DE69919479T2 - Herstellung stärkehaltiger Kautschuke, Reife aus vulcanisiertem Gummi und hergestellter Gegenstand - Google Patents
Herstellung stärkehaltiger Kautschuke, Reife aus vulcanisiertem Gummi und hergestellter Gegenstand Download PDFInfo
- Publication number
- DE69919479T2 DE69919479T2 DE69919479T DE69919479T DE69919479T2 DE 69919479 T2 DE69919479 T2 DE 69919479T2 DE 69919479 T DE69919479 T DE 69919479T DE 69919479 T DE69919479 T DE 69919479T DE 69919479 T2 DE69919479 T2 DE 69919479T2
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- Germany
- Prior art keywords
- bis
- disulfide
- organosilane
- rubber
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920001971 elastomer Polymers 0.000 title claims description 155
- 239000005060 rubber Substances 0.000 title claims description 125
- 238000002360 preparation method Methods 0.000 title description 6
- 239000004636 vulcanized rubber Substances 0.000 title description 3
- 238000002156 mixing Methods 0.000 claims description 104
- 239000000203 mixture Substances 0.000 claims description 101
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 95
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 90
- 239000011593 sulfur Substances 0.000 claims description 86
- 229910052717 sulfur Inorganic materials 0.000 claims description 86
- -1 aromatic vinyl compound Chemical class 0.000 claims description 81
- 150000008117 polysulfides Polymers 0.000 claims description 77
- 239000005077 polysulfide Substances 0.000 claims description 76
- 229920001021 polysulfide Polymers 0.000 claims description 76
- 150000001282 organosilanes Chemical class 0.000 claims description 70
- 150000001875 compounds Chemical class 0.000 claims description 58
- 229920002472 Starch Polymers 0.000 claims description 57
- 239000008107 starch Substances 0.000 claims description 57
- 235000019698 starch Nutrition 0.000 claims description 57
- 239000002131 composite material Substances 0.000 claims description 51
- 239000000377 silicon dioxide Substances 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 41
- 239000004014 plasticizer Substances 0.000 claims description 36
- 239000000806 elastomer Substances 0.000 claims description 30
- 239000000945 filler Substances 0.000 claims description 27
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 25
- 229910000077 silane Inorganic materials 0.000 claims description 24
- 238000004073 vulcanization Methods 0.000 claims description 20
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 19
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 19
- 239000006229 carbon black Substances 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 150000001993 dienes Chemical class 0.000 claims description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000012763 reinforcing filler Substances 0.000 claims description 11
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 230000002787 reinforcement Effects 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 8
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 230000000930 thermomechanical effect Effects 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 6
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 6
- 229920000856 Amylose Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 150000001721 carbon Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 238000010059 sulfur vulcanization Methods 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- JOKQTNPABXVGSM-UHFFFAOYSA-N C(C)O[Si](OCC)(OCC)CCC1=C2C(C)=CC=C1SSS2 Chemical compound C(C)O[Si](OCC)(OCC)CCC1=C2C(C)=CC=C1SSS2 JOKQTNPABXVGSM-UHFFFAOYSA-N 0.000 claims description 3
