EP0056880B1 - Verfahren zur Herstellung eines brikettierten Einsatzmaterials für Zink-Schachtöfen - Google Patents
Verfahren zur Herstellung eines brikettierten Einsatzmaterials für Zink-Schachtöfen Download PDFInfo
- Publication number
- EP0056880B1 EP0056880B1 EP81201243A EP81201243A EP0056880B1 EP 0056880 B1 EP0056880 B1 EP 0056880B1 EP 81201243 A EP81201243 A EP 81201243A EP 81201243 A EP81201243 A EP 81201243A EP 0056880 B1 EP0056880 B1 EP 0056880B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lead
- content
- zinc
- calcine
- shaft furnaces
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011701 zinc Substances 0.000 title claims description 15
- 229910052725 zinc Inorganic materials 0.000 title claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 5
- 229910000464 lead oxide Inorganic materials 0.000 claims description 4
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 description 13
- 239000004484 Briquette Substances 0.000 description 5
- 239000000571 coke Substances 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 206010016334 Feeling hot Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/02—Preliminary treatment of ores; Preliminary refining of zinc oxide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
Definitions
- the invention relates to a method for producing a briquetted feed material for zinc shaft furnaces, wherein roasted material containing zinc oxide from a fluidized bed roasting is subjected to hot briquetting.
- the sulfidic ore concentrates must first be roasted and made into pieces.
- the sintering roasting on a traveling grate is relatively complex, leads to an exhaust gas with a relatively low S0 2 content and causes problems with regard to pollution of the environment.
- the roasting in the fluidized bed largely avoids these problems, but the roasted fine-grained material has to be made into pieces in a separate process step.
- the object of the invention is to produce briquettes from the roasted material of fluidized bed roasts with as little effort as possible, which have good properties for processing in a zinc shaft furnace.
- This object is achieved according to the invention in that a metallic lead content and / or lead oxide content of at least 3%, calculated as lead, is set in the roasted material, non-baking coal with a low content of volatile constituents is mixed into the roasted material, the ratio of Pb to C. in% by weight is set to at least 1, and the mixture is briquetted at a press temperature of 250 to 470 ° C under a press pressure of 4 to 20 t / cm roll width, measured dynamically.
- the roasted material is obtained as bed discharge, cyclone discharge and possibly discharge from other dedusting plants in a wide grain range of approximately 0 to 5 mm.
- the vast majority is in a grain size of less than 2 mm. It is very important that the individual discharges are mixed together very well.
- the admixed metallic lead and / or oxidic lead generally comes from the operation of the zinc shaft furnace itself, e.g. Trass from the pump sump of the condenser, dust from the room dust and filter sludge from the gas wash.
- the substances containing the metallic lead and / or oxidic lead are also used in a grain size of about 0 to 5 mm.
- the addition of metallic lead and / or lead oxide can be up to about 15% by weight, calculated as lead.
- the non-baking coals can contain up to about 6% volatiles such as coke breeze and anthracite. Temperatures in the upper range of the pressing temperature result in higher strength of the briquettes. This also applies to higher pressures. The pressures are measured dynamically, i.e. during the operation of the press.
- a preferred embodiment is that the lead content is 3 to 12%, the carbon content is 2 to 6% and the ratio of Pb to C is set to 1.5 to 2. These areas result in briquettes with particularly good properties.
- the advantages of the invention are that the pellets have a good initial reducibility and thus a good overall reducibility in a relatively short time, have good and sufficient mechanical strength, can be produced without great effort, and the briquetting takes place without subsequent heating of the discharge material of the fluidized bed can.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813101886 DE3101886A1 (de) | 1981-01-22 | 1981-01-22 | Verfahren zur herstellung eines brikettierten einsatzmaterials fuer zink-schachtoefen |
| DE3101886 | 1981-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0056880A1 EP0056880A1 (de) | 1982-08-04 |
| EP0056880B1 true EP0056880B1 (de) | 1984-06-20 |
Family
ID=6123064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81201243A Expired EP0056880B1 (de) | 1981-01-22 | 1981-11-02 | Verfahren zur Herstellung eines brikettierten Einsatzmaterials für Zink-Schachtöfen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4525207A (ro) |
| EP (1) | EP0056880B1 (ro) |
| JP (1) | JPS57143446A (ro) |
| DE (2) | DE3101886A1 (ro) |
| PL (1) | PL234779A1 (ro) |
| RO (1) | RO84192B (ro) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3529084C1 (de) * | 1985-08-14 | 1986-10-16 | Thyssen Stahl AG, 4100 Duisburg | Verfahren und Anlage zur Herstellung bindemittelloser Heissbriketts |
