EA201270827A1 - Модифицированные носители катализатора - Google Patents
Модифицированные носители катализатораInfo
- Publication number
- EA201270827A1 EA201270827A1 EA201270827A EA201270827A EA201270827A1 EA 201270827 A1 EA201270827 A1 EA 201270827A1 EA 201270827 A EA201270827 A EA 201270827A EA 201270827 A EA201270827 A EA 201270827A EA 201270827 A1 EA201270827 A1 EA 201270827A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- silica
- weight
- titanium
- modified catalyst
- catalyst carrier
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
Abstract
Настоящее изобретение охватывает каталитическую систему на носителе, полученную по способу, включающему следующий этап, на котором: i) пропитывают кремнеземсодержащий носитель катализатора с удельной площадью поверхности от 150 до 800 м/г, предпочтительно от 280 до 600 м/г, одним или несколькими соединениями титана с общей формулой, выбранной из RTi(OR')и (RO)Ti(OR'), где R и R', одинаковые или различные, выбраны из гидрокарбильных групп, содержащих от 1 до 12 атомов углерода, и галогенов и где n составляет 0-4, m составляет 0-4 и m+n равняется 4, для образования титанированного кремнеземсодержащего носителя катализатора с содержанием Ti по меньшей мере 0,1 вес.% на основе веса пропитанного Ti носителя катализатора, где каталитическая система на носителе дополнительно включает алюмоксан и металлоцен.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10168151 | 2010-07-01 | ||
EP10172640 | 2010-08-12 | ||
PCT/EP2011/061146 WO2012001160A2 (en) | 2010-07-01 | 2011-07-01 | Modified catalyst supports |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201270827A1 true EA201270827A1 (ru) | 2013-08-30 |
EA024402B1 EA024402B1 (ru) | 2016-09-30 |
Family
ID=45402476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201270827A EA024402B1 (ru) | 2010-07-01 | 2011-07-01 | Применение каталитической системы на носителе для получения полиолефинов |
Country Status (8)
Country | Link |
---|---|
US (2) | US10233268B2 (ru) |
EP (1) | EP2588501B1 (ru) |
KR (1) | KR101502673B1 (ru) |
CN (1) | CN103237817B (ru) |
DK (1) | DK2588501T3 (ru) |
EA (1) | EA024402B1 (ru) |
ES (1) | ES2575852T3 (ru) |
WO (1) | WO2012001160A2 (ru) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2664955T3 (es) * | 2010-03-04 | 2018-04-24 | Total Research & Technology Feluy | Soportes de catalizador modificado |
EP2751149B1 (en) * | 2011-09-09 | 2017-05-31 | Total Research & Technology Feluy | Polyethylene with low catalytic residues |
CN104507980B (zh) | 2012-07-27 | 2017-03-22 | 道达尔研究技术弗吕公司 | 用于制备聚乙烯树脂的方法 |
BR112016008354A2 (pt) | 2013-10-28 | 2017-09-12 | Akzo Nobel Chemicals Int Bv | processo de preparação de alquilaluminoxanos por meio da reação de alquilalumínio com um álcool alílico substituído da fórmula, produto que pode ser obtido por meio do processo, e, uso do produto |
PL3077714T3 (pl) | 2014-04-23 | 2019-04-30 | Total Res & Technology Feluy | Rura zawierająca żywicę polietylenową katalizowaną metalocenem |
WO2017009386A1 (en) | 2015-07-15 | 2017-01-19 | Total Research & Technology Feluy | Process for preparing a polyethylene product |
EP3390468B1 (en) | 2015-12-17 | 2024-03-13 | TotalEnergies OneTech Belgium | Process for determining one or more operating conditions of an olefin polymerization reactor |
KR20180137002A (ko) | 2016-04-26 | 2018-12-26 | 토탈 리서치 앤드 테크놀로지 펠루이 | 나노입자를 포함하는 폴리올레핀 조성물 |
CN109196040A (zh) | 2016-04-26 | 2019-01-11 | 道达尔研究技术弗吕公司 | 聚烯烃组合物 |
CN109661426B (zh) | 2016-07-01 | 2021-11-16 | 道达尔研究技术弗吕公司 | 用于人造草皮纱的聚乙烯组合物 |
CN109642062A (zh) | 2016-08-31 | 2019-04-16 | 道达尔研究技术弗吕公司 | 包括由单中心催化剂制造的全同立构聚丙烯和聚乙烯的聚烯烃共混物、工艺及由这些共混物制成的制品 |
FR3056119B1 (fr) | 2016-09-20 | 2018-10-05 | Total Raffinage Chimie | Paroi cylindrique de filtrage de particules solides dans un fluide |
TW201840688A (zh) | 2017-01-13 | 2018-11-16 | 比利時商道達爾研究及技術弗呂公司 | 由複合材料製得的導電物品及製造這些物品的方法 |
