DK2775842T3 - 1-substituerede-5-fluor-3,6-dihydro-6-imino-2 (1h)-pyrimidinonderivater som fungicide midler til anvendelse i plantebeskyttelse - Google Patents
1-substituerede-5-fluor-3,6-dihydro-6-imino-2 (1h)-pyrimidinonderivater som fungicide midler til anvendelse i plantebeskyttelse Download PDFInfo
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- DK2775842T3 DK2775842T3 DK12824035.5T DK12824035T DK2775842T3 DK 2775842 T3 DK2775842 T3 DK 2775842T3 DK 12824035 T DK12824035 T DK 12824035T DK 2775842 T3 DK2775842 T3 DK 2775842T3
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/47—One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/495—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with two or more nitrogen atoms as the only ring heteroatoms, e.g. piperazine or tetrazines
- A61K31/505—Pyrimidines; Hydrogenated pyrimidines, e.g. trimethoprim
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- Agronomy & Crop Science (AREA)
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- Plural Heterocyclic Compounds (AREA)
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Claims (15)
1. Forbindelse med formel I:
Formel I hvor R1 er: Ci-C6-alkyl, der eventuelt er substitueret med 1 - 3 R3; CrCe-alkenyl, der eventuelt er substitueret med 1 - 3 R3; C3-C6-alkynyl, der eventuelt er substitueret med 1 - 3 R3; phenyl eller benzyl, hvor hver af phenyl eller benzyl eventuelt kan være substitueret med 1 - 3 R4, eller med et 5- eller 6-leddet mættet eller umættet ringsystem, eller med et 5 - 6 kondenseret ringsystem eller med et 6 - 6 kondenseret ringsystem, der hver indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt er substitueret med 1 - 3 R4, - (CHR5)mOR6; -C(=0)R7; -C(=S)R7; -C(=0)0R7; C(=S)7; -S(0)2R7; -(CHR5)mN(R8)R9; -C(=0)N(R8)R9; eller -C(=S)N(R8)R9; hvor m er et helt tal 1 - 3; R2 er: H; eller CrCe-alkyl, der eventuelt er substitueret med R3; R3 er uafhængigt halogen, CrC6-alkyl, Ci-C4-haloalkyl, CrC4-alkoxy, Cr C4-haloalkoxy, C1 -C4-alkylthio, Ci-C4-haloalkylthio, amino, halothio, Cr C3-alkylamino, C2-C6-alkoxycarbonyl, C2-C6-alkylcarbonyl, C2-C6-alkylaminocarbonyl, hydroxyl, C3-C6-trialkylsilyl, eller med et 5- eller 6-leddet mættet eller umættet ringsystem, eller med et 5 - 6 kondenseret ringsystem, eller med et 6 - 6 kondenseret ringsystem, der hver indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt er substitueret med 1 - 3 R; R4 er uafhængigt halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy, Cr C6-haloalkoxy, C1 -C6-al kylth io, Ci-C6-haloalkylthio, halothio, amino, Cr C6-alkylamino, C2-C6-dialkylamino, C2-C6-alkoxycarbonyl, CrC6-alkylsulfonyl eller C2-C6-alkylcarbonyl, nitro, hydroxyl eller cyano; R5 er H, Ci-C6-alkyl, Ci-C6-alkoxy, phenyl eller benzyl, hvor hver af benzylen eller phenylen eventuelt kan være substitueret med 1 - 3 R4; R6 er H, CrCe-alkyl, C2-C6-alkenyl, C3-C6-alkynyl, CrCe-haloalkyl, CrC6-alkoxyalkyl, C2-C6-alkylcarbonyl, phenyl eller benzyl, hvor hver af phenylen eller benzylen eventuelt kan være substitueret med 1 - 3 R4, eller med et 5- eller 6-leddet mættet eller umættet ringsystem, eller med 5 - 6 kondenseret ringsystem, eller med et 6 - 6 kondenseret ringsystem, der hver indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt er substitueret med 1 - 3 R4, biphenyl eller naphthyl eventuelt substitueret med 1 - 3 R4; R7 er H, CrCe-alkyl, C2-C6-alkenyl, C3-C6-alkynyl, CrCe-haloalkyl, CrC6-alkoxyalkyl, phenyl eller benzyl, hvor hver af phenylen eller benzylen eventuelt kan være substitueret med 1 - 3 R4, eller med et 5- eller 6-leddet mættet eller umættet ringsystem, eller med et 5 - 6 kondenseret ringsystem eller 6 - 6 kondenseret ringsystem, der hver indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt er substitueret med 1 - 3 R4, biphenyl eller naphthyl eventuelt substitueret med 1 - 3 R4; R8 er H, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxyalkyl, C2-C6-alkylcarbonyl, phenyl eller benzyl, hvor hver af phenylen eller benzylen eventuelt kan være substitueret med 1 - 3 R4, eller med et 5- eller 6-leddet mættet eller umættet ringsystem, eller med et 5 - 6 kondenseret ringsystem eller med et 6 - 6 kondenseret ringsystem, der hver indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt er substitueret med 1 - 3 R4, biphenyl eller naphthyl eventuelt substitueret med 1 - 3 R4; og R9 er H, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxyalkyl, C2-C6-alkylcarbonyl eller benzyl, hvor benzyl eventuelt kan være substitueret med 1 - 3 R4; alternativt kan R8 og R9 tages sammen for at danne en 5- eller 6- leddet mættet eller umættet ring, der indeholder 1 - 3 heteroatomer, hvor hver ring eventuelt kan være substitueret med 1 - 3 R4.
