DK171799B1 - Fremgangsmåde til fremstilling af fedtsyreestere eller til omlejring af fedtstoffer og vegetabilske olier - Google Patents
Fremgangsmåde til fremstilling af fedtsyreestere eller til omlejring af fedtstoffer og vegetabilske olier Download PDFInfo
- Publication number
- DK171799B1 DK171799B1 DK714888A DK714888A DK171799B1 DK 171799 B1 DK171799 B1 DK 171799B1 DK 714888 A DK714888 A DK 714888A DK 714888 A DK714888 A DK 714888A DK 171799 B1 DK171799 B1 DK 171799B1
- Authority
- DK
- Denmark
- Prior art keywords
- lipase
- fatty acid
- catalyst
- water
- solution
- Prior art date
Links
- -1 fatty acid esters Chemical class 0.000 title claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 15
- 239000000194 fatty acid Substances 0.000 title claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 15
- 239000003925 fat Substances 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 title claims description 5
- 239000008158 vegetable oil Substances 0.000 title claims description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 49
- 108090001060 Lipase Proteins 0.000 claims abstract description 47
- 102000004882 Lipase Human genes 0.000 claims abstract description 47
- 239000004367 Lipase Substances 0.000 claims abstract description 44
- 235000019421 lipase Nutrition 0.000 claims abstract description 44
- 239000011148 porous material Substances 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 27
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 19
- 238000001179 sorption measurement Methods 0.000 claims abstract description 14
- 239000000376 reactant Substances 0.000 claims abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 8
- 239000007791 liquid phase Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 29
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- 239000012876 carrier material Substances 0.000 claims description 12
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- 235000019198 oils Nutrition 0.000 claims description 9
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- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 235000021588 free fatty acids Nutrition 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
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- 238000002360 preparation method Methods 0.000 abstract description 6
- 125000000373 fatty alcohol group Chemical group 0.000 abstract 1
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- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 41
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- 108090000790 Enzymes Proteins 0.000 description 26
- 102000004190 Enzymes Human genes 0.000 description 26
- 239000005639 Lauric acid Substances 0.000 description 20
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- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 12
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- 235000019486 Sunflower oil Nutrition 0.000 description 10
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 10
- 239000003208 petroleum Substances 0.000 description 10
- 229920006395 saturated elastomer Polymers 0.000 description 10
- 239000012064 sodium phosphate buffer Substances 0.000 description 10
- 239000002600 sunflower oil Substances 0.000 description 10
- 108010048733 Lipozyme Proteins 0.000 description 9
- 241000235403 Rhizomucor miehei Species 0.000 description 9
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 9
- 235000019626 lipase activity Nutrition 0.000 description 9
- FCCDDURTIIUXBY-UHFFFAOYSA-N lipoamide Chemical compound NC(=O)CCCCC1CCSS1 FCCDDURTIIUXBY-UHFFFAOYSA-N 0.000 description 9
- 238000011068 loading method Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 8
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- 239000008363 phosphate buffer Substances 0.000 description 8
- 229920002223 polystyrene Polymers 0.000 description 8
- 229940049964 oleate Drugs 0.000 description 7
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- 229910002027 silica gel Inorganic materials 0.000 description 7
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- 239000000839 emulsion Substances 0.000 description 4
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
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- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 3
