EP0094655A2 - Concentrated laundry softening agents - Google Patents

Concentrated laundry softening agents Download PDF

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Publication number
EP0094655A2
EP0094655A2 EP83104774A EP83104774A EP0094655A2 EP 0094655 A2 EP0094655 A2 EP 0094655A2 EP 83104774 A EP83104774 A EP 83104774A EP 83104774 A EP83104774 A EP 83104774A EP 0094655 A2 EP0094655 A2 EP 0094655A2
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methyl
weight
alkyl
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carbon atoms
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German (de)
French (fr)
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EP0094655B2 (en
EP0094655A3 (en
EP0094655B1 (en
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Herbert Dr. Stühler
Adolf Dr. May
Hans-Walter Dr. Bücking
Manfred Schreiber
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Hoechst AG
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Hoechst AG
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Abstract

1. A concentrated fabric softener composed of : a) 15 to 25% by weight of a compound of the formulae : see diagramm : EP0094655,P4,F5 see diagramm : EP0094655,P4,F7 see diagramm : EP0094655,P5,F1 wherein R1 denotes alkyl or alkenyl having 8-22, preferably 16-18, carbon atoms, R2 denotes alkyl having 1-4 carbon atoms, preferably methyl, R3 denotes methyl or hydrogen, x denotes a number from 1 to 5 and A denotes an anion, such as, for example, Cl**(-) , Br**(-) , CH3 OSO3 **(-) or (CH3 O)2 PO2 **(-) , b) 0.05 to 35% by weight of a fatty amine polyglykol ether of the formula IV : see diagramm : EP0094655,P5,F3 wherein R1 denotes alkyl or alkenyl having 8-2, preferably 16-18, carbon atoms, x and y denote hydrogen or methyl, but x and y should not both be methyl, n1 and n2 together denote a whole number from 2 to 50, preferably 25, and p and m are both 0 or p is 1 and m is 1, 2 or, preferably, 3, c) 0.05 to 35% by weight of a compound of the formula V : see diagramm : EP0094655,P5,F6 wherein R1 denotes alkyl or alkenyl having 8-35, preferably 16-30, carbon atoms, x and y denote hydrogen or methyl, but x and y should not both be methyl, n denotes a whole number from 1 to 20, preferably 2 to 5, and m denotes a whole number from 0 to 1, preferably 1, of a polyethylene or polypropylene glycol having a molecular weight from 100 to 2,000, preferably 400, or their C1 -C4 -alkyl ethers or of a propylene oxid/ethylene oxide graft polymere having a parent polypropylene oxide molecule of molecular weight 1,500 to 2,500 and a content of ethylene oxide of 5 to 30% relative to the propylene oxide polymer, d) 3-20, preferably 5-10% by weight of a C1 -C3 -alcohol, e) an acid in equimolar amount of component b) and f) water and optionally other customary auxiliaries appropriate for balancing out to 100% by weight.

Description

Es ist bekannt, daß gewaschene Textilien, besonders solche aus Cellulosefasern, nach dem Trocknen eine unangenehme Verhärtung aufweisen. Dies tritt insbesondere dann ein, wenn die Wäsche im Waschautomaten erfolgt. Eine solche unerwünschte Griffverhärtung kann man dadurch beseitigen, daß man die Textilien nach der Wäsche in einem Spülbad mit kationischen Substanzen behandelt, die mindestens zwei langkettige aliphatische Reste im Molekül enthalten. In der Praxis werden für diesen Zweck besonders in Wasser dispergierbare Dialkyldimethylammoniumsalze bzw. Imidazolinderivate verwendet.It is known that washed textiles, especially those made from cellulose fibers, have an unpleasant hardening after drying. This is particularly the case when the laundry is done in the washing machine. Such undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule. In practice, water-dispersible dialkyldimethylammonium salts or imidazoline derivatives are used for this purpose.

