EP2794067A4 - Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes - Google Patents

Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes

Info

Publication number
EP2794067A4
EP2794067A4 EP12860299.2A EP12860299A EP2794067A4 EP 2794067 A4 EP2794067 A4 EP 2794067A4 EP 12860299 A EP12860299 A EP 12860299A EP 2794067 A4 EP2794067 A4 EP 2794067A4
Authority
EP
European Patent Office
Prior art keywords
stabilization
molecular sieve
high performance
hollow fiber
fiber membranes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12860299.2A
Other languages
German (de)
French (fr)
Other versions
EP2794067B1 (en
EP2794067A1 (en
Inventor
Nitesh Bhuwania
William John Koros
Paul Jason Williams
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Georgia Tech Research Corp
Original Assignee
Shell Internationale Research Maatschappij BV
Georgia Tech Research Institute
Georgia Tech Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV, Georgia Tech Research Institute, Georgia Tech Research Corp filed Critical Shell Internationale Research Maatschappij BV
Publication of EP2794067A1 publication Critical patent/EP2794067A1/en
Publication of EP2794067A4 publication Critical patent/EP2794067A4/en
Application granted granted Critical
Publication of EP2794067B1 publication Critical patent/EP2794067B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0076—Pretreatment of inorganic membrane material prior to membrane formation, e.g. coating of metal powder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/022—Asymmetric membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
EP12860299.2A 2011-12-20 2012-10-29 Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes Active EP2794067B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161577949P 2011-12-20 2011-12-20
PCT/US2012/062440 WO2013095775A1 (en) 2011-12-20 2012-10-29 Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes

Publications (3)

Publication Number Publication Date
EP2794067A1 EP2794067A1 (en) 2014-10-29
EP2794067A4 true EP2794067A4 (en) 2015-08-12
EP2794067B1 EP2794067B1 (en) 2020-03-25

Family

ID=48608794

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12860299.2A Active EP2794067B1 (en) 2011-12-20 2012-10-29 Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes

Country Status (10)

Country Link
US (1) US9211504B2 (en)
EP (1) EP2794067B1 (en)
JP (1) JP6145113B2 (en)
KR (1) KR102062413B1 (en)
CN (1) CN104125855B (en)
AU (1) AU2012354175B2 (en)
BR (1) BR112014015191B1 (en)
EA (1) EA027725B1 (en)
MY (1) MY188200A (en)
WO (1) WO2013095775A1 (en)

