DK1590081T3 - Fremgangsmåde til fremstilling af ikke-pyrophore kobber-aluminakatalysatorer - Google Patents

Fremgangsmåde til fremstilling af ikke-pyrophore kobber-aluminakatalysatorer Download PDF

Info

Publication number
DK1590081T3
DK1590081T3 DK03770758.5T DK03770758T DK1590081T3 DK 1590081 T3 DK1590081 T3 DK 1590081T3 DK 03770758 T DK03770758 T DK 03770758T DK 1590081 T3 DK1590081 T3 DK 1590081T3
Authority
DK
Denmark
Prior art keywords
catalyst
copper
gas
catalysts
temperature
Prior art date
Application number
DK03770758.5T
Other languages
English (en)
Inventor
Oleg M Ilinich
Wolfgang F Ruettinger
Ronald T Mentz
Robert J Farrauto
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Application granted granted Critical
Publication of DK1590081T3 publication Critical patent/DK1590081T3/da

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0675—Removal of sulfur
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Claims (9)

1. Fremgangsmåde til fremstilling afen ikke-pyrophor katalysator, omfattende: dannelse afen blanding afen kobberprecursor og en aluminaprecursor; coekstrudere blandingen; tørre coekstrudatet; og calcinere det tørrede 5 coekstrudat ved en temperatur på mindst 600°C for at danne den ikke-pyrophore katalysator; hvor den ikke-pyrophore katalysator omfatter ca. 2 til 20 vægtprocent af en kobberkomponent, og mindst 50 vægtprocent af kobberkomponenten er i form af et kobberoxid, aluminiumoxid-spinel.
2. Fremgangsmåden ifølge krav 1, hvor ikke-pyrophor katalysatoren omfatter mindst 80 vægtprocent alumina.
3. Fremgangsmåden ifølge krav 1, hvor calcineringstemperaturen er mindst 650°C. 15
4. Fremgangsmåden ifølge krav 1, hvor dannelsen af blandingen omfatter blanding af en pasta af et vand-opløseligt kobbersalt og hydreret alumina i en vandig opløsning.
5. Fremgangsmåden ifølge krav 1, hvor fremgangsmåden yderligere omfatter aktivering af ikke-pyrophor katalysatoren med en reducerende gasstrøm omfattende en reduktionsmiddelkomponent og en inert gas ved en temperatur på ca. 150 til 300°C.
6. Fremgangsmåden ifølge krav 5, hvor reduktionsmiddelkomponenten omfatter hydrogen, carbonmonoxid eller en kombination deraf.
7. Fremgangsmåden ifølge krav 5, hvor den reducerende gasstrøm er i det væsentlige tør. 30
8. Fremgangsmåden ifølge krav 5, hvor fremgangsmåden yderligere omfatter passivering af ikke-pyrophor katalysatoren med en gasstrøm omfattende oxygen og en inert gas ved en temperatur under 50°C.
9. Fremgangsmåden ifølge krav 8, hvor gasstrømmen omfattende oxygen og den inerte gas er i det væsentlige tør.
DK03770758.5T 2002-10-28 2003-10-14 Fremgangsmåde til fremstilling af ikke-pyrophore kobber-aluminakatalysatorer DK1590081T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/281,635 US6903050B2 (en) 2002-10-28 2002-10-28 Method of preparation of non-pyrophoric copper-alumina catalysts
PCT/US2003/032499 WO2004039484A2 (en) 2002-10-28 2003-10-14 Method of preparation of non-pyrophoric copper-alumina catalysts

Publications (1)

Publication Number Publication Date
DK1590081T3 true DK1590081T3 (da) 2016-05-30

Family

ID=32107198

Family Applications (1)

Application Number Title Priority Date Filing Date
DK03770758.5T DK1590081T3 (da) 2002-10-28 2003-10-14 Fremgangsmåde til fremstilling af ikke-pyrophore kobber-aluminakatalysatorer

Country Status (7)