Wäßrige Dispersionen dieser Rohstoffe lassen sich bis zu einer Konzentration von 10 - 15 % mit kaltem Wasser herstellen. Höher konzentrierte Formulierungen werden jedoch nach kurzer Lagerzeit dickflüssig, gelartig und lassen sich nicht ohne Gelbildung in kaltem Wasser dispergieren. An ein gutes Konzentrat von Wäscheweichspülmitteln werden daher folgende Anforderungen gestellt: Gute Kaltwasserdispergierbarkeit, kein Nachdicken der Formulierung beim Lagern, keine Trennungserscheinung der Formulierung und keine Bildung von Bodensatz.Aqueous dispersions of these raw materials can be produced with a concentration of 10 - 15% with cold water. However, more concentrated formulations become viscous, gel-like after a short period of storage and cannot be dispersed in cold water without gel formation. The following requirements are therefore placed on a good concentrate of fabric softener: good cold water dispersibility, no thickening of the formulation when stored, no separation of the formulation and no formation of sediment.

Es wurde nun gefunden, daß man diese Forderungen erfüllen kann, wenn man die oben aufgeführten quarternären Ammoniumverbindungen mit bestimmten oxalkylierten Verbindungen kombiniert.It has now been found that these requirements can be met if the quaternary ammonium compounds listed above are combined with certain oxyalkylated compounds.

Gegenstand der Erfindung sind somit konzentrierte Wäscheweichspülmittel, die bestehen aus

  • a) 6 bis 30, vorzugsweise 15 bis 25 Gew.-%. einer Verbindung der Formeln
    Figure imgb0001
    Figure imgb0002
    Figure imgb0003
    worin R1 Alkyl oder Alkenyl mit 8 - 22, vorzugsweise 16 - 18 Kohlenstoffatomen, R2 Alkyl mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff, x eine Zahl von 1 - 5 und A ein Anion wie z.B. Cl(-), Br(-), CH3OSO3 (-) oder CH3OPO3 (-) bedeutet,
  • b) 0,05 bis 35, vorzugsweise 2 bis 5 Gew.-% eines Fettaminpolyglykölethers der Formel IV
    Figure imgb0004
    worin R1 Alkyl oder Alkenyl mit 8 - 22, vorzugsweise 16 - 18 Kohlenstoffatomen, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl sein sollen, n und n2 zusammen eine ganze Zahl von 2 bis 50, bevorzugt,25, bedeuten und p und m sind gleichzeitig 0 oder p ist 1 und m ist 1, 2 oder vorzugsweise 3,
  • c) 0,05 bis 35 Gew.-% einer Verbindung der Formel V
    Figure imgb0005
    worin R1- Alkyl oder Alkenyl mit 8-35, vorzugsweise 16 - 30 Kohlenstoffatomen, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl sein soll, n eine ganze Zahl von 1 - 20, bevorzugt 2 - 5 und m eine ganze Zahl von 0 bis 1 bevorzugt 1, bedeutet, eines Polyethylen- oder Polypropylenglykols mit einem Molgewicht von 100 bis 2000, bevorzugt 400 oder deren C1-C4-Alkylether oder eines Propylenoxid-Ethylenoxid-Pfropfpolymerisats mit einem Polypropylenoxid-Grundkörper vom Molekulargewicht 1500 bis 2500 und einem Gehalt an Ethylenoxid von 5 bis 30 %, bezogen auf das Propylenoxid-Polymer,
  • d) 3 - 20, vorzugsweise 5 - 10 Gew.-%. eines C1-C3-Alkohols,
  • e) einer Säure in einer zur Komponente b) equimolaren Menge und
  • f) Wasser und gegebenenfalls weiteren üblichen Hilfsstoffen entsprechend dem Ausgleich zu 100 Gew.-%.
The invention thus relates to concentrated fabric softeners which consist of
  • a) 6 to 30, preferably 15 to 25 wt .-%. a connection of the formulas
    Figure imgb0001
    Figure imgb0002
    Figure imgb0003
     wherein R 1 is alkyl or alkenyl with 8-22, preferably 16-18, carbon atoms, R 2 alkyl with 1-4 carbon atoms, preferably methyl, R 3 is methyl or hydrogen, x is a number from 1-5 and A is an anion such as Cl ( -) , Br (-) , CH 3 OSO 3 (-) or CH 3 OPO 3 (-) ,
  • b) 0.05 to 35, preferably 2 to 5% by weight of a fatty amine polyglycol ether of the formula IV
    Figure imgb0004
     in which R 1 is alkyl or alkenyl having 8-22, preferably 16-18, carbon atoms, x and y are hydrogen or methyl, where x and y should not be methyl at the same time, n and n 2 together are an integer from 2 to 50, preferably, 25, and p and m are simultaneously 0 or p is 1 and m is 1, 2 or preferably 3,
  • c) 0.05 to 35 wt .-% of a compound of formula V
    Figure imgb0005
     wherein R 1 - alkyl or alkenyl with 8-35, preferably 16 - 30 carbon atoms, x and y are hydrogen or methyl, but x and y should not be methyl at the same time, n is an integer from 1 to 20, preferably 2 to 5 and m is an integer from 0 to 1, preferably 1, means a polyethylene or polypropylene glycol with a molecular weight of 100 to 2000, preferably 400 or their C 1 -C 4 -alkyl ether or a propylene oxide / ethylene oxide graft polymer with a polypropylene oxide base body of Molecular weight 1500 to 2500 and an ethylene oxide content of 5 to 30%, based on the propylene oxide polymer,
  • d) 3-20, preferably 5-10% by weight. a C 1 -C 3 alcohol,
  • e) an acid in an amount equimolar to component b) and
  • f) water and, if appropriate, other customary auxiliaries in accordance with the balance at 100% by weight.

Bei den Fettaminpolyglykolethern b) und den Propylenoxid-Ethylenoxid Pfropfpolymerisaten c) handelt es sich um kommerziell verfügbare Produkte (Genamin® und Genapol® PF Marken). Auch die oxalkylierten Fettalkohole und Fettsäuren unter c) sowie die Polyalkylenglykole und deren Ether stellen Handelsprodukte dar.The fatty amine polyglycol ethers b) and the propylene oxide-ethylene oxide graft polymers c) are commercially available products (Genamin® and Genapol® PF brands). The oxyalkylated fatty alcohols and fatty acids under c) and the polyalkylene glycols and their ethers are also commercial products.

Als Komponente c) können entweder nur eine der dort aufgeführten Verbindungstypen oder aber deren Mischungen zugegen sein. Die oxalkylierten Fettalkohole und Fettsäuren der Formel V werden vorzugsweise in Mengen von 1 bis 5 Gew.-%, die Polyalkylenglykole und die Pfropfpolymerisate vorzugsweise in Mengen von 5 bis 10 Gew.-% eingesetzt.Component c) can be either only one of the types of compounds listed there or mixtures thereof. The oxyalkylated fatty alcohols and fatty acids of the formula V are preferably used in amounts of 1 to 5% by weight, the polyalkylene glycols and the graft polymers are preferably used in amounts of 5 to 10% by weight.