2. Sammensætning til bekæmpelse af et svampepatogen, hvilken sammensætning omfatter forbindelsen ifølge krav 1 og etfytologisk acceptabelt bæremateriale.
3. Sammensætningen ifølge krav 2, hvor svampepatogenet er mindst en af æbleskurv (Venturia inaequalis), bladpletskimmel på hvede (Septoria tritici), bladpletter på sukkerroer (Cercospora beticola), bladpletter på jordnødder (Cercospora arachidicola og Cercosporidium personatum) og sort Sigatoka på banan (Mycosphaerella fijiensis).
4. Fremgangsmåde til bekæmpelse og forebyggelse af svampeangreb på en plante, hvilken fremgangsmåde indbefatter følgende trin: at anvende en fungicid effektiv mængde af mindst en af forbindelserne ifølge krav 1 til mindst en af følgende: planten, et område, der støder op til planten, jord, der er tilpasset til vækst af planten, en rod af planten, plantens løv, og et frø, der er tilpasset til at producere planten.
5. Pesticidformulering, der omfatter forbindelsen ifølge krav 1 og en anden pesticidforbindelse, der er valgt fra gruppen, so består af fungicider, insekticider, herbicider, nematocider, miticider, artropodicider, baktericider eller kombinationer deraf.
6. Pesticidformuleringen ifølge krav 5, hvor vægtforholdet af forbindelsen ifølge krav 1 til den anden pesticidforbindelse er fra 1 : 100 til 100 : 1.
7. Pesticidformuleringen ifølge krav 5, hvor den anden pesticidforbindelse er en fungicidforbindelse, der er valgt fra gruppen, som består af: 2-(thiocyanatomethylthio)-benzothiazol, 2-phenylphenol, 8-hydroxyquinolinsulfat, ametoctradin, amisulbrom, antimycin, ampelomyces quisqualis, azaconazol , azoxystrobin, Bacillus subtilis, benalaxyl, benomyl, benthiavalicarb-isopropyl, benzylaminobenzensulfonat (BABS) salt, bicarbonater, biphenyl, bismerthiazol, bitertanol, bixafen, blasticidin-S, borax, Bordeaux-blanding, boscalid, bromuconazol, bupirimid, calciumpolysulfid, captafol, captan, carbendazim, carboxin, carpropamid, carvon, chloroneb, chlorothalonil, chlozolinat, coniothyrium minitaner, kobberhydroxid, kobberoctanoat, kobberoxychlorid, kobbersulfat, kobbersulfat (tribasisk), kobberoxid, cyazofamid, cyflufenamid, cymoxanil, cyproconazol, cyprodinil, dazomet, debacarb, diammoniumethylenbis-(ditiocarbamat), dichlofluanid, dichlorphen, diclocymet, diclomezin, dichloran, diethofencarb, difenoconazol, difenzoquation, diflumetorim, dimethomorph, dimoxystrobin, diniconazol, diniconazol-M, dinobuton, dinocap, diphenylamin, dithianon, dodemorph, dodemorphacetat, dodin, doin-fri base, edifenphos, enestrobin, epoxiconazol, ethaboxam, ethoxyquin, ethoxquinol, ethoxquinazol, fenamidon, famoxadon, fenamidon, fenarimol, fenbuconazol, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpropidin, fenpropimorph, fenpyrazamin, fentin, fentinacetat, fentinhydroxid, ferbam, ferimzon, fluazinam, fludioxonil, flumorph, fluopicolid, fluopyram, fluorimid, fluoxastrobin, fluquinconazol, flusilazol, flusulfamid, flutianil, flutolanil, flutriafol, fluxapyroxad, folpet, formaldehyd, fosetyl, fosethyl-aluminium, fuberidazol, furalaxyl, furametpyr, guazatin, guazatinacetater, GY-81, hexachlorbenzen, hexaconazol, hymexazol, imazalil, imazalilsulfat, imibenconazol, iminoctadin, iminoctadintriacetat, iminoctadintri (albesilat), iodcarb, ipconazol, ipfenpyrazolon, iprobenfos, iprodion, iprovalicarb, isoprothiolan, isopyrazam, isotianil, laminarin, kasugamycin, kasugamycinhydrochloridhydrat, kresoximmethyl, mankobber, mancozeb, mandipropamid, maneb, mefenoxam, mepanipyrim, mepronil, meptyl-dinocap, mercuricchlorid, mercuroxid, mercurouschlorid, metalaxyl, metalaxyl-M, metam, metamammonium, metamkalium, metamnatrium, metconazol, methasulfocarb, methyliodid, methyl isothiocyanat, metiram, metominostrobin, metrafenon, mildomycin, myclobutanil, nabam, nitrothalisopropyl, nuarimol, octhilinon, ofurace, oleinsyre (fedtsyrer), orysastrobin, oxadixyl, oxinkobber, oxpoconazolfumarat, oxycarboxin, pefurazoat, penconazol, pencycuron, penflufen, pentachlorphenol, pentachlorphenyllaurat, penthiopyrad, phenylmercuryacetat, phosphonsyre, phthalid, picoxystrobin, polyoxin B, polyoxiner, polyoxorim, kaliumbicarbonat, kaliumhydroxyquinolinsulfat, probenazol, prochloraz, procymidon, propamocarb, propamocarbhydrochlorid, propiconazol, propineb, proquinazid, prothioconazol, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyrazophos, pyribencarb, pyributicarb, pyrifenox, pyrimethanil, pyriofenon, pyroquilon, quinoclamin, quinoxyfen, quintozen, Reynoutria sachalinensis ekstrakt, sedaxan, silthiofam, simeconazol, natrium-2-phenylphenoxid, natriumbicarbonat, natriumpentachlorphenoxid, spiroxamin, svovl, SYP-Z071, SYP-Z048, tjæreolier, tebuconazol, tebufloquin, tecnazen, tetraconazol, thiabendazol, thifluzamid, thiophanatmethyl, thiram, tiadinil, tolclofosmethyl, tolylfluanid, triadimefon, triadimenol, triazimid, tricyclazol, tridemorph, trifloxystrobin, triflumizol, triforin, triticonazol, validamycin, valifenalat, valiphenal, vinclozolin, zineb, ziram, zoxamid, Candida oleophila, Fusarium oxysporum, Gliocladium spp., Phlebiopsis gigantea, Streptomyces griseoviridis, Trichoderma spp., (RS)-N-(3,5-dichlorphenyl)-2-(methoxymethyl)-succinimid, 1,2-dichlorpropan, 1,3-dichlor-1,1,3,3-tetrafluoracetonhydrat, 1 -chlor-2,4-dinitronaphthalen, 1 -chlor-2-nitropropan, 2-(2-heptadecyl-2-imidazolin-l-yl) ethanol, 2,3-dihydro-5-phenyl-1,4-dithi-in-1,1,4,4-tetraoxid, 2- methoxyethylmercuryacetat, 2-methoxyethylmercurychlorid, 2- methoxyethylmercurysilicat, 3-(4-chlorphenyl)-5-methylrhodanin, 4-(2-nitroprop-1-enyl)-phenylthiocyanatem, ampropylfos, anilazin, azithiram, bariumpolysulfid, Bayer 32394, benodanil, benquinox, bentaluron, benzamacril; benzamacril-isobutyl, benzamorf, binapacryl, bis(methylmercury)sulfat, bis(tributyltin)oxid, buthiobat, cadmium calcium kobber zink chromat sulfat, carbamorph, CECA, chlobenthiazon, chloraniformethan, chlorfenazol, chlorquinox, climbazol, cyclafuramid, cypendazol, cyprofuram, decafentin, dichlon, dichlozolin, diclobutrazol, dimethirimol, dinocton, dinosulfon, dinoterbon, dipyrithion, ditalimfos, dodicin, drazoxolon, EBP, ESBP, etaconazol, etem, ethirim, fenaminosulf, fenapanil, fenitropan, fluotrimazol, furcarbanil, furconazol, furconazol-cis, furmecyclox, furophanat, glyodin, griseofulvin, halacrinat, Hercules 3944, hexylthiofos, ICIA0858, isopamphos, isovaledion, mebenil, mecarbinzid, metazoxolon, methfuroxam, methylmercury dicyandiamid, metsulfovax, milneb, mucochloric anhydrid, myclozolin, N-3,5-dichlorophenyl-succinimid, N-3-nitrophenylitaconimid, natamycin, N-ethylmercurio-4-toluenesulfonanilid, nikkelbis(dimethyldithiocarbamat), OCH, phenyl-kviksølvdimethyldithiocarbamat, phenylkviksølvnitrat, phosdiphen, picolinamid UK-2A og derivater deraf, prothiocarb; prothiocarb hydrochlorid, pyracarbolid, pyridinitril, pyroxychlor, pyroxyfur, quinacetol, quinacetolsulfat, quinazamid, quinconazol, rabenzazol, salicylanilid, SSF-109, sultropen, tecoram, thiadifluor, thicyofen, thiochlorfenphim, thiophanat, thioquinox, tioxymid, triamiphos, triarimol, triazbutil, trichlamid, urbacid, og zarilamid, og enhver kombination deraf.
