EP0105835A1 - Procédé de production d'une couche dure sur des pièces en Ti ou alliages de Ti - Google Patents
Procédé de production d'une couche dure sur des pièces en Ti ou alliages de Ti Download PDFInfo
- Publication number
- EP0105835A1 EP0105835A1 EP83810395A EP83810395A EP0105835A1 EP 0105835 A1 EP0105835 A1 EP 0105835A1 EP 83810395 A EP83810395 A EP 83810395A EP 83810395 A EP83810395 A EP 83810395A EP 0105835 A1 EP0105835 A1 EP 0105835A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- component
- autoclave
- titanium
- alloys
- nitride layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/048—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
Definitions
- the invention is based on a method for forming a nitride layer in the edge zone of a component consisting of elements of the fourth, fifth or sixth subgroups of the periodic system or their alloys.
- the nitride layer is intended to increase the wear properties of the surface of, for example, titanium or its alloys.
- titanium with H ärteober Diagram yarn guide for textile machines balls, for example, turbine blades for prosthesis shafts, wear and corrosion resistant parts of the apparatus of the chemical industry prepared.
- Another way of hardening the surface of the titanium component is to immerse the the same in a molten salt cyanide base at about 800 0 C. Such a treatment creates a mixed crystal zone that contains nitrogen, carbon and small amounts of oxygen.
- the layer thickness is approx. 0.035 mm with a hardness of 7 00 HV 0.025 at the outer zone. This is Degussa's well-known Tiduran process.
- the known ionitriding is carried out at treatment temperatures of 400 ° to 600 ° C. With the help of an abnormal glow discharge, nitrogen is generated in ionized form and stored in the workpiece surfaces.
- the hardness values at the edge are approx. 1500 HV 0.1 and drop to a depth of 30 u to 400 HV 0.1 .
- GB-PS 1,537,891 describes a method for embroidering hard metal bodies after their sintering. Immediately after sintering, the nitrogen is pressed into the vacancies of the hard metal grid, which tensions the hard metal matrix and improves the cutting properties. A measurable increase in hardness is not achieved.
- the invention specified in claim 1 is based on the object of cost-effectively remedying the disadvantages of the known methods described above. In the process, there should be no distortion of the component and no uneven tensions on the surface layer. The part to be nitrided should not carry any electrical current.
- the object is achieved in a method according to the preamble of patent claim 1, characterized in that the chemically untreated component in an autoclave with a group consisting of nitrogen gas or gaseous nitrogen compounds atmosphere during at least one hour to an isostatic pressure of at least 100 bar and a temperature of at least 200 0 C is suspended, after which the pressure and the The heat in the autoclave is gradually reduced evenly.
- a continuous, evenly distributed nitride layer with a thickness of approximately 20 ⁇ is formed on the component.
- the z. B. made of chemically untreated titanium or its alloys is placed in an autoclave in which pure nitrogen gas is pumped. Instead of titanium, the remaining elements of the fourth, fifth or sixth subgroups of the periodic system or their alloys can also be used.
- the titanium component in the autoclave must be exposed to an isostatic pressure of at least 100 bar and a temperature of at least 200 ° C for at least one hour.
- the isostatic pressure in the autoclave ensures a continuous, even distribution of the nitrogen in the surface of the titanium component at every geometrical location. When cooling down, the pressure and heat drop evenly slowly. As a result, there is no distortion of the component and no uneven tensions in the surface layer.
- the autoclave is known in the art under the name "hot isostatic press” and is used for this treatment with some changes in the gas supply and discharge.
- One or more additional hardening layers can be applied to the titanium nitride layer produced in the above-mentioned method in the edge zone of the titanium component by chemical or physical vapor deposition. This would not be possible without the titanium nitric layer formed first in the edge zone of the titanium component, because the hard layers applied to a component made of titanium, the surface of which was not treated as described above, are subject to peeling abrasion.
- the nitrogen combines with titanium to form a TiN layer which is formed in the edge zone of the titanium component and has a thickness of approximately 20 ⁇ m. It is possible to keep the isostatic pressure up to 5000 bar and the temperature up to 1200 C during the holding time phase of nitrogen diffusion into the titanium component. The higher these values, the limited the thickness of the nitride layer. There is no material application to the component; the hardness layer grows inside the component.