Bei der Bereitung der konzentrierten Weichspülmittel gemäß der Erfindung werden die kationischen weichmachenden Verbindungen der Formel I - III zweckmäßig in Form ihrer konzentrierten Lösungen in niederen Alkoholen, vorzugsweise Isopropanol oder im Gemisch dieser Alkohole mit Wasser eingesetzt. Die erfindungsgemäßen Wäscheweichspülmittel enthalten daher eine bestimmte Menge solcher niederer Alkohole. Als Säuren kommen in Frage, beispielsweise Essigsäure, Phosphorsäure, Schwefelsäure, org. Säuren oder Salzsäure. Diese Säuren werden in einer Menge eingesetzt, die einem Säureequivalent pro Amingruppe in dem Fettaminpolyglykolether b) entspricht.In the preparation of the concentrated fabric softener according to the invention, the cationic softening compounds of the formula I - III are expediently used in the form of their concentrated solutions in lower alcohols, preferably isopropanol or in a mixture of these alcohols with water. The fabric softeners according to the invention therefore contain a certain amount of such lower alcohols. Possible acids are, for example acetic acid, phosphoric acid, sulfuric acid, org. Acids or hydrochloric acid. These acids are used in an amount which corresponds to one acid equivalent per amine group in the fatty amine polyglycol ether b).

Darüber hinaus können die erfindungsgemäßen konzentrierten Wäscheweichspülmittel noch weitere übliche Substanzen und Hilfsmittel enthalten, wie z.B. kationische oder nichtionische oberflächenaktive Substanzen, Lösungsvermittler wie z.B. p-Cumolsulfonat, Elektrolyte, Absäuerungsmittel wie z.B. Phosphorsäure, Essigsäure, H2S04, organische Komolexbildner, optische Aufhellungsmittel sowie Farb- und Duftstoffe. Sie dienen zur zusätzlichen Beeinflussung des Warengriffs oder sonstigen Eigenschaften der zu behandelnden Textilien oder zur Viskositätseinstellung (MgCl2), zur pH-Regulierung oder zur Erhöhung der Kältestabilität.In addition, the concentrated fabric softening agents according to the invention can also contain other customary substances and auxiliaries, such as, for example, cationic or nonionic surface-active substances, solubilizers such as, for example, p-cumene sulfonate, electrolytes, acidifying agents such as, for example, phosphoric acid, acetic acid, H 2 SO 4 , organic comolex formers, optical brighteners and Dyes and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity (MgCl 2 ), to regulate the pH or to increase the stability at low temperatures.

Die erfindungsgemäßen konzentrierten Wäscheweichspülmittel verleihen beliebigen Textilmaterialien, besonders solchen aus natürlicher oder regenerierter Cellulose, Wolle, Celluloseacetat, -triacetat, Polyamid, Polyacrylnitril, Polyester, Polypropylen einen angenehmen und weichen Griff. Besonders vorteilhaft ist der Einsatz als Wäschenachbehandlungsmittel für Frottee und Leibwäsche. Die Herstellung dieser Wäscheweichspülmischungen erfolgt durch einfaches Vermischen oder Dispergieren der Einzelkomponenten in Wasser. Diese Wäscheweichspülmittel gemäß der Erfindung können entweder eine einzige Verbindung der Formel I bis III enthalten oder aber sie enthalten ein Gemisch aus 2 oder mehr Verbindungen der Formel I bis III innerhalb der angegebenen Grenzen. Liegt ein Gemisch von zwei oder mehr Verbindungen der Formel I bis III vor, so ist das Mischungsverhältnis untereinander völlig unkritisch und kann jeden beliebigen Wert annehmen.The concentrated fabric softening agents according to the invention give any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel. The use as a laundry treatment agent for terry cloth and underwear is particularly advantageous. These fabric softener mixtures are produced by simply mixing or dispersing the individual components in water. These fabric softeners according to the invention can either contain a single compound of the formula I to III or else they contain a mixture of 2 or more compounds of the formula I to III within the stated limits. If a mixture of two or more compounds of the formulas I to III is present, the mixing ratio with one another is completely uncritical and can have any value.

