EP0098484B1 - Herstellung lösungsmittelarmer Polyacrylnitril-Spinnfäden - Google Patents
Herstellung lösungsmittelarmer Polyacrylnitril-Spinnfäden Download PDFInfo
- Publication number
- EP0098484B1 EP0098484B1 EP83106187A EP83106187A EP0098484B1 EP 0098484 B1 EP0098484 B1 EP 0098484B1 EP 83106187 A EP83106187 A EP 83106187A EP 83106187 A EP83106187 A EP 83106187A EP 0098484 B1 EP0098484 B1 EP 0098484B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spinning
- weight
- filaments
- spun
- threads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002904 solvent Substances 0.000 title claims description 14
- 229920002239 polyacrylonitrile Polymers 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000009987 spinning Methods 0.000 claims description 62
- 238000000034 method Methods 0.000 claims description 15
- 239000013557 residual solvent Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000000314 lubricant Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 238000000578 dry spinning Methods 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 33
- 239000000463 material Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920002972 Acrylic fiber Polymers 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 2
- -1 alkyl ether sulfates Chemical class 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920002821 Modacrylic Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/04—Dry spinning methods
Definitions
- Spinning delay V is defined as the ratio of take-off speed A to ejection speed S:
- the preparation is expediently brought into contact with the individual thread ribbons at elevated temperatures of 50-90 ° C. in order to prevent the hot thread sheet from cooling.
- the manhole tapes spun from a spinning machine with, for example, 20 spinning shafts, with a total titer of 100,000 dtex and more, are prepared in this way, bundled after leaving the fusing unit and directly subjected to further post-treatment, e.g. B. with the process steps stretching - crimping - shrinking - cutting.
- the warm acrylic cable with a total titre of 344,000 dtex still has a residual solvent content of 0.8% by weight of DMF.
- the cable can then be stretched, crimped, shrink and cut into staple fibers.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19823225267 DE3225267A1 (de) | 1982-07-06 | 1982-07-06 | Herstellung loesungsmittelarmer polyacrylnitril-spinnfaeden |
DE3225267 | 1982-07-06 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0098484A2 EP0098484A2 (de) | 1984-01-18 |
EP0098484A3 EP0098484A3 (en) | 1985-09-11 |
EP0098484B1 true EP0098484B1 (de) | 1987-01-21 |
Family
ID=6167767
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83106187A Expired EP0098484B1 (de) | 1982-07-06 | 1983-06-24 | Herstellung lösungsmittelarmer Polyacrylnitril-Spinnfäden |
Country Status (4)
Country | Link |
---|---|
US (1) | US4505870A (enrdf_load_stackoverflow) |
EP (1) | EP0098484B1 (enrdf_load_stackoverflow) |
JP (1) | JPS5921712A (enrdf_load_stackoverflow) |
DE (2) | DE3225267A1 (enrdf_load_stackoverflow) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3634753A1 (de) * | 1986-09-05 | 1988-03-17 | Bayer Ag | Kontinuierliche spinnverfahren fuer acrylnitrilfaeden und -fasern mit daempfung des spinngutes |
JPS6366318A (ja) * | 1986-09-05 | 1988-03-25 | バイエル・アクチエンゲゼルシヤフト | アクリロニトリルのフイラメント又は繊維の連続紡糸法 |
DE3832872A1 (de) * | 1988-09-28 | 1990-04-05 | Bayer Ag | Trockenspinnverfahren mit heissluft bei spinnschachtleistungen groesser 20 kg pro schacht und stunde |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2417294A (en) * | 1944-02-25 | 1947-03-11 | Prophylactic Brush Co | Method of preparing molecularly oriented copolymerizates of acrylonitrile and other monoethylenic monomers |
US2811409A (en) * | 1952-12-31 | 1957-10-29 | Eastman Kodak Co | Spinning of acrylonitrile polymer fibers |
BE528519A (enrdf_load_stackoverflow) * | 1953-06-25 | |||
FR1198455A (fr) * | 1957-01-18 | 1959-12-08 | Union Carbide Corp | Procédé de filage de polymères vinyliques |
DE1494553A1 (de) * | 1965-03-02 | 1970-05-06 | Boehme Chem Fab Kg | Verfahren zur Herstellung von Fasern aus Polymeren oder Mischpolymeren des Acrylnitrils nach dem Trockenspinnverfahren |
US3739054A (en) * | 1971-04-05 | 1973-06-12 | Bayer Ag | Process for the production of high shrinkage threads yarns and fibersfrom acrylonitrile polymers |
DE2658916A1 (de) * | 1976-12-24 | 1978-07-06 | Bayer Ag | Polyacrylnitril-filamentgarne |
JPS5541329A (en) * | 1978-09-14 | 1980-03-24 | Toshiba Corp | Switching method of capacity of heating or cooling |
DE2951803A1 (de) * | 1979-12-21 | 1981-07-02 | Bayer Ag, 5090 Leverkusen | Feinsttitrige synthesefasern und -faeden und trockenspinnverfahren zu ihrer herstellung |
DE3026946A1 (de) * | 1980-07-16 | 1982-02-11 | Hoechst Ag, 6000 Frankfurt | Verfahren zum faerben von fasergut aus trockengesponnenen acrylnitril-polymerisaten im gelzustand |
-
1982
- 1982-07-06 DE DE19823225267 patent/DE3225267A1/de active Granted
-
1983
- 1983-06-17 US US06/505,514 patent/US4505870A/en not_active Expired - Fee Related
- 1983-06-24 DE DE8383106187T patent/DE3369350D1/de not_active Expired
- 1983-06-24 EP EP83106187A patent/EP0098484B1/de not_active Expired
- 1983-07-05 JP JP58121119A patent/JPS5921712A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0098484A2 (de) | 1984-01-18 |
US4505870A (en) | 1985-03-19 |
DE3225267C2 (enrdf_load_stackoverflow) | 1990-11-08 |
DE3225267A1 (de) | 1984-01-12 |
EP0098484A3 (en) | 1985-09-11 |
DE3369350D1 (en) | 1987-02-26 |
JPS5921712A (ja) | 1984-02-03 |
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