- a component of the alloy Ti6 A14 V was exposed to nitrogen, and a temperature of 1000 0 C bar for three hours at a pressure of 900th
- the hardness at the edge is 800 HV 0, ⁇ at a film thickness of 20 05 (see Fig. 1).
- a component of the alloy Ti6 A14 V was exposed to a pressure of 1300 bar nitrogen and a temperature of 930 ° C for three hours.
- the hardness at the edge is 800 HV 0.05 with a layer thickness of 0.012 mm (see Fig. 2).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT83810395T ATE31559T1 (de) | 1982-09-07 | 1983-08-31 | Verfahren zur bildung einer haerteschicht im bauteil aus titan oder titanlegierungen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH5313/82A CH650532A5 (de) | 1982-09-07 | 1982-09-07 | Verfahren zur bildung einer haerteschicht im bauteil aus elementen der vierten, fuenften oder sechsten nebengruppen des periodischen systems oder deren legierungen. |
CH5313/82 | 1982-09-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0105835A1 true EP0105835A1 (fr) | 1984-04-18 |
EP0105835B1 EP0105835B1 (fr) | 1987-12-23 |
Family
ID=4291498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83810395A Expired EP0105835B1 (fr) | 1982-09-07 | 1983-08-31 | Procédé de production d'une couche dure sur des pièces en Ti ou alliages de Ti |
Country Status (8)
Country | Link |
---|---|
US (1) | US4511411A (fr) |
EP (1) | EP0105835B1 (fr) |
JP (1) | JPS59140372A (fr) |
AT (1) | ATE31559T1 (fr) |
CA (1) | CA1214364A (fr) |
CH (1) | CH650532A5 (fr) |
DE (1) | DE3375027D1 (fr) |
IL (1) | IL69633A (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992009716A1 (fr) * | 1990-11-26 | 1992-06-11 | Siemens Power Corporation | Composants resistants a l'usure pour conduits de combustible nucleaire |
US5211768A (en) * | 1990-11-15 | 1993-05-18 | Degussa Aktiengesellschaft | Method of nitriding work pieces of steel under pressure |
EP0545069A1 (fr) * | 1991-12-04 | 1993-06-09 | Leybold Durferrit GmbH | Procédé de traitement d'aciers et de métaux réfractaires |
EP0544987A1 (fr) * | 1991-12-04 | 1993-06-09 | Leybold Durferrit GmbH | Procédé de traitement d'acier alliés et de métaux réfractaires |
US5292555A (en) * | 1990-07-04 | 1994-03-08 | Degussa Aktiengesellschaft | Process for applying nitride layers to titanium |
DE4332912C1 (de) * | 1993-09-23 | 1994-06-01 | Johann Grosch | Thermochemisches Verfahren zur induktiven Randschichtbehandlung von Bauteilen aus Titan oder Titanlegierungen in stickstoffhaltigen Atmosphären |
EP0464265B1 (fr) * | 1990-07-04 | 1996-03-06 | Degussa Aktiengesellschaft | Procédé de nitruration de titane |
WO1998011272A1 (fr) * | 1996-09-13 | 1998-03-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Structure de couche marginale pour titane ou ses alliages, resistant a l'usure, pouvant etre fortement sollicitee sur le plan mecanique et a faible coefficient de frottement, et procede permettant de la realiser |
CN109154040A (zh) * | 2016-05-23 | 2019-01-04 | 森蒂纳贝公司 | 包含钛金属的工件的处理方法和物品 |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6483653A (en) * | 1987-09-24 | 1989-03-29 | Fujikura Ltd | Wear-resistant member |
US5573401A (en) * | 1989-12-21 | 1996-11-12 | Smith & Nephew Richards, Inc. | Biocompatible, low modulus dental devices |
US5683442A (en) * | 1989-12-21 | 1997-11-04 | Smith & Nephew, Inc. | Cardiovascular implants of enhanced biocompatibility |
US5509933A (en) * | 1989-12-21 | 1996-04-23 | Smith & Nephew Richards, Inc. | Medical implants of hot worked, high strength, biocompatible, low modulus titanium alloys |