Die Anwendung dieser Wäscheweichspülmittelkonzentrate erfolgt wie üblich, indem man sie im Anschluß an die Textilwäsche in das letzte Spülwasser gibt. Das so behandelte Textilmaterial wird dann getrocknet. Man kann diese Konzentrate aber zuvor auch verdünnen auf einen Gehalt an Wirksubstanz von 4 bis 8 %, wie es bei den handelsüblichen Wäscheweichspülmitteln der Fall ist.These fabric softener concentrates are used as usual by adding them to the last rinse water after the textile wash. The textile material treated in this way is then dried. One can however, these concentrates must also be diluted beforehand to a content of 4 to 8% of active substance, as is the case with commercially available fabric softeners.

Die oben beschriebenen Wäscheweichspülmittelkonzentrate weisen gute weichmachende Eigenschaften auf. Sie zeichnen sich durch eine gute Stabilität aus. Die Kaltwasserdispergierbarkeit ist hervorragend. Eine Gelbildung wurde nicht beobachtet.Die Formulierungen zeigen auch in dieser konzentrierten Form eine niedrige Viskosität. Ein Nachdicken (Gelieren) nach längerer Lagerzeit tritt nicht auf.The fabric softener concentrates described above have good softening properties. They are characterized by good stability. The cold water dispersibility is excellent. No gel formation was observed. The formulations also show a low viscosity in this concentrated form. Thickening (gelling) after a longer storage period does not occur.

Auch wurde eine Verbesserung des Griffeffektes festgestellt, so daß überraschenderweise die Fettaminpolyglykoläther b) sowie die unter c) aufgeführten Komponenten nicht nur als Emulgator, sondern als Weichmachungskomponente wirken. Diese Verbindungen zeigen für sich allein keinen weichmachenden Effekt auf, da sie nicht auf das Gewebe aufziehen.An improvement in the grip effect was also found, so that, surprisingly, the fatty amine polyglycol ethers b) and the components listed under c) act not only as an emulsifier but as a softening component. These compounds on their own do not have a softening effect because they do not absorb onto the tissue.

In den folgenden Beispielen sind einige erfindungsgemäße Wäscheweichspülmittel beschrieben. Prozentangaben sind in allen Fällen Gewichtsprozente. Die Herstellung dieser Wäscheweichspülmittel erfolgt in allen Fällen durch ein einfaches Verrühren in der Kälte von wäßrigen Lösungen der einzelnen Komponenten.The following examples describe some fabric softening agents according to the invention. Percentages are percentages by weight in all cases. In all cases, these fabric softeners are produced by simply stirring in the cold of aqueous solutions of the individual components.

Beispiel 1example 1

Figure imgb0006
Figure imgb0006

Beispiel 2Example 2

Figure imgb0007
Figure imgb0007

Beispiel 3Example 3

Figure imgb0008
Figure imgb0008

Beispiel 4Example 4

Figure imgb0009
Figure imgb0009
Figure imgb0010
Figure imgb0010

Beispiel 5Example 5

Figure imgb0011
Figure imgb0011

Beispiel 6Example 6

Figure imgb0012
Figure imgb0012

Beispiel 7Example 7

Figure imgb0013
Alle Dispersionen der Beispiele 1 - 7 sind niedrig viskos, über einen längeren Zeitraum lagerstabil und lassen sich mit kalten Wasser gut verdünnen.
Figure imgb0013
 All of the dispersions of Examples 1-7 are low-viscosity, have a long shelf life and can be diluted well with cold water.

Claims (2)