8. Pesticidformuleringen ifølge krav 5, hvor den anden pesticidforbindelse er en pesticidforbindelse, der er udvalgt fra gruppen, som består af: 1,2-dichlorpropan, abamectin, acephat, acetamiprid, acethion, acetoprol, acrinathrin, acrylonitril, alanycarb, aldicarb, aldoxycarb, aldrin , allethrin, allosamidin, allyxycarb, alfa- cypermethrin, alfa-ecdyson, alfaendosulfan, amidithion, aminocarb, amiton, amitonoxalat, amitraz, anabasin, athidathion, azadirachtin, azamethiphos, azinphosethyl, azinphos-methyl, azothoat, bariumhexafluorosilikat , barthrin, bendiocarb, benfuracarb, bensultap, beta-cyfluthrin, beta-cypermethrin, bifenthrin, bioallethrin, bioethanomethrin, biopermethrin, bistrifluoron, borax, borsyre, bromfenvinfos, bromcycylen, brom-DDT, bromophos, bromophosethyl, bufencarb, buprofezin, butacarb, butathiofos, butocarboxim, butonat, butoxycarboxim, cadusafos, calciumarsenat, calciumpolysulfid, camphechlor, carbanolat, carbaryl, carbofuran, carbondisulfid, carbontetrachlorid, carbophenothion, carbosulfan, cartap, cartaphydrochlorid, chlorantraniliprol, chlorbicyclen, chlorantran, chlorconon, chloridimeform, chloridimformhydrochlorid, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlorphosphor, chloroform, chloropicrin, chlorphoxim, chlorprazophos, chlorpyrifos, chlorpyrifos-methyl, chlorthiophos , chromafenozid, cinerin I, cinerin II, cineriner, cismethrin, cloethocarb, closantel, clothianidin, kobberacetoarsenit, kobberarsenat, kobbernaphthenat, kobberoleat, coumaphos, coumithoat, crotamiton, crotoxyphos, crufomate, kryolit, cyanofenphos, cyanophos, cyanthoat, cyantraniliprol, cyclothrin, cycloprothrin, cyfluthrin, cyhalothrin, cypermethrin, cyphenothrin, cyromazin, cythioat, DDT, decarbofuran, deltamethrin, demephion, demephion-O, demephion-S, demeton, demetonmethyl, demeton-O, demeton-O-methyl, demeton-S, demeton-S-methyl, demeton-S-methylsulfon, diafenthiuron, dialifos, diatoméjord, diazinon, dicapthon, dichlofenthion, dichlorvos, dicresyl, dicrotophos, dicyclanil, dieldrin, diflubenzuron, dilor, dimefluthrin, dimefox, dimethan, dimethoat, dimethrin, dimethylvinphos, dimetilan, dinx, dinxdiclexin, dinoprop, dinosam, dinotefuran, diofenolan, dioxabenzofos, dioxacarb, dioxathion, disulfoton, dithicrofos, d-limonen, DNOC, DNOC-ammonium, DNOC-kalium, DNOC-natrium, doramectin, ecdysteron, emamectin, emamectinbenzoat, EMPC, empenthrin, endosulfan, endothion, endrin, EPN, epofenonan, eprinomectin, esdepallethrin, esfenvalerat, etaphos, ethiofencarb, ethion, ethiprol, ethoat-methyl, ethoprophos, ethylformat, ethyl-DDD, ethylendibromid, ethylendichlorid, ethylenoxid, etofenprox, etrimfos, EXD, famphur, fenamiphos, fenazaflor, fenchlorphos, fenethacarb, fenfluthrin, fenitrothion, fenobucarb, fenoxacrim, fenoxycarb, fenpirithrin, fenpropathrin, fensulfothion, fenthion, fenthionethyl, fenvalerat, fipronil, flonicamid, flubendiamid, flucofuron, flucycloxuron, flucythrinat, flufenerim, flufenoxuron, flufenprox, flufiprol, fluvalinat, fonofos, formetanat, formetanathydrochlorid, formothion, formaparanat, formaparanathydrochlorid, fosmetilan, fospirat, fosthietan, furathiocarb, furethrin, gamma-cyhalothrin, gamma-HCH, halvanprox, halofenozid, HCH, HEOD, heptachlor, heptenophos, heterophos, hexaflumuron, HHDN, hydramethylnon, hydrogencyanid, hydropren, hyquincarb, imidacloprid, imiprothrin, indoxacarb, jodmethan, IPSP, isazofos, isobenzan, isocarbophos, isodrin, isofenphos, isofenphosmethyl, isoprocarb, isoprothiolan , isothioat, isoxathion, ivermectin, jasmolin I, jasmolin II, jodfenphos, juvenilhormon I, juvenilhormon II, juvenilhormon III, kelevan, kinopren, lambda-cyhalothrin, blyarsenat, lepimectin, leptofos, lindan, lirimfos, lufenuron, lythidathion, malathion, malonoben, mazidox, mecarbam, mecarphon, menazon, meperflutrin, mephosfolan, kviksølvchlorid, mesulfenfos, metaflumizon, methacrifos, methamidophos, methidathion, methiocarb, methocrotophos, methomyl, methopren, methoxychlor, methoxyfenozid, methylbromid, methylisothiocyanat, methylchloroform, methylenchlorid, metofluthrin, metolcarb, metoxadiazon, mevinphos, mexacarbat, milbemectin, milbemycinoxim, mipafox, mirex, molosultap, monocrotophos, monomehypo, monosultap, morphothion, moxidectin, naphthalofos, naled, naphthalen, nikotin, nifluridid, nitenpyram, nithiazin, nitrilacarb, novaluron, noviflumuron, omethoat, oxamyl, oxydemetonmethyl, oxydeprofos, oxydisulfoton, para-dichlorbenzen, parathion, parathionmethyl, penfluoron, pentachlorphenol, permethrin, phenkapton, phenothrin, phenthoat, phorat, phosalon, phosfolan, phosmet, phosnichlor, phosphamidon, phosphin, phoxim, phoximmethyl, pirimetaphos, pirimicarb, pirimiphosethyl, pirimiphosmethyl, kaliumarsenit, kaliumthiocyanat, pp'-DDT, prallethrin, precocen I, precocen II, precocen III, primidofos, profenofos, profluralin, promacyl, promecarb, propafos, propetamphos, propoxur, prothidathion, protothiofos, protothoat, protrifenbut, pyraclofos, pyrafluprol, pyrazophos, pyresmethrin, pyrethrin I, pyrethrin II, pyrethriner, pyridaben, pyridalyl, pyridaphenthion, pyrifluquinazon, pyrimidifen, pyrimitat, pyriprol, pyriproxyfen, quassia, quinalphos, quinalphos-methyl, quinothion, rafoxanid, resmethrin, rotenon, ryania, sabadilla, schradan, selamectin, silafluofen, silicagel, natriumarsenit, natriumfluorid, natriumhexafluorsilicat, natriumthiocyanat, sophamid, spinetoram, spinosad, spiromesifen, spirotetramat, sulcofuron, sulcofuron-natrium, sulfluramid, sulfotep, sulfoxaflor, sulfurylfluorid, sulprofos, taufluvalinat, tazimcarb, TDE, tebufenozid, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temefos, TEPP, terallethrin, terbufos, tetrachlorethan, tetrachlorvinphos, tetramethrin, tetramethylflutrin, theta-cypermethrin, thiacloprid, thiamethoxam, thicrofos, thiocarboxim, thiocyclam, thiocyclamoxalat, thiodicarb, thiofanox, thiometon, thiosultap, thiosultapdisodium, thiosultapmonosodium, thuringiensin, tolfenpyrad, tralomethrin, transflutrin, transpermethrin, triarathen, triazamat, triazophos, trichlorfon, trichlormetaphos-3, trichloronat, tripenofos, triflumuron, trimethacarb, tripren, vamidothion, vaniliprol, XMC, xylylcarb, zeta-cypermethrin, zolaprofos og eventuelle kombinationer deraf.
