EA201270729A1 - Модифицированные носители катализатора - Google Patents

Модифицированные носители катализатора

Info

Publication number
EA201270729A1
EA201270729A1 EA201270729A EA201270729A EA201270729A1 EA 201270729 A1 EA201270729 A1 EA 201270729A1 EA 201270729 A EA201270729 A EA 201270729A EA 201270729 A EA201270729 A EA 201270729A EA 201270729 A1 EA201270729 A1 EA 201270729A1
Authority
EA
Eurasian Patent Office
Prior art keywords
silica
support
catalyst
treating
titanated
Prior art date
Application number
EA201270729A
Other languages
English (en)
Other versions
EA019933B1 (ru
Inventor
Кристофер Вийок
Мартин Славински
Орельен Вантомм
Original Assignee
Тотал Ресерч Энд Текнолоджи Фелюи
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Тотал Ресерч Энд Текнолоджи Фелюи filed Critical Тотал Ресерч Энд Текнолоджи Фелюи
Publication of EA201270729A1 publication Critical patent/EA201270729A1/ru
Publication of EA019933B1 publication Critical patent/EA019933B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/025—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Abstract

Способ получения каталитической системы на носителе, включающий следующие этапы, на которых а) титанируют кремнеземсодержащий носитель катализатора с удельной поверхностью 150-800 м/г, предпочтительно 280-260 м/г, по меньшей мере одним парообразным соединением титана с общей формулой, выбранной из RTi(OR')и (RO)(OR'), где R и R' одинаковые или различные и выбраны из гидрокарбильных групп, содержащих от 1 до 12 атомов углерода и галогены, и где n составляет 0-4, m составляет 0-4 и m+n равняется 4, для образования титанированного кремнеземсодержащего носителя катализатора по меньшей мере с 0,1 вес.% Ti из расчета веса титанированного кремнеземсодержащего носителя катализатора; b) обрабатывают носитель активирующим катализатор средством, предпочтительно алюмоксаном; с) обрабатывают титанированный носитель по меньшей мере одним металлоценом во время или после этапа (b).
EA201270729A 2010-03-04 2011-03-03 Модифицированные носители катализатора EA019933B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10155537 2010-03-04
EP10172638 2010-08-12
PCT/EP2011/053233 WO2011107560A1 (en) 2010-03-04 2011-03-03 Modified catalyst supports

Publications (2)

Publication Number Publication Date
EA201270729A1 true EA201270729A1 (ru) 2013-01-30
EA019933B1 EA019933B1 (ru) 2014-07-30

Family

ID=43891093

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201270729A EA019933B1 (ru) 2010-03-04 2011-03-03 Модифицированные носители катализатора

Country Status (9)

Country Link
US (2) US9156922B2 (ru)
EP (1) EP2542594B1 (ru)
KR (1) KR101422976B1 (ru)
CN (1) CN102869686B (ru)
BR (1) BR112012022316B1 (ru)
DK (1) DK2542594T3 (ru)
EA (1) EA019933B1 (ru)
ES (1) ES2664955T3 (ru)
WO (1) WO2011107560A1 (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012001160A2 (en) * 2010-07-01 2012-01-05 Total Petrochemicals Research Feluy Modified catalyst supports
US9221930B2 (en) * 2011-09-09 2015-12-29 Total Research & Technology Feluy Polyethylene with low catalytic residues
CN107987192B (zh) * 2016-10-26 2021-07-02 中国石油化工股份有限公司 一种负载型茂金属催化剂及其应用
ES2849568T3 (es) * 2017-01-13 2021-08-19 Total Res & Technology Feluy Polipropilenos de alta pureza y composiciones de polipropileno para moldeo
WO2018211079A1 (en) 2017-05-18 2018-11-22 Total Research & Technology Feluy Drawn articles of low mfi metallocene polypropylene and process to produce such drawn articles