1. Konzentrierte Wäscheweichspülmittel bestehend aus a) 6 bis 30 Gew.-% einer Verbindung der Formeln
Figure imgb0014
Figure imgb0015
Figure imgb0016
worin R1 Alkyl oder Alkenyl mit 8 - 22,.vorzugsweise 16 - 18 Kohlenstoffatomen, R2 Alkyl mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff, x eine Zahl von 1 - 5 und A ein Anion wie z.B. C1(-), Br(-), CH3OSO3 (-) oder CH3OPO3 (-) bedeutet, b) 0,05 bis 35 Gew.-% eines Fettaminpolyglykolethers der Formel IV
Figure imgb0017
worin R1 Alkyl oder Alkenyl mit 8 - 22, vorzugsweise 16 - 18 Kohlenstoffatomen, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl sein sollen, n1 und n2 zusammen eine ganze Zahl von 2 bis 50, bevorzugt 25, bedeuten und p und m sind gleichzeitig 0 oder p ist 1 und m ist 1, 2 oder vorzugsweise 3. c) 0,05 bis 35 Gew.-% einer Verbindung der Formel V
Figure imgb0018
worin R1-Alkyl oder Alkenyl mit 8 - 35, vorzugsweise 16 - 30 Kohlenstoffatomen, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl sein soll, n eine ganze Zahl von 1 - 20, bevorzugt 2 - 5 und m eine ganze Zahl von 0 bis 1, bevorzugt 1, bedeutet, eines Polyethylen- oder Polypropylenglykols mit einem Molgewicht von 100 bis 2000 bevorzugt 400 oder deren C1-C4-Alkylether oder eines Propylenoxid-Ethylenoxid-Pfropfpolymerisats mit einem Polypropylenoxid-Grundkörper vom Molekulargewicht 1500 bis 2500 und einem Gehalt an Ethylenoxid von 5 bis 30 %, bezogen auf das Propylenoxid-Polymer, d) 3 - 20, vorzugsweise 5 - 10 Gew.-% eines C1-C3-Alkohols, e) einer Säure in einer zur Komponente b) equimolaren Menge und f) Wasser und gegebenenfalls weiteren üblichen Hilfsstoffen entsprechend dem Ausgleich zu 100 Gew.-%. 1. Concentrated fabric softener consisting of a) 6 to 30 wt .-% of a compound of the formulas
Figure imgb0014
Figure imgb0015
Figure imgb0016
 wherein R 1 is alkyl or alkenyl with 8-22, preferably 16-18, carbon atoms, R 2 alkyl with 1-4 carbons atoms, preferably methyl, R 3 methyl or hydrogen, x is a number from 1-5 and A is an anion such as C1 (-) , Br (-) , CH 3 OSO 3 (-) or CH 3 OPO 3 (-) , b) 0.05 to 35% by weight of a fatty amine polyglycol ether of the formula IV
Figure imgb0017
 wherein R 1 is alkyl or alkenyl having 8-22, preferably 16-18, carbon atoms, x and y are hydrogen or methyl, but x and y are not supposed to be methyl at the same time, n 1 and n 2 together are an integer from 2 to 50, preferably 25, and p and m are simultaneously 0 or p is 1 and m is 1, 2 or preferably 3. c) 0.05 to 35 wt .-% of a compound of formula V
Figure imgb0018
 wherein R 1 alkyl or alkenyl having 8-35, preferably 16-30 carbon atoms, x and y are hydrogen or methyl, but x and y should not be methyl at the same time, n is an integer from 1-20, preferably 2-5 and m is an integer from 0 to 1, preferably 1, of a polyethylene or polypropylene glycol with a molecular weight of 100 to 2000, preferably 400, or their C 1 -C 4 -alkyl ether or a propylene oxide-ethylene oxide graft polymer with a polypropylene oxide base having a molecular weight of 1500 to 2500 and an ethylene oxide content of 5 to 30%, based on the propylene oxide polymer, d) 3-20, preferably 5-10% by weight of a C 1 -C 3 alcohol, e) an acid in an amount equimolar to component b) and f) water and, if appropriate, other customary auxiliaries in accordance with the balance at 100% by weight. 2. Konzentrierte Wäscheweichspülmittel nach Anspruch 1 enthaltend 15 bis 25 Gew.-% der Verbindungen der Formeln I, II und III, 2 bis 25 Gew.-% des Fettaminpolyglykolethers der Formel IV, 1 bis 5 Gew.-% der Verbindung der Formel V und/oder 5 bis 10 Gew.-% der unter c) aufgeführten Polyalkylenoxide oder Propylenoxid--Ethylenoxid-Pfropfpolymerisate sowie 5 bis 10 Gew.-% eines C1-C3-Alkohols.2. Concentrated fabric softeners as claimed in claim 1 containing 15 to 25 wt .-% of compounds of formulas I, II and III, 2 to 25 wt .-% of fatty amine polyglycol ether of the formula I V, 1 to 5 wt .-% of the compound of formula V and / or 5 to 10% by weight of the polyalkylene oxides or propylene oxide - ethylene oxide graft polymers listed under c) and 5 to 10% by weight of a C1-C3 alcohol.
EP83104774A 1982-05-18 1983-05-14 Concentrated laundry softening agents Expired - Lifetime EP0094655B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83104774T ATE18573T1 (en) 1982-05-18 1983-05-14 CONCENTRATED LAUNDRY DETERGENTS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3218667 1982-05-18
DE19823218667 DE3218667A1 (en) 1982-05-18 1982-05-18 CONCENTRATED SOFT SOFTENER

