EP0111213B1 - Appareil et procédé pour couler du métal liquide - Google Patents
Appareil et procédé pour couler du métal liquide Download PDFInfo
- Publication number
- EP0111213B1 EP0111213B1 EP83111706A EP83111706A EP0111213B1 EP 0111213 B1 EP0111213 B1 EP 0111213B1 EP 83111706 A EP83111706 A EP 83111706A EP 83111706 A EP83111706 A EP 83111706A EP 0111213 B1 EP0111213 B1 EP 0111213B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ingate
- rotation chamber
- molten metal
- chamber
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 47
- 239000002184 metal Substances 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims description 10
- 238000005266 casting Methods 0.000 claims abstract description 40
- 239000011819 refractory material Substances 0.000 claims abstract description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 239000011261 inert gas Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 239000002054 inoculum Substances 0.000 claims description 7
- 238000011010 flushing procedure Methods 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 230000003628 erosive effect Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000011449 brick Substances 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000008021 deposition Effects 0.000 description 3
- 238000011081 inoculation Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 238000002255 vaccination Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229960005486 vaccine Drugs 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001141 Ductile iron Inorganic materials 0.000 description 1
- 241000792859 Enema Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000007920 enema Substances 0.000 description 1
- 229940095399 enema Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003110 molding sand Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000161 steel melt Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D35/00—Equipment for conveying molten metal into beds or moulds
- B22D35/04—Equipment for conveying molten metal into beds or moulds into moulds, e.g. base plates, runners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/08—Features with respect to supply of molten metal, e.g. ingates, circular gates, skim gates
Definitions
- the invention relates to a pouring device for casting a molten metal, as described in the preamble of claim 1, and a method for casting a molten metal according to the preamble of claim 15.
- the increasing quality requirements for castings with regard to improving the degree of purity and the demand for lowering the production costs by reducing the cleaning and reworking costs for castings are the reason to use improved casting techniques.
- the improvement of the casting technique includes the use of pouring pools with partitions and / or constrictions, which are intended to catch slag and non-metallic inclusions from the pouring stream. This also includes so-called rotating pots and swirl funnels or rotating chambers.
- DE-C-21 59 964 describes a vortex funnel which is primarily used in high-alloy steel castings for reactor parts, pumps, turbine housings, etc.
- This known vortex funnel is designed as an eddy current chamber, which consists of at least three superimposed elements, each of which is composed of building blocks which are interchangeable independently of the other elements.
- This vortex funnel is placed on the bottom of a casting mold and integrated into it and can only be used once.
- DE-A-29 50 393 describes a separator which is made from gasifiable plastic and is also stamped into the casting mold. This separator can also only be used once. It also has the disadvantage that, in the operating state, its wall consists essentially only of stamped-in molding sand, that it is very susceptible to erosion and can therefore itself become a source of non-metallic inclusions.
- DE-A-2544492 describes a casting stone for casting in molds or investment casting molds.
- the known casting stone has a receiving part called a template for the metal.
- melt from the bottom area of which an outlet duct runs to an outlet pipe, which is followed by a form funnel in the direction of the casting mold.
- the impurities in the steel melt should be separated by an extended residence time of the melt in the receiver with the possibility of physical separation due to different densities of impurities and melt.
- the deposition effect of such a device is very limited. In the transition area between the outlet duct and the outlet pipe, there is not only turbulence formation, but also undesired air intake, which leads to oxidation of the pouring jet and thus undesired formation of non-metallic inclusions.
- the object of the invention is to further develop a pouring device designed as a compact unit according to DE-A-25 14 492. that an increased degree of separation of non-metallic inclusions is achieved and in which air absorption (oxidation) of the molten metal is also ruled out.
- a pouring device not only in the casting of quality steels, but also in simple alloy steels, gray and nodular cast iron and non-ferrous metal casting, which do not tolerate high costs for additional techniques to improve the quality properties.
- a method according to the invention to be created is intended to simplify and improve the casting of molten metal while at the same time increasing the deposition of non-metallic inclusions.
- the receiving part is designed as a conically expanding rotary chamber and the inlet part opens tangentially into the rotary chamber, causing the incoming molten metal to undergo violent rotation.
- the design of the outlet part with a discharge gradient further ensures that no metallic material from the previous use is present when the pouring device is used again, so that its constant functionality is guaranteed.
- Solidified casting material remaining in the so-called bottom sump after the casting process can easily be removed by the conical design of the rotary chamber.