9. Pesticidformulering ifølge krav 5, hvor den anden pesticidforbindelse er en herbicidforbindelse, der er udvalgt fra gruppen, som består af: 4-CPA; 4-CPB; 4-CPP; 2,4-D; 3,4-DA; 2,4-DB; 3,4-DB; 2,4-DEB; 2,4-DEP; 3,4-DP; 2,3,6-TBA; 2,4,5-T; 2,4,5-TB; acetochlor, acifluorfen, aclonifen, acrolein, alachlor, allidochlor, alloxydim, allylalkohol, alorac, ametridion, ametryn, amibuzin, amicarbazon, amidosulfuron, aminocyclopyrachlor, aminopyralid, amiprofosmethyl, amitrol, ammoniumsulfamat, anilofos, anisuron, asulam, atraton, atrazin, azafenidin, azimsulfuron, aziprotryne, barban, BCPC, beflubutamid, benzazol, bencarbazon, benfluralin, benfuresat, bensulfuron, bensulid, bentazon, benzadox, benzfendizon, benzipram, benzobicyclon, benzofenap, benzofluor, benzoylprop, benzthiazuron, bicyclopyron, bifenox, bilanafos, bispyribac, borax, bromacil, bromobonil, brombutid, bromfenoxim, bromoxynil, brompyrazon, butachlor, butafenacil, butamifos, butenachlor, buthidazol, buthiuron, butralin, butroxydim, buturon, butylat, cacodylsyre, cafenstrol, calciumchlorat, calciumcyanamid, cambendichlor, carbasulam , carbetamid, carboxazolchlorprocarb, carfentrazon, CDEA, CEPC, chlomethoxyfen, chloramben, chloranocryl, chlorazifop, chlorazin, chlorbromuron, chlorbufam, chlorperon, chlorfenac, chlorfenprop, chlorfluorazol, chlorfluorol, chloridazon, chlorimuron, chlornitrofen, chloropon, chlorotoluron, chloroxuron, chloroxynil, chlorpropham, chlorsulfuron, chlorthal, chlorthiamid, cinidonethyl, cinmethylin, cinosulfuron, cisanilid, clethodim, cliodinat, clodinafop, clofop, clomazon, clomeprop, cloprop, cloproxydim, clopyralid, cloransulam, CMA, kobbersulfat, CPMF, CPPC, credazin, cresol, cumyluron, cyanatryn, cyanazin, cycloat, cyclosulfamuron, cycloxydim, cycluron, cyhalofop, cyperquat, cyprazin, cyprazol, cypromid, daimuron, dalapon, dazomet, delachlor, desmedipham, desmetryn, di-allat, dicamba, dichlobenil, dichloralurea, dichlormat, dichlorprop, dichlorprop-P, diclofop, diclosulam, diethamquat, diethatyl, difenopenten, difenoxuron, difenzoquat, diflufenican, diflufenzopyr, dimefuron, dimepiperat, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimexan, dimidazon, dinitramin, dinofen, dinoprop, dinosam, dinoseb, dinoterb, diphenamid, dipropetryn, diquat, disul, dithiopyr, diuron, DMPA, DNOC, DSMA, EBEP, eglinazin, endothal, epronaz, EPTC, erbon, esprocarb, ethalfluralin, ethametsulfuron, ethidimuron, ethiolat, etoxysulfuron, etoxyfen, etoxysulfuron, etinofen, etnipromid, etobenzanid, EXD, fenasulam, fenoprop, fenoxaprop, fenoxaprop-P, phenoxasulfon, fenteracol, fenthiaprop, fentrazamid, fenuron, ferrosulfat, flamprop, flamprop-M, flazasulfuron, florasulam, fluazifop, fluazifop-P, fluazolat, flucarbazon, flucetosulfuron, flufloralin, flufenacet, flufenican, flufenpyr, flumensulam, flumezin, flumiclorac, flumioxazin, flumipropyn, fluometuron, fluorodifen, fluoroglycofen, fluoromidin, fluoritrofen, fluothiuron, flupoxam, flupropacil, flupropanat, flupyrsulfuron, fluridon, fluorchloridon , fluoroxypyr, flurtamon, fluthiacet, fomesafen, foramsulfuron, fosamin, furyloxyfen, glufosinat, glufosinat-P, glyphosat, halosafen, halosulfuron, haloxydin, haloxyfop, haloxyfop-P, hexachloracetone, hexaflurat, hexazinon, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodobonil, iodomethan, iodosulfuron, ioxynil, ipazin, ipfencarbazon, iprymidam, isocarbamid, isocil, isomethiozin, isonoruron, isopolinat, isopropalin, isoproturon, isouron, isoxaben, isoxachlortol, isoxaflutol, isoxapyrifop, karbutilat, ketospiradox, lactofen, lenacil, linuron, MAA, MAMA, MCPA, MCPA-thioethyl, MCPB, mecoprop, mecoprop-P, medinoterb, mefenacet, mefluidid, mesoprazin, mesosulfuron, mesotrion, metam, metamifop, metamitron, metazachlor, metazosulfuron, metflurazon, methabenzthiazuron, methalpropalin, methazol, methiobencarb, methiozolin, methiuron, methometon, methoprotryn, methylbromid, methyl isothiocyanat, methyldymron, metobenzuron, metobromuron, metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, molinat, monalid, monisouron, monochloreddikesyre, monolinuron, monuron, morfamquat, MSMA, naproanilid, napropamid, naptalam, neburon, nicosulfuron, nipyraclofen, nitralin, nitrofen, nitrofluorfen, norflurazon, noruron, OCH, orbencarb, ortho-dichlorbenzen, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxapyrazon, oxasulfuron, oxaziclomefon, oxyfluorfen, parafluoron, paraquat, pebulat, pelargonsyre, pendimethalin, penoxsulam, pentachlorphenol, pentanochlor, pentoxazon, perfluidon, pethoxamid, phenisopham, phenmedipham, phenmedipham-ethyl, phenobenzuron, phenylkviksølvacetat, picloram, picolinafen, pinoxaden, piperophos, kaliumarsenit, kaliumazid, kaliumcyanat, pretilachlor, primisulfuron, procyazin, prodiamin, profluazol, profluralin, profoxydim, proglinazin, prometon, prometryn, propachlor, propanil, propaquizafop propazin, propam, propisochlor, propoxycarbazon, propyrisulfuron, propyzamid, prosulfalin, prosulfocarb, prosulfuron, proxan, prynachlor, pydanon, pyraclonil, pyraflufen, pyrasulfotol, pyrazolynat, pyrazosulfuron, pyrazoxyfen, pyribenzoxim, pyributicarb, pyriclor, pyridafol, pyridat, pyriftalid, pyrimobac, pyrimisulfan, pyrithiobac, pyroxasulfon, pyroxer ulam, quinclorac, quinmerac, quinoclamin, quinonamid, quizalofop, quizalofop-P, rhodethanil, rimsulfuron, saflufenacil, S-metolachlor, sebuthylazin, secbumeton, sethoxydim, siduron, simazin, simeton, simetryn, SMA, natriumarsenit, natriumazid, natriumchlorat, sulcotrion, sulfaturon, sulfentrazon, sulfometuron, sulfosulfuron, svovlsyre, sulglycapin, swep, TCA, tebutam, tebuthiuron, tefuryltrion, tembotrion, tepraloxydim, terbacil, terbucarb, terbuchlor, terbumeton, terbutylazin, terbutryn, tetrafluoron, thenylchlor, thiazafluoron, thiazopyr, thidiazimin, thidiazuron, thiencarbazonmethyl, thifensulfuron, thiobencarb, tiocarbazil, tioclorim, topramezon, tralkoxydim, triafamon, triallat, triasulfuron, triaziflam, tribenuron, tricamba, triclopyr, tridiphan, trietazin, trifloxysulfuron, trifluralin, triflusulfuron, trifop, trifopsim, trihydroxytriazin, trimeturon, tripropindan, tritactritosulfuron, vernolat og xylachlor.
10. Sammensætningen ifølge krav 2, hvor koncentrationen af forbindelsen er fra 0,1 til 1000 ppm.
11. Sammensætningen ifølge krav 2, hvor koncentrationen af forbindelsen er fra 1 til 500 ppm.
12. Fremgangsmåden ifølge krav 4, hvor den fungicide effektive mængde er fra 0,01 til 0,45 gram pr. kvadratmeter.
13. Forbindelsen ifølge krav 1, hvor forbindelsen med formel I er 5-fluor-4-imino-3-methyl-3,4-dihydropyrimidin-2(1/-/)-on.
14. Forbindelsen ifølge krav 1, hvor forbindelsen med formel I er 5-fluor-4-imino-3-(thiophen-2-ylmethyl)-3,4-dihydropyrimidin-2(1/-/)-on.
15. Forbindelse ifølge krav 1, hvor forbindelsen med formel I er 5-fluor-4-imino-3- (trideuteriomethyl)-l /-/-pyrimidin-2-on.
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US201161524506P | 2011-08-17 | 2011-08-17 | |
PCT/US2012/050930 WO2013025795A1 (en) | 2011-08-17 | 2012-08-15 | 5-fluoro-4-imino-3-(substituted)-3,4-dihydropyrimidin-2-(1h)-one derivatives |
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JP6128658B2 (ja) * | 2011-08-17 | 2017-05-17 | アダマ・マクテシム・リミテッド | 5−フルオロ−4−イミノ−3−(置換)−3,4−ジヒドロピリミジン−2−(1h)−オン誘導体 |
MX2015008441A (es) | 2012-12-28 | 2015-09-23 | Dow Agrosciences Llc | Derivados de n-(sustituido)-5-fluoro-4-imino-3-metil-2-oxo-3, 4-dihidropirimidin-1 (2h)-carboxilato. |
RU2015131149A (ru) | 2012-12-28 | 2017-02-03 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | N-(замещенные)-5-фтор-4-имино-3-метил-2-оксо-3,4-дигидропиримидин-1(2н)-карбоксамидные производные |
MX2015008565A (es) | 2012-12-31 | 2015-09-07 | Dow Agrosciences Llc | Derivados de 3-alquil-5-fluoro-4-sustituido-imino-3,4-dihidropirim idin-2(1h)-ona como fungicidas. |
CN103819412B (zh) * | 2013-12-11 | 2016-02-03 | 浙江先锋科技股份有限公司 | 一种5-氟胞嘧啶的制备方法 |
WO2015103142A1 (en) * | 2013-12-31 | 2015-07-09 | Dow Agrosciences Llc | 5-fluoro-4-imino-3-(alkyl/substituted alkyl)-1- (arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one and processes for their preparation |
UA124962C2 (uk) | 2013-12-31 | 2021-12-22 | Адама Махтешім Лтд. | Синергічні фунгіцидні суміші та композиції для контролю грибків |
MA41272A (fr) * | 2014-12-23 | 2017-10-31 | Adama Makhteshim Ltd | 5-fluoro-4-imino-3-(alkyle/alkyle substitué)-1-(arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one en tant que traitement des semences |
TWI774761B (zh) * | 2017-05-02 | 2022-08-21 | 美商科迪華農業科技有限責任公司 | 用於穀物中的真菌防治之協同性混合物 |
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2017
- 2017-04-07 JP JP2017076823A patent/JP2017125060A/ja not_active Withdrawn
- 2017-11-16 HR HRP20171776TT patent/HRP20171776T1/hr unknown
-
2018
- 2018-12-21 JP JP2018239307A patent/JP6901462B2/ja active Active
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