- XZXIVOQWJAUCMM-UHFFFAOYSA-N C(C)O[Si](OCC)(OCC)CCC1=C2C(C)=CC=C1SSSS2 Chemical compound C(C)O[Si](OCC)(OCC)CCC1=C2C(C)=CC=C1SSSS2 XZXIVOQWJAUCMM-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 150000001343 alkyl silanes Chemical class 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- 238000000975 co-precipitation Methods 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 claims description 3
- KLFNHRIZTXWZHT-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSCCC[Si](OCC)(OCC)OCC KLFNHRIZTXWZHT-UHFFFAOYSA-N 0.000 claims description 3
- JQBSHJQOBJRYIX-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyldisulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSCC[Si](OC)(OC)OC JQBSHJQOBJRYIX-UHFFFAOYSA-N 0.000 claims description 3
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 claims description 3
- HLYOLBTWIFIQGU-UHFFFAOYSA-N 1-[1,1-dioctoxy-3-(3,3,3-trioctoxypropyldisulfanyl)propoxy]octane Chemical compound CCCCCCCCOC(OCCCCCCCC)(OCCCCCCCC)CCSSCCC(OCCCCCCCC)(OCCCCCCCC)OCCCCCCCC HLYOLBTWIFIQGU-UHFFFAOYSA-N 0.000 claims description 2
- BZFCHYVROSGOOI-UHFFFAOYSA-N 2-[1,1-bis[(2-methylpropan-2-yl)oxy]-2-[2,2,2-tris[(2-methylpropan-2-yl)oxy]ethyldisulfanyl]ethoxy]-2-methylpropane Chemical compound CC(C)(C)OC(OC(C)(C)C)(OC(C)(C)C)CSSCC(OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C BZFCHYVROSGOOI-UHFFFAOYSA-N 0.000 claims description 2
- CNWFIIFQWMBTBW-UHFFFAOYSA-N 3-(6,7-dithiabicyclo[3.2.1]octa-1(8),2,4-trien-4-yl)propyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCC1=CC=C2SSC1=C2 CNWFIIFQWMBTBW-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- HCCRVSCHHLWZBR-UHFFFAOYSA-N CCC(C)O[SiH2]C(CSSCC([SiH2]OC(C)CC)([SiH2]OC(C)CC)[SiH2]OC(C)CC)([SiH2]OC(C)CC)[SiH2]OC(C)CC Chemical compound CCC(C)O[SiH2]C(CSSCC([SiH2]OC(C)CC)([SiH2]OC(C)CC)[SiH2]OC(C)CC)([SiH2]OC(C)CC)[SiH2]OC(C)CC HCCRVSCHHLWZBR-UHFFFAOYSA-N 0.000 claims description 2
- SURAFTVKHCVUMA-UHFFFAOYSA-N COCCOCCCO[SiH2]CCCSSCCC[SiH2]OCCCOCCOC Chemical compound COCCOCCCO[SiH2]CCCSSCCC[SiH2]OCCCOCCOC SURAFTVKHCVUMA-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- NVHLTUPSVCBIJJ-UHFFFAOYSA-N [1-[(1,2-dimethoxy-2-methyl-1-phenylsilylpropyl)disulfanyl]-1,2-dimethoxy-2-methylpropyl]-phenylsilane Chemical compound COC(C([SiH2]C1=CC=CC=C1)(OC)SSC(C(C)(OC)C)(OC)[SiH2]C1=CC=CC=C1)(C)C NVHLTUPSVCBIJJ-UHFFFAOYSA-N 0.000 claims description 2
- PFHZTQKNPKSWKD-UHFFFAOYSA-N [1-cyclohexyloxy-3-[(3-cyclohexyloxy-3-dimethylsilylpropyl)disulfanyl]propyl]-dimethylsilane Chemical compound C1(CCCCC1)OC(CCSSCCC(OC1CCCCC1)[SiH](C)C)[SiH](C)C PFHZTQKNPKSWKD-UHFFFAOYSA-N 0.000 claims description 2
- WAFAIXONZKBUDA-UHFFFAOYSA-N [18-[(18-dimethylsilyl-18-methoxyoctadecyl)disulfanyl]-1-methoxyoctadecyl]-dimethylsilane Chemical compound COC(CCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC(OC)[SiH](C)C)[SiH](C)C WAFAIXONZKBUDA-UHFFFAOYSA-N 0.000 claims description 2
- IGSQDVCPURPOHD-UHFFFAOYSA-N [3-[(3-dimethylsilyl-3-methoxypropyl)disulfanyl]-1-methoxypropyl]-dimethylsilane Chemical compound COC(CCSSCCC(OC)[SiH](C)C)[SiH](C)C IGSQDVCPURPOHD-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- RTACIUYXLGWTAE-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1 RTACIUYXLGWTAE-UHFFFAOYSA-N 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 2
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 claims description 2
- 150000005690 diesters Chemical class 0.000 claims description 2
- IBWGVHYLBXYOEQ-UHFFFAOYSA-N dimethoxymethyl-[1-[1-(dimethoxymethylsilyl)pentyldisulfanyl]pentyl]silane Chemical compound COC(OC)[SiH2]C(CCCC)SSC(CCCC)[SiH2]C(OC)OC IBWGVHYLBXYOEQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 229920003049 isoprene rubber Polymers 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 claims description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 claims description 2
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims description 2