- a rounded transition between the floor and the peripheral wall further facilitates the removability.
- the solidified residual content is significantly reduced compared to that of the known fluidized funnels, which gives a significant improvement in the economy of casting metal melts.
- the metal yield per casting is significantly improved and a higher utilization of the melting capacity is achieved, which is ultimately reflected in an energy saving.
- the pouring device according to the invention no longer has any joints that can be rinsed out or through which liquid metal can break through. This completely avoids the fact that the vortex funnel itself can become a source of non-metallic inclusions.
- the outlet opening on the rotation chamber is designed as a horizontal slot and the molten metal emerges from the rotation chamber in the radial direction.
- the length of the horizontal slot is greater than its width, which ensures a largely loss-free radial escape of the molten metal.
- the outlet opening of the outlet part is arranged at the bottom of the rotation chamber, so that the molten metal leaves the rotation chamber through the bottom. It is advantageous if the outlet opening is not arranged in the middle of the bottom, but eccentrically.
- the inlet opening on the rotation chamber is designed as a vertical slot.
- a special rotational effect of the molten metal is achieved together with the feature of tangential inflow.
- the inlet part into the rotation chamber is then designed as a vertical slot, the length of which is greater than its width.
- the advantageous triangular arrangement of the rotation chamber, filler opening and outlet opening enables the compact trapezoidal design of the pouring device, as a result of which a material-saving design is achieved.
- Sealing fire chamotte, tabular clay, sintered mullite and corundum are proposed as temperature change and erosion-resistant refractory raw materials.
- a feed device for an inert purge gas enables the liquid metal rotating in the rotation chamber to be purged with an inert gas.
- This has the advantage that oxygen that may have been introduced is immediately removed again during the filling of the pouring device, so that an essential source of formation for the formation of non-metallic inclusions is thereby eliminated.
- flushing the rotary vortex with an inert flushing gas, in particular with argon increases the deposition effect of already existing, non-metallic, macroscopic and, above all, microscopic inclusions in a way that was not to be expected.
- the feed device for the purge gas is preferably arranged at the bottom of the rotation chamber by using a gas-permeable base part, such as a gas purge stone.
- the pouring device according to the invention has an addition chamber for inoculants. Accordingly, vaccination with inoculation metals, for example magnesium or silicon, can take place during the casting. Since the vaccination is carried out in a rotating pouring stream, the vaccination effect is improved and the vaccine metal can be used more economically and better.
- inoculation metals for example magnesium or silicon
- the addition chamber is advantageously arranged diametrically opposite the outlet cross section as a pocket or opening for receiving or feeding in the inoculant.
- the inoculation metal can be placed in this pocket or chamber before the start of watering or can be fed continuously in the form of a wire or granules through the opening.
- the supply of the seed metal in the rotating metal stream results in a better mixing of the seed metal and thus a higher effectiveness.
- the invention also provides for the outlet cross section to be closed with a metal plate which melts after the pouring device has been filled with molten metal.
- the avoidance of air access is optimized if the pouring device is flanged directly to the casting system of the mold via a tongue and groove connection. This eliminates the otherwise necessary pouring funnel, through which atmospheric oxygen is sucked into the liquid melt.
- This reusable compact unit combines the advantages of the well-known rotating puddle and the pouring basin and creates optimal hydraulic flow conditions in a confined space for separating non-metallic inclusions.
- the invention further relates to a method for casting molten metal, in which the rotating molten metal is flushed with an inert gas and / or, if appropriate, a vaccine is added.
- An inert gas can also be fed into the casting mold before the start of casting, so that the oxygen partial pressure of the casting chamber atmosphere is decisively reduced.
- inert gases such as argon or nitrogen, can also be flushed. So the separation effect is not me metallic inclusions significantly improved because the flushing action in the rotating vortex creates an additional possibility that micro- and macroscopic non-metallic inclusions are enlarged by coagulation and can then be separated in the rotating vortex.
- argon or nitrogen can also be flushed.
- the pouring device designed as a compact unit consists of an inlet part 1, a rotation chamber 2, preferably with a circular cross section, with a base 5 and an outlet part 4.
- the inlet part 1 opens into the rotation chamber 2 with an inlet opening 7 and the outlet part 4 is via the Outlet opening 6 connected to the rotation chamber 2.
- the upper area of the inlet part 1 is designed as a funnel 8 and has a filling opening 14.
- the molten metal flows into the rotation chamber 2 via the funnel 8.