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1415649A (en) * 1971-12-23 1975-11-26 Bp Chem Int Ltd Olefin polymerisation process and catalyst for use therein
US5124418A (en) * 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
IT1250706B (it) 1991-07-25 1995-04-21 Enichem Polimeri Catalizzatore per la polimerizzazione di olefine
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
FI952098A (fi) 1995-05-02 1996-11-03 Borealis As LLDPE-polymeerien valmistusmenetelmä
EP0882743B1 (en) * 1997-06-06 2003-11-12 ATOFINA Research Titanated chromium-based catalysts to produce polyethylene
EP0882740A1 (en) * 1997-06-06 1998-12-09 Fina Research S.A. Titanated chromium-based catalysts to produce polyethylene exhibiting better environmental stress crack resistance
US6096678A (en) * 1998-04-22 2000-08-01 Ray; Sabyasachi Sinha Process for the preparation of supported aluminium chloride catalyst containing organo aluminium compound
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
EP1162210A1 (en) * 2000-06-08 2001-12-12 ATOFINA Research Multimodal polyethylene obtained with multilayer chromium catalyst
CN1181105C (zh) * 2000-08-22 2004-12-22 中国石油化工股份有限公司 用于乙烯聚合或共聚合的高活性硅胶载体催化剂组分及其催化剂和该催化剂的应用
US7192901B2 (en) * 2004-10-27 2007-03-20 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7381778B2 (en) * 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
ES2366651T3 (es) * 2004-12-31 2011-10-24 Borealis Technology Oy Procedimiento para preparar un catalizador sólido para la polimerización de olefinas.
US7595364B2 (en) * 2005-12-07 2009-09-29 Univation Technologies, Llc High density polyethylene
US20090215190A1 (en) * 2008-02-26 2009-08-27 Stirn Pamela J Apparatus and method for exothermic and endothermic reactions
WO2012001160A2 (en) * 2010-07-01 2012-01-05 Total Petrochemicals Research Feluy Modified catalyst supports

Also Published As

Publication number Publication date
CN102869686A (zh) 2013-01-09
WO2011107560A1 (en) 2011-09-09
EP2542594B1 (en) 2018-02-21
KR101422976B1 (ko) 2014-07-23
US20130144016A1 (en) 2013-06-06
US9475893B2 (en) 2016-10-25
EA019933B1 (ru) 2014-07-30
BR112012022316B1 (pt) 2019-12-24
DK2542594T3 (en) 2018-05-07
US9156922B2 (en) 2015-10-13
EP2542594A1 (en) 2013-01-09
ES2664955T3 (es) 2018-04-24
KR20120123139A (ko) 2012-11-07
US20150315304A1 (en) 2015-11-05
BR112012022316A2 (pt) 2017-02-14
CN102869686B (zh) 2015-07-22

Similar Documents

Publication Publication Date Title
EA201270827A1 (ru) Модифицированные носители катализатора
EA201270729A1 (ru) Модифицированные носители катализатора
EA201692461A1 (ru) Прокатализатор для полимеризации олефинов
EA201400692A1 (ru) Способ получения бимодального полиэтилена в присутствии данной системы катализатора
BRPI0918697A8 (pt) Processo para melhorar as propriedades de um procatalisador e composição de procatalisador
EA201500781A1 (ru) Способ получения компонента катализатора полимеризации олефинов
WO2011135004A3 (en) Solid particulate catalysts comprising bridged metallocenes
RU2012141048A (ru) Композиция прокатализатора с замещенным амидоэфиром в качестве внутреннего донора электронов
RU2016118260A (ru) Процесс подготовки пористых пропиленовых полимеров
BR112012026842A2 (pt) composições de catalisador para produção de poliolefinas de mz/mw elevados
EA201492139A1 (ru) Метатезис натурального масла, композиции и способы
EA201201511A1 (ru) Получение твердой каталитической системы
WO2012105887A8 (en) Active principle for mitigating undesired medical conditions
JP2010513625A5 (ru)
EA201691281A1 (ru) Композиция катализатора полимеризации олефинов
BR112015012107A2 (pt) sistemas de catalisador ziegler-natta de alto desempenho, processo para produzir tais catalisadores sustentados e uso dos mesmos
EA201990805A1 (ru) Прокатализатор для полимеризации олефинов
ES2542080T3 (es) Sistema catalizador para la polimerización de olefinas
EA201400693A1 (ru) Система катализатора для получения сверхвысокомолекулярного полиэтилена
EA201290872A1 (ru) Способ получения бензоксаборолов
WO2012134719A8 (en) Novel catalysts and methods of use thereof to produce vinyl terminated polymers
RU2013133888A (ru) Прокаталитическая композиция с алкоксипропиловым сложным эфиром в качестве внутреннего электронодонора и полимер из нее
RU2012146091A (ru) Способ получения уретонимин-модифицированной изоцианатной композиции
EA201990812A1 (ru) Прокатализатор для полимеризации олефинов
ATE533794T1 (de) Katalysatorsystem und verfahren zur herstellung von polyethylen in gegenwart dieses katalysatorsystems

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM