DK2571887T3 - Fremgangsmåde til fremstilling af dithiin-tetracarboxy-diimider - Google Patents
Fremgangsmåde til fremstilling af dithiin-tetracarboxy-diimider Download PDFInfo
- Publication number
- DK2571887T3 DK2571887T3 DK11719280.7T DK11719280T DK2571887T3 DK 2571887 T3 DK2571887 T3 DK 2571887T3 DK 11719280 T DK11719280 T DK 11719280T DK 2571887 T3 DK2571887 T3 DK 2571887T3
- Authority
- DK
- Denmark
- Prior art keywords
- sulphide
- alkyl
- hydrogen
- halogen
- formula
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
- C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
- C07D207/456—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
- C07D495/14—Ortho-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Indole Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Pyrrole Compounds (AREA)
- Thiazole And Isothizaole Compounds (AREA)
Claims (4)
1. Fremgangsmåde til fremstilling af dithiin-tetracarboxy- diimider med den almene formel (I)
<D hvor R1 og R2 er ens eller forskellige og står for hydrogen, for Ci-Cs-alkyl, i givet fald substitueret en eller flere gange med halogen, -OR3, -COR4, for C3-C7-cycloalkyl, i givet fald substitueret en eller flere gange med halogen, Ci-C4_alkyl eller Ci-C4-halogenalkyl, for aryl eller aryl- (Ci-C4-alkyl) , hver især i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl, Ci-C^-halogenalkyl, -COR4 eller sulfony1amino, R3 står for hydrogen, Ci-C4-alkyl, Ci-C4-alkylcarbonyl eller for aryl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-akyl eller Ci-C4-halogenalkyl, R4 står for hydroxy, Ci-C4-alkyl eller Ci-C4~alkoxy, kendetegnet ved, at man omsætter (A) dichlormaleinsyreimider med formel (VI)
(VI) hvor R står for R1 eller R2, med et uorganisk sulfid eller hydrogensulfid i et opløsningsmiddel eller en opløsningsmiddelblanding i et molforhold mellem 0,2 og 0,95 mol af sulfid eller hydrogensulfid pr. mol dichlormaleinsyreimid med formel (VI) og opvarmer (B) reaktionsproduktet, som består af en blanding af forbindelser med formel (I) og polymere forbindelser med den almene formel (VII),
<VIT) hvor R uafhængigt af hinanden står for R1 eller R2, n står for et helt tal mellem 1 og 50, i et fortyndingsmiddel.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at sulfidet eller hydrogensulfidet er udvalgt af gruppen bestående af lithiumsulfid, natriumsulfid, natriumhydrogensulfid, kaliumsulfid, calciumsulfid, calciumhydrogensulfid, magnesiumsulfid eller ammoniumsulfid eller blandinger af disse eller hydrater af disse.
3. Fremgangsmåde ifølge krav 1, kendetegnet ved, at opløsningsmidlet anvendes fra gruppen af amider, såsom formamid, N,N-dimethyl-formamid, N,N-dimethyl-acetamid, N-methyl-pyrrolidon; alkoholer såsom propanol, isobutanol, pentanol, ethylenglykol; estere såsom eddikesyremethylester, eddikesyreethylester, butylacetat; nitriler såsom acetonitril, butyronitril; ketoner såsom pinakolon, methyl-isobutylketon; dimethylsulfoxid eller sulfolan eller vand eller blandinger af disse.
4. Polymere forbindelser med formel (VII)
(Vil) hvor R uafhængigt af hinanden står for R1 eller R2, R1 og R2 er ens eller forskellige og står for hydrogen, for Ci-Cs-alkyl, i givet fald substitueret en eller flere gange med halogen, -OR3, -COR4, for C3-C7-cycloalkyl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-akyl eller Ci-C4~halogenalkyl, for aryl eller aryl-(Ci-C4-alkyl), hver især i givet fald substitueret en eller flere gange med halogen, Ci-C^-alkyl, Ci-C^-halogenalkyl, -COR4 eller sulfonylamino, R3 står for hydrogen, Ci-C4-alkyl, Ci-C4-alkylcarbonyl eller for aryl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl eller Ci-C4-halogenalkyl, R4 står for hydroxy, Ci-C4-alkyl eller Ci-C4-alkoxy, n står for et helt tal mellem 1 og 50.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10163519 | 2010-05-21 | ||
| US34835510P | 2010-05-26 | 2010-05-26 | |
| PCT/EP2011/057829 WO2011144550A1 (de) | 2010-05-21 | 2011-05-16 | Verfahren zur herstellung von dithiin-tetracarboxy-diimiden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2571887T3 true DK2571887T3 (da) | 2014-11-24 |
Family
ID=42634835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK11719280.7T DK2571887T3 (da) | 2010-05-21 | 2011-05-16 | Fremgangsmåde til fremstilling af dithiin-tetracarboxy-diimider |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8729275B2 (da) |
| EP (1) | EP2571887B1 (da) |