- the inlet opening 7 is designed as a vertical slot. This slit-shaped design is necessary so that the liquid metal stream can enter tangentially into the rotation feature 2 in accordance with arrow 11 (see FIG. 2) in order to generate a strong rotating vortex.
- the outlet opening 6 is designed as a horizontal slot radially to the rotation chamber, so that the rotating liquid metal leaves the rotation chamber 2 in the radial direction according to arrow 12.
- the outlet part 4 has a drainage gradient up to the outlet opening 15, which is preferably directed downward, so that no liquid metal can remain in the outlet part 4.
- the outlet opening 6, which is designed as a horizontal slot and is arranged radially, ensures a space-saving design and a low bottom sump height H in good flow conditions. So that no metal melt remains in the inlet nozzle, the bottom edge of the inlet opening 7 must be at the same height or higher than the bottom edge of the outlet opening 6 .
- the ratio of width to height at the inlet opening should be in the range 1: 1.5 to 1: 4, that at the outlet opening should preferably be in a range from 1.5: 1 to 4: 1.
- the rotation chamber 2 is designed to widen conically from bottom to top, at least to the lower edge of the outlet opening 6, the taper being at least 1%.
- This height H of the so-called bottom sump is 0 to 50% - preferably 5 to 20% - of the total height of the rotation chamber 2.
- the transition from the bottom 5 to the peripheral wall of the rotation chamber is rounded.
- the lower edge of the outlet opening 6 can also be arranged with the bottom 5, so that the rotation chamber is completely emptied.
- the rotation chamber has at the bottom 5 a gas-permeable bottom part 9, such as. B. a ceramic gas purging plug, which with a tube 10, a feed device for an inert purging gas, such as. B. forms argon.
- the feed device can also be arranged so that the inert gas is fed radially or tangentially into the rotation chamber.
- the rotation chamber 2, the filler opening 14 and the outlet opening 15 are arranged in a triangular arrangement with respect to one another, as viewed from above, whereby the compact unit can be made trapezoidal in terms of material, seen in the same view.
- the metal melt entering the inlet part 1 via the funnel 8 flows through the inlet opening 7 into the rotation chamber 2.
- the arrangement of the inlet opening 7 ensures that the metal melt enters the rotation chamber 2 in the tangential direction according to arrow 11. This causes the liquid metal to rotate vigorously.
- the metal melt rotating in the rotation chamber 2 can be admixed with inoculant via an addition chamber 3.
- the addition chamber 3 is preferably arranged diametrically opposite the outlet opening 6.
- the molten metal enters the outlet part 4 through the outlet opening 6 in the radial direction according to arrow 12. Possibly the outlet opening 6 is closed with a metal plate which melts after the pouring device is filled with molten metal.
- Figure 3 shows an alternative embodiment, which is characterized in that the molten metal does not exit radially but vertically downwards.
- the outlet opening 13 is advantageously arranged eccentrically on the base 5.
- the pouring device according to the invention can be used several times in succession without impairing its functionality.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Furnace Charging Or Discharging (AREA)
Claims (17)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT83111706T ATE27419T1 (de) | 1982-12-03 | 1983-11-23 | Eingussvorrichtung zum vergiessen von metallschmelzen sowie ein verfahren zum vergiessen von metallschmelze. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3244824 | 1982-12-03 | ||
DE3244824A DE3244824C2 (de) | 1982-12-03 | 1982-12-03 | Eingießvorrichtung zum Vergießen einer Metallschmelze sowie Verfahren zum Vergießen derselben |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0111213A2 EP0111213A2 (fr) | 1984-06-20 |
EP0111213A3 EP0111213A3 (en) | 1984-08-01 |
