DE69834390T2 - Polykristalline keramik auf basis von beta-und beta''-aluminiumoxid und gallaten sowie deren herstellung durch ein gasphasenverfahren - Google Patents
Polykristalline keramik auf basis von beta-und beta''-aluminiumoxid und gallaten sowie deren herstellung durch ein gasphasenverfahren Download PDFInfo
- Publication number
- DE69834390T2 DE69834390T2 DE69834390T DE69834390T DE69834390T2 DE 69834390 T2 DE69834390 T2 DE 69834390T2 DE 69834390 T DE69834390 T DE 69834390T DE 69834390 T DE69834390 T DE 69834390T DE 69834390 T2 DE69834390 T2 DE 69834390T2
- Authority
- DE
- Germany
- Prior art keywords
- alumina
- alkali metal
- ceramic
- sodium
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 54
- 239000000919 ceramic Substances 0.000 title claims description 42
- 230000008569 process Effects 0.000 title claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 118
- 239000011734 sodium Substances 0.000 claims description 59
- 229910052760 oxygen Inorganic materials 0.000 claims description 55
- 239000001301 oxygen Substances 0.000 claims description 52
- 229910052783 alkali metal Inorganic materials 0.000 claims description 51
- 150000001340 alkali metals Chemical class 0.000 claims description 49
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 46
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 46
- 229910052708 sodium Inorganic materials 0.000 claims description 44
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 42
- 239000002131 composite material Substances 0.000 claims description 39
- 239000010416 ion conductor Substances 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 26
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 19
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 18
- 229910052700 potassium Inorganic materials 0.000 claims description 17
- 239000011591 potassium Substances 0.000 claims description 17
- -1 oxygen ion Chemical class 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 12
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 11
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 claims description 10
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 9
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 9
- RPMPQTVHEJVLCR-UHFFFAOYSA-N pentaaluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3] RPMPQTVHEJVLCR-UHFFFAOYSA-N 0.000 claims description 9
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 7
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 5
- 241000588731 Hafnia Species 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052792 caesium Inorganic materials 0.000 claims description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 4
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 4
- 229910052701 rubidium Inorganic materials 0.000 claims description 4
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 4
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims 2
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 claims 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims 1
- 229910000449 hafnium oxide Inorganic materials 0.000 claims 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims 1
- 229910001950 potassium oxide Inorganic materials 0.000 claims 1
- 238000009792 diffusion process Methods 0.000 description 18
- 239000012071 phase Substances 0.000 description 14
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000003792 electrolyte Substances 0.000 description 9
- 239000004020 conductor Substances 0.000 description 7
- 229910001415 sodium ion Inorganic materials 0.000 description 7
- 229910001195 gallium oxide Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000000462 isostatic pressing Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000000879 optical micrograph Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 239000010987 cubic zirconia Substances 0.000 description 1
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000001093 holography Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical class [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/111—Fine ceramics
- C04B35/113—Fine ceramics based on beta-aluminium oxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Secondary Cells (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/002,483 US6117807A (en) | 1998-01-02 | 1998-01-02 | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
| US2483 | 1998-01-02 | ||
| PCT/US1998/027859 WO1999035104A1 (en) | 1998-01-02 | 1998-12-31 | ALKALI-METAL-β-AND $G(b)''-ALUMINA AND GALLATE POLYCRYSTALLINE CERAMICS AND FABRICATION BY A VAPOR PHASE METHOD |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69834390D1 DE69834390D1 (de) | 2006-06-08 |
| DE69834390T2 true DE69834390T2 (de) | 2006-09-07 |
Family