| CA2087557C (en) * | 1992-07-31 | 2000-04-25 | Matthew Raskin | Method for removing catalyst |
| JP2580799Y2 (ja) * | 1993-05-25 | 1998-09-17 | 三相電機株式会社 | 電動機およびその固定子 |
| JP2653018B2 (ja) * | 1993-11-24 | 1997-09-10 | 日本電気株式会社 | トランスインピーダンス形増幅回路 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1041256B (de) * | 1953-05-13 | 1958-10-16 | Nat Smelting Co Ltd | Verfahren zur Gewinnung von Blei und Zink |
| BE653612A (ro) * | 1963-09-30 | |||
| ES340602A1 (es) * | 1966-05-17 | 1968-06-01 | Boliden Ab | Procedimiento para la aglomeracion de un producto de grano fino. |
| GB1149760A (en) * | 1966-07-05 | 1969-04-23 | Imp Smelting Corp Ltd | Improvements in or relating to blast furnace operation |
| IL34874A0 (en) * | 1969-07-14 | 1970-09-17 | Metallurgical Processes Ltd | The preparation of feed material for a blast furnace |
| IE38603B1 (en) * | 1972-12-11 | 1978-04-26 | Metallurgical Processes Ltd | Preparation of feed material for a blast furnace |
| DE2335669A1 (de) * | 1973-07-13 | 1975-02-06 | Metallgesellschaft Ag | Verfahren zur herstellung von erzkoks-heissbriketts fuer die selbstgaengige verhuettung |
| ZA793158B (en) * | 1978-07-04 | 1980-07-30 | Isc Smelting | Roasting of sulphide materials |
-
1981
- 1981-01-22 DE DE19813101886 patent/DE3101886A1/de not_active Withdrawn
- 1981-11-02 DE DE8181201243T patent/DE3164341D1/de not_active Expired
- 1981-11-02 EP EP81201243A patent/EP0056880B1/de not_active Expired
-
1982
- 1982-01-14 RO RO106327A patent/RO84192B/ro unknown
- 1982-01-21 JP JP57008235A patent/JPS57143446A/ja active Pending
- 1982-01-21 PL PL23477982A patent/PL234779A1/xx unknown
-
1984
- 1984-01-13 US US06/570,481 patent/US4525207A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4525207A (en) | 1985-06-25 |
| RO84192A (ro) | 1984-05-23 |
| DE3164341D1 (en) | 1984-07-26 |
| DE3101886A1 (de) | 1982-08-26 |
| PL234779A1 (ro) | 1982-08-16 |
| RO84192B (ro) | 1984-07-30 |
| JPS57143446A (en) | 1982-09-04 |
| EP0056880A1 (de) | 1982-08-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1254363B (de) | Verfahren zur Reduktion von oxydischen Rohstoffen | |
| EP0217139A1 (de) | Verfahren zum Aufarbeiten zink- und bleihaltiger Reststoffe der Stahlindustrie im Hinblick auf eine metallurgische Weiterverarbeitung | |
| DE2653794A1 (de) | Verfahren zur kokserzeugung und koksofen | |
| EP0056880B1 (de) | Verfahren zur Herstellung eines brikettierten Einsatzmaterials für Zink-Schachtöfen | |
| DE2357736C2 (de) | Verfahren zur Entschwefelung von Koks | |
| DE2519810A1 (de) | Verfahren zur verarbeitung von staubfoermigem gut aus metallurgischen abgasen | |
| DE1758951C3 (de) | Verfahren zur Herstellung von Eisenschwamm | |
| DE2538864C3 (de) | Verfahren zur Herstellung von reduzierten Pellets | |
| DE2253454A1 (de) | Verfahren zum herstellen kohleund eisenhaltiger briketts | |
| DE2743282A1 (de) | Waelzverfahren zur verfluechtigung von zink und blei aus eisenoxydhaltigen materialien | |
| DE2029344C2 (de) | Verfahren zur Herstellung stark vorreduzierter Pellets | |
| EP0012363A1 (de) | Verfahren und Anlage zur Reduktion von Erzen | |
| DE2825691A1 (de) | Verfahren zur herstellung von koks | |
| DE2017816C3 (de) | Verfahren zur Herstellung von Gleichstückkoks in Verkokungskammern | |
| DE1696509B1 (de) | Verfahren zum Herstellen von Brennstoffbriketts | |
| DE910060C (de) | Verfahren zur Erzeugung von fuer Huettenprozesse geeigneten festen Erzkoksbriketten | |
| DE1943763C3 (de) | Verfahren und Vorrichtung für die Herstellung von Gleichstückkoks | |
| DE970686C (de) | Verfahren zum Verhuetten von Eisenerzen | |
| DE1961829A1 (de) | Brennstoff fuer Schachtoefen | |
| DE423422C (de) | Verfahren zum Brikettieren von pulverfoermigen Erzen | |
| AT210384B (de) | Verfahren zum unmittelbaren Karbonisieren, insbesondere Schwelen von Ligniten, Braunkohlen od. änhl. geologisch jungen Kohlen | |
| DE1458743C (de) | Verfahren zur Herstellung von Erz Formkoksen | |
| AT222674B (de) | Verfahren zur Herstellung von Eisen sowie dessen Verwendung zur Herstellung von Briketts | |
| DE376087C (de) | Verfahren zur Vorbereitung und zur Verhuettung zinkhaltiger Produkte und Mischerze | |
| DE2914305A1 (de) | Verfahren zur herstellung von koksgrus aus backendenkohlen in verkokungsofenkammern fuer den generatorbe trieb. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): DE FR GB IT |
|
| 17P | Request for examination filed |
Effective date: 19820729 |
|
| ITF | It: translation for a ep patent filed | ||
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Designated state(s): DE FR GB IT |
|
| REF | Corresponds to: |
Ref document number: 3164341 Country of ref document: DE Date of ref document: 19840726 |
|
| ET | Fr: translation filed | ||
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 19891031 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19891214 Year of fee payment: 9 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Effective date: 19901102 |
|
| ITTA | It: last paid annual fee | ||
| GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19910801 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19930917 Year of fee payment: 13 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Effective date: 19950731 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |