DK1415700T3 - Fremgangsmåde og apparat til fjernelse af kviksølv i røggas - Google Patents

Fremgangsmåde og apparat til fjernelse af kviksølv i røggas

Info

Publication number
DK1415700T3
DK1415700T3 DK02758810.2T DK02758810T DK1415700T3 DK 1415700 T3 DK1415700 T3 DK 1415700T3 DK 02758810 T DK02758810 T DK 02758810T DK 1415700 T3 DK1415700 T3 DK 1415700T3
Authority
DK
Denmark
Prior art keywords
flue gas
removing mercury
mercury
flue
gas
Prior art date
Application number
DK02758810.2T
Other languages
English (en)
Inventor
Shintaro Honjo
Toru Takashina
Kozo Iida
Tetsuya Imai
Koichiro Iwashita
Tatsuto Nagayasu
Original Assignee
Mitsubishi Heavy Ind Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Ind Ltd filed Critical Mitsubishi Heavy Ind Ltd
Application granted granted Critical
Publication of DK1415700T3 publication Critical patent/DK1415700T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof
DK02758810.2T 2001-08-09 2002-08-08 Fremgangsmåde og apparat til fjernelse af kviksølv i røggas DK1415700T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001242596A JP4831801B2 (ja) 2001-08-09 2001-08-09 排ガスの水銀除去方法及び装置
PCT/JP2002/008121 WO2003015900A1 (fr) 2001-08-09 2002-08-08 Procede et appareil d'elimination du mercure contenu dans des gaz de fumees

Publications (1)

Publication Number Publication Date
DK1415700T3 true DK1415700T3 (da) 2011-05-09

Family

ID=19072847

Family Applications (1)

Application Number Title Priority Date Filing Date
DK02758810.2T DK1415700T3 (da) 2001-08-09 2002-08-08 Fremgangsmåde og apparat til fjernelse af kviksølv i røggas

Country Status (7)