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- 239000011819 refractory material Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241000235545 Rhizopus niveus Species 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
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- 238000009826 distribution Methods 0.000 description 2
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- 239000008384 inner phase Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- QTDSLDJPJJBBLE-PFONDFGASA-N octyl (z)-octadec-9-enoate Chemical compound CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC QTDSLDJPJJBBLE-PFONDFGASA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
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- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
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- 241000589516 Pseudomonas Species 0.000 description 1
- 241000235527 Rhizopus Species 0.000 description 1
- 101000966371 Rhizopus niveus Lipase Proteins 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 241000223257 Thermomyces Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
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- 238000004868 gas analysis Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000012052 hydrophilic carrier Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000008385 outer phase Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
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- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000012289 standard assay Methods 0.000 description 1
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- 239000008107 starch Substances 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
- C12P7/6436—Fatty acid esters
- C12P7/6445—Glycerides
- C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
- C12P7/6436—Fatty acid esters
- C12P7/6445—Glycerides
- C12P7/6454—Glycerides by esterification
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Genetics & Genomics (AREA)
- Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8729890 | 1987-12-22 | ||
| GB878729890A GB8729890D0 (en) | 1987-12-22 | 1987-12-22 | Improvements in & relating to fat processes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DK714888D0 DK714888D0 (da) | 1988-12-21 |
| DK714888A DK714888A (da) | 1989-06-23 |
| DK171799B1 true DK171799B1 (da) | 1997-06-02 |
Family
ID=10628879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK714888A DK171799B1 (da) | 1987-12-22 | 1988-12-21 | Fremgangsmåde til fremstilling af fedtsyreestere eller til omlejring af fedtstoffer og vegetabilske olier |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0322213B1 (zh) |
| JP (1) | JPH02138986A (zh) |
| AT (1) | ATE104354T1 (zh) |
| AU (1) | AU614563B2 (zh) |
| CA (1) | CA1333370C (zh) |
| DE (1) | DE3889088T2 (zh) |
| DK (1) | DK171799B1 (zh) |
| ES (1) | ES2050715T3 (zh) |
| GB (1) | GB8729890D0 (zh) |
| ZA (1) | ZA889591B (zh) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| DK306189D0 (da) * | 1989-06-21 | 1989-06-21 | Novo Nordisk As | Immobiliseret lipasepraeparat og anvendelse deraf til estersyntese |
| EP0407959A3 (en) * | 1989-07-11 | 1992-01-02 | Lion Corporation | Process for producing polyol fatty acid monoesters |
| CA2027649C (en) * | 1989-10-20 | 1996-01-16 | John Anthony Bosley | Supported enzyme |
| US5232843A (en) * | 1989-10-20 | 1993-08-03 | Unilever Patent Holdings Bv | Preparation of immobilized lipase by adsorption of lipase and a non-lipase protein on a support |
| WO1991014784A1 (en) * | 1990-03-23 | 1991-10-03 | Novo Nordisk A/S | A process for increasing the amount of triglyceride of a fat or oil |
| DK95490D0 (da) * | 1990-04-18 | 1990-04-18 | Novo Nordisk As | Fremgangsmaade til fremstilling af triglycerid og triglyceridsammensaetning |
| DK0492497T3 (da) * | 1990-12-24 | 1997-01-06 | Hoechst Ag | Fremgangsmåde til acylering af alkoholer med en immobiliseret pseudomonas-lipase |
| EP0506159A1 (en) | 1991-03-19 | 1992-09-30 | Unichema Chemie B.V. | Esterification process |
| CA2064676A1 (en) * | 1991-04-02 | 1992-10-03 | Manfred Schneider | Immobilized biocatalyst, its preparation and use for ester synthesis in a column reactor |
