DK1200347T3 - Syntese af ZSM-5 og ZSM-11 - Google Patents

Syntese af ZSM-5 og ZSM-11

Info

Publication number
DK1200347T3
DK1200347T3 DK00945366T DK00945366T DK1200347T3 DK 1200347 T3 DK1200347 T3 DK 1200347T3 DK 00945366 T DK00945366 T DK 00945366T DK 00945366 T DK00945366 T DK 00945366T DK 1200347 T3 DK1200347 T3 DK 1200347T3
Authority
DK
Denmark
Prior art keywords
zsm
synthesis
nnmhq
c2h6n
formula
Prior art date
Application number
DK00945366T
Other languages
Danish (da)
English (en)
Inventor
Carrie L Kennedy
Louis D Rollmann
John L Schlenker
Original Assignee
Exxonmobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Oil Corp filed Critical Exxonmobil Oil Corp
Application granted granted Critical
Publication of DK1200347T3 publication Critical patent/DK1200347T3/da

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/365Type ZSM-8; Type ZSM-11; ZSM 5/11 intermediate
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • C01B39/40Type ZSM-5 using at least one organic template directing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00Chemistry of inorganic compounds
    • Y10S423/22MFI, e.g. ZSM-5. silicalite, LZ-241
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00Chemistry of inorganic compounds
    • Y10S423/29MEL, e.g. ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Insulating Materials (AREA)
DK00945366T 1999-07-13 2000-07-13 Syntese af ZSM-5 og ZSM-11 DK1200347T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/351,850 US6277355B1 (en) 1999-07-13 1999-07-13 Synthesis of ZSM-5 and ZSM-11
PCT/US2000/019058 WO2001004051A1 (en) 1999-07-13 2000-07-13 Synthesis of zsm-5 and zsm-11

Publications (1)

Publication Number Publication Date
DK1200347T3 true DK1200347T3 (da) 2004-08-09

Family

ID=23382682

Family Applications (1)

Application Number Title Priority Date Filing Date
DK00945366T DK1200347T3 (da) 1999-07-13 2000-07-13 Syntese af ZSM-5 og ZSM-11

Country Status (15)

Country Link
US (1) US6277355B1 (zh)
EP (1) EP1200347B1 (zh)
JP (1) JP4744756B2 (zh)
KR (1) KR100681587B1 (zh)
CN (1) CN1164491C (zh)
AT (1) ATE264268T1 (zh)
AU (1) AU5932300A (zh)
CA (1) CA2379364C (zh)
DE (1) DE60009910T2 (zh)
DK (1) DK1200347T3 (zh)
MX (1) MXPA02000371A (zh)
RU (1) RU2243156C2 (zh)
TW (1) TWI234547B (zh)
WO (1) WO2001004051A1 (zh)
ZA (1) ZA200200144B (zh)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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US6419894B1 (en) * 2000-12-22 2002-07-16 California Institute Of Technology Process for preparing zeolites having MEL structure using 2,2-diethoxyethyltrimethylammonium structure directing agent
US6846778B2 (en) * 2002-10-08 2005-01-25 Exxonmobil Research And Engineering Company Synthetic isoparaffinic premium heavy lubricant base stock
US20040065584A1 (en) * 2002-10-08 2004-04-08 Bishop Adeana Richelle Heavy lube oil from fischer- tropsch wax
US7132042B2 (en) * 2002-10-08 2006-11-07 Exxonmobil Research And Engineering Company Production of fuels and lube oils from fischer-tropsch wax
US7344631B2 (en) * 2002-10-08 2008-03-18 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
US7201838B2 (en) * 2002-10-08 2007-04-10 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
CN101124161B (zh) 2004-11-12 2010-09-01 苏德-化学股份公司 用二亚乙基三胺合成沸石β的方法
CN100372769C (zh) * 2004-12-16 2008-03-05 复旦大学 一种用于合成纳米/亚微米高硅zsm-5沸石的非晶态无机结构导向剂及其制备方法
CN101941710B (zh) * 2009-07-06 2012-02-08 中国石油化工股份有限公司 多孔材料及其合成方法
KR101614544B1 (ko) * 2009-10-20 2016-04-22 에스케이이노베이션 주식회사 나노 크기의 결정성 zsm-5 핵을 사용한 zsm-5의 제조 방법
WO2011112503A1 (en) 2010-03-08 2011-09-15 Dow Global Technologies Llc Catalyst composition for direct conversion of ethanol to propylene
CN102372580B (zh) * 2010-08-23 2014-01-22 中国石油化工股份有限公司 苯与乙醇烷基化的方法
CN102502696B (zh) * 2011-11-16 2014-04-23 大连理工大学 一种zsm-5沸石的合成方法
SG11201502434YA (en) * 2012-12-07 2015-04-29 Exxonmobil Res & Eng Co Synthesis of zsm-5 crystals with improved morphology
CN104624226B (zh) * 2013-11-13 2017-04-05 中国石油天然气股份有限公司 一种zsm‑5 和zsm‑11 共晶沸石分子筛及其制备和应用
RU2544017C1 (ru) * 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
CN106672999B (zh) * 2015-11-09 2018-10-23 中国石油化工股份有限公司 含卤素和稀土金属的zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
CN106673001B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11分子筛的合成方法及其合成的zsm-11分子筛
CN106673002B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
RU2712549C1 (ru) * 2018-11-29 2020-01-29 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ получения цеолита типа mel
WO2020205354A1 (en) 2019-03-29 2020-10-08 Exxonmobil Chemical Patents Inc. Mel-type zeolite for converting aromatic hydrocarbons, process for making and catalytic composition comprising said zeolite
KR20210126696A (ko) 2019-03-29 2021-10-20 엑손모빌 케미칼 패턴츠 인코포레이티드 신규한 제올라이트, 이의 제조 방법, 및 방향족 탄화수소의 전환에서의 이의 용도

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
CA1040187A (en) 1973-09-07 1978-10-10 Mobil Oil Corporation Method of preparing a crystalline aluminosilicate zeolite
US4139600A (en) 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4296083A (en) * 1977-04-22 1981-10-20 Mobil Oil Corporation Zeolite synthesis
US4108881A (en) 1977-08-01 1978-08-22 Mobil Oil Corporation Synthesis of zeolite ZSM-11
US4229424A (en) 1979-04-09 1980-10-21 Mobil Oil Corporation Crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
NL8006977A (nl) * 1979-12-26 1981-07-16 Chevron Res Werkwijze ter bereiding van kristallijne zeolieten.
DE3006471A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
DE3021580A1 (de) * 1980-06-07 1981-12-24 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von zeolithen und verwendung derselben als katalysatoren
DE3031557C2 (de) * 1980-08-21 1986-05-22 Basf Ag, 6700 Ludwigshafen Kristalliner Borsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung
AU572518B2 (en) * 1983-06-30 1988-05-12 Mobil Oil Corp. Low sodium porous crystalline zeolite
DE3402842A1 (de) * 1984-01-27 1985-08-08 Süd-Chemie AG, 8000 München Verfahren zur herstellung von kristallinen zeolithischen alumosilicaten
US4565681A (en) 1984-05-03 1986-01-21 Mobil Oil Corporation Synthetic zeolite ZSM-5 having a dimethylethylpropylammonium component
US5174977A (en) 1991-10-04 1992-12-29 Mobil Oil Corp. Synthesis of crystalline ZSM-5-type material
US5369071A (en) 1992-12-11 1994-11-29 Mobil Oil Corporation Manufacture of improved catalyst
DE4323774A1 (de) * 1993-07-15 1995-02-09 Basf Ag Hohlkugelartig agglomerierte Pentasilzeolithe
CN1041399C (zh) * 1994-12-30 1998-12-30 中国石油化工总公司 一种含稀土的结晶硅酸铝沸石
CN1260126C (zh) * 1999-04-21 2006-06-21 中国石油化工集团公司 超细颗粒五元环型沸石的制备方法

Also Published As

Publication number Publication date
US6277355B1 (en) 2001-08-21
JP2003504299A (ja) 2003-02-04
CA2379364A1 (en) 2001-01-18
EP1200347A1 (en) 2002-05-02
KR20020048374A (ko) 2002-06-22
TWI234547B (en) 2005-06-21
CN1164491C (zh) 2004-09-01
JP4744756B2 (ja) 2011-08-10
ATE264268T1 (de) 2004-04-15
AU5932300A (en) 2001-01-30
DE60009910T2 (de) 2005-03-10
WO2001004051A1 (en) 2001-01-18
CN1367758A (zh) 2002-09-04
CA2379364C (en) 2008-09-30
WO2001004051A9 (en) 2002-08-08
EP1200347B1 (en) 2004-04-14
ZA200200144B (en) 2002-10-30
DE60009910D1 (de) 2004-05-19
KR100681587B1 (ko) 2007-02-09
MXPA02000371A (es) 2005-04-08
RU2243156C2 (ru) 2004-12-27

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