EP0111213B1 true EP0111213B1 (fr) | 1987-05-27 |
Family
ID=6179761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83111706A Expired EP0111213B1 (fr) | 1982-12-03 | 1983-11-23 | Appareil et procédé pour couler du métal liquide |
Country Status (4)
Country | Link |
---|---|
US (1) | US4741463A (fr) |
EP (1) | EP0111213B1 (fr) |
AT (1) | ATE27419T1 (fr) |
DE (2) | DE3244824C2 (fr) |
Cited By (11)
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---|---|---|---|---|
US7781108B2 (en) | 2003-11-10 | 2010-08-24 | Polyplus Battery Company | Active metal fuel cells |
US7829212B2 (en) | 2004-02-06 | 2010-11-09 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
US7838144B2 (en) | 2002-10-15 | 2010-11-23 | Polyplus Battery Company | Protective composite battery separator and electrochemical device component with red phosphorus |
US7858223B2 (en) | 2002-10-15 | 2010-12-28 | Polyplus Battery Company | Electrochemical device component with protected alkali metal electrode |
US8182943B2 (en) | 2005-12-19 | 2012-05-22 | Polyplus Battery Company | Composite solid electrolyte for protection of active metal anodes |
US8202649B2 (en) | 2003-10-14 | 2012-06-19 | Polyplus Battery Company | Active metal/aqueous electrochemical cells and systems |
US8652692B2 (en) | 2005-11-23 | 2014-02-18 | Polyplus Battery Company | Li/Air non-aqueous batteries |
US8828574B2 (en) | 2011-11-15 | 2014-09-09 | Polyplus Battery Company | Electrolyte compositions for aqueous electrolyte lithium sulfur batteries |
US8828575B2 (en) | 2011-11-15 | 2014-09-09 | PolyPlus Batter Company | Aqueous electrolyte lithium sulfur batteries |
US8828573B2 (en) | 2011-11-15 | 2014-09-09 | Polyplus Battery Company | Electrode structures for aqueous electrolyte lithium sulfur batteries |
US9368775B2 (en) | 2004-02-06 | 2016-06-14 | Polyplus Battery Company | Protected lithium electrodes having porous ceramic separators, including an integrated structure of porous and dense Li ion conducting garnet solid electrolyte layers |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07185739A (ja) * | 1993-11-30 | 1995-07-25 | John Campbell | 溶融金属の鋳造方法 |
US5516081A (en) * | 1994-07-18 | 1996-05-14 | General Electric Company | Water-cooled molten metal refining hearth |
US6214061B1 (en) | 1998-05-01 | 2001-04-10 | Polyplus Battery Company, Inc. | Method for forming encapsulated lithium electrodes having glass protective layers |
US6019158A (en) * | 1998-05-14 | 2000-02-01 | Howmet Research Corporation | Investment casting using pour cup reservoir with inverted melt feed gate |
US6413285B1 (en) | 1999-11-01 | 2002-07-02 | Polyplus Battery Company | Layered arrangements of lithium electrodes |
US6413284B1 (en) | 1999-11-01 | 2002-07-02 | Polyplus Battery Company | Encapsulated lithium alloy electrodes having barrier layers |
KR20120118511A (ko) | 2002-10-15 | 2012-10-26 | 폴리플러스 배터리 컴퍼니 | 활성 금속 애노드를 보호하기 위한 이온 전도성 합성물 |
US9660265B2 (en) | 2011-11-15 | 2017-05-23 | Polyplus Battery Company | Lithium sulfur batteries and electrolytes and sulfur cathodes thereof |
US9905860B2 (en) | 2013-06-28 | 2018-02-27 | Polyplus Battery Company | Water activated battery system having enhanced start-up behavior |
DE102017100805A1 (de) | 2017-01-17 | 2018-07-19 | Nemak, S.A.B. De C.V. | Gießform zum Gießen von komplex geformten Gussteilen und Verwendung einer solchen Gießform |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US889723A (en) * | 1907-05-14 | 1908-06-02 | Philip Schwickart | Casting device. |
AT243051B (de) * | 1963-11-09 | 1965-10-25 | Buna Chem Werke Veb | Gießform für die aluminothermische Schweißung von senkrecht gestoßenen Rundstählen |
US3892272A (en) * | 1969-03-14 | 1975-07-01 | Amsted Ind Inc | Apparatus for the removal of non-metallic impurities from molten metal |
CH550624A (de) * | 1970-12-31 | 1974-06-28 | Fischer Ag Georg | Wirbelstromkammer zum entfernen von verunreinigungen, insbesondere schlacke, aus metallschmelzen. |
DE2215273C3 (de) * | 1972-03-29 | 1978-11-23 | Friedrich 7130 Muehlacker Nielsen | Wirbelmassel-Bremslauf-Kombination |