CN110612313A (zh) * | 2017-03-23 | 2019-12-24 | 埃克森美孚化学专利公司 | 催化剂体系及其制备和使用方法 |
EP3625382B1 (en) | 2017-05-18 | 2020-12-09 | Total Research & Technology Feluy | Drawn articles of low mfi metallocene polypropylene and process to produce such drawn articles |
TW201903229A (zh) | 2017-06-06 | 2019-01-16 | 比利時商道達爾研究及技術弗呂公司 | 聚乙烯布、以及由其製成的襯裡和人造草皮 |
EP3907258A1 (en) | 2020-05-05 | 2021-11-10 | Total Research & Technology Feluy | Polyethylene-based masterbatches comprising carbon nanotubes for preparing conductive articles, process and conductive articles produced therefrom |
EP3912956A1 (en) | 2020-05-19 | 2021-11-24 | Total Research & Technology Feluy | Polyethylene-based masterbatches comprising carbon nanotubes and metallic stearate for preparing conductive articles, process and conductive articles produced therefrom |
EP3919529A1 (en) | 2020-06-04 | 2021-12-08 | Total Research & Technology Feluy | Process to produce propylene copolymer, the polypropylene produced and articles made from this polypropylene |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1415649A (en) * | 1971-12-23 | 1975-11-26 | Bp Chem Int Ltd | Olefin polymerisation process and catalyst for use therein |
US5124418A (en) * | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5001205A (en) * | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US5441920A (en) * | 1989-03-21 | 1995-08-15 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5032562A (en) | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
US5739368A (en) * | 1996-05-10 | 1998-04-14 | Albemarle Corporation | Use of heat treated alumoxanes in preparing supported catalysts |
US5705579A (en) * | 1996-07-17 | 1998-01-06 | Phillips Petroleum Company | Olefin polymerization |
US6556862B2 (en) * | 1998-03-19 | 2003-04-29 | Cardiac Pacemakers, Inc. | Method and apparatus for treating supraventricular tachyarrhythmias |
AU4716301A (en) * | 1999-12-16 | 2001-06-25 | Phillips Petroleum Company | Organometal compound catalyst |
US20080281063A9 (en) * | 1999-12-30 | 2008-11-13 | Sukhadia Ashish M | Ethylene polymers and copolymers with high optical opacity and methods of making the same |
EP1162210A1 (en) * | 2000-06-08 | 2001-12-12 | ATOFINA Research | Multimodal polyethylene obtained with multilayer chromium catalyst |
KR20060104657A (ko) * | 2005-03-31 | 2006-10-09 | 삼성에스디아이 주식회사 | 전자 방출 소자 |
US20070299222A1 (en) * | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
ES2664955T3 (es) * | 2010-03-04 | 2018-04-24 | Total Research & Technology Feluy | Soportes de catalizador modificado |
-
2011
- 2011-07-01 EA EA201270827A patent/EA024402B1/ru not_active IP Right Cessation
- 2011-07-01 EP EP11728855.5A patent/EP2588501B1/en active Active
- 2011-07-01 KR KR1020127033840A patent/KR101502673B1/ko active IP Right Grant
- 2011-07-01 CN CN201180041525.4A patent/CN103237817B/zh active Active
- 2011-07-01 US US13/807,559 patent/US10233268B2/en active Active
- 2011-07-01 WO PCT/EP2011/061146 patent/WO2012001160A2/en active Application Filing
- 2011-07-01 ES ES11728855.5T patent/ES2575852T3/es active Active
- 2011-07-01 DK DK11728855.5T patent/DK2588501T3/en active
-
2019
- 2019-01-30 US US16/262,514 patent/US10618987B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EA024402B1 (ru) | 2016-09-30 |
EP2588501A2 (en) | 2013-05-08 |
US10233268B2 (en) | 2019-03-19 |
EP2588501B1 (en) | 2016-03-23 |
US20130211018A1 (en) | 2013-08-15 |
KR101502673B1 (ko) | 2015-03-13 |
DK2588501T3 (en) | 2016-07-04 |
WO2012001160A2 (en) | 2012-01-05 |
WO2012001160A3 (en) | 2013-06-13 |
ES2575852T3 (es) | 2016-07-01 |
CN103237817B (zh) | 2016-03-16 |
KR20130037690A (ko) | 2013-04-16 |
CN103237817A (zh) | 2013-08-07 |
US20190161565A1 (en) | 2019-05-30 |
US10618987B2 (en) | 2020-04-14 |
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