- UJWZHWUKKGGWAE-UHFFFAOYSA-N triethoxy-[1-(1-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)C(CC)SSC(CC)[Si](OCC)(OCC)OCC UJWZHWUKKGGWAE-UHFFFAOYSA-N 0.000 claims description 2
- TVHMODORFJSZPY-UHFFFAOYSA-N triethoxy-[12-(12-triethoxysilyldodecyldisulfanyl)dodecyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCCCCCCCSSCCCCCCCCCCCC[Si](OCC)(OCC)OCC TVHMODORFJSZPY-UHFFFAOYSA-N 0.000 claims description 2
- FJXRKYLOOJTENP-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyldisulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSCC[Si](OCC)(OCC)OCC FJXRKYLOOJTENP-UHFFFAOYSA-N 0.000 claims description 2
- UNQNFILHQQXQDD-UHFFFAOYSA-N trimethoxy-[1-(1-trimethoxysilylbutyldisulfanyl)butyl]silane Chemical compound CCCC([Si](OC)(OC)OC)SSC(CCC)[Si](OC)(OC)OC UNQNFILHQQXQDD-UHFFFAOYSA-N 0.000 claims description 2
- ZJZYSOYOZYZVAQ-UHFFFAOYSA-N trimethoxy-[1-(1-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)C(CC)SSC(CC)[Si](OC)(OC)OC ZJZYSOYOZYZVAQ-UHFFFAOYSA-N 0.000 claims description 2
- WTMORQWBQCDQQE-UHFFFAOYSA-N trimethoxy-[1-[(1-trimethoxysilylcyclohexyl)disulfanyl]cyclohexyl]silane Chemical compound C1CCCCC1([Si](OC)(OC)OC)SSC1([Si](OC)(OC)OC)CCCCC1 WTMORQWBQCDQQE-UHFFFAOYSA-N 0.000 claims description 2
- XBFRFOJRCIWLOJ-UHFFFAOYSA-N trimethoxy-[12-(12-trimethoxysilyldodecyldisulfanyl)dodecyl]silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCSSCCCCCCCCCCCC[Si](OC)(OC)OC XBFRFOJRCIWLOJ-UHFFFAOYSA-N 0.000 claims description 2
- RIFBNNJOLBIURG-UHFFFAOYSA-N trimethoxy-[18-(18-trimethoxysilyloctadecyldisulfanyl)octadecyl]silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC RIFBNNJOLBIURG-UHFFFAOYSA-N 0.000 claims description 2
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 claims description 2
- BNBXBRPOAJZBNB-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyldisulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSCCCC[Si](OC)(OC)OC BNBXBRPOAJZBNB-UHFFFAOYSA-N 0.000 claims description 2
- DINWTBWPUZJNSA-UHFFFAOYSA-N trioctoxy-[1-(1-trioctoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCCCCCCO[Si](OCCCCCCCC)(OCCCCCCCC)C(CC)SSC(CC)[Si](OCCCCCCCC)(OCCCCCCCC)OCCCCCCCC DINWTBWPUZJNSA-UHFFFAOYSA-N 0.000 claims description 2
- PFCLFCFVVOQDPP-UHFFFAOYSA-N tripropoxy-[1-(1-tripropoxysilylbutyldisulfanyl)butyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)C(CCC)SSC(CCC)[Si](OCCC)(OCCC)OCCC PFCLFCFVVOQDPP-UHFFFAOYSA-N 0.000 claims description 2
- QNMHMQIJGSSITD-UHFFFAOYSA-N tripropoxy-[1-(1-tripropoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)C(CC)SSC(CC)[Si](OCCC)(OCCC)OCCC QNMHMQIJGSSITD-UHFFFAOYSA-N 0.000 claims description 2
- IBMJMAJDCOPBML-UHFFFAOYSA-N tripropoxy-[2-(2-tripropoxysilylethyldisulfanyl)ethyl]silane Chemical compound CCCO[Si](OCCC)(OCCC)CCSSCC[Si](OCCC)(OCCC)OCCC IBMJMAJDCOPBML-UHFFFAOYSA-N 0.000 claims description 2
- 125000005353 silylalkyl group Chemical group 0.000 claims 2
- KOFGNZOFJYBHIN-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSCCC[Si](OC)(OC)OC KOFGNZOFJYBHIN-UHFFFAOYSA-N 0.000 claims 2
- HQCUQWHGNNIXMT-UHFFFAOYSA-N 2,2-dimethoxyethoxy-[2-[2-(2,2-dimethoxyethoxysilyl)ethyldisulfanyl]ethyl]silane Chemical compound COC(CO[SiH2]CCSSCC[SiH2]OCC(OC)OC)OC HQCUQWHGNNIXMT-UHFFFAOYSA-N 0.000 claims 1
- 150000005840 aryl radicals Chemical class 0.000 claims 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- IMZLMJVTHIPHCC-UHFFFAOYSA-N trimethoxy-[2-methyl-1-[(2-methyl-1-trimethoxysilylpropyl)disulfanyl]propyl]silane Chemical compound CO[Si](OC)(OC)C(C(C)C)SSC(C(C)C)[Si](OC)(OC)OC IMZLMJVTHIPHCC-UHFFFAOYSA-N 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 description 15
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- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