Publications (4)

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EP0094655A2 true EP0094655A2 (en) 1983-11-23
EP0094655A3 EP0094655A3 (en) 1984-01-04
EP0094655B1 EP0094655B1 (en) 1986-03-12
EP0094655B2 EP0094655B2 (en) 1990-03-21

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EP (1) EP0094655B2 (en)
JP (1) JPS58208468A (en)
AT (1) ATE18573T1 (en)
BR (1) BR8302605A (en)
DE (2) DE3218667A1 (en)
DK (1) DK218683A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0159919A2 (en) * 1984-04-19 1985-10-30 Unilever N.V. Aqueous concentrated fabric softening composition
EP0159921A2 (en) * 1984-04-19 1985-10-30 Unilever N.V. Aqueous fabric softening composition
EP0199383A2 (en) * 1985-03-28 1986-10-29 The Procter & Gamble Company Textile treatment compositions
WO1986007603A1 (en) * 1985-06-22 1986-12-31 Henkel Kommanditgesellschaft Auf Aktien Washing agent for low washing temperatures
EP0275478A2 (en) * 1986-12-22 1988-07-27 Henkel Kommanditgesellschaft auf Aktien Use of diethanol amine derivatives as solubilizers for low-foaming tensides
WO1990003423A1 (en) * 1988-09-24 1990-04-05 Henkel Kommanditgesellschaft Auf Aktien Washing agents for low temperatures
EP0569847A1 (en) * 1992-05-14 1993-11-18 Hüls Aktiengesellschaft Nitrogen-free active components used in soften formulations
WO1994013772A1 (en) * 1992-12-16 1994-06-23 Henkel Kommanditgesellschaft Auf Aktien Aqueous textile softener dispersions
US5908854A (en) * 1996-11-12 1999-06-01 Reckitt & Colman Inc. Mycobacterial compositions and methods for their use
GB2357302A (en) * 1999-12-16 2001-06-20 Reckitt & Colman France Laundry compositions comprising quaternary ammonium polymers
WO2018007199A1 (en) * 2016-07-06 2018-01-11 Henkel Ag & Co. Kgaa Acceleration of the drying of laundry

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2522659B2 (en) * 1987-03-31 1996-08-07 ライオン株式会社 Softener composition
JP2660205B2 (en) * 1988-06-03 1997-10-08 ミヨシ油脂株式会社 Manufacturing method of fiber treatment agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB947714A (en) * 1960-07-18 1964-01-29 Armour Chemical Ind Ltd Improvements in or relating to surface active compositions
US4233164A (en) * 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener
EP0056695A2 (en) * 1981-01-16 1982-07-28 THE PROCTER & GAMBLE COMPANY Textile treatment compositions
EP0059502A1 (en) * 1981-02-28 1982-09-08 THE PROCTER & GAMBLE COMPANY Textile treatment compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB947714A (en) * 1960-07-18 1964-01-29 Armour Chemical Ind Ltd Improvements in or relating to surface active compositions
US4233164A (en) * 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener
EP0056695A2 (en) * 1981-01-16 1982-07-28 THE PROCTER & GAMBLE COMPANY Textile treatment compositions
EP0059502A1 (en) * 1981-02-28 1982-09-08 THE PROCTER & GAMBLE COMPANY Textile treatment compositions