US5477864A (en) * | 1989-12-21 | 1995-12-26 | Smith & Nephew Richards, Inc. | Cardiovascular guidewire of enhanced biocompatibility |
US5674280A (en) * | 1989-12-21 | 1997-10-07 | Smith & Nephew, Inc. | Valvular annuloplasty rings of a biocompatible low elastic modulus titanium-niobium-zirconium alloy |
SE9001009L (sv) * | 1990-03-21 | 1991-09-22 | Ytbolaget I Uppsala Ab | Foerfarande foer att bilda ett haart och slitagebestaendigt skikt med god vidhaeftning paa titan eller titanregleringar och produkter, framstaellda enligt foerfarandet |
US5123972A (en) * | 1990-04-30 | 1992-06-23 | Dana Corporation | Hardened insert and brake shoe for backstopping clutch |
US5039357A (en) * | 1990-06-15 | 1991-08-13 | Dynamic Metal Treating, Inc. | Method for nitriding and nitrocarburizing rifle barrels in a fluidized bed furnace |
US5254183A (en) * | 1991-12-20 | 1993-10-19 | United Techynologies Corporation | Gas turbine elements with coke resistant surfaces |
US5298091A (en) * | 1991-12-20 | 1994-03-29 | United Technologies Corporation | Inhibiting coke formation by heat treating in nitrogen atmosphere |
US5518820A (en) * | 1992-06-16 | 1996-05-21 | General Electric Company | Case-hardened titanium aluminide bearing |
CN1054647C (zh) * | 1994-03-17 | 2000-07-19 | 泰利达因工业有限公司 | 复合制品的制备方法 |
US5820707A (en) * | 1995-03-17 | 1998-10-13 | Teledyne Industries, Inc. | Composite article, alloy and method |
US5954724A (en) | 1997-03-27 | 1999-09-21 | Davidson; James A. | Titanium molybdenum hafnium alloys for medical implants and devices |
US6238491B1 (en) | 1999-05-05 | 2001-05-29 | Davitech, Inc. | Niobium-titanium-zirconium-molybdenum (nbtizrmo) alloys for dental and other medical device applications |
US7338529B1 (en) | 2004-03-30 | 2008-03-04 | Biomet Manufacturing Corp. | Methods and apparatuses for enhancing prosthetic implant durability |
GB2412701B (en) | 2004-03-31 | 2006-03-22 | Minebea Co Ltd | A metal-to-metal spherical bearing |
US7833339B2 (en) * | 2006-04-18 | 2010-11-16 | Franklin Industrial Minerals | Mineral filler composition |
DE102008030186A1 (de) * | 2008-06-26 | 2009-12-31 | Siemens Aktiengesellschaft | Verfahren zum Erzeugen eines Bauteils durch selektives Laserschmelzen sowie hierfür geeignete Prozesskammer |
GB2497354B (en) * | 2011-12-07 | 2014-09-24 | Solaris Holdings Ltd | Method of improvement of mechanical properties of products made of metals and alloys |
CN104711632A (zh) * | 2013-12-13 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种用于氧碘化学激光器原料再生的电化学反应器及再生方法 |
WO2022170009A1 (fr) | 2021-02-05 | 2022-08-11 | Xylem Water Solutions U.S.A., Inc. | Système et procédé de récupération de ressources à partir de courants d'eaux usées |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE970456C (de) * | 1952-11-11 | 1958-09-18 | Metallgesellschaft Ag | Verfahren zur Herstellung von UEberzuegen aus hochschmelzenden Nitriden auf Metallen |
FR2302350A1 (fr) * | 1975-02-28 | 1976-09-24 | Plansee Metallwerk | Objets d'usage cour |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1793309A (en) * | 1930-02-26 | 1931-02-17 | Electro Metallurg Co | Process of case hardening |
JPS4991074A (fr) * | 1972-12-29 | 1974-08-30 | ||
JPS52145343A (en) * | 1976-05-29 | 1977-12-03 | Kiyoichi Ogawa | Pressurized nitriding |
DE2717842C2 (de) * | 1977-04-22 | 1983-09-01 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zur Oberflächenbehandlung von gesinterten Hartmetallkörpern |
-
1982
- 1982-09-07 CH CH5313/82A patent/CH650532A5/de not_active IP Right Cessation
-
1983
- 1983-08-31 DE DE8383810395T patent/DE3375027D1/de not_active Expired
