DE69942646D1 - Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren - Google Patents

Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren

Info

Publication number
DE69942646D1
DE69942646D1 DE69942646T DE69942646T DE69942646D1 DE 69942646 D1 DE69942646 D1 DE 69942646D1 DE 69942646 T DE69942646 T DE 69942646T DE 69942646 T DE69942646 T DE 69942646T DE 69942646 D1 DE69942646 D1 DE 69942646D1
Authority
DE
Germany
Prior art keywords
iron
alkali metal
catalyst
containing alkali
catalysts containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69942646T
Other languages
English (en)
Inventor
David Williams
Yuji Mishima
Andrzej Rokicki
Kazuhiko Shinyama
Dennis Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sued Chemie Catalysts Japan Inc
Sued Chemie Inc
Original Assignee
Sued Chemie Catalysts Japan Inc
Sued Chemie Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Catalysts Japan Inc, Sued Chemie Inc filed Critical Sued Chemie Catalysts Japan Inc
Priority claimed from PCT/US1999/006603 external-priority patent/WO1999049968A1/en
Application granted granted Critical
Publication of DE69942646D1 publication Critical patent/DE69942646D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321Catalytic processes
    • C07C5/324Catalytic processes with metals
    • C07C5/325Catalytic processes with metals of the platinum group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3335Catalytic processes with metals
    • C07C5/3337Catalytic processes with metals of the platinum group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42Platinum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44Palladium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46Ruthenium, rhodium, osmium or iridium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/745Iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20Carbon compounds
    • C07C2527/232Carbonates
DE69942646T 1998-04-01 1999-03-25 Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren Expired - Lifetime DE69942646D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/053,234 US6242379B1 (en) 1998-04-01 1998-04-01 Dehydrogenation catalysts
US09/237,408 US6191065B1 (en) 1998-04-01 1999-01-26 Dehydrogenation catalysts
PCT/US1999/006603 WO1999049968A1 (en) 1998-04-01 1999-03-25 Dehydrogenation catalysts comprising at least iron, alkali metal and a noble metal

Publications (1)

Publication Number Publication Date
DE69942646D1 true DE69942646D1 (de) 2010-09-16

Family

ID=21982811

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69942646T Expired - Lifetime DE69942646D1 (de) 1998-04-01 1999-03-25 Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren

Country Status (4)