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- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
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- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
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- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
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- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
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- ATYBNKYOXTWSBY-UHFFFAOYSA-N ethoxy-[3-(3-ethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[SiH2]CCCSSSSCCC[SiH2]OCC ATYBNKYOXTWSBY-UHFFFAOYSA-N 0.000 description 1
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- 150000002780 morpholines Chemical class 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- ILSQBBRAYMWZLQ-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-propan-2-ylpropan-2-amine Chemical compound C1=CC=C2SC(SN(C(C)C)C(C)C)=NC2=C1 ILSQBBRAYMWZLQ-UHFFFAOYSA-N 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000001979 organolithium group Chemical group 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
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- 239000011118 polyvinyl acetate Substances 0.000 description 1
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- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- NEYNBSGIXOOZGZ-UHFFFAOYSA-L zinc;butoxymethanedithioate Chemical compound [Zn+2].CCCCOC([S-])=S.CCCCOC([S-])=S NEYNBSGIXOOZGZ-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10437798P | 1998-10-15 | 1998-10-15 | |
| US104377P | 1998-10-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69919479D1 DE69919479D1 (de) | 2004-09-23 |
| DE69919479T2 true DE69919479T2 (de) | 2005-09-01 |
Family
ID=22300182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69919479T Expired - Fee Related DE69919479T2 (de) | 1998-10-15 | 1999-10-07 | Herstellung stärkehaltiger Kautschuke, Reife aus vulcanisiertem Gummi und hergestellter Gegenstand |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0995775B1 (enExample) |
| JP (1) | JP2000119444A (enExample) |
| KR (1) | KR100569519B1 (enExample) |
| CN (1) | CN1222568C (enExample) |
| BR (1) | BR9904447A (enExample) |
| CA (1) | CA2282963A1 (enExample) |
| DE (1) | DE69919479T2 (enExample) |
| ES (1) | ES2227946T3 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2282629A1 (en) * | 1998-10-15 | 2000-04-15 | The Goodyear Tire & Rubber Company | Preparation of reinforced rubber and use in tires |
| US6528592B1 (en) * | 2000-09-14 | 2003-03-04 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains non-silane coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
| US6548578B2 (en) | 2001-02-20 | 2003-04-15 | Bridgestone/Firestone North American Tire, Llc | Vulcanizable elastomer compositions containing starch/styrene butadiene rubber copolymer as a reinforcing filler |
| KR100445835B1 (ko) * | 2001-05-25 | 2004-08-25 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 |
| KR100533266B1 (ko) * | 2002-05-24 | 2005-12-05 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 |
| US20040024093A1 (en) * | 2002-07-30 | 2004-02-05 | Marc Weydert | Starch composite reinforced rubber composition and tire with at least one component thereof |
| JP4633471B2 (ja) * | 2002-12-19 | 2011-02-16 | ソシエテ ド テクノロジー ミシュラン | 補強アルミノシリケートに基づくタイヤゴム組成物 |
| EP1514900B1 (en) * | 2003-09-12 | 2007-12-05 | The Goodyear Tire & Rubber Company | Farm tire with tread of rubber composition containing starch/plasticizer composite |
| KR100526256B1 (ko) * | 2004-04-01 | 2005-11-08 | 한국타이어 주식회사 | 타이어 백색 사이드월용 고무 조성물 |
| JP2007039585A (ja) | 2005-08-04 | 2007-02-15 | Sumitomo Rubber Ind Ltd | ゴム組成物およびこれを用いた空気入りタイヤ |
| KR100829358B1 (ko) * | 2006-03-09 | 2008-05-13 | 주식회사 엘지화학 | 투명 ａｂｓ계 열가소성 수지 조성물 |
| US7833341B2 (en) * | 2007-06-07 | 2010-11-16 | Shell Oil Company | Modified sulphur and product comprising modified sulphur as binder |
| JP5294047B2 (ja) * | 2007-10-18 | 2013-09-18 | 住友ゴム工業株式会社 | トレッド用ゴム組成物、トレッドおよびタイヤ |
| FR2927084B1 (fr) * | 2008-02-01 | 2011-02-25 | Roquette Freres | Procede de preparation de compositions thermoplastiques a base d'amidon plastifie et compositions ainsi obtenues. |
| FR2927088B1 (fr) * | 2008-02-01 | 2011-02-25 | Roquette Freres | Compositions thermoplastiques a base d'amidon plastifie et procede de preparation de telles compositions. |
| US20110119719A1 (en) * | 2009-11-13 | 2011-05-19 | Echostar Technologies L.L.C. | Mosaic Application for Generating Output Utilizing Content from Multiple Television Receivers |
| KR101141490B1 (ko) * | 2010-01-05 | 2012-05-03 | 금호타이어 주식회사 | 타이어용 고무조성물 및 이를 이용하여 제조된 타이어 |
| US9273195B2 (en) * | 2010-06-29 | 2016-03-01 | Eastman Chemical Company | Tires comprising cellulose ester/elastomer compositions |
| US9708474B2 (en) | 2011-12-07 | 2017-07-18 | Eastman Chemical Company | Cellulose esters in pneumatic tires |
| JP6026902B2 (ja) * | 2013-01-30 | 2016-11-16 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| CN104861219A (zh) * | 2014-02-25 | 2015-08-26 | 淮安智祥科技有限公司 | 一种橡胶复合材料及其制备方法 |
| DE102014209226A1 (de) * | 2014-05-15 | 2015-11-19 | Evonik Degussa Gmbh | Harnstoffhaltige Silane, Verfahren zu deren Herstellung und deren Verwendung |
| CN104403133A (zh) * | 2014-11-29 | 2015-03-11 | 安徽同丰橡塑工业有限公司 | 一种高强度橡胶复合材料制备方法 |
| US10077343B2 (en) | 2016-01-21 | 2018-09-18 | Eastman Chemical Company | Process to produce elastomeric compositions comprising cellulose ester additives |
| US10030127B2 (en) | 2016-03-16 | 2018-07-24 | Bridgestone Americas Tire Operations, Llc | Starch pre-blend, starch-filled rubber composition, and related processes |
| KR102000728B1 (ko) | 2016-09-09 | 2019-07-22 | 주식회사 엘지화학 | 알루미노실리케이트 입자를 포함한 고무 보강재 및 이를 포함한 타이어용 고무 조성물 |
| KR102060640B1 (ko) | 2016-09-09 | 2019-12-30 | 주식회사 엘지화학 | 알루미노실리케이트 입자를 포함한 고무 보강재 및 이를 포함한 타이어용 고무 조성물 |
| JP6848490B2 (ja) * | 2017-02-02 | 2021-03-24 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| WO2018206787A1 (de) * | 2017-05-12 | 2018-11-15 | Lanxess Deutschland Gmbh | Kautschukmischungen enthaltend schwefelhaltige organosiliciumverbindungen |
| CN114786739B (zh) | 2019-12-16 | 2023-10-31 | 固特异轮胎和橡胶公司 | 二氧化硅涂覆的淀粉 |
| CN118812931B (zh) * | 2024-07-26 | 2025-02-28 | 佛山市大唐新新橡塑有限公司 | 一种高弹性橡胶及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5672639A (en) * | 1996-03-12 | 1997-09-30 | The Goodyear Tire & Rubber Company | Starch composite reinforced rubber composition and tire with at least one component thereof |
-
1999
- 1999-09-16 CA CA002282963A patent/CA2282963A1/en not_active Abandoned
- 1999-10-05 BR BR9904447-1A patent/BR9904447A/pt not_active Application Discontinuation
- 1999-10-07 DE DE69919479T patent/DE69919479T2/de not_active Expired - Fee Related
- 1999-10-07 EP EP99119826A patent/EP0995775B1/en not_active Expired - Lifetime
- 1999-10-07 ES ES99119826T patent/ES2227946T3/es not_active Expired - Lifetime
- 1999-10-13 JP JP11290716A patent/JP2000119444A/ja active Pending
- 1999-10-14 KR KR1019990044508A patent/KR100569519B1/ko not_active Expired - Fee Related
- 1999-10-15 CN CNB991213890A patent/CN1222568C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0995775A1 (en) | 2000-04-26 |
| CN1251374A (zh) | 2000-04-26 |
| JP2000119444A (ja) | 2000-04-25 |
| BR9904447A (pt) | 2000-08-15 |
| DE69919479D1 (de) | 2004-09-23 |
| ES2227946T3 (es) | 2005-04-01 |
| CN1222568C (zh) | 2005-10-12 |
| CA2282963A1 (en) | 2000-04-15 |
| KR20000029071A (ko) | 2000-05-25 |
| KR100569519B1 (ko) | 2006-04-07 |
| EP0995775B1 (en) | 2004-08-18 |
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