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EA027725B1 (en) * 2011-12-20 2017-08-31 Джорджия Тек Рисёч Корпорейшн Process for forming a carbon membrane
ES2744606T3 (en) * 2012-05-01 2020-02-25 Dow Global Technologies Llc Use of a hollow carbon fiber molecular sieve membrane
US10000294B2 (en) 2012-08-24 2018-06-19 The Boeing Company Aircraft fuel tank flammability reduction method and system
US9327243B2 (en) 2012-08-24 2016-05-03 The Boeing Company Aircraft fuel tank flammability reduction methods and systems
US9061249B2 (en) * 2012-08-24 2015-06-23 The Boeing Company Aircraft fuel tank flammability reduction method and system
EP3052222B1 (en) * 2013-09-30 2021-05-12 Georgia Tech Research Corporation Process for preparing an asymmetric modified carbon molecular sieve hollow fiber membrane and use of the same
WO2015100161A1 (en) 2013-12-26 2015-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers
US10500548B2 (en) 2014-09-22 2019-12-10 Georgia Tech Research Corporation Composite nanoparticle stabilized core carbon molecular sieve hollow fiber membranes having improved permeance
CN106794430B (en) 2014-09-24 2020-11-06 陶氏环球技术有限责任公司 Carbon Molecular Sieve (CMS) hollow fiber membranes and their preparation starting from pre-oxidized polyimides
US10086337B2 (en) 2014-11-30 2018-10-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Composite carbon molecular sieve membranes having anti-substructure collapse particles loaded in a core thereof
US10456751B2 (en) * 2015-03-27 2019-10-29 National Institute Of Advanced Industrial Science And Technology Method for producing hollow fiber carbon membrane and separation membrane module
EP3302762A4 (en) * 2015-06-01 2019-01-23 Georgia Tech Research Corporation Ultra-selective carbon molecular sieve membranes and methods of making
US10351780B2 (en) 2015-07-28 2019-07-16 Shell Oil Company Process for preparing a paraffin product
CN106823821A (en) * 2015-12-04 2017-06-13 中国科学院大连化学物理研究所 The complementing method of Carbon Molecular Sieve Membrane defect
CA3008242C (en) 2015-12-17 2024-01-02 Dow Global Technologies Llc Method of making carbon molecular sieve membranes
WO2017160815A1 (en) * 2016-03-16 2017-09-21 Dow Global Technologies Llc Separation of gases via carbonized vinylidene chloride copolymer gas separation membranes and process for the preparation of the membranes
US11084000B2 (en) * 2016-03-21 2021-08-10 Dow Global Technologies Llc Method of making carbon molecular sieve membranes
US10968105B2 (en) 2016-03-28 2021-04-06 Board Of Regents, The University Of Texas System Low-temperature pyrolysis of organic acid salts providing graphene rich carbons
EP3538251B1 (en) * 2016-11-10 2022-07-13 Dow Global Technologies, LLC Improved method to make carbon molecular sieve hollow fiber membranes
US10549244B2 (en) * 2016-12-14 2020-02-04 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hollow fiber carbon molecular sieve membranes and method of manufacturing using radial-flow pyrolysis
US10543462B2 (en) 2016-12-14 2020-01-28 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hollow fiber carbon molecular sieve membranes and method of manufacturing using radial-flow pyrolysis
BR112019016289B1 (en) * 2017-02-10 2023-11-14 Georgia Tech Research Corporation PROCESS TO SEPARATE GASEOUS COMPONENTS USING CARBON MOLECULAR SIEVE MEMBRANES
KR102606593B1 (en) * 2017-04-06 2023-11-28 다우 글로벌 테크놀로지스 엘엘씨 Asymmetric polyvinylidine chloride membrane and carbon molecular sieve membrane prepared therefrom
CN110740804B (en) * 2017-06-15 2022-05-27 陶氏环球技术有限责任公司 Supported carbon molecular sieve diaphragm and forming method thereof
CN107469640B (en) * 2017-07-20 2019-11-26 大连理工大学 A kind of preparation method of high gas permeability carbon membrane
KR102542793B1 (en) 2017-08-14 2023-06-14 다우 글로벌 테크놀로지스 엘엘씨 Improved Manufacturing Method of Carbon Molecular Sieve Hollow Fiber Membrane
KR102086921B1 (en) 2017-12-12 2020-03-09 서강대학교산학협력단 Hybrid polymeric hollow fiber membrane, carbon molecular sieve hollow fiber membrane, and processes for fabricating the same
BR112021001258A2 (en) 2018-08-23 2021-04-20 Dow Global Technologies Llc cross-linked polyimide, methods for forming a cross-linked polyimide, and for forming a carbon molecular sieve membrane, and, carbon molecular sieve membrane
DE102018216163A1 (en) 2018-09-21 2020-03-26 Forschungszentrum Jülich GmbH CMS membrane, process for its production and its use
US11660575B2 (en) * 2018-12-31 2023-05-30 ExxonMobil Technology and Engineering Company Reactive inhibition of pore structure collapse during pyrolytic formation of carbon molecular sieves
CN113272049A (en) * 2019-01-18 2021-08-17 东丽株式会社 Carbon membrane for fluid separation
WO2020154146A1 (en) 2019-01-25 2020-07-30 Dow Global Technologies Llc A carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend
CN109738507B (en) * 2019-01-28 2022-03-04 哈尔滨工业大学（威海） Micro-plastic detection device and method based on pyrolysis-mass spectrometry technology
CN112044273B (en) * 2019-06-05 2023-04-25 中国石油天然气股份有限公司 Carbon molecular sieve membrane with improved permeability and selectivity, and preparation method and application thereof
EP4072715A1 (en) * 2019-12-11 2022-10-19 Fundación Tecnalia Research & Innovation Carbon molecular sieve membrane and its use in separation processes
EP4081339A1 (en) * 2019-12-27 2022-11-02 Dow Global Technologies LLC Carbon molecular sieve adsorbent monoliths and methods for making the same
GB202009004D0 (en) 2020-06-12 2020-07-29 Norwegian Univ Of Science And Technology (Ntnu) Carbon hollow fibre membrane
CN117210975B (en) * 2023-10-26 2024-08-23 江苏恒神股份有限公司 High-strength high-modulus high-toughness carbon fiber and preparation method thereof

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US20050235825A1 (en) * 2004-02-26 2005-10-27 Tin Pei S Method for making carbon membranes for fluid separation

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Also Published As

Publication number Publication date
US20130152793A1 (en) 2013-06-20
KR102062413B1 (en) 2020-01-03
EP2794067B1 (en) 2020-03-25
BR112014015191A8 (en) 2017-07-04
EA201491202A1 (en) 2014-11-28
US9211504B2 (en) 2015-12-15
AU2012354175A1 (en) 2013-07-11
CN104125855B (en) 2017-05-17
BR112014015191A2 (en) 2017-06-13
JP6145113B2 (en) 2017-06-07
AU2012354175B2 (en) 2015-04-30
CN104125855A (en) 2014-10-29
BR112014015191B1 (en) 2021-10-13
EA027725B1 (en) 2017-08-31
WO2013095775A1 (en) 2013-06-27
KR20140108695A (en) 2014-09-12
MY188200A (en) 2021-11-24
EP2794067A1 (en) 2014-10-29
JP2015504778A (en) 2015-02-16

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