Country Link
US (4) US6242379B1 (de)
KR (1) KR100584112B1 (de)
AT (1) ATE476253T1 (de)
DE (1) DE69942646D1 (de)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6756339B1 (en) 1998-04-01 2004-06-29 Sud-Chemie Inc. Dehydrogenation catalysts
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US7435862B2 (en) 2000-11-30 2008-10-14 Sud-Chemie Inc. Radial reactor loading of a dehydrogenation catalyst
US20020183571A1 (en) * 2000-11-30 2002-12-05 Sud-Chemie Inc. Radial reactor loading of a dehydrogenation catalyst
AU2002316153A1 (en) 2001-05-22 2003-01-02 California Institute Of Technology Transition metal oxo, sulfido and amido complexes as catalysts of nucleophilic addition reactions
TWI267401B (en) * 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7271126B2 (en) * 2002-05-15 2007-09-18 Sud-Chemie Inc. Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
US6676606B2 (en) * 2002-06-11 2004-01-13 Koninklijke Philips Electronics N.V. Ultrasonic diagnostic micro-vascular imaging
US7244868B2 (en) 2002-06-25 2007-07-17 Shell Oil Company Process for the dehydrogenation of an unsaturated hydrocarbon
AR043243A1 (es) * 2003-02-24 2005-07-20 Shell Int Research Composicion de catalizador ,su preparacion y uso
CN1302847C (zh) * 2003-09-03 2007-03-07 中国石油化工股份有限公司 用于乙苯制苯乙烯的脱氢催化剂
US20050228203A1 (en) * 2003-11-25 2005-10-13 Manzer Leo E Process for the preparation of xylene
KR20070104517A (ko) * 2004-09-08 2007-10-26 쉘 인터내셔날 리써취 마트샤피지 비.브이. 수소화분해 촉매 조성물
CN100368364C (zh) * 2004-10-29 2008-02-13 中国石油化工股份有限公司 用于生产苯乙烯的多段式绝热负压脱氢方法
TW200624170A (en) * 2004-11-18 2006-07-16 Shell Int Research A high activity and high stability iron oxide based dehydrogenation catalyst having a low concentration of titanium and the manufacture and use thereof
RU2385313C2 (ru) 2004-11-18 2010-03-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Улучшенный способ получения алкенилароматического соединения при низком отношении пар/углеводород
TW200800387A (en) * 2006-06-01 2008-01-01 Ritek Corp Catalyst for catalyzing carbon nanotubes growth
AR064916A1 (es) * 2007-01-18 2009-05-06 Shell Int Research Catalizador preparacion y uso
BRPI0806589A2 (pt) * 2007-01-18 2014-05-13 Shell Int Research Catalisador, sua preparação e uso.
WO2009126601A1 (en) * 2008-04-09 2009-10-15 Shell Oil Company A method of improving a dehydrogenation process
US8101541B2 (en) * 2008-07-14 2012-01-24 Sud-Chemie Inc. Catalyst for dehydrogenation of hydrocarbons
US20100081855A1 (en) * 2008-09-30 2010-04-01 Fina Technology, Inc. Semi-Supported Dehydrogenation Catalyst
US20110004037A1 (en) * 2009-07-02 2011-01-06 Uop Llc Use of Mixed Activity Dehydrogenation Catalyst Following Oxidative Reheat
US20110105818A1 (en) * 2009-10-31 2011-05-05 Fina Technology, Inc. Dehydrogenation Catalyst with a Water Gas Shift Co-Catalyst
US20120078024A1 (en) * 2010-09-24 2012-03-29 Fina Technology Inc. Removal of Hydrogen From Dehydrogenation Processes
KR101361045B1 (ko) * 2011-09-20 2014-02-11 전남대학교산학협력단 칼슘 및 마그네슘 함유용액에서 칼슘 및 마그네슘의 선택적 분리방법, 상기 분리방법에 의해 얻어진 칼슘옥살레이트 및 마그네슘옥살레이트, 및 상기 옥살레이트들로부터 얻어진 칼슘옥사이드 및 마그네슘옥사이드
RU2509604C1 (ru) * 2012-12-05 2014-03-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" Катализатор для дегидрирования алкилароматических углеводородов
KR101953919B1 (ko) * 2012-12-18 2019-03-04 에스케이이노베이션 주식회사 혼성 망간 페라이트 허니컴형 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법
JP6720086B2 (ja) * 2014-05-09 2020-07-08 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 炭化水素の脱水素化のための改良された触媒
BR102016022962B1 (pt) * 2016-10-03 2021-10-26 Petróleo Brasileiro S.A. - Petrobras Processo de preparação de um catalisador de ferro-cromo promovido com platina, e, catalisador composto de ferro-cromo promovido com platina
CN106994353A (zh) * 2017-04-24 2017-08-01 苏州拓瑞特新材料有限公司 一种不含粘结剂高强度低水比乙苯脱氢催化剂
KR20210090195A (ko) * 2018-11-19 2021-07-19 클라리언트 인터내셔널 리미티드 에틸벤젠과 같은 알킬 방향족 화합물을 전환시키기 위한 탈수소화 촉매
CN114425358B (zh) 2020-10-14 2023-05-02 中国石油化工股份有限公司 低甲苯副产的乙苯脱氢制苯乙烯用催化剂及其制备方法和应用以及乙苯脱氢方法
EP4015078A1 (de) 2020-12-15 2022-06-22 Clariant International Ltd Verfahren zur herstellung von alkenylaromatischen verbindungen unter verwendung eines dehydrierungskatalysators

