns thick can be applied. In many cases, an average film thickness of 1 to 2 microns is sufficient for the agent to have a high lubricating capacity. Compared to the known oil-based lubricants, there is no smoke, smoke or environmental pollution.
  • This mixture gives a transfer film, lubricating at a temperature of 80 to 90 o C.
  • This mixture gives a transfer film, lubricating between 50 and 100 ° C.
  • This mixture gives a transfer film at a temperature of 100 to 150 ° C.
  • This mixture gives a transfer film at a temperature of 50 to 70 ° C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Fats And Perfumes (AREA)
EP84101118A 1983-02-18 1984-02-03 Agent de séparation et de lubrification à l'état solide Expired EP0116882B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84101118T ATE49018T1 (de) 1983-02-18 1984-02-03 Trenn- und schmiermittel in fester form.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH934/83 1983-02-18
CH93483 1983-02-18

Publications (3)

Publication Number Publication Date
EP0116882A2 true EP0116882A2 (fr) 1984-08-29
EP0116882A3 EP0116882A3 (en) 1986-07-09
EP0116882B1 EP0116882B1 (fr) 1989-12-27

Family

ID=4198568

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84101118A Expired EP0116882B1 (fr) 1983-02-18 1984-02-03 Agent de séparation et de lubrification à l'état solide

Country Status (11)

Country Link
US (1) US4575430A (fr)
EP (1) EP0116882B1 (fr)
JP (1) JPS59157189A (fr)
AT (1) ATE49018T1 (fr)
BR (1) BR8400703A (fr)
CA (1) CA1210750A (fr)
DE (1) DE3480852D1 (fr)
ES (1) ES8503025A1 (fr)
MX (1) MX160923A (fr)
NO (1) NO164251C (fr)
ZA (1) ZA84247B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2601686A1 (fr) * 1986-07-17 1988-01-22 Mitsui Toatsu Chemicals Lubrifiant
EP0369007A1 (fr) * 1987-03-10 1990-05-23 Nippon Kokan Kabushiki Kaisha Procede de lubrification pour le laminage a chaud d'acier a teneur elevee en silicium
GB2227022A (en) * 1989-01-13 1990-07-18 Hanano Commercial Co Ltd Die-casting powdery mould releasing agent
EP0403306A1 (fr) * 1989-06-16 1990-12-19 Castrol Industrial Inc. Lubrifiant de forge sans support et méthode pour l'utiliser
EP0468278A1 (fr) * 1990-07-12 1992-01-29 DAIDO MACHINERY, Ltd. Lubrifiant de forgeage et méthode pour former un revêtement de lubrifiant à la surface d'un matériau filiforme
EP0469906A1 (fr) * 1990-08-02 1992-02-05 Oiles Corporation Lubrifiant solide, et pièce coulissante ayant le lubrifiant solide enchâssé dedans
EP0507449A1 (fr) * 1991-03-04 1992-10-07 Castrol Ind Inc Lubrifiant sans support pour le travail des métaux et méthode de préparation et d'utilisation.
CN100425681C (zh) * 2005-09-28 2008-10-15 中国石油化工股份有限公司 含油分散性粘土抗磨防滑剂的热轧油组合物
CN100443576C (zh) * 2005-09-28 2008-12-17 中国石油化工股份有限公司 由水分散性粘土制备的热轧油组合物
WO2012022284A3 (fr) * 2010-06-28 2012-06-28 Sms Meer Gmbh Procédé de laminage à chaud de corps creux métalliques et laminoir à chaud correspondant

