EA201491202A1 - Стабилизация пористых морфологий для высококачественных половолоконных мембран на основе углеродных молекулярных сит - Google Patents

Стабилизация пористых морфологий для высококачественных половолоконных мембран на основе углеродных молекулярных сит

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Publication number
EA201491202A1
EA201491202A1 EA201491202A EA201491202A EA201491202A1 EA 201491202 A1 EA201491202 A1 EA 201491202A1 EA 201491202 A EA201491202 A EA 201491202A EA 201491202 A EA201491202 A EA 201491202A EA 201491202 A1 EA201491202 A1 EA 201491202A1
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EA
Eurasian Patent Office
Prior art keywords
carbon molecular
reactor
membranes based
stabilization
quality value
Prior art date
Application number
EA201491202A
Other languages
English (en)
Other versions
EA027725B1 (ru
Inventor
Нитеш Бхуваниа
Уилльям Джон Корос
Пол Джейсон Уилльямс
Original Assignee
Джорджия Тек Рисёч Корпорейшн
Шелл Интернационале Рисёч Маатсаппей Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джорджия Тек Рисёч Корпорейшн, Шелл Интернационале Рисёч Маатсаппей Б.В. filed Critical Джорджия Тек Рисёч Корпорейшн
Publication of EA201491202A1 publication Critical patent/EA201491202A1/ru
Publication of EA027725B1 publication Critical patent/EA027725B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0076—Pretreatment of inorganic membrane material prior to membrane formation, e.g. coating of metal powder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/022—Asymmetric membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

В изобретении раскрыты мембраны на основе углеродных молекулярных сит, обладающие улучшенными термическими и/или механическими свойствами. В одной форме осуществления изобретения мембрана на основе углеродных молекулярных сит для отделения первого и одного или более вторых газов от исходной смеси первого газа и одного или более вторых газов содержит половолоконный углеродный средний слой и термостабилизированный полимерный предшественник, расположенный, по меньшей мере, на наружной части среднего слоя. В некоторых формах осуществления изобретения термостабилизированный полимерный предшественник образуют способом помещения в реактор мембраны на основе углеродных молекулярных сит, содержащей немодифицированный полимер ароматического имида, заполнения реактора модифицирующим агентом и изменения температуры реактора с такой скоростью подъема и скоростью снижения температуры и в течение такого периода времени, что данный модифицирующий агент изменяет немодифицированный полимер ароматического имида с образованием термостабилизированного полимерного предшественника.
EA201491202A 2011-12-20 2012-10-29 Способ формирования углеродной мембраны EA027725B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161577949P 2011-12-20 2011-12-20
PCT/US2012/062440 WO2013095775A1 (en) 2011-12-20 2012-10-29 Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes

Publications (2)

Publication Number Publication Date
EA201491202A1 true EA201491202A1 (ru) 2014-11-28
EA027725B1 EA027725B1 (ru) 2017-08-31

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA201491202A EA027725B1 (ru) 2011-12-20 2012-10-29 Способ формирования углеродной мембраны

Country Status (10)