SU480487A1 (ru) * | 1974-02-11 | 1975-08-15 | Владимирский политехнический институт | Центробежный шлакоулавитель |
DE2514492B2 (de) * | 1975-04-03 | 1977-06-02 | Fried. Krupp Gmbh, 4300 Essen | Giesstein |
SU558746A1 (ru) * | 1975-10-06 | 1977-05-25 | Предприятие П/Я В-8495 | Литникова система |
FR2350909A1 (fr) * | 1976-05-10 | 1977-12-09 | Zeppellini Dino | Recipient ou poche de coulee pour pieces moulees ou matieres diverses |
DE2708135A1 (de) * | 1977-02-25 | 1978-08-31 | Schauenburg Masch | Vorrichtung zur aufbereitung von truebe |
SU622558A1 (ru) * | 1977-04-06 | 1978-09-05 | Нижне-Тагильский Филиал Производственно-Технического Объединения "Оргсантехпром" | Литникова система |
DE2830811C2 (de) * | 1978-07-13 | 1982-07-29 | Eisen- und Stahlwerk Pleissner GmbH, 3420 Herzberg | Verfahren und Vorrichtung zum Gießen von Formgußstücken |
SU776739A1 (ru) * | 1978-09-08 | 1980-11-07 | Харьковский автомобильно-дорожный институт | Литникова система |
WO1980000546A1 (fr) * | 1978-09-15 | 1980-04-03 | Ssab Svenskt Stal Ab | Procede d'ouverture de la buse d'une cuve refractaire dans la coulee continue de l'acier |
DE2919880C2 (de) * | 1979-05-17 | 1983-10-13 | Didier-Werke Ag, 6200 Wiesbaden | Feuerfestes Gießrohr zwischen Gießpfanne und Zwischenbehältern von Stranggießanlagen |
DE2950393A1 (de) * | 1979-12-14 | 1981-06-19 | Rheinhold & Mahla Gmbh, 6800 Mannheim | Seperator |
SU967668A1 (ru) * | 1981-04-03 | 1982-10-23 | Институт проблем литья АН УССР | Литникова система дл обработки расплава реагентами |
WO1982003582A1 (fr) * | 1981-04-23 | 1982-10-28 | Kobzar Vladimir Evgenevich | Poche de coulee |
US4779668A (en) * | 1981-10-16 | 1988-10-25 | General Motors Corporation | Treatment of cast metal in cope mold pouring basin |
-
1982
- 1982-12-03 DE DE3244824A patent/DE3244824C2/de not_active Expired
-
1983
- 1983-11-23 AT AT83111706T patent/ATE27419T1/de not_active IP Right Cessation
- 1983-11-23 EP EP83111706A patent/EP0111213B1/fr not_active Expired
- 1983-11-23 DE DE8383111706T patent/DE3371752D1/de not_active Expired
-
1984
- 1984-11-29 US US06/676,242 patent/US4741463A/en not_active Expired - Fee Related
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US7838144B2 (en) | 2002-10-15 | 2010-11-23 | Polyplus Battery Company | Protective composite battery separator and electrochemical device component with red phosphorus |
US7858223B2 (en) | 2002-10-15 | 2010-12-28 | Polyplus Battery Company | Electrochemical device component with protected alkali metal electrode |
US8114171B2 (en) | 2002-10-15 | 2012-02-14 | Polyplus Battery Company | In situ formed ionically conductive membranes for protection of active metal anodes and battery cells |
US9362538B2 (en) | 2002-10-15 | 2016-06-07 | Polyplus Battery Company | Advanced lithium ion batteries based on solid state protected lithium electrodes |
US8778522B2 (en) | 2002-10-15 | 2014-07-15 | Polyplus Battery Company | Protected lithium electrodes based on sintered ceramic or glass ceramic membranes |
US9601779B2 (en) | 2003-10-14 | 2017-03-21 | Polyplus Battery Company | Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes |
US9419299B2 (en) | 2003-10-14 | 2016-08-16 | Polyplus Battery Company | Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes |
US8202649B2 (en) | 2003-10-14 | 2012-06-19 | Polyplus Battery Company | Active metal/aqueous electrochemical cells and systems |
US9136568B2 (en) | 2003-10-14 | 2015-09-15 | Polyplus Battery Company | Protected lithium electrodes having tape cast ceramic and glass-ceramic membranes |
US8709679B2 (en) | 2003-11-10 | 2014-04-29 | Polyplus Battery Company | Active metal fuel cells |
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Also Published As
Publication number | Publication date |
---|---|
EP0111213A2 (fr) | 1984-06-20 |
ATE27419T1 (de) | 1987-06-15 |
DE3244824A1 (de) | 1984-06-14 |
US4741463A (en) | 1988-05-03 |
DE3371752D1 (en) | 1987-07-02 |
DE3244824C2 (de) | 1985-10-24 |
EP0111213A3 (en) | 1984-08-01 |
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