| US5445955A (en) * | 1992-05-25 | 1995-08-29 | The Nisshin Oil Mills, Ltd. | Immobilization of lipase on a polymer carrier containing epoxy and tertiary amino groups |
| GB9211708D0 (en) † | 1992-06-03 | 1992-07-15 | Unilever Plc | Cosmetic composition |
| DE69407038T2 (de) * | 1993-05-20 | 1998-04-16 | Loders Croklaan Bv | Verfahren zur herstellung immobilisierter lipasen |
| JP2668187B2 (ja) * | 1993-09-17 | 1997-10-27 | 日清製油株式会社 | リパーゼ粉末を用いたエステル交換法 |
| JP2001511354A (ja) | 1997-07-25 | 2001-08-14 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 第三級パーエステルの製造法 |
| ES2147121B1 (es) * | 1998-04-03 | 2001-04-16 | Vita Invest Sa | Nuevos biocatalizadores de lipasas inmovilizadas. |
| BR0302166A (pt) | 2002-07-02 | 2004-09-08 | Kao Corp | Processo para preparação de enzima imobilizada |
| MY142014A (en) | 2004-04-08 | 2010-08-16 | Nisshin Oillio Group Ltd | A lipase powder, methods for producing the same and use thereof |
| JP4394598B2 (ja) | 2004-08-24 | 2010-01-06 | 日清オイリオグループ株式会社 | リパーゼ粉末組成物及びそれを用いたエステル化物の製造方法 |
| JP4478540B2 (ja) | 2004-09-16 | 2010-06-09 | 日清オイリオグループ株式会社 | リパーゼ粉末、その製造方法及びその使用 |
| JP5048957B2 (ja) * | 2005-03-04 | 2012-10-17 | 国立大学法人静岡大学 | エステル合成触媒及びその製造方法並びに該触媒を用いたバイオ燃料の製造方法 |
| RU2412245C2 (ru) * | 2005-06-09 | 2011-02-20 | Дзе Ниссин Ойллио Груп, Лтд. | Липазные порошковые составы |
| JP4917349B2 (ja) | 2006-05-11 | 2012-04-18 | 日清オイリオグループ株式会社 | リパーゼ活性の回復方法 |
| TWI438279B (zh) | 2007-03-16 | 2014-05-21 | Nisshin Oillio Group Ltd | 脂肪酶粉末製劑，其製造方法及使用 |
| US20100216209A1 (en) * | 2007-07-31 | 2010-08-26 | Eiji Iwaoka | Immobilized lipase and method for producing the same |
| JP5284663B2 (ja) * | 2008-03-19 | 2013-09-11 | 株式会社Ａｄｅｋａ | 油脂のエステル交換反応方法 |
| WO2010056200A1 (en) * | 2008-11-17 | 2010-05-20 | Agency For Science, Technology And Research | Hydrophobic magnetic particles |
| JP5586855B2 (ja) * | 2009-02-12 | 2014-09-10 | 花王株式会社 | モノアシルグリセロール高含有油脂の製造方法 |
| JP5494913B2 (ja) | 2009-03-27 | 2014-05-21 | 日清オイリオグループ株式会社 | リパーゼ粉末組成物の製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56127087A (en) * | 1980-03-08 | 1981-10-05 | Fuji Oil Co Ltd | Enzymatic agent and its preparation |
| JPS5920357A (ja) * | 1982-07-26 | 1984-02-02 | Tokiwa Shokubutsu Kagaku Kenkyusho:Kk | クチナシ色素転換物の製造方法 |
| JPS6078586A (ja) * | 1983-10-05 | 1985-05-04 | Lion Corp | 液体油脂の製造方法 |
| DE3672270D1 (de) * | 1985-03-06 | 1990-08-02 | Yoshikawa Oil & Fat | Verfahren zur herstellung von fettsaeureestern. |
| US4629742A (en) * | 1986-01-27 | 1986-12-16 | Akzo America Inc. | Hydrolysis of fats |
| JPS62239982A (ja) * | 1986-04-10 | 1987-10-20 | Nishihara Environ Sanit Res Corp | 廃水による酵母の培養方法 |
| JPS6485089A (en) * | 1987-09-26 | 1989-03-30 | Japan Res & Dev Ass | Synthesis of ester using lipase |
| DE3854761T2 (de) * | 1987-10-13 | 1996-04-25 | Lubrizol Corp | Verfahren zur herstellung von hochreiner ölsäure durch hydrolyse von sonnenblumenkernöl. |
-
1987
- 1987-12-22 GB GB878729890A patent/GB8729890D0/en active Pending
-
1988
- 1988-12-19 AU AU27034/88A patent/AU614563B2/en not_active Expired
- 1988-12-21 DK DK714888A patent/DK171799B1/da not_active IP Right Cessation
- 1988-12-21 ES ES88312116T patent/ES2050715T3/es not_active Expired - Lifetime
- 1988-12-21 DE DE3889088T patent/DE3889088T2/de not_active Expired - Lifetime
- 1988-12-21 EP EP88312116A patent/EP0322213B1/en not_active Expired - Lifetime
- 1988-12-21 CA CA000586659A patent/CA1333370C/en not_active Expired - Lifetime
- 1988-12-21 JP JP63320747A patent/JPH02138986A/ja active Granted
- 1988-12-21 AT AT88312116T patent/ATE104354T1/de not_active IP Right Cessation
- 1988-12-22 ZA ZA889591A patent/ZA889591B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0458958B2 (zh) | 1992-09-18 |
| ATE104354T1 (de) | 1994-04-15 |
| DK714888A (da) | 1989-06-23 |
| DE3889088T2 (de) | 1994-07-28 |
| ES2050715T3 (es) | 1994-06-01 |
| EP0322213A3 (en) | 1990-05-30 |
| AU614563B2 (en) | 1991-09-05 |
| ZA889591B (en) | 1990-08-29 |
| AU2703488A (en) | 1989-06-22 |
| DK714888D0 (da) | 1988-12-21 |
| DE3889088D1 (de) | 1994-05-19 |
| CA1333370C (en) | 1994-12-06 |
| JPH02138986A (ja) | 1990-05-28 |
| EP0322213B1 (en) | 1994-04-13 |
| GB8729890D0 (en) | 1988-02-03 |
| EP0322213A2 (en) | 1989-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B1 | Patent granted (law 1993) | ||
| PUP | Patent expired |