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3571562D1 (en) * 1984-05-21 1989-08-24 Sumitomo Metal Ind Method for continuous drawing of wire rod
CH665847A5 (de) * 1985-10-02 1988-06-15 Lonza Ag Verfahren zum suspendieren von festschmierstoffen.
JPS6291560A (ja) * 1985-10-18 1987-04-27 Asahi Glass Co Ltd 潤滑性樹脂組成物
JPH0670234B2 (ja) * 1985-11-27 1994-09-07 株式会社河端製作所 金属の摺動部又は回転部のコーティング減摩方法
CH669129A5 (de) * 1986-04-04 1989-02-28 Lonza Ag Schmierstoffsystem fuer blech- und profilwalzwerke.
US4945832A (en) * 1986-05-16 1990-08-07 Odom Jimmie L Doctor blade system
US4735144A (en) * 1986-05-21 1988-04-05 Jenkins Jerome D Doctor blade and holder for metering system
US5271854A (en) * 1986-09-23 1993-12-21 Lonza Ltd. High temperature lubricant containing carboxylated styrene-butadiene latex
US4764293A (en) * 1987-08-28 1988-08-16 Witco Corporation Lubricant compositions
CH674164A5 (fr) * 1987-09-29 1990-05-15 Lonza Ag
CH674096A5 (fr) * 1988-01-19 1990-04-30 Lonza Ag
CH674477A5 (fr) * 1988-03-30 1990-06-15 Lonza Ag
US4840758A (en) * 1988-09-09 1989-06-20 Phillips Petroleum Company Methods of preparing molded thermoplastic articles wherein radio frequency energy is utilized to heat the thermoplastic material
JPH02263898A (ja) * 1989-04-04 1990-10-26 Yushiro Chem Ind Co Ltd 熱間圧延加工用固形潤滑剤
US5099667A (en) * 1989-06-16 1992-03-31 Lonza Ltd. System for suspending and applying solid lubricants to tools or work pieces
US5468401A (en) * 1989-06-16 1995-11-21 Chem-Trend, Incorporated Carrier-free metalworking lubricant and method of making and using same
EP0448944B1 (fr) * 1990-03-26 1994-09-14 Lonza Ag Procédé et dispositif pour une atomisation intermittente d'une suspension de lubrifiant
JP2819480B2 (ja) * 1990-05-31 1998-10-30 オリエンタル産業株式会社 固形離型剤
US5415791A (en) * 1990-08-02 1995-05-16 Oiles Corporation Lubricating composition and a sliding member comprising the composition
US5279749A (en) * 1991-03-06 1994-01-18 Hanano Commercial Co., Ltd. Method for permanent mold casting with permanent mold casting powdery mold releasing agent
US5277831A (en) * 1991-03-06 1994-01-11 Hanano Commercial Co., Ltd. Method for low pressure die casting with low pressure die casting powdery mold releasing agent
US5279750A (en) * 1991-03-06 1994-01-18 Hanano Commercial Co., Ltd. Method for squeeze casting powdery mold releasing agent
US5085828A (en) * 1991-05-15 1992-02-04 General Motors Corporation Cold press die lubrication method
GB2262784B (en) * 1991-12-24 1995-05-10 T & N Technology Ltd Bearing material
GB9227058D0 (en) * 1992-12-29 1993-02-24 Castrol Ltd Lubricant
US6207627B1 (en) 1994-01-19 2001-03-27 The United States Of America As Represented By The Secretary Of Commerce Oxygen-containing organic compounds as boundary lubricants for silicon nitride ceramics
US7767631B2 (en) * 1995-06-07 2010-08-03 Lee County Mosquito Control District Lubricant compositions and methods
US20020198114A1 (en) * 1995-06-07 2002-12-26 Lee County Mosquito Control District Lubricant compositions and methods
CA2223286C (fr) * 1995-06-07 2006-11-14 Lee County Mosquito Control District Compositions de lubrifiants et procedes de preparation
US5865884A (en) * 1996-05-08 1999-02-02 Asahi Glass Company Ltd. Glass forming lubricant and glass forming method using it
US6291407B1 (en) 1999-09-08 2001-09-18 Lafrance Manufacturing Co. Agglomerated die casting lubricant
US6432886B1 (en) 1999-09-08 2002-08-13 Mary R. Reidmeyer Agglomerated lubricant
JP3467529B2 (ja) * 2000-06-13 2003-11-17 広島大学長 金型鋳造用の粉体離型潤滑剤および金型鋳造法
US7683014B2 (en) 2001-04-13 2010-03-23 Mitrovich Michael J Process for making a two-part solid lubricant stick
US7820598B2 (en) * 2001-04-13 2010-10-26 Mitrovich Michael J Solid lubricant sticks having a two part formulation
WO2002083822A2 (fr) * 2001-04-13 2002-10-24 Mitrovich Michael J Lubrifiant solide et composition appropriee
US7943556B2 (en) * 2001-04-13 2011-05-17 Mitrovich Michael J Environmentally friendly solid lubricant sticks
KR101045735B1 (ko) * 2002-11-21 2011-06-30 오이레스 고교 가부시끼가이샤 고체 윤활제 및 접동 부재
CA2597830C (fr) * 2005-02-14 2015-06-02 Kelsan Technologies Corp. Compositions sous forme de baton solide comprenant un plastique thermodurcissable
US7709426B2 (en) * 2005-07-08 2010-05-04 Kelsan Technologies Corp. Solid stick grease compositions
US8445416B2 (en) * 2007-01-26 2013-05-21 L.B. Foster Rail Technologies, Corp. Solid stick compositions comprising vinyl ester
US8250890B2 (en) * 2009-04-22 2012-08-28 GM Global Technology Operations LLC Method to improve solid lubricant film tribological performance and adhesion to hot forming material
CN101638606B (zh) * 2009-07-14 2012-10-17 荆门市兴泰工贸有限公司 环保型金属锻造脱模剂
US20140087980A1 (en) 2012-09-21 2014-03-27 Mpl Technology, Inc. Lubricant compositions
JP6512204B2 (ja) * 2015-12-04 2019-05-15 Ｊｆｅスチール株式会社 ステンレス鋼板用潤滑塗料および潤滑ステンレス鋼板
CN109651699B (zh) * 2018-10-31 2021-09-10 宁波万盛实业有限公司 一种高性能聚丙烯材料制品的制备方法
WO2024116556A1 (fr) * 2022-11-28 2024-06-06 日本製鉄株式会社 Composition lubrifiante et procédé de fabrication de tuyaux métalliques sans soudure l'utilisant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2041774A1 (de) * 1970-08-22 1972-02-24 Bayer Ag Hilfsscheibe fuer das Warmstrangpressen von Metallen,insbesondere schwer verformbaren Metallen,z.B. Stahl
FR2270319A1 (fr) * 1974-05-08 1975-12-05 Lonza Ag
GB2018820A (en) * 1978-04-05 1979-10-24 Ntn Toyo Bearing Co Ltd Polyethylene/grease bearing lubricants
GB2022471A (en) * 1978-03-31 1979-12-19 Ti Tube Division Services Ltd Applying lubricant to elongate articles