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2426829A (en) 1942-09-26 1947-09-02 Standard Oil Dev Co Production of olefins
US2408140A (en) 1944-09-18 1946-09-24 Shell Dev Dehydrogenation catalyst
US2414585A (en) 1945-06-26 1947-01-21 Shell Dev Catalytic dehydrogenation
US2866791A (en) 1956-08-01 1958-12-30 Phillips Petroleum Co Catalyst and dehydrogenation process
US2870228A (en) 1956-12-24 1959-01-20 Shell Dev Dehydrogenation of hydrocarbons
US2866790A (en) 1957-02-18 1958-12-30 Phillips Petroleum Co Catalyst and dehydrogenation process
US3084125A (en) 1958-12-22 1963-04-02 Dow Chemical Co Method of dehydrogenating ethylbenzene to styrene and a catalyst therefor
US3360579A (en) 1965-05-21 1967-12-26 Shell Oil Co Catalytic dehydrogenation of alkylaromatics
US3364277A (en) 1965-05-21 1968-01-16 Shell Oil Co Dehydrogenating olefins to diolefins in the presence of a yellow iron oxide catalyst
US3437703A (en) * 1966-05-05 1969-04-08 Foster Grant Co Inc Catalytic dehydrogenation process and compositions
US3424808A (en) 1967-10-03 1969-01-28 Foster Grant Co Inc Dehydrogenation and methanation catalyst and process
US3505422A (en) 1969-01-23 1970-04-07 Foster Grant Co Inc Dehydrogenation and methanation catalyst and process
US3843745A (en) * 1970-02-13 1974-10-22 Petro Tex Chem Corp Oxidative dehydrogenation process catalyzed by magnesium ferrite
US3872027A (en) * 1970-02-13 1975-03-18 Petro Tex Chem Corp Oxidative dehydrogenation catalysts and their method of preparation
US3798178A (en) 1972-02-17 1974-03-19 Dow Chemical Co Self-regenerative dehydrogenation catalyst
US3900525A (en) * 1972-05-16 1975-08-19 Petro Tex Chem Corp Manganese ferrite catalyzed oxidative dehydrogenation
JPS4939973A (de) 1972-08-25 1974-04-15
US3904552A (en) 1973-03-08 1975-09-09 Girdler Chemical Dehyrogenation catalyst
US3809178A (en) 1973-04-30 1974-05-07 Boeing Co Clamshell exhaust nozzle and sound deflector
US3901552A (en) 1973-12-10 1975-08-26 Jack C Stone Granular-floor supported cargo hauling trailer apparatus
US4134858A (en) 1974-05-07 1979-01-16 Institut Francais Du Petrole Catalysts, their manufacture for use in dehydrogenation reactions
US4098723A (en) 1977-01-27 1978-07-04 Shell Oil Company Catalyst for dehydrogenation
IN148558B (de) 1977-04-14 1981-04-04 Shell Int Research
US4418237A (en) 1981-03-30 1983-11-29 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4435607A (en) 1981-04-28 1984-03-06 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4376225A (en) 1981-08-05 1983-03-08 Uop Inc. Dehydrogenation process utilizing indirect heat exchange and direct combustion heating
US4467046A (en) 1982-01-07 1984-08-21 Smith James L Dehydrogenation catalyst
DE3200483A1 (de) * 1982-01-09 1983-07-21 Bayer Ag, 5090 Leverkusen Kieselsaeurehaltige formkoerper, verfahren zu ihrer herstellung und ihre verwendung
US4404123A (en) 1982-12-15 1983-09-13 Mobil Oil Corporation Catalysts for para-ethyltoluene dehydrogenation
US4433186A (en) 1982-12-15 1984-02-21 Mobil Oil Corporation Catalysts for para-ethyltoluene dehydrogenation
US4628137A (en) 1982-12-23 1986-12-09 Mobil Oil Corporation Process for para-ethyltoluene dehydrogenation
US4496662A (en) 1982-12-23 1985-01-29 Mobil Oil Corporation Catalysts for para-ethyltoluene dehydrogenation
US4684619A (en) * 1985-02-20 1987-08-04 The Dow Chemical Company Process for making a dehydrogenation catalyst having improved moisture stability
US4565898A (en) 1985-03-06 1986-01-21 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
FR2592375B1 (fr) 1985-12-27 1988-04-08 Shell Int Research Procede de deshydrogenation sans oxydation
US4652687A (en) 1986-07-07 1987-03-24 Uop Inc. Process for the dehydrogenation of dehydrogenatable hydrocarbons
US4691071A (en) 1986-12-11 1987-09-01 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US5591315A (en) * 1987-03-13 1997-01-07 The Standard Oil Company Solid-component membranes electrochemical reactor components electrochemical reactors use of membranes reactor components and reactor for oxidation reactions
US4717781A (en) 1987-03-23 1988-01-05 Uop Inc. Process for the dehydrogenation of dehydrogenatable hydrocarbons
US4806624A (en) * 1987-06-17 1989-02-21 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4758543A (en) 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
ES2024072B3 (es) * 1988-02-11 1992-02-16 Fina Research Procedimiento para preparar catalizadores que contienen un metal del grupo del platino, y sus usos
FR2630662A1 (fr) * 1988-04-29 1989-11-03 Shell Int Research Catalyseur pour la deshydrogenation de composes organiques, procede pour sa preparation et son utilisation
US4827066A (en) * 1988-05-23 1989-05-02 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4914249A (en) 1988-12-29 1990-04-03 Uop Dehydrogenation of dehydrogenatable hydrocarbons
US5023225A (en) * 1989-07-21 1991-06-11 United Catalysts Inc. Dehydrogenation catalyst and process for its preparation
JPH04277030A (ja) * 1991-03-05 1992-10-02 Nissan Gaadoraa Shokubai Kk エチルベンゼン脱水素触媒
CN1028495C (zh) 1991-10-30 1995-05-24 中国石油化工总公司 用于烷基芳烃的脱氢催化剂
DE4303715A1 (de) 1993-02-09 1994-08-11 Sued Chemie Ag Chromfreier Katalysator auf Basis Eisenoxid zur Konvertierung von Kohlenmonoxid
US5830425A (en) 1993-02-09 1998-11-03 Sud-Chemie Ag Chromium-free catalyst based on iron oxide for conversion of carbon monoxide
US5376613A (en) 1993-05-04 1994-12-27 The Dow Chemical Company Dehydrogenation catalyst and process for preparing same
TW349033B (en) * 1994-05-31 1999-01-01 Nippon Catalytic Chem Ind Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound
EP0797559B1 (de) 1994-12-14 1999-04-07 Shell Internationale Researchmaatschappij B.V. Dehydrierungskatalisator mit bimodaler porengrössenverteilung
JP4376966B2 (ja) 1994-12-14 2009-12-02 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 再構造化された酸化鉄
CA2207560A1 (en) 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Large particle dehydrogenation catalyst and process
KR100373572B1 (ko) 1994-12-14 2003-04-21 쉘 인터내셔널 리써치 마챠피즈 비 브이 탈수소화촉매및방법
CN1047097C (zh) 1995-09-15 1999-12-08 中国石油化工总公司上海石油化工研究院 用于生产烷烯基芳烃的脱氢催化剂
CN1050535C (zh) 1995-11-15 2000-03-22 中国石油化工总公司 用于生产不饱和芳烃的脱氢催化剂
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts

Also Published As

Publication number Publication date
KR20010052231A (ko) 2001-06-25
US20010020118A1 (en) 2001-09-06
US6242379B1 (en) 2001-06-05
US6191065B1 (en) 2001-02-20
KR100584112B1 (ko) 2006-05-30
US6465704B2 (en) 2002-10-15
US6177602B1 (en) 2001-01-23
ATE476253T1 (de) 2010-08-15

Similar Documents

Publication Publication Date Title
DE69942646D1 (de) Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren
MY102984A (en) Ethylene oxide catalyst and process for the catalytic production of ethylene oxide
DE69839728D1 (de) Ethylenoxid-katalysatoren
AU5993298A (en) Process for the presulphurization of catalysts
YU57298A (sh) Katalizator vinil acetata koji sadrži metalni paladium, zlato, bakar i ma koji od izvesnih četvrtih metala
BG103001A (en) Oxidation catalyst
CA2326538A1 (en) Dehydrogenation catalysts comprising at least iron, alkali metal and a noble metal
ES2115379T3 (es) Catalizador heterogeneo de metatesis.
ATE79566T1 (de) Hydrierungsverfahren von chlorfluoroalkenen.
MY110501A (en) Epoxidation catalyst
EA200100683A1 (ru) Катализаторы, содержащие металлы на материалах носителя на основе гидротальцита, и способ их получения
AR042322A1 (es) Catalizador de deshidrogenacion y proceso para preparar el mismo
TR199802529A2 (xx) Kullan�lm�� molibden esasl� katalizat�r performans�n�n amonyum dimolibdat ilave edilmesi yoluyla iyile�tirilmesi.
ES2189158T3 (es) Sintesis directa de oxidos de orano-renio a partir de compuestos que contienen renio.
FR2605900B1 (fr) Perfectionnement au procede de desulfuration des essences terpeniques
NO823631L (no) Fremgangsmaate for fremstilling av aromatiske isocyanater ved karbonylering av nitroderivater
EA200100324A1 (ru) Поливалентный бифункциональный катализатор и способ получения такого катализатора
BR9711433A (pt) Catalisador de prata ativado
HUP9702210A2 (hu) Eljárás 4-hidroxi-karbazol előállítására