| JP (1) | JP5816268B2 (da) |
| KR (1) | KR20130112719A (da) |
| CN (1) | CN102939294B (da) |
| BR (1) | BR112012029626A2 (da) |
| DK (1) | DK2571887T3 (da) |
| ES (1) | ES2518118T3 (da) |
| IL (1) | IL223145A (da) |
| MX (1) | MX2012013539A (da) |
| PL (1) | PL2571887T3 (da) |
| RU (1) | RU2574393C9 (da) |
| WO (1) | WO2011144550A1 (da) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK2558472T3 (da) * | 2010-04-14 | 2014-10-27 | Bayer Cropscience Ag | Fremgangsmåde til fremstilling af dithiin-tetracarboxy-diimider |
| DK2558473T3 (da) | 2010-04-14 | 2016-12-19 | Bayer Ip Gmbh | Fremgangsmåde til fremstilling af dithiin-tetracarboximider |
| EP2611814B1 (de) | 2010-09-03 | 2014-09-24 | Bayer Intellectual Property GmbH | Verfahren zur herstellung von dithiin-tetracarboximiden |
| EP2641908A1 (de) * | 2012-03-23 | 2013-09-25 | Bayer CropScience AG | Verfahren zur Herstellung von Dithiin-tetracarboximiden |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3364229A (en) * | 1964-01-30 | 1968-01-16 | Shell Oil Co | 1, 4 dithiin-2, 3, 5, 6-tetracarboximides and process for their preparation |
| SU649292A3 (ru) * | 1974-05-22 | 1979-02-25 | Юниройял Инк | Состав дл регулировани роста растений |
| US4067879A (en) * | 1975-10-23 | 1978-01-10 | E. I. Du Pont De Nemours And Company | 1,4-Dithiino[2,3-c; 6,5-c']diisothiazole and related compounds |
| CA1150284A (en) * | 1980-12-02 | 1983-07-19 | Allan K.S. Tsai | Method of making certain 2,3-dihydro-1,4-dithiins |
| PL143804B2 (en) | 1985-10-15 | 1988-03-31 | Univ Lodzki | Process for preparing novel derivatives of 2,6-diphenyl-2,3,6,7-tetrahydro-1h,5h-1,4-dithiin-/2,3-c:5,6-c/-diprolo-1,3,5,7-tetraon substituted in phenyl ring |
| JP3530702B2 (ja) | 1997-03-06 | 2004-05-24 | 京セラミタ株式会社 | ジチオマレイン酸イミド誘導体を用いた電子写真感光体 |
| CN100554251C (zh) * | 2005-07-12 | 2009-10-28 | 中国科学院化学研究所 | 一种马来酰亚胺衍生物及其制备方法 |
| US8865759B2 (en) | 2008-10-15 | 2014-10-21 | Bayer Intellectual Property Gmbh | Use of dithiine-tetracarboximides for controlling phytopathogenic fungi |
-
2011
- 2011-05-16 WO PCT/EP2011/057829 patent/WO2011144550A1/de active Application Filing
- 2011-05-16 MX MX2012013539A patent/MX2012013539A/es active IP Right Grant
- 2011-05-16 DK DK11719280.7T patent/DK2571887T3/da active
- 2011-05-16 CN CN201180030514.6A patent/CN102939294B/zh not_active Expired - Fee Related
- 2011-05-16 BR BR112012029626A patent/BR112012029626A2/pt not_active Application Discontinuation
- 2011-05-16 RU RU2012155464/04A patent/RU2574393C9/ru not_active IP Right Cessation
- 2011-05-16 PL PL11719280T patent/PL2571887T3/pl unknown
- 2011-05-16 EP EP11719280.7A patent/EP2571887B1/de not_active Not-in-force
- 2011-05-16 KR KR1020127033251A patent/KR20130112719A/ko not_active Application Discontinuation
- 2011-05-16 JP JP2013510576A patent/JP5816268B2/ja not_active Expired - Fee Related
- 2011-05-16 ES ES11719280.7T patent/ES2518118T3/es active Active
- 2011-05-20 US US13/112,680 patent/US8729275B2/en not_active Expired - Fee Related
-
2012
- 2012-11-20 IL IL223145A patent/IL223145A/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130112719A (ko) | 2013-10-14 |
| PL2571887T3 (pl) | 2015-01-30 |
| CN102939294A (zh) | 2013-02-20 |
| IL223145A (en) | 2016-05-31 |
| US8729275B2 (en) | 2014-05-20 |
| EP2571887B1 (de) | 2014-08-20 |
| US20120022270A1 (en) | 2012-01-26 |
| BR112012029626A2 (pt) | 2015-10-13 |
| EP2571887A1 (de) | 2013-03-27 |
| MX2012013539A (es) | 2013-01-24 |
| RU2574393C2 (ru) | 2016-02-10 |
| CN102939294B (zh) | 2015-09-02 |
| RU2574393C9 (ru) | 2016-10-10 |
| RU2012155464A (ru) | 2014-06-27 |
| ES2518118T3 (es) | 2014-11-04 |
| JP5816268B2 (ja) | 2015-11-18 |
| IL223145A0 (en) | 2013-02-03 |
| JP2013527180A (ja) | 2013-06-27 |
| WO2011144550A1 (de) | 2011-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR20130065663A (ko) | 디티인 테트라카복시디이미드의 제조방법 | |
| DK2571887T3 (da) | Fremgangsmåde til fremstilling af dithiin-tetracarboxy-diimider | |
| KR101746023B1 (ko) | 디티인 테트라카복시-디이미드의 제조방법 | |
| KR101863621B1 (ko) | 디티인 테트라카복시미드의 제조방법 | |
| ES2471240T3 (es) | Procedimiento de preparación de derivados de tioalquilamina | |
| TW201321387A (zh) | 製備二硫雜己環并－四甲醯胺類之方法 | |
| MX2014004096A (es) | Procedimiento de preparción de ditiin-tetracarboximidas. | |
| DK2828268T3 (da) | Fremgangsmåde til fremstilling af dithiin-tetracarboximider | |
| JP2021524461A (ja) | 置換ｎ−アリールピラゾールの製造方法 |