EP0052186A1 - Article stratifié - Google Patents

Article stratifié Download PDF

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Publication number
EP0052186A1
EP0052186A1 EP81106667A EP81106667A EP0052186A1 EP 0052186 A1 EP0052186 A1 EP 0052186A1 EP 81106667 A EP81106667 A EP 81106667A EP 81106667 A EP81106667 A EP 81106667A EP 0052186 A1 EP0052186 A1 EP 0052186A1
Authority
EP
European Patent Office
Prior art keywords
intermediate layer
surface coating
melting
plastic
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81106667A
Other languages
German (de)
English (en)
Other versions
EP0052186B1 (fr
Inventor
Heinz Huber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Airbus Defence and Space GmbH
Original Assignee
Messerschmitt Bolkow Blohm AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Messerschmitt Bolkow Blohm AG filed Critical Messerschmitt Bolkow Blohm AG
Publication of EP0052186A1 publication Critical patent/EP0052186A1/fr
Application granted granted Critical
Publication of EP0052186B1 publication Critical patent/EP0052186B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/08—Flame spraying
    • B05D1/10—Applying particulate materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00—Polymeric substrate or laminate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2508/00—Polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00—Inorganic fillers
    • B05D2601/20—Inorganic fillers used for non-pigmentation effect

Definitions

  • the invention relates to a composite body according to the preamble of patent claim 1.
  • thermal spraying of high-melting substances is known, but could not previously be used to form surface coatings on plastic bodies, because the surface of the plastic would coke. ' Thermal spraying was therefore only possible with low-melting substances, for example with pure aluminum, whereby only a relatively low adhesive strength of the surface coating on the plastic base body could be achieved, even if the surface had previously been roughened.
  • thermal spraying is now applied without damage to a plastic base body to form a firmly adhering surface coating from a high-melting substance in such a way that the surface coating is bound via an intermediate layer, which is both made of a thermally sprayable plastic as well as the high-melting material chosen for the surface coating.
  • the intermediate layer decreases from the plastic base body to the outside in the plastic portion and correspondingly in the portion of the high-melting material to at least approximately plastic freedom at the transition to the surface coating.
  • the high-melting substance is thus already contained in the intermediate layer that binds the surface coating.
  • this substance initially only has a small proportion in relation to the plastic of the intermediate layer, this plastic will nevertheless have to meet relatively high requirements for its resistance to decomposition when heated by thermal spraying, and not under certain circumstances, depending on the choice of the high-melting substance to coke yourself.
  • the invention is therefore based on the object of providing a composite body of the type mentioned in the preamble of patent claim 1 for the binding of the surface coating with a thermally sprayable intermediate layer, with which damage occurs during thermal spraying both with regard to the plastic of the base body and with regard to its own plastic component is equally excluded.
  • the drawing shows in section a section of a base body 1 made of plastic, e.g. Polyvinyl chloride, which for reasons of erosion protection is provided with a surface coating 2 made of a high-melting metal, e.g. Titanium. Since the surface coating 2 for economic reasons by thermal spraying, for. B. plasma spraying is to be produced, a thermally sprayed intermediate layer 3 is provided as a composite layer between the base body 1 and the surface coating 2 to prevent coking or similar damage to the plastic.
  • the intermediate product for the intermediate layer 3 is a mixture e.g. Made of polyester resin and aluminum alloyed with silicon.
  • This mixture is available in the quantity ratio required for the intended function as so-called 601 NS powder from METCO INC., 1101 Prospect Ave., Westbury, LI, New York and has so far been used in engines for surface coatings of metal surfaces which are used in the Protect the run-in phase of the blades against their contact. It has been found that the intermediate layer 3 sprayed from such powder, the medium-melting metal part of which is harmless to the plastic of the base body 1, does not only suffer damage during the subsequent thermal spraying of the surface coating 2, but also ensures the desired high adhesive strength of the surface coating.
  • the invention is not limited to an intermediate layer with an unchanged ratio of metal to plastic. According to the proposal of the earlier patent application, it can, starting from the plastic base body, remove the intermediate layer in layers or continuously in the plastic portion and correspondingly increase in the proportion of the low-melting metal up to at least approximately plastic freedom at the transition to the surface coating.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Coating By Spraying Or Casting (AREA)
EP81106667A 1980-11-14 1981-08-27 Article stratifié Expired EP0052186B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803042922 DE3042922A1 (de) 1980-11-14 1980-11-14 Verbundkoerper
DE3042922 1980-11-14