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3341454A (en) * 1963-02-25 1967-09-12 Hodson Corp Lubricant composition
US3838048A (en) * 1968-06-17 1974-09-24 Diamond Shamrock Corp Polyvinylfluoride bearings
JPS4835654A (fr) * 1971-09-08 1973-05-25
US3908038A (en) * 1973-03-28 1975-09-23 Allied Chem Thermoplastic molding compositions
JPS5337817B2 (fr) * 1974-07-08 1978-10-12
CA1075223A (fr) * 1975-12-12 1980-04-08 Donald G. Needham Produit anti-friction a base de poly (sulfure d'arylene)
US4357249A (en) * 1980-09-11 1982-11-02 Arguto, Inc. Self-lubricating bearing and the like, and method of making same
JPS5819395A (ja) * 1981-07-28 1983-02-04 Nippon Steel Corp 鋼材の熱間成形用潤滑剤

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2041774A1 (de) * 1970-08-22 1972-02-24 Bayer Ag Hilfsscheibe fuer das Warmstrangpressen von Metallen,insbesondere schwer verformbaren Metallen,z.B. Stahl
FR2270319A1 (fr) * 1974-05-08 1975-12-05 Lonza Ag
GB2022471A (en) * 1978-03-31 1979-12-19 Ti Tube Division Services Ltd Applying lubricant to elongate articles
GB2018820A (en) * 1978-04-05 1979-10-24 Ntn Toyo Bearing Co Ltd Polyethylene/grease bearing lubricants

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2601686A1 (fr) * 1986-07-17 1988-01-22 Mitsui Toatsu Chemicals Lubrifiant
EP0369007A4 (en) * 1987-03-10 1991-09-04 Nippon Kokan Kabushiki Kaisha Lubricating method for hot rolling of high-silicon steel
EP0369007A1 (fr) * 1987-03-10 1990-05-23 Nippon Kokan Kabushiki Kaisha Procede de lubrification pour le laminage a chaud d'acier a teneur elevee en silicium
GB2227022B (en) * 1989-01-13 1992-11-04 Hanano Commercial Co Ltd Die-casting powdery mould releasing agent
DE3917726A1 (de) * 1989-01-13 1990-07-19 Hanano Commercial Co Ltd Formentrennmittel fuer druckgussverfahren
GB2227022A (en) * 1989-01-13 1990-07-18 Hanano Commercial Co Ltd Die-casting powdery mould releasing agent
EP0403306A1 (fr) * 1989-06-16 1990-12-19 Castrol Industrial Inc. Lubrifiant de forge sans support et méthode pour l'utiliser
EP0468278A1 (fr) * 1990-07-12 1992-01-29 DAIDO MACHINERY, Ltd. Lubrifiant de forgeage et méthode pour former un revêtement de lubrifiant à la surface d'un matériau filiforme
EP0469906A1 (fr) * 1990-08-02 1992-02-05 Oiles Corporation Lubrifiant solide, et pièce coulissante ayant le lubrifiant solide enchâssé dedans
EP0507449A1 (fr) * 1991-03-04 1992-10-07 Castrol Ind Inc Lubrifiant sans support pour le travail des métaux et méthode de préparation et d'utilisation.
CN100425681C (zh) * 2005-09-28 2008-10-15 中国石油化工股份有限公司 含油分散性粘土抗磨防滑剂的热轧油组合物
CN100443576C (zh) * 2005-09-28 2008-12-17 中国石油化工股份有限公司 由水分散性粘土制备的热轧油组合物
WO2012022284A3 (fr) * 2010-06-28 2012-06-28 Sms Meer Gmbh Procédé de laminage à chaud de corps creux métalliques et laminoir à chaud correspondant
US10166583B2 (en) 2010-06-28 2019-01-01 Sms Group Gmbh Process for hot-rolling metallic hollow bodies and corresponding hot-rolling mill

Also Published As

Publication number Publication date
NO164251C (no) 1990-09-12
JPH0316998B2 (fr) 1991-03-06
BR8400703A (pt) 1984-09-25
CA1210750A (fr) 1986-09-02
ZA84247B (en) 1984-09-26
ATE49018T1 (de) 1990-01-15
EP0116882A3 (en) 1986-07-09
NO164251B (no) 1990-06-05
EP0116882B1 (fr) 1989-12-27
ES529809A0 (es) 1985-02-01
DE3480852D1 (de) 1990-02-01
JPS59157189A (ja) 1984-09-06
MX160923A (es) 1990-06-19
ES8503025A1 (es) 1985-02-01
NO840596L (no) 1984-08-20
US4575430A (en) 1986-03-11

Similar Documents

Publication Publication Date Title
EP0116882B1 (fr) Agent de séparation et de lubrification à l'état solide
DE2043885C3 (de) Schmiermittel für die spanende und spanlose Bearbeitung von Metallwerkstoffen
EP0185863B1 (fr) Procédé pour fabriquer des feuilles, notamment à base de polyvinyl-butyral à adhésivité superficielle minimale
DE2549249A1 (de) Tiefziehblech und verfahren zu seiner herstellung
DE2413221B2 (de) Verfahren zur herstellung von poroesen polytetrafluoraethylenfolien und vorrichtung zur durchfuehrung des verfahrens
DE1286248B (de) Schmiermittel
DE1954040A1 (de) Schmiermittel zur Metallbearbeitung und Verfahren zur Vorbehandlung von Metallen
EP0008623A1 (fr) Feuille laminée de polypropylène orientée biaxialement et son utilisation
EP0613770B1 (fr) Film multicouche thermosoudable et orienté en polyoléfine, procédé pour sa préparation et son utilisation
EP0563806A2 (fr) Compositions comprenant du 1-chloro-2,2,2-trifluoroéthyl-difluorométhyléther
DE2907863C2 (de) Metallbearbeitungsemulsion
CH669207A5 (en) Compsn. for reducing friction noise on contacting metal surfaces - contg. thermoplastic (co)polymer lubricant for synthetics and solid lubricant
DE1452441A1 (de) Verfahren zum Strangpressen metallischer Erzeugnisse
DE2700518C2 (de) Hilfsbindemittel und dessen Verwendung
EP0307832B1 (fr) Composition avec du dichlorotrifluoréthane
DE2807759C2 (de) Verfahren und Elastomermischung zur Herstellung von Dichtungen
DE10212861A1 (de) Formtrennmittel für langsamen Spritzguß
EP0630730A1 (fr) Compositions sans chlore, basées en hydrocarbures fluorés
EP0709404B1 (fr) Procédé de dégradation thermomécanique de polyoléfines
DE19824279C1 (de) Trennmittel, dessen Verwendung sowie Verfahren zu seiner Herstellung
EP0451327A2 (fr) Tube métallique comprenant à l'intérieur un revêtement anticorrosion de lubrifiant craqué
DE1132710B (de) Verfahren und Vorrichtung zum kontinuierlichen Einbringen von Polytetrafluoraethylenteilchen in die Poren eines bandfoermigen Metallstreifens mit poroeser Schwammstruktur
EP0386245A1 (fr) Procede d'obtention de revetements composites a base de chrome
EP0384243B1 (fr) Combinaisons avec du dichloromonofluoréthane
DE2004062C3 (de) Verfahren zum Verformen metallischer Werkstücke

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI LU SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE FR GB IT LI LU SE

17P Request for examination filed

Effective date: 19870108

17Q First examination report despatched

Effective date: 19880628

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE FR GB IT LI LU SE

REF Corresponds to:

Ref document number: 49018

Country of ref document: AT

Date of ref document: 19900115

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3480852

Country of ref document: DE

Date of ref document: 19900201

ITF It: translation for a ep patent filed

Owner name: SOCIETA' ITALIANA BREVETTI S.P.A.

ET Fr: translation filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
ITTA It: last paid annual fee
EPTA Lu: last paid annual fee
EAL Se: european patent in force in sweden

Ref document number: 84101118.2

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19970121

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19970123

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19970214

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19970221

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19970304

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 19970318

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19970326

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19970527

Year of fee payment: 14

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980203

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980203

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980203

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980228

Ref country code: FR

Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY

Effective date: 19980228

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980228

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980228

BERE Be: lapsed

Owner name: LONZA A.G.

Effective date: 19980228

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19980203

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

EUG Se: european patent has lapsed

Ref document number: 84101118.2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19981103

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST