DE69942646D1 - Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren - Google Patents
Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatorenInfo
- Publication number
- DE69942646D1 DE69942646D1 DE69942646T DE69942646T DE69942646D1 DE 69942646 D1 DE69942646 D1 DE 69942646D1 DE 69942646 T DE69942646 T DE 69942646T DE 69942646 T DE69942646 T DE 69942646T DE 69942646 D1 DE69942646 D1 DE 69942646D1
- Authority
- DE
- Germany
- Prior art keywords
- iron
- alkali metal
- catalyst
- containing alkali
- catalysts containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/20—Carbon compounds
- C07C2527/232—Carbonates
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/053,234 US6242379B1 (en) | 1998-04-01 | 1998-04-01 | Dehydrogenation catalysts |
US09/237,408 US6191065B1 (en) | 1998-04-01 | 1999-01-26 | Dehydrogenation catalysts |
PCT/US1999/006603 WO1999049968A1 (en) | 1998-04-01 | 1999-03-25 | Dehydrogenation catalysts comprising at least iron, alkali metal and a noble metal |
Publications (1)
Publication Number | Publication Date |
---|---|
DE69942646D1 true DE69942646D1 (de) | 2010-09-16 |
Family
ID=21982811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69942646T Expired - Lifetime DE69942646D1 (de) | 1998-04-01 | 1999-03-25 | Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren |
Country Status (4)
Country | Link |
---|---|
US (4) | US6242379B1 (de) |
KR (1) | KR100584112B1 (de) |
AT (1) | ATE476253T1 (de) |
DE (1) | DE69942646D1 (de) |
Families Citing this family (35)
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US6756339B1 (en) | 1998-04-01 | 2004-06-29 | Sud-Chemie Inc. | Dehydrogenation catalysts |
US6242379B1 (en) * | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
US6417135B1 (en) * | 1999-08-27 | 2002-07-09 | Huntsman Petrochemical Corporation | Advances in dehydrogenation catalysis |
US7435862B2 (en) | 2000-11-30 | 2008-10-14 | Sud-Chemie Inc. | Radial reactor loading of a dehydrogenation catalyst |
US20020183571A1 (en) * | 2000-11-30 | 2002-12-05 | Sud-Chemie Inc. | Radial reactor loading of a dehydrogenation catalyst |
AU2002316153A1 (en) | 2001-05-22 | 2003-01-02 | California Institute Of Technology | Transition metal oxo, sulfido and amido complexes as catalysts of nucleophilic addition reactions |
TWI267401B (en) * | 2002-01-30 | 2006-12-01 | Shell Int Research | A catalyst, its preparation and its use in a dehydrogenation process |
US7271126B2 (en) * | 2002-05-15 | 2007-09-18 | Sud-Chemie Inc. | Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor |
US6676606B2 (en) * | 2002-06-11 | 2004-01-13 | Koninklijke Philips Electronics N.V. | Ultrasonic diagnostic micro-vascular imaging |
US7244868B2 (en) | 2002-06-25 | 2007-07-17 | Shell Oil Company | Process for the dehydrogenation of an unsaturated hydrocarbon |
AR043243A1 (es) * | 2003-02-24 | 2005-07-20 | Shell Int Research | Composicion de catalizador ,su preparacion y uso |
CN1302847C (zh) * | 2003-09-03 | 2007-03-07 | 中国石油化工股份有限公司 | 用于乙苯制苯乙烯的脱氢催化剂 |
US20050228203A1 (en) * | 2003-11-25 | 2005-10-13 | Manzer Leo E | Process for the preparation of xylene |
KR20070104517A (ko) * | 2004-09-08 | 2007-10-26 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 수소화분해 촉매 조성물 |
CN100368364C (zh) * | 2004-10-29 | 2008-02-13 | 中国石油化工股份有限公司 | 用于生产苯乙烯的多段式绝热负压脱氢方法 |
TW200624170A (en) * | 2004-11-18 | 2006-07-16 | Shell Int Research | A high activity and high stability iron oxide based dehydrogenation catalyst having a low concentration of titanium and the manufacture and use thereof |
RU2385313C2 (ru) | 2004-11-18 | 2010-03-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Улучшенный способ получения алкенилароматического соединения при низком отношении пар/углеводород |
TW200800387A (en) * | 2006-06-01 | 2008-01-01 | Ritek Corp | Catalyst for catalyzing carbon nanotubes growth |
AR064916A1 (es) * | 2007-01-18 | 2009-05-06 | Shell Int Research | Catalizador preparacion y uso |
BRPI0806589A2 (pt) * | 2007-01-18 | 2014-05-13 | Shell Int Research | Catalisador, sua preparação e uso. |
WO2009126601A1 (en) * | 2008-04-09 | 2009-10-15 | Shell Oil Company | A method of improving a dehydrogenation process |
US8101541B2 (en) * | 2008-07-14 | 2012-01-24 | Sud-Chemie Inc. | Catalyst for dehydrogenation of hydrocarbons |
US20100081855A1 (en) * | 2008-09-30 | 2010-04-01 | Fina Technology, Inc. | Semi-Supported Dehydrogenation Catalyst |
US20110004037A1 (en) * | 2009-07-02 | 2011-01-06 | Uop Llc | Use of Mixed Activity Dehydrogenation Catalyst Following Oxidative Reheat |
US20110105818A1 (en) * | 2009-10-31 | 2011-05-05 | Fina Technology, Inc. | Dehydrogenation Catalyst with a Water Gas Shift Co-Catalyst |
US20120078024A1 (en) * | 2010-09-24 | 2012-03-29 | Fina Technology Inc. | Removal of Hydrogen From Dehydrogenation Processes |
KR101361045B1 (ko) * | 2011-09-20 | 2014-02-11 | 전남대학교산학협력단 | 칼슘 및 마그네슘 함유용액에서 칼슘 및 마그네슘의 선택적 분리방법, 상기 분리방법에 의해 얻어진 칼슘옥살레이트 및 마그네슘옥살레이트, 및 상기 옥살레이트들로부터 얻어진 칼슘옥사이드 및 마그네슘옥사이드 |
RU2509604C1 (ru) * | 2012-12-05 | 2014-03-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" | Катализатор для дегидрирования алкилароматических углеводородов |
KR101953919B1 (ko) * | 2012-12-18 | 2019-03-04 | 에스케이이노베이션 주식회사 | 혼성 망간 페라이트 허니컴형 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법 |
JP6720086B2 (ja) * | 2014-05-09 | 2020-07-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 炭化水素の脱水素化のための改良された触媒 |
BR102016022962B1 (pt) * | 2016-10-03 | 2021-10-26 | Petróleo Brasileiro S.A. - Petrobras | Processo de preparação de um catalisador de ferro-cromo promovido com platina, e, catalisador composto de ferro-cromo promovido com platina |
CN106994353A (zh) * | 2017-04-24 | 2017-08-01 | 苏州拓瑞特新材料有限公司 | 一种不含粘结剂高强度低水比乙苯脱氢催化剂 |
KR20210090195A (ko) * | 2018-11-19 | 2021-07-19 | 클라리언트 인터내셔널 리미티드 | 에틸벤젠과 같은 알킬 방향족 화합물을 전환시키기 위한 탈수소화 촉매 |
CN114425358B (zh) | 2020-10-14 | 2023-05-02 | 中国石油化工股份有限公司 | 低甲苯副产的乙苯脱氢制苯乙烯用催化剂及其制备方法和应用以及乙苯脱氢方法 |
EP4015078A1 (de) | 2020-12-15 | 2022-06-22 | Clariant International Ltd | Verfahren zur herstellung von alkenylaromatischen verbindungen unter verwendung eines dehydrierungskatalysators |
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DE4303715A1 (de) | 1993-02-09 | 1994-08-11 | Sued Chemie Ag | Chromfreier Katalysator auf Basis Eisenoxid zur Konvertierung von Kohlenmonoxid |
US5830425A (en) | 1993-02-09 | 1998-11-03 | Sud-Chemie Ag | Chromium-free catalyst based on iron oxide for conversion of carbon monoxide |
US5376613A (en) | 1993-05-04 | 1994-12-27 | The Dow Chemical Company | Dehydrogenation catalyst and process for preparing same |
TW349033B (en) * | 1994-05-31 | 1999-01-01 | Nippon Catalytic Chem Ind | Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound |
EP0797559B1 (de) | 1994-12-14 | 1999-04-07 | Shell Internationale Researchmaatschappij B.V. | Dehydrierungskatalisator mit bimodaler porengrössenverteilung |
JP4376966B2 (ja) | 1994-12-14 | 2009-12-02 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 再構造化された酸化鉄 |
CA2207560A1 (en) | 1994-12-14 | 1996-06-20 | Shell Internationale Research Maatschappij B.V. | Large particle dehydrogenation catalyst and process |
KR100373572B1 (ko) | 1994-12-14 | 2003-04-21 | 쉘 인터내셔널 리써치 마챠피즈 비 브이 | 탈수소화촉매및방법 |
CN1047097C (zh) | 1995-09-15 | 1999-12-08 | 中国石油化工总公司上海石油化工研究院 | 用于生产烷烯基芳烃的脱氢催化剂 |
CN1050535C (zh) | 1995-11-15 | 2000-03-22 | 中国石油化工总公司 | 用于生产不饱和芳烃的脱氢催化剂 |
US6242379B1 (en) * | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
-
1998
- 1998-04-01 US US09/053,234 patent/US6242379B1/en not_active Expired - Lifetime
- 1998-08-28 US US09/143,637 patent/US6177602B1/en not_active Expired - Lifetime
-
1999
- 1999-01-26 US US09/237,408 patent/US6191065B1/en not_active Expired - Lifetime
- 1999-03-25 AT AT99914152T patent/ATE476253T1/de not_active IP Right Cessation
- 1999-03-25 DE DE69942646T patent/DE69942646D1/de not_active Expired - Lifetime
- 1999-03-25 KR KR1020007010941A patent/KR100584112B1/ko not_active IP Right Cessation
-
2001
- 2001-03-26 US US09/817,399 patent/US6465704B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR20010052231A (ko) | 2001-06-25 |
US20010020118A1 (en) | 2001-09-06 |
US6242379B1 (en) | 2001-06-05 |
US6191065B1 (en) | 2001-02-20 |
KR100584112B1 (ko) | 2006-05-30 |
US6465704B2 (en) | 2002-10-15 |
US6177602B1 (en) | 2001-01-23 |
ATE476253T1 (de) | 2010-08-15 |
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