EA199800515A1 - Усовершенствованные способы, катализируемые комплексом металл-лиганд - Google Patents

Усовершенствованные способы, катализируемые комплексом металл-лиганд

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Publication number
EA199800515A1
EA199800515A1 EA199800515A EA199800515A EA199800515A1 EA 199800515 A1 EA199800515 A1 EA 199800515A1 EA 199800515 A EA199800515 A EA 199800515A EA 199800515 A EA199800515 A EA 199800515A EA 199800515 A1 EA199800515 A1 EA 199800515A1
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EA
Eurasian Patent Office
Prior art keywords
lihand
catalized
metal
complex
improved methods
Prior art date
Application number
EA199800515A
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English (en)
Other versions
EA001502B1 (ru
Inventor
Эрнст Биллиг
Дэвид Роберт Брайант
Original Assignee
Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27533266&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EA199800515(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн filed Critical Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн
Publication of EA199800515A1 publication Critical patent/EA199800515A1/ru
Publication of EA001502B1 publication Critical patent/EA001502B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0259—Phosphorus acids or phosphorus acid esters comprising phosphorous acid (-ester) groups ((RO)P(OR')2) or the isomeric phosphonic acid (-ester) groups (R(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Настоящее изобретение касается способа, который включает взаимодействие одного или нескольких реагентов в присутствии металлокомплексного катализатора с органополифосфитными лигандами с получением жидкого продукта реакции, содержащего один или несколько продуктов, при котором указанный процесс проводится при концентрации свободного органополифосфитного лиганда, достаточной для предотвращения и/или уменьшения гидролитического разложения органополифосфитного лиганда и дезактивации металлокомплексного катализатора с органополифосфитными лигандами.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199800515A 1995-12-06 1996-12-05 Усовершенствованные способы, катализируемые комплексом металл-лиганд EA001502B1 (ru)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US876395P 1995-12-06 1995-12-06
US828495P 1995-12-06 1995-12-06
US828995P 1995-12-06 1995-12-06
US828695P 1995-12-06 1995-12-06
US08/757,740 US5767321A (en) 1995-12-06 1996-11-26 Metal-ligand complex catalyzed processes
PCT/US1996/019412 WO1997020800A1 (en) 1995-12-06 1996-12-05 Improved metal-ligand complex catalyzed processes

Publications (2)

Publication Number Publication Date
EA199800515A1 true EA199800515A1 (ru) 1998-12-24
EA001502B1 EA001502B1 (ru) 2001-04-23

Family

ID=27533266

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199800515A EA001502B1 (ru) 1995-12-06 1996-12-05 Усовершенствованные способы, катализируемые комплексом металл-лиганд

Country Status (14)

Country Link
US (1) US5767321A (ru)
EP (1) EP1019352B2 (ru)
JP (1) JP4050792B2 (ru)
CN (1) CN1078580C (ru)
AU (1) AU720249B2 (ru)
BR (1) BR9611808A (ru)
CA (1) CA2239618C (ru)
CZ (1) CZ174898A3 (ru)
DE (1) DE69630322T3 (ru)
EA (1) EA001502B1 (ru)
MX (1) MX9804076A (ru)
PL (1) PL327088A1 (ru)
SK (1) SK69298A3 (ru)
WO (1) WO1997020800A1 (ru)

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JP3812095B2 (ja) * 1997-10-28 2006-08-23 三菱化学株式会社 アルデヒド類の製造方法及びこれに用いるビスホスファイト
DE19852104A1 (de) * 1998-11-12 2000-05-18 Degussa Verfahren zur Herstellung von ß-Hydroxyaldehyden
DE10048301A1 (de) 2000-09-29 2002-04-11 Oxeno Olefinchemie Gmbh Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE102004050935A1 (de) * 2004-10-18 2006-04-20 Basf Ag Extraktion von Nickel(0)-Komplexen aus Nitrilgemischen mit verminderter Mulmbildung
JP2008517995A (ja) * 2004-10-27 2008-05-29 ダニスコ エイ／エス プロセス
JP2006306815A (ja) * 2005-04-28 2006-11-09 Mitsubishi Chemicals Corp アルデヒドの製造方法
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
EP2488539B2 (en) 2009-10-16 2023-12-20 Dow Technology Investments LLC Gas phase hydroformylation process
KR101346977B1 (ko) 2010-06-04 2014-01-02 주식회사 엘지화학 하이드로포르밀화 반응 부산물 제거용 장치 및 방법
WO2012064586A1 (en) * 2010-11-12 2012-05-18 Dow Technology Investments Llc Mitigation of fouling in hydroformylation processes by water addition
SA112330271B1 (ar) * 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
BR112014016137B1 (pt) 2011-12-30 2021-02-09 Basf Se forma cristalina não solvatada, monossolvato de tolueno cristalino, solvato de acetona cristalino, composição, processo para a preparação do monossolvato de tolueno cristalino, processo para a preparação de uma forma cristalina não solvatada, processo para a preparação do solvato de acetona cristalino, método para obter o solvato de acetona cristalino, uso de uma forma cristalina, e, método para produzir um catalisador de metal de transição
MY164954A (en) 2011-12-30 2018-02-28 Basf Se Method for purifying organic diphosphite compounds
WO2013184350A1 (en) * 2012-06-04 2013-12-12 Dow Technology Investments Llc Hydroformylation process
WO2014051975A1 (en) 2012-09-25 2014-04-03 Dow Technology Investments Llc Process for stabilizing a phosphite ligand against degradation
WO2014073663A1 (ja) * 2012-11-09 2014-05-15 三井化学株式会社 アルデヒド化合物の精製方法
KR102098429B1 (ko) * 2012-12-06 2020-04-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 방법
CN104045532B (zh) * 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
DE102013217166A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Verfahren zur Hydroformylierung von ungesättigten Verbindungen durch SILP-Katalyse
DE102013217174A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
EP3126319B1 (en) * 2014-03-31 2019-07-17 Dow Technology Investments LLC Hydroformylation process
JP6694396B2 (ja) * 2014-05-14 2020-05-13 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 安定化された有機リン化合物
WO2017019259A1 (en) 2015-07-28 2017-02-02 Dow Technology Investments Llc Method for the preparation of a stabilized organophosphorous compound solution
CA3100778A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes
CN112088153A (zh) 2018-05-30 2020-12-15 陶氏技术投资有限责任公司 控制加氢甲酰化过程的方法
JPWO2020203950A1 (ru) * 2019-03-29 2020-10-08
BR112023017950A2 (pt) 2021-03-31 2023-10-10 Dow Technology Investments Llc Processo de hidroformilação contínuo

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Publication number Publication date
BR9611808A (pt) 1999-02-17
DE69630322T3 (de) 2010-02-18
CZ174898A3 (cs) 1998-10-14
PL327088A1 (en) 1998-11-23
EP1019352A1 (en) 2000-07-19
CA2239618C (en) 2007-02-13
MX9804076A (es) 1998-09-30
EP1019352B1 (en) 2003-10-08
CN1203579A (zh) 1998-12-30
EP1019352B2 (en) 2009-08-12
CA2239618A1 (en) 1997-06-12
DE69630322D1 (de) 2003-11-13
JP4050792B2 (ja) 2008-02-20
AU720249B2 (en) 2000-05-25
JP2000501712A (ja) 2000-02-15
SK69298A3 (en) 1999-03-12
AU1147797A (en) 1997-06-27
US5767321A (en) 1998-06-16
WO1997020800A1 (en) 1997-06-12
CN1078580C (zh) 2002-01-30
EA001502B1 (ru) 2001-04-23
DE69630322T2 (de) 2004-07-29

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