EA201792360A1 - Ультра-селективная углеродная молекулярно-ситовая мембрана и способ ее изготовления - Google Patents
Ультра-селективная углеродная молекулярно-ситовая мембрана и способ ее изготовленияInfo
- Publication number
- EA201792360A1 EA201792360A1 EA201792360A EA201792360A EA201792360A1 EA 201792360 A1 EA201792360 A1 EA 201792360A1 EA 201792360 A EA201792360 A EA 201792360A EA 201792360 A EA201792360 A EA 201792360A EA 201792360 A1 EA201792360 A1 EA 201792360A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- gas
- carbon molecular
- ultra
- manufacture
- molecule
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052799 carbon Inorganic materials 0.000 title abstract 3
- 239000012528 membrane Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002808 molecular sieve Substances 0.000 abstract 2
- 230000035699 permeability Effects 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 238000000197 pyrolysis Methods 0.000 abstract 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/225—Multiple stage diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0083—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D2053/221—Devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D2053/221—Devices
- B01D2053/223—Devices with hollow tubes
- B01D2053/224—Devices with hollow tubes with hollow fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2317/00—Membrane module arrangements within a plant or an apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
- B01D2323/081—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Carbon And Carbon Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Варианты осуществления настоящего изобретения направлены на способ изготовления углеродной молекулярно-ситовой мембраны, имеющей требуемую селективную проницаемость в отношении разделения молекул первого газа и молекул второго газа, где молекула второго газа имеет больший кинетический диаметр, чем молекула первого газа. Способ включает в себя предоставление полимерного предшественника и пиролиз полимерного предшественника при температуре пиролиза, которая является эффективной для селективного уменьшения коэффициента сорбции молекулы второго газа, вследствие чего увеличивается селективная проницаемость получаемой в результате углеродной молекулярно-ситовой мембраны.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562169218P | 2015-06-01 | 2015-06-01 | |
US201562168982P | 2015-06-01 | 2015-06-01 | |
PCT/US2016/035217 WO2016196595A1 (en) | 2015-06-01 | 2016-06-01 | Ultra-selective carbon molecular sieve membranes and methods of making |
Publications (1)
Publication Number | Publication Date |
---|---|
EA201792360A1 true EA201792360A1 (ru) | 2018-06-29 |
Family
ID=57399815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201792360A EA201792360A1 (ru) | 2015-06-01 | 2016-06-01 | Ультра-селективная углеродная молекулярно-ситовая мембрана и способ ее изготовления |
Country Status (9)
Country | Link |
---|---|
US (1) | US20160346740A1 (ru) |
EP (1) | EP3302762A4 (ru) |
JP (1) | JP2018522713A (ru) |
KR (1) | KR20180013985A (ru) |
CN (1) | CN107635646A (ru) |
AU (1) | AU2016270740A1 (ru) |
BR (1) | BR112017025825A2 (ru) |
EA (1) | EA201792360A1 (ru) |
WO (1) | WO2016196595A1 (ru) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018216163A1 (de) | 2018-09-21 | 2020-03-26 | Forschungszentrum Jülich GmbH | CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung |
CN111111465A (zh) * | 2018-11-01 | 2020-05-08 | 中国科学院宁波材料技术与工程研究所 | 一种co2/n2气体分离膜、其制备方法及应用 |
US11660575B2 (en) * | 2018-12-31 | 2023-05-30 | ExxonMobil Technology and Engineering Company | Reactive inhibition of pore structure collapse during pyrolytic formation of carbon molecular sieves |
EP3962631A1 (en) * | 2019-05-01 | 2022-03-09 | King Abdullah University of Science and Technology | Hybrid inorganic oxide-carbon molecular sieve membranes |
KR102539238B1 (ko) | 2020-04-17 | 2023-06-01 | 서강대학교산학협력단 | 탄소 분자체 분리막 및 그 제조방법 |
CN112717725B (zh) * | 2020-12-21 | 2022-04-12 | 太原理工大学 | 一种掺杂多孔含氮微球的混合基质碳分子筛膜的制备方法及应用 |
CN112717726B (zh) * | 2020-12-21 | 2022-03-22 | 太原理工大学 | 一种原位掺杂碳化氮的混合基质碳分子筛膜的制备方法及应用 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4685940A (en) * | 1984-03-12 | 1987-08-11 | Abraham Soffer | Separation device |