- 1983-08-31 AT AT83810395T patent/ATE31559T1/de not_active IP Right Cessation
- 1983-08-31 EP EP83810395A patent/EP0105835B1/fr not_active Expired
- 1983-09-02 IL IL69633A patent/IL69633A/xx unknown
- 1983-09-02 US US06/528,954 patent/US4511411A/en not_active Expired - Fee Related
- 1983-09-07 CA CA000436180A patent/CA1214364A/fr not_active Expired
- 1983-09-07 JP JP58163386A patent/JPS59140372A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE970456C (de) * | 1952-11-11 | 1958-09-18 | Metallgesellschaft Ag | Verfahren zur Herstellung von UEberzuegen aus hochschmelzenden Nitriden auf Metallen |
FR2302350A1 (fr) * | 1975-02-28 | 1976-09-24 | Plansee Metallwerk | Objets d'usage cour |
Non-Patent Citations (6)
Title |
---|
CHEMICAL ABSTRACTS, Band 91, Nr. 20, November 1979, Seite 243, Nr. 161561c, Columbus, Ohio, US * |
CHEMICAL ABSTRACTS, Band 92, Nr. 10, März 1980, Seite 263, Nr. 80578g, Columbus, Ohio, US * |
CHEMICAL ABSTRACTS, Band 93, Nr. 6, August 1980, Seite 338, Nr. 52058q, Columbus, Ohio, US * |
CHEMICAL ABSTRACTS, Band 96, Nr. 2, Januar 1982, Seite 220, Nr. 23520r, Columbus, Ohio, US * |
PATENTS ABSTRACTS OF JAPAN, Band 6, Nr. 143(C-117)[1021], 3. August 1982 * |
ZEITSCHRIFT FÜR PHYSIK, Band 210, Nr. 1, 1968, Seiten 70-79 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5292555A (en) * | 1990-07-04 | 1994-03-08 | Degussa Aktiengesellschaft | Process for applying nitride layers to titanium |
EP0464265B1 (fr) * | 1990-07-04 | 1996-03-06 | Degussa Aktiengesellschaft | Procédé de nitruration de titane |
US5211768A (en) * | 1990-11-15 | 1993-05-18 | Degussa Aktiengesellschaft | Method of nitriding work pieces of steel under pressure |
WO1992009716A1 (fr) * | 1990-11-26 | 1992-06-11 | Siemens Power Corporation | Composants resistants a l'usure pour conduits de combustible nucleaire |
US5265137A (en) * | 1990-11-26 | 1993-11-23 | Siemens Power Corporation | Wear resistant nuclear fuel assembly components |
EP0545069A1 (fr) * | 1991-12-04 | 1993-06-09 | Leybold Durferrit GmbH | Procédé de traitement d'aciers et de métaux réfractaires |
EP0544987A1 (fr) * | 1991-12-04 | 1993-06-09 | Leybold Durferrit GmbH | Procédé de traitement d'acier alliés et de métaux réfractaires |
DE4332912C1 (de) * | 1993-09-23 | 1994-06-01 | Johann Grosch | Thermochemisches Verfahren zur induktiven Randschichtbehandlung von Bauteilen aus Titan oder Titanlegierungen in stickstoffhaltigen Atmosphären |
WO1998011272A1 (fr) * | 1996-09-13 | 1998-03-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Structure de couche marginale pour titane ou ses alliages, resistant a l'usure, pouvant etre fortement sollicitee sur le plan mecanique et a faible coefficient de frottement, et procede permettant de la realiser |
US6231956B1 (en) | 1996-09-13 | 2001-05-15 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V | Wear-resistance edge layer structure for titanium or its alloys which can be subjected to a high mechanical load and has a low coefficient of friction, and method of producing the same |
CN109154040A (zh) * | 2016-05-23 | 2019-01-04 | 森蒂纳贝公司 | 包含钛金属的工件的处理方法和物品 |
CN109154040B (zh) * | 2016-05-23 | 2019-12-10 | 森蒂纳贝公司 | 包含钛金属的工件的处理方法和物品 |
Also Published As
Publication number | Publication date |
---|---|
EP0105835B1 (fr) | 1987-12-23 |
IL69633A (en) | 1987-02-27 |
CH650532A5 (de) | 1985-07-31 |
JPS59140372A (ja) | 1984-08-11 |
ATE31559T1 (de) | 1988-01-15 |
DE3375027D1 (en) | 1988-02-04 |
IL69633A0 (en) | 1983-12-30 |
CA1214364A (fr) | 1986-11-25 |
US4511411A (en) | 1985-04-16 |
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