Country Link
US (1) US9211504B2 (ru)
EP (1) EP2794067B1 (ru)
JP (1) JP6145113B2 (ru)
KR (1) KR102062413B1 (ru)
CN (1) CN104125855B (ru)
AU (1) AU2012354175B2 (ru)
BR (1) BR112014015191B1 (ru)
EA (1) EA027725B1 (ru)
MY (1) MY188200A (ru)
WO (1) WO2013095775A1 (ru)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014015191B1 (pt) * 2011-12-20 2021-10-13 Shell Internationale Research Maatschappij B.V. Processo para formar uma membrana de carbono de fibra oca
US9346011B2 (en) * 2012-05-01 2016-05-24 Dow Global Technologies Llc Hollow fiber carbon molecular sieve membrane and preparation and use thereof
US9327243B2 (en) 2012-08-24 2016-05-03 The Boeing Company Aircraft fuel tank flammability reduction methods and systems
US9061249B2 (en) * 2012-08-24 2015-06-23 The Boeing Company Aircraft fuel tank flammability reduction method and system
US10000294B2 (en) 2012-08-24 2018-06-19 The Boeing Company Aircraft fuel tank flammability reduction method and system
EP3862073A1 (en) * 2013-09-30 2021-08-11 Georgia Tech Research Corporation Asymmetric modified carbon molecular sieve hollow fiber membranes having improved permeance
WO2015100161A1 (en) 2013-12-26 2015-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers
CA2961885C (en) 2014-09-22 2023-01-24 Georgia Institute Of Technology Composite nanoparticle stabilized core carbon molecular sieve hollow fiber membranes having improved permeance
ES2798126T3 (es) * 2014-09-24 2020-12-09 Dow Global Technologies Llc Preparación de membranas de fibra hueca de tamiz molecular de carbono (CMS) y su preparación a partir de poliimidas pre-oxidadas
US10086337B2 (en) 2014-11-30 2018-10-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Composite carbon molecular sieve membranes having anti-substructure collapse particles loaded in a core thereof
US10456751B2 (en) * 2015-03-27 2019-10-29 National Institute Of Advanced Industrial Science And Technology Method for producing hollow fiber carbon membrane and separation membrane module
US20160346740A1 (en) * 2015-06-01 2016-12-01 Georgia Tech Research Corporation Ultra-selective carbon molecular sieve membranes and methods of making
WO2017017083A1 (en) 2015-07-28 2017-02-02 Shell Internationale Research Maatschappij B.V. Process for preparing a paraffin product
CN106823821A (zh) * 2015-12-04 2017-06-13 中国科学院大连化学物理研究所 碳分子筛膜缺陷的填补方法
EP3389835B1 (en) 2015-12-17 2021-03-03 Dow Global Technologies LLC Process of using carbon molecular sieve membranes for ethylene/ethane and propylene/propane separations
CA3017949A1 (en) * 2016-03-16 2017-09-21 Dow Global Technologies Llc Separation of gases via carbonized vinylidene chloride copolymer gas separation membranes and membrane preparation method
EP3433009A1 (en) * 2016-03-21 2019-01-30 Dow Global Technologies, LLC Improved method of making carbon molecular sieve membranes
US10968105B2 (en) 2016-03-28 2021-04-06 Board Of Regents, The University Of Texas System Low-temperature pyrolysis of organic acid salts providing graphene rich carbons
KR102447406B1 (ko) 2016-11-10 2022-09-28 다우 글로벌 테크놀로지스 엘엘씨 탄소 분자체 중공 섬유 멤브레인을 제조하기 위한 개선 방법
US10543462B2 (en) 2016-12-14 2020-01-28 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hollow fiber carbon molecular sieve membranes and method of manufacturing using radial-flow pyrolysis
US10549244B2 (en) * 2016-12-14 2020-02-04 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hollow fiber carbon molecular sieve membranes and method of manufacturing using radial-flow pyrolysis
US10717041B2 (en) 2017-02-10 2020-07-21 Shell Oil Company Carbon molecular sieve membranes for aggressive gas separations
JP7114626B2 (ja) * 2017-04-06 2022-08-08 ダウ グローバル テクノロジーズ エルエルシー 非対称ポリ塩化ビニリデン膜およびそれから作製された炭素分子篩膜
CA3066352A1 (en) * 2017-06-15 2018-12-20 Dow Global Technologies Llc Supported carbon molecular sieve membranes and method to form them
CN107469640B (zh) * 2017-07-20 2019-11-26 大连理工大学 一种高气体渗透性炭膜的制备方法
JP2020530811A (ja) 2017-08-14 2020-10-29 ダウ グローバル テクノロジーズ エルエルシー 炭素分子篩中空繊維膜を作製するための改良された方法
KR102086921B1 (ko) 2017-12-12 2020-03-09 서강대학교산학협력단 하이브리드 고분자 중공사막, 탄소 분자체 중공사막 및 그 제조방법
CN112533978A (zh) 2018-08-23 2021-03-19 陶氏环球技术有限责任公司 交联聚酰亚胺膜和由其制造的碳分子筛中空纤维膜
DE102018216163A1 (de) 2018-09-21 2020-03-26 Forschungszentrum Jülich GmbH CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung
US11660575B2 (en) * 2018-12-31 2023-05-30 ExxonMobil Technology and Engineering Company Reactive inhibition of pore structure collapse during pyrolytic formation of carbon molecular sieves
AU2020207924A1 (en) * 2019-01-18 2021-07-08 Toray Industries, Inc. Carbon membrane for fluid separation use
CN113453790A (zh) 2019-01-25 2021-09-28 陶氏环球技术有限责任公司 由碳形成聚合物-聚偏二氯乙烯共聚物共混物生产的碳分子筛膜
CN109738507B (zh) * 2019-01-28 2022-03-04 哈尔滨工业大学（威海） 一种基于热解-质谱技术的微塑料检测装置及方法
CN112044273B (zh) * 2019-06-05 2023-04-25 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