JP2688751B2 (ja) * | 1988-02-29 | 1997-12-10 | 三菱レイヨン株式会社 | 中空炭素膜繊維の製造方法 |
JPH07121344B2 (ja) * | 1990-04-27 | 1995-12-25 | 宇部興産株式会社 | 非対称性中空糸炭素膜及びその製法 |
DE69102350T2 (de) * | 1990-04-27 | 1995-01-19 | Ube Industries | Asymmetrische Hohlfadenmembran aus Kohlenstoff und Verfahren zu deren Herstellung. |
US5288304A (en) * | 1993-03-30 | 1994-02-22 | The University Of Texas System | Composite carbon fluid separation membranes |
JP3361655B2 (ja) * | 1995-05-10 | 2003-01-07 | エヌオーケー株式会社 | 多孔質セラミックス複合中空糸膜およびその製造法 |
US5972079A (en) * | 1996-06-28 | 1999-10-26 | University Of Delaware | Supported carbogenic molecular sieve membrane and method of producing the same |
US6471745B1 (en) * | 1996-06-28 | 2002-10-29 | University Of Delaware | Nanoporous carbon catalytic membranes and method for making the same |
JP3647985B2 (ja) * | 1996-08-09 | 2005-05-18 | カネボウ株式会社 | 分子ふるい炭素膜およびその製造法 |
US6004374A (en) * | 1997-10-10 | 1999-12-21 | Air Products And Chemicals, Inc. | Carbonaceous adsorbent membranes for gas dehydration |
US6395066B1 (en) * | 1999-03-05 | 2002-05-28 | Ube Industries, Ltd. | Partially carbonized asymmetric hollow fiber separation membrane, process for its production, and gas separation method |
JP4081956B2 (ja) * | 1999-03-05 | 2008-04-30 | 宇部興産株式会社 | 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法 |
US6740143B2 (en) * | 2000-06-22 | 2004-05-25 | E. I. Du Pont De Nemours And Company | Mixed matrix nanoporous carbon membranes |
US6503295B1 (en) * | 2000-09-20 | 2003-01-07 | Chevron U.S.A. Inc. | Gas separations using mixed matrix membranes |
US6730364B2 (en) * | 2002-03-28 | 2004-05-04 | National Science Council | Preparation of carbon molecular sieve membranes on porous substrate |
US7404844B2 (en) * | 2004-02-26 | 2008-07-29 | National University Of Singapore | Method for making carbon membranes for fluid separation |
US20070245897A1 (en) * | 2006-04-20 | 2007-10-25 | Innovene Usa | Electron, hydrogen and oxygen conveying membranes |
US8486179B2 (en) * | 2009-10-29 | 2013-07-16 | Georgia Tech Research Corporation | Method for producing carbon molecular sieve membranes in controlled atmospheres |
US8911534B2 (en) * | 2011-03-07 | 2014-12-16 | Georgia Tech Research Corporation | Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations |
CN102824857A (zh) * | 2011-06-14 | 2012-12-19 | 北京航空航天大学 | 一种气体分离炭膜的制备方法 |
BR112014015191B1 (pt) * | 2011-12-20 | 2021-10-13 | Shell Internationale Research Maatschappij B.V. | Processo para formar uma membrana de carbono de fibra oca |
US9346011B2 (en) * | 2012-05-01 | 2016-05-24 | Dow Global Technologies Llc | Hollow fiber carbon molecular sieve membrane and preparation and use thereof |
US8999037B2 (en) * | 2012-05-30 | 2015-04-07 | Georgia Tech Research Corporation | Carbon molecular sieve membrane (CMSM) performance tuning by dual temperature secondary oxygen doping (DTSOD) |
WO2015100161A1 (en) * | 2013-12-26 | 2015-07-02 | L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude | Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers |
-
2016
- 2016-06-01 US US15/170,529 patent/US20160346740A1/en not_active Abandoned
- 2016-06-01 KR KR1020177036953A patent/KR20180013985A/ko unknown
- 2016-06-01 EP EP16804307.3A patent/EP3302762A4/en not_active Withdrawn
- 2016-06-01 BR BR112017025825A patent/BR112017025825A2/pt not_active Application Discontinuation
- 2016-06-01 AU AU2016270740A patent/AU2016270740A1/en not_active Abandoned
- 2016-06-01 JP JP2017560930A patent/JP2018522713A/ja active Pending
- 2016-06-01 CN CN201680032282.0A patent/CN107635646A/zh active Pending
- 2016-06-01 WO PCT/US2016/035217 patent/WO2016196595A1/en active Application Filing
- 2016-06-01 EA EA201792360A patent/EA201792360A1/ru unknown
Also Published As
Publication number | Publication date |
---|---|
WO2016196595A1 (en) | 2016-12-08 |
EP3302762A1 (en) | 2018-04-11 |
JP2018522713A (ja) | 2018-08-16 |
BR112017025825A2 (pt) | 2018-08-14 |
AU2016270740A1 (en) | 2017-12-21 |
EP3302762A4 (en) | 2019-01-23 |
CN107635646A (zh) | 2018-01-26 |
KR20180013985A (ko) | 2018-02-07 |
US20160346740A1 (en) | 2016-12-01 |
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