Country Link
US (1) US20030170159A1 (da)
EP (1) EP1415700B1 (da)
JP (1) JP4831801B2 (da)
DE (1) DE60239617D1 (da)
DK (1) DK1415700T3 (da)
ES (1) ES2360934T3 (da)
WO (1) WO2003015900A1 (da)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004080574A1 (en) * 2003-03-12 2004-09-23 F.L. Smidth Airtech A/S Mercury and process for removing mercury from gases
US7517511B2 (en) * 2003-05-01 2009-04-14 The Regents Of The University Of California Method and apparatus for mitigating mercury emissions in exhaust gases
JP2004337781A (ja) 2003-05-16 2004-12-02 Mitsubishi Heavy Ind Ltd 排ガス処理方法、排ガス処理システム及び触媒酸化装置
US7033419B1 (en) * 2003-09-16 2006-04-25 The United States Of America As Represented By The United States Department Of Energy Method for high temperature mercury capture from gas streams
JP4098697B2 (ja) * 2003-10-22 2008-06-11 株式会社日本触媒 排ガス処理方法
US7264784B2 (en) * 2003-10-22 2007-09-04 Nippon Shokubai Co., Ltd. Method for treating exhaust gas
US7438876B2 (en) * 2003-12-02 2008-10-21 Cichanowicz J Edward Multi-stage heat absorbing reactor and process for SCR of NOx and for oxidation of elemental mercury
US7585487B2 (en) * 2003-12-12 2009-09-08 Conocophillips Company Composition for the removal of heavy metals from gases
JP4503378B2 (ja) * 2004-07-15 2010-07-14 株式会社Ｉｈｉ 排ガス中のガス状水銀除去方法及び除去装置
WO2006037213A1 (en) * 2004-10-01 2006-04-13 William Digdon Composition and method for oxidizing mercury in combustion processes
EP1842836A4 (en) * 2005-01-06 2013-12-11 Taiheiyo Cement Corp APPARATUS AND METHOD FOR TREATING A GASEOUS COMBUSTION EFFLUENT OF CEMENT OVEN
JP5051977B2 (ja) * 2005-01-31 2012-10-17 バブコック日立株式会社 排ガス中微量有害物質の除去装置及びその運転方法
US20060198777A1 (en) * 2005-03-03 2006-09-07 Cross Joseph B Mercury removal sorbent
US20060198774A1 (en) * 2005-03-03 2006-09-07 Cross Joseph B Mercury Removal sorbent
US7404939B2 (en) * 2005-03-03 2008-07-29 Conocophillips Company Mercury removal sorbent
US7504080B2 (en) 2005-04-12 2009-03-17 Conocophillips Company Process for the removal of heavy metals from gases, and compositions therefor and therewith
KR100635719B1 (ko) * 2005-05-11 2006-10-17 한국전력공사 연소 배기가스 중의 수은의 산화방법
JP2007007580A (ja) * 2005-06-30 2007-01-18 Mitsubishi Heavy Ind Ltd 排ガス処理装置及び方法
US20070092418A1 (en) * 2005-10-17 2007-04-26 Chemical Products Corporation Sorbents for Removal of Mercury from Flue Gas
JP4981318B2 (ja) 2005-12-19 2012-07-18 三菱重工業株式会社 排ガス処理装置および排ガス処理方法
JP4838579B2 (ja) * 2005-12-21 2011-12-14 三菱重工業株式会社 水銀除去システムおよび水銀除去方法
JP4277226B2 (ja) 2006-02-09 2009-06-10 バブコック日立株式会社 金属水銀酸化用触媒及び金属水銀酸化用触媒を備えた排ガス浄化用触媒とその製造方法
US8202482B2 (en) 2006-07-26 2012-06-19 Babcock-Hitachi Kabushiki Kaisha Apparatus for removing of trace of toxic substance from exhaust gas and method of operating the same
JP2008030017A (ja) * 2006-07-26 2008-02-14 Babcock Hitachi Kk 排ガス中微量有害物質の除去装置及びその運転方法
CN101528343B (zh) 2006-09-22 2012-04-25 巴布考克日立株式会社 金属汞的氧化催化剂
JP4388542B2 (ja) * 2006-12-07 2009-12-24 三菱重工業株式会社 水銀除去方法及び水銀除去システム
JP5144967B2 (ja) * 2007-06-11 2013-02-13 バブコック日立株式会社 排ガス処理システム
CN101332424B (zh) * 2007-06-28 2011-04-06 长春融成环保科技有限公司 脱氮催化剂及其制备方法
US20100239467A1 (en) 2008-06-17 2010-09-23 Brent Constantz Methods and systems for utilizing waste sources of metal oxides
CN201138790Y (zh) * 2008-01-03 2008-10-22 中山大洋电机股份有限公司 一种单相交流电机的电子启动电路
JP2009166011A (ja) * 2008-01-21 2009-07-30 Mitsubishi Heavy Ind Ltd 石炭焚ボイラの排ガス処理システム及び方法
WO2010009273A1 (en) 2008-07-16 2010-01-21 Calera Corporation Co2 utilization in electrochemical systems
JP5636577B2 (ja) 2008-07-29 2014-12-10 バブコック日立株式会社 金属水銀を含む排ガスの浄化方法および排ガス中の金属水銀の酸化触媒
JP5398193B2 (ja) * 2008-08-07 2014-01-29 三菱重工業株式会社 排ガス処理装置、排ガス処理システム及び排ガス中の水銀酸化性能管理システム
AU2009287462B2 (en) 2008-09-30 2011-10-06 Arelac, Inc. CO2-sequestering formed building materials
US7815880B2 (en) 2008-09-30 2010-10-19 Calera Corporation Reduced-carbon footprint concrete compositions
US8869477B2 (en) 2008-09-30 2014-10-28 Calera Corporation Formed building materials
JP5186699B2 (ja) * 2008-10-06 2013-04-17 バブコック日立株式会社 排ガス中の金属水銀の酸化触媒及び該触媒を用いた金属水銀の酸化処理方法
CN101391178B (zh) * 2008-10-24 2012-07-25 中国科学院山西煤炭化学研究所 一种应用v2o5/炭材料催化剂脱除烟气中汞的方法
US9133581B2 (en) 2008-10-31 2015-09-15 Calera Corporation Non-cementitious compositions comprising vaterite and methods thereof
JP4905996B2 (ja) * 2008-12-15 2012-03-28 バブコック日立株式会社 水銀除去方法と装置
WO2010093716A1 (en) 2009-02-10 2010-08-19 Calera Corporation Low-voltage alkaline production using hydrogen and electrocatlytic electrodes
JP2012519076A (ja) * 2009-03-02 2012-08-23 カレラ コーポレイション ガス流複合汚染物質制御システムおよび方法
JP5564846B2 (ja) * 2009-07-23 2014-08-06 株式会社Ｉｈｉ 排ガス処理方法及び排ガス処理設備
CN102470345B (zh) * 2009-10-01 2014-02-26 三菱重工业株式会社 汞氧化催化剂及其制造方法
US20130004395A1 (en) * 2011-06-30 2013-01-03 Uop Llc Processes and apparatuses for oxidizing elemental mercury in flue gas using oxychlorination catalysts
US20130004396A1 (en) * 2011-06-30 2013-01-03 Uop Llc Processes and apparatuses for eliminating elemental mercury from flue gas using deacon reaction catalysts at low temperatures
JP6249689B2 (ja) * 2012-09-05 2017-12-20 三菱日立パワーシステムズ株式会社 排ガス処理再生触媒及び排ガス処理触媒の再生方法
CN103337647B (zh) * 2013-06-19 2015-06-24 初强 太阳能热再生氯铜燃料电池再生技术
WO2015051363A1 (en) * 2013-10-04 2015-04-09 University Of Cincinnati Method and system for removing gaseous mercury in flue gases
CN104147909B (zh) * 2014-08-06 2017-10-10 华北电力大学 一种基于光催化氧化脱硝脱汞及深度脱硫的系统及方法
US10569221B2 (en) * 2015-08-21 2020-02-25 Ecolab Usa Inc. Complexation and removal of mercury from flue gas desulfurization systems
CR20180165A (es) 2015-08-21 2018-06-14 Ecolab Usa Inc Complejación y eliminación del mercurio de sistema de desulfuración de gas de combustión
CN106439882A (zh) * 2016-08-26 2017-02-22 舒少辛 一种利用烟气余热的脱硫废水处理装置
CN110997111B (zh) 2017-07-06 2022-09-27 埃科莱布美国股份有限公司 增强的汞氧化剂注入
CN107715837A (zh) * 2017-10-30 2018-02-23 太原理工大学 一种脱汞用钼改性生物质基炭吸附材料及其制备方法和应用
CN109173710A (zh) * 2018-09-30 2019-01-11 重庆大学 一种低温下催化脱除燃煤烟气中零价汞的系统及方法
CN110052225A (zh) * 2019-05-17 2019-07-26 中南大学 一种产生稳定，可调节浓度的气相HgCl2的装置及方法
CN112519283B (zh) * 2020-11-21 2022-12-06 西安热工研究院有限公司 一种熔融沉积成型3d打印脱汞袋笼及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05115750A (ja) * 1991-10-28 1993-05-14 Kawasaki Steel Corp 焼結炉排ガス中の一酸化炭素の酸化制御方法
TW267951B (da) * 1993-09-24 1996-01-11 Ikemukyatto Kk N
JP3935547B2 (ja) * 1997-02-19 2007-06-27 三菱重工業株式会社 排ガス処理方法及び排ガス処理装置
JP3023102B1 (ja) * 1999-01-11 2000-03-21 川崎重工業株式会社 排ガス中の水銀除去方法及び装置
US6136281A (en) * 1999-03-31 2000-10-24 Tennessee Valley Authority Method to control mercury emissions from exhaust gases