Publications (2)

Publication Number Publication Date
EP0052186A1 true EP0052186A1 (fr) 1982-05-26
EP0052186B1 EP0052186B1 (fr) 1984-11-14

Family

ID=6116733

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81106667A Expired EP0052186B1 (fr) 1980-11-14 1981-08-27 Article stratifié

Country Status (2)

Country Link
EP (1) EP0052186B1 (fr)
DE (2) DE3042922A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0178648A2 (fr) * 1984-10-17 1986-04-23 Mitsubishi Rayon Co., Ltd. Composition de sous-revêtement et des articles moulés composites produits en employant cette composition
EP0396528A2 (fr) * 1989-05-03 1990-11-07 Lenzing Aktiengesellschaft Procédé d'enduction de surfaces
WO2002004694A1 (fr) * 2000-07-07 2002-01-17 Linde Ag Surface en plastique a revetement pulverise thermiquement et son procede de production
WO2006074549A1 (fr) * 2005-01-14 2006-07-20 National Research Council Of Canada Couche de liaison et procede de formation de thermoplastique
GB2519444A (en) * 2013-10-21 2015-04-22 Boeing Co Method of coating a composite material and a coated edge of a composite structure

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019208092A1 (fr) * 2018-04-23 2019-10-31 パナソニックＩｐマネジメント株式会社 Corps moulé en résine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1379044A (fr) * 1963-10-09 1964-11-20 Desmarquest & Cie L Procédé de revêtement par projection à haute température d'oxydes réfractairessur la surface d'objets en matières organiques combustibles
DE2142474A1 (de) * 1971-08-25 1973-03-08 Alban Puetz Verfahren zum auftragen von metallschichten auf kunststoffgegenstaende
DE3004869B1 (de) * 1980-02-09 1981-12-17 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Verbundkoerper und Verfahren zu dessen Herstellung

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1379044A (fr) * 1963-10-09 1964-11-20 Desmarquest & Cie L Procédé de revêtement par projection à haute température d'oxydes réfractairessur la surface d'objets en matières organiques combustibles
DE2142474A1 (de) * 1971-08-25 1973-03-08 Alban Puetz Verfahren zum auftragen von metallschichten auf kunststoffgegenstaende
DE3004869B1 (de) * 1980-02-09 1981-12-17 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Verbundkoerper und Verfahren zu dessen Herstellung

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0178648A2 (fr) * 1984-10-17 1986-04-23 Mitsubishi Rayon Co., Ltd. Composition de sous-revêtement et des articles moulés composites produits en employant cette composition
EP0178648A3 (en) * 1984-10-17 1986-07-30 Mitsubishi Rayon Co. Ltd. Undercoat composition and composite molded articles produced usin said compositon
EP0396528A2 (fr) * 1989-05-03 1990-11-07 Lenzing Aktiengesellschaft Procédé d'enduction de surfaces
EP0396528A3 (fr) * 1989-05-03 1991-10-02 Lenzing Aktiengesellschaft Procédé d'enduction de surfaces
WO2002004694A1 (fr) * 2000-07-07 2002-01-17 Linde Ag Surface en plastique a revetement pulverise thermiquement et son procede de production
WO2006074549A1 (fr) * 2005-01-14 2006-07-20 National Research Council Of Canada Couche de liaison et procede de formation de thermoplastique
GB2519444A (en) * 2013-10-21 2015-04-22 Boeing Co Method of coating a composite material and a coated edge of a composite structure
GB2519444B (en) * 2013-10-21 2016-08-17 Boeing Co Coating composite materials

Also Published As

Publication number Publication date
EP0052186B1 (fr) 1984-11-14
DE3167214D1 (en) 1984-12-20
DE3042922A1 (de) 1982-07-01

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