Country Link
US (1) US6903050B2 (da)
EP (1) EP1590081B1 (da)
JP (1) JP2006503703A (da)
CN (1) CN1717276A (da)
AU (1) AU2003279274A1 (da)
DK (1) DK1590081T3 (da)
WO (1) WO2004039484A2 (da)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040082669A1 (en) * 2002-10-28 2004-04-29 Ruettinger Wolfgang Friedrich Operating conditions for copper-based water-gas shift catalysts
JP3951127B2 (ja) * 2003-02-28 2007-08-01 国立大学法人静岡大学 ジメチルエーテル水蒸気改質触媒およびその製造方法
US7704486B2 (en) * 2005-02-16 2010-04-27 Basf Corporation Precious metal water-gas shift catalyst with oxide support modified with rare earth elements
US8863221B2 (en) * 2006-03-07 2014-10-14 Samsung Electronics Co., Ltd. Method and system for integrating content and services among multiple networks
JP4772561B2 (ja) * 2006-03-31 2011-09-14 株式会社東芝 メタノール改質触媒、シフト触媒、メタノール改質触媒の製造方法およびシフト触媒の製造方法
KR20090086106A (ko) * 2006-12-01 2009-08-10 바스프 에스이 흡착 조성물 및 스트림으로부터 ｃｏ의 제거 방법
WO2010005127A2 (en) * 2008-07-09 2010-01-14 Postech Academy-Industry Foundation Heterogeneous copper nanocatalyst and manufacturing methods thereof
JP5225026B2 (ja) * 2008-10-31 2013-07-03 株式会社ダイセル 銅触媒の再生方法
US8828903B2 (en) * 2008-11-10 2014-09-09 Basf Corporation Copper catalyst for dehydrogenation application
CN101977840A (zh) * 2009-01-19 2011-02-16 松下电器产业株式会社 氢生成装置、燃料电池系统及氢生成装置的停止方法
CN103433055B (zh) * 2013-09-10 2015-01-28 南京大学 一种脱氧催化剂的制备方法及利用其进行脱氧的方法
RU2019131267A (ru) * 2017-03-06 2021-04-07 Басф Корпорейшн Катализатор, объединяющий металл платиновой группы со шпинелью на основе меди-оксида алюминия
CN107754815B (zh) * 2017-10-30 2020-05-01 福州大学 一种铜/四氧化三铁水煤气变换催化剂的再生方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1131631A (en) 1965-01-05 1968-10-23 Ici Ltd Catalysts of high activity at low temperature
FR2054524A1 (da) 1969-07-25 1971-04-23 Inst Francais Du Petrole
US4131616A (en) * 1974-06-24 1978-12-26 E. I. Du Pont De Nemours And Company Methanation catalyst
US4446249A (en) * 1979-11-05 1984-05-01 The B. F. Goodrich Company Copper catalyst compositions for fluid-bed oxyhydrochlorination of ethylene
NO146046L (da) 1980-03-28
NO154486C (no) * 1984-04-12 1986-10-01 Norsk Hydro As Katalysator og dens anvendelse for spalting av metanol.
GB8610196D0 (en) 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US5849966A (en) * 1991-05-14 1998-12-15 Exxon Chemical Patents Inc. Catalyst and process for the isomerization of olefins in the presence of reactive impurities
EP2650048A3 (en) * 1996-03-21 2014-01-08 BASF Catalysts LLC Non-chrome catalysts for Cu/Cr catalyst applications
DE19809418A1 (de) * 1998-03-05 1999-09-09 Basf Ag Verfahren zur Hydrierung von Carbonylverbindungen
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
US6417136B2 (en) * 1999-09-17 2002-07-09 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US20020061277A1 (en) 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
US6664207B2 (en) * 2001-09-26 2003-12-16 Conocophillips Company Catalyst for converting carbon dioxide to oxygenates and processes therefor and therewith

Also Published As

Publication number Publication date
US6903050B2 (en) 2005-06-07
WO2004039484A2 (en) 2004-05-13
AU2003279274A8 (en) 2004-05-25
EP1590081B1 (en) 2016-02-17
EP1590081A2 (en) 2005-11-02
US20040082471A1 (en) 2004-04-29
AU2003279274A1 (en) 2004-05-25
CN1717276A (zh) 2006-01-04
EP1590081A4 (en) 2012-01-25
WO2004039484A3 (en) 2004-07-15
JP2006503703A (ja) 2006-02-02

Similar Documents

Publication Publication Date Title
DK1590081T3 (da) Fremgangsmåde til fremstilling af ikke-pyrophore kobber-aluminakatalysatorer
US20020061277A1 (en) Non-pyrophoric water-gas shift reaction catalysts
JP2004522672A (ja) 水性ガス転換反応触媒によるメタン化活性の抑制
CA2680431A1 (en) Metal-doped nickel oxides as catalysts for the methanation of carbon monoxide
US6790432B2 (en) Suppression of methanation activity of platinum group metal water-gas shift catalysts
JP4689508B2 (ja) 一酸化炭素メタネーション用触媒および該触媒を用いた一酸化炭素のメタネーション方法
TWI294413B (en) Method for converting co and hydrogen into methane and water
JP4864688B2 (ja) 一酸化炭素メタネーション用触媒および該触媒を用いた一酸化炭素のメタネーション方法
Zhao et al. Catalytic combustion of lean methane over MnCo2O4/SiC catalysts: Enhanced activity and sulfur resistance
JPH022881A (ja) ＣｕＯ／ＺｎＯ／Ａｌ↓２Ｏ↓３触媒の活性法
JP4195786B2 (ja) 改質油ガスから一酸化炭素を除去するための触媒およびプロセス
CN104645970B (zh) 可用于酸气变换反应的催化剂材料
EP1485202B1 (en) Process for the preferential oxidation of carbon monoxide using a catalyst containing ruthenium and zinc oxide
WO2003051493A2 (en) Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation
JP2003340280A (ja) Ｃｏ選択酸化触媒及びその製造方法並びにｃｏ選択酸化触媒を用いた熱交換型反応器及びその使用方法
US20040082669A1 (en) Operating conditions for copper-based water-gas shift catalysts
Messaoudi et al. Syngas production via methane dry reforming over La-Ni-Co and La-Ni-Cu catalysts with spinel and perovskite structures
US20040156770A1 (en) Process for catalytic, selective oxidation of carbon monoxide in gaseous mixtures containing excess hydrogen, a catalyst and a process for its preparation
JP4083556B2 (ja) 改質ガス中の一酸化炭素の選択酸化触媒
Mileva et al. NANOSIZED MESOPOROUS CuO-CeO 2-TiO 2 AND CuO-ZrO 2-TiO 2 COMPOSITES AS CATALYSTS FOR METHANOL DECOMPOSITION: EFFECT OF MODIFICATION PROCEDURE.
JP2005131471A (ja) Ｃｏ変成触媒およびその製造方法
JP2024500507A (ja) メタン改質用触媒及びその製造方法
CN112705191A (zh) 一种制备一氧化碳的催化剂及其制备方法和应用