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2157730A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous concentrated fabric softening composition
EP0159921A2 (en) * 1984-04-19 1985-10-30 Unilever N.V. Aqueous fabric softening composition
EP0159920A2 (en) * 1984-04-19 1985-10-30 Unilever N.V. Aqueous fabric softening composition
EP0159920A3 (en) * 1984-04-19 1987-03-18 Unilever N.V. Aqueous fabric softening composition
EP0159919A3 (en) * 1984-04-19 1987-03-18 Unilever N.V. Aqueous concentrated fabric softening composition
EP0159921A3 (en) * 1984-04-19 1987-03-25 Unilever N.V. Aqueous fabric softening composition
EP0159919A2 (en) * 1984-04-19 1985-10-30 Unilever N.V. Aqueous concentrated fabric softening composition
EP0199383A2 (en) * 1985-03-28 1986-10-29 The Procter & Gamble Company Textile treatment compositions
EP0199383A3 (en) * 1985-03-28 1987-12-02 The Procter & Gamble Company Textile treatment compositions
US4820436A (en) * 1985-06-22 1989-04-11 Henkel Kommanditgesellschaft Auf Aktien Detergents for low laundering temperatures
WO1986007603A1 (en) * 1985-06-22 1986-12-31 Henkel Kommanditgesellschaft Auf Aktien Washing agent for low washing temperatures
EP0275478A2 (en) * 1986-12-22 1988-07-27 Henkel Kommanditgesellschaft auf Aktien Use of diethanol amine derivatives as solubilizers for low-foaming tensides
EP0275478A3 (en) * 1986-12-22 1989-06-28 Henkel Kommanditgesellschaft Auf Aktien Use of diethanol amine derivatives as solubilizers for low-foaming tensides
WO1990003423A1 (en) * 1988-09-24 1990-04-05 Henkel Kommanditgesellschaft Auf Aktien Washing agents for low temperatures
EP0364739A2 (en) * 1988-09-24 1990-04-25 Henkel Kommanditgesellschaft auf Aktien Low-temperature detergent
EP0364739A3 (en) * 1988-09-24 1990-05-23 Henkel Kommanditgesellschaft auf Aktien Low-temperature detergent
EP0569847A1 (en) * 1992-05-14 1993-11-18 Hüls Aktiengesellschaft Nitrogen-free active components used in soften formulations
WO1994013772A1 (en) * 1992-12-16 1994-06-23 Henkel Kommanditgesellschaft Auf Aktien Aqueous textile softener dispersions
US5908854A (en) * 1996-11-12 1999-06-01 Reckitt & Colman Inc. Mycobacterial compositions and methods for their use
GB2357302A (en) * 1999-12-16 2001-06-20 Reckitt & Colman France Laundry compositions comprising quaternary ammonium polymers
WO2018007199A1 (en) * 2016-07-06 2018-01-11 Henkel Ag & Co. Kgaa Acceleration of the drying of laundry

Also Published As

Publication number Publication date
ATE18573T1 (en) 1986-03-15
JPS58208468A (en) 1983-12-05
BR8302605A (en) 1984-01-17
DK218683A (en) 1983-11-19
DE3218667A1 (en) 1983-11-24
DE3362517D1 (en) 1986-04-17
DK218683D0 (en) 1983-05-17
EP0094655B2 (en) 1990-03-21
EP0094655A3 (en) 1984-01-04
EP0094655B1 (en) 1986-03-12

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