US20220347632A1 (en) * 2019-12-11 2022-11-03 Fundacion Tecnalia Research & Innovation Carbon molecular sieve membrane and its use in separation processes
KR20220113815A (ko) * 2019-12-27 2022-08-16 다우 글로벌 테크놀로지스 엘엘씨 탄소 분자체 흡착제 모노리스 및 이의 제조 방법
GB202009004D0 (en) 2020-06-12 2020-07-29 Norwegian Univ Of Science And Technology (Ntnu) Carbon hollow fibre membrane
CN117210975B (zh) * 2023-10-26 2024-08-23 江苏恒神股份有限公司 一种高强度高模量高韧性碳纤维及其制备方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3621257A1 (de) * 1986-06-25 1988-01-07 Akzo Gmbh Verfahren zur herstellung poren aufweisender kohlenstoffmembranen
DE3769242D1 (de) * 1986-08-14 1991-05-16 Toray Industries Gastrennungsmembran.
JP2555617B2 (ja) * 1986-08-14 1996-11-20 東レ株式会社 気体分離膜およびその製造方法
US4902422A (en) 1988-12-06 1990-02-20 Board Regents The University Of Texas System Defect-free ultrahigh flux asymmetric membranes
US5234471A (en) 1992-02-04 1993-08-10 E. I. Du Pont De Nemours And Company Polyimide gas separation membranes for carbon dioxide enrichment
JPH10149002A (ja) * 1996-11-20 1998-06-02 Konica Corp 電子写真複写方法
JP4081956B2 (ja) * 1999-03-05 2008-04-30 宇部興産株式会社 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法
US6299669B1 (en) 1999-11-10 2001-10-09 The University Of Texas System Process for CO2/natural gas separation
US6740143B2 (en) * 2000-06-22 2004-05-25 E. I. Du Pont De Nemours And Company Mixed matrix nanoporous carbon membranes
US6503295B1 (en) * 2000-09-20 2003-01-07 Chevron U.S.A. Inc. Gas separations using mixed matrix membranes
JP2004514546A (ja) * 2000-09-20 2004-05-20 シェブロン　ユー．エス．エー．　インコーポレイテッド 熱分解炭素ふるい粒子を混合したマトリックス膜及びその製法と使用法
US6719147B2 (en) * 2001-04-27 2004-04-13 The University Of Delaware Supported mesoporous carbon ultrafiltration membrane and process for making the same
US20030126990A1 (en) * 2001-12-20 2003-07-10 Koros William J. Crosslinked and crosslinkable hollow fiber membrane and method of making same
JP4253459B2 (ja) * 2002-03-27 2009-04-15 日本碍子株式会社 炭素膜構造体及びその製造方法
US6730364B2 (en) * 2002-03-28 2004-05-04 National Science Council Preparation of carbon molecular sieve membranes on porous substrate
US7404844B2 (en) * 2004-02-26 2008-07-29 National University Of Singapore Method for making carbon membranes for fluid separation
US7393383B2 (en) * 2005-01-14 2008-07-01 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Separation membrane made from blends of polyimide with polyamide or polyimide-amide polymers
GB0516154D0 (en) * 2005-08-05 2005-09-14 Ntnu Technology Transfer As Carbon membranes
AU2007330155A1 (en) * 2006-11-29 2008-06-12 Ngk Insulators, Ltd. Carbon membrane laminated body and method for manufacturing the same
US8318377B2 (en) * 2007-03-16 2012-11-27 Sekisui Chemical Co., Ltd. Membrane-electrode junction agent, proton conducting membrane having junction layer, membrane-electrode assembly, polymer electrolyte fuel cell, and manufacturing method of the membrane-electrode assembly
CN101959577A (zh) * 2007-06-01 2011-01-26 环球油品公司 Uv交联的聚合物官能化分子筛/聚合物混合基质膜
US20090282802A1 (en) * 2008-05-15 2009-11-19 Cooper Christopher H Carbon nanotube yarn, thread, rope, fabric and composite and methods of making the same
US8013103B2 (en) * 2008-10-10 2011-09-06 Industry-University Cooperation Foundation, Hanyang University Polymer compounds and a preparation method thereof
EP2471592A4 (en) * 2009-08-26 2014-07-30 Ibiden Co Ltd GAS SEPARATION MEMBRANE
US8486179B2 (en) * 2009-10-29 2013-07-16 Georgia Tech Research Corporation Method for producing carbon molecular sieve membranes in controlled atmospheres
US8608828B2 (en) * 2010-10-01 2013-12-17 Basf Se Process for producing carbon membranes
US8912288B2 (en) * 2011-06-17 2014-12-16 Uop Llc Separation process using a polyimide membrane
BR112014015191B1 (pt) * 2011-12-20 2021-10-13 Shell Internationale Research Maatschappij B.V. Processo para formar uma membrana de carbono de fibra oca
US9346011B2 (en) * 2012-05-01 2016-05-24 Dow Global Technologies Llc Hollow fiber carbon molecular sieve membrane and preparation and use thereof
US8999037B2 (en) * 2012-05-30 2015-04-07 Georgia Tech Research Corporation Carbon molecular sieve membrane (CMSM) performance tuning by dual temperature secondary oxygen doping (DTSOD)

Also Published As

Publication number Publication date
US20130152793A1 (en) 2013-06-20
US9211504B2 (en) 2015-12-15
BR112014015191B1 (pt) 2021-10-13
MY188200A (en) 2021-11-24
WO2013095775A1 (en) 2013-06-27
EP2794067A4 (en) 2015-08-12
EP2794067B1 (en) 2020-03-25
EP2794067A1 (en) 2014-10-29
KR20140108695A (ko) 2014-09-12
BR112014015191A8 (pt) 2017-07-04
EA027725B1 (ru) 2017-08-31
BR112014015191A2 (pt) 2017-06-13
JP2015504778A (ja) 2015-02-16
KR102062413B1 (ko) 2020-01-03
CN104125855A (zh) 2014-10-29
CN104125855B (zh) 2017-05-17
JP6145113B2 (ja) 2017-06-07
AU2012354175A1 (en) 2013-07-11
AU2012354175B2 (en) 2015-04-30

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