Also Published As

Publication number Publication date
US20030170159A1 (en) 2003-09-11
EP1415700A4 (en) 2006-04-19
ES2360934T3 (es) 2011-06-10
DE60239617D1 (de) 2011-05-12
JP2003053142A (ja) 2003-02-25
EP1415700A1 (en) 2004-05-06
WO2003015900A1 (fr) 2003-02-27
EP1415700B1 (en) 2011-03-30
JP4831801B2 (ja) 2011-12-07

Similar Documents

Publication Publication Date Title
DK1415700T3 (da) Fremgangsmåde og apparat til fjernelse af kviksølv i røggas
DK1195336T3 (da) Apparat og fremgangsmåde til inspektion af glasartikler
PL370508A1 (en) Method and apparatus for removing mercury species from hot flue gas
IS7914A (is) Aðferð og búnaður til að fjarlægja gaskennda mengunarvalda úr útblástursgasi
NO20034618L (no) Fremgangsmåte og apparat for nedihulls gassanalyse
DK1649922T3 (da) Indretning og fremgangsmåde til behandling af forbrændt udstødningsgas
DK1458564T3 (da) Fremgangsmåde og apparat til fremstilling af glas
DK1411789T3 (da) Fremgangsmåde og anordning til forögelse af hårvolumen
DK1308198T3 (da) Fremgangsmåde og system til fjernelse af kviksölv
DK1404512T3 (da) Fremgangsmåde og apparat til fremstilling af forstærket gipsplade
DK1421802T3 (da) Fremgangsmåde og apparat til trådløs netværksopkobling
DK1345530T3 (da) Fremgangsmåde og apparat til måling af intra-abdominalt tryk
DK1606491T3 (da) Foringsrörfört bröndboringsperforerende apparat og fremgangsmåde
DK1479175T3 (da) Fremgangsmåde og apparat til synkronisering af basisstationer
DK1373645T3 (da) Fremgangsmåde og apparat til skæring af undervandskonstruktioner
NO20030863D0 (no) Metode og apparat for brönnsementering
ATE303559T1 (de) Kompakte gasbrennvorrichtung mit niedrigem nox und verfahren
NO20042280L (no) Fremgangsmate og apparat for damp-metanreformering
NO20004439L (no) Fremgangsmåte og anordning for brönntesting
NO20044234L (no) Fremgangsmate og apparat for enturs-rorekspansjon
DK1197594T3 (da) Fremgangsmåde til spredning af vaskede rektangulære stofstykker og et apparat dertil
DK1278587T3 (da) Indretning og fremgangsmåde til neutralisering af gasstrøm
DK3468045T3 (da) Fremgangsmåde og apparat til aritmetisk kodning
NO20030023L (no) Apparat og fremgangsmåte for fluidseparasjon
NO20015189L (no) Fremgangsmåte og anordning ved oppsamlingsskrue