ID=21700991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69834390T Expired - Lifetime DE69834390T2 (de) | 1998-01-02 | 1998-12-31 | Polykristalline keramik auf basis von beta-und beta''-aluminiumoxid und gallaten sowie deren herstellung durch ein gasphasenverfahren |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US6117807A (enExample) |
| EP (1) | EP0973700B1 (enExample) |
| JP (1) | JP4434321B2 (enExample) |
| AU (1) | AU2099299A (enExample) |
| DE (1) | DE69834390T2 (enExample) |
| WO (1) | WO1999035104A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6117807A (en) | 1998-01-02 | 2000-09-12 | Materials And Systems Research, Inc. | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
| FR2799194B1 (fr) | 1999-10-05 | 2001-12-14 | Corning Sa | Billes d'un fluorure d'alcalin ou d'alcalino-terreux polycristallin, leur preparation et leur utilisation pour preparer des monocristaux |
| GB2421238A (en) | 2004-12-16 | 2006-06-21 | Basf Ag | Solid polycrystalline potassium ion conductor having beta-alumina structure |
| US20060213772A1 (en) * | 2005-03-22 | 2006-09-28 | Jain Kailash C | Sensing element and method of making |
| US20090233170A1 (en) * | 2006-12-19 | 2009-09-17 | General Electric Company | Energy storage device and method |
| US7632604B2 (en) * | 2006-12-19 | 2009-12-15 | General Electric Company | Energy storage device and method |
| CN102244304A (zh) * | 2006-12-19 | 2011-11-16 | 通用电气公司 | 铜基储能装置和方法 |
| US8110301B2 (en) * | 2006-12-19 | 2012-02-07 | General Electric Company | Energy storage device and cell configuration therefor |
| US20080145746A1 (en) * | 2006-12-19 | 2008-06-19 | General Electric Company | Copper-based energy storage device and method |
| US20090291365A1 (en) * | 2006-12-19 | 2009-11-26 | General Electric Company | Energy storage device and method |
| US9073773B2 (en) | 2011-03-11 | 2015-07-07 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory object, glass overflow forming block, and process for glass object manufacture |
| CN103261118A (zh) | 2011-03-30 | 2013-08-21 | 圣戈本陶瓷及塑料股份有限公司 | 耐火物体、玻璃溢流形成块、以及形成和使用该耐火物体的方法 |
| EP2697177B1 (en) | 2011-04-13 | 2020-11-18 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory object including beta alumina and processes of making and using the same |
| US9634353B2 (en) | 2011-11-08 | 2017-04-25 | Na4B, Llc | Low internal resistance beta—and beta″—alumina electrolyte produced via vapor phase method |
| KR102223591B1 (ko) | 2012-01-11 | 2021-03-08 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 내화체 및 내화체를 이용한 유리판 성형방법 |
| KR101669112B1 (ko) * | 2012-05-08 | 2016-10-25 | 삼성에스디아이 주식회사 | 복합 금속 전구체, 이로부터 형성된 양극 활물질, 이를 포함하는 리튬 이차 전지용 양극 및 이를 구비한 리튬 이차 전지 |
| WO2013177088A1 (en) * | 2012-05-23 | 2013-11-28 | Materials And Systems Research, Inc. | Porous metal supported thin film sodium ion conducting solid state electrolyte |
| JP2014025875A (ja) * | 2012-07-30 | 2014-02-06 | Nippon Steel & Sumitomo Metal | セシウム分圧測定装置及びセシウム分圧測定方法 |
| US9054394B2 (en) * | 2013-06-28 | 2015-06-09 | Dynantis Corporation | Secondary alkali metal/oxygen batteries |
| US20150017490A1 (en) | 2013-07-09 | 2015-01-15 | Material and Systems Research, Inc. | Planar alkali metal-beta battery |
| US11145894B2 (en) | 2014-08-21 | 2021-10-12 | Battelle Memorial Institute | Process for fabrication of enhanced β″-alumina solid electrolytes for energy storage devices and energy applications |
| WO2016138111A1 (en) | 2015-02-24 | 2016-09-01 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory article and method of making |
| WO2018031689A1 (en) * | 2016-08-10 | 2018-02-15 | The Board Of Trustees Of The Leland Stanford Junior University | Near ambient temperature, high potential secondary battery with liquid electrode materials separated by a solid electrolyte |
| JP6959788B2 (ja) * | 2017-08-03 | 2021-11-05 | 東京窯業株式会社 | ガスセンサ |
| KR102191515B1 (ko) * | 2018-12-28 | 2020-12-15 | 경상대학교산학협력단 | 나트륨 이차 전지용 고체 전해질, 이의 제조 방법 및 이를 포함하는 나트륨 이차 전지 |
| US11515564B2 (en) | 2019-09-04 | 2022-11-29 | The Regents Of The University Of Michigan | Surface treatment of a solid electrolyte to lower the interfacial resistance between the solid electrolyte and an electrode |
| KR102836793B1 (ko) * | 2023-02-21 | 2025-07-18 | 건국대학교 산학협력단 | 기상 전환법에 의한 나트륨 고체 전해질의 제조 방법, 나트륨 고체 전해질 및 나트륨 고체 전해질 제조용 적층체 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS502607B1 (enExample) * | 1968-08-10 | 1975-01-28 | ||
| US3707589A (en) * | 1971-04-13 | 1972-12-26 | Toyoda Chuo Kenkyusho Kk | Reheating a beta-alumina article in an alkali metal atmosphere to improve its permeability |
| US4263381A (en) * | 1978-10-27 | 1981-04-21 | The United States Of America As Represented By The United States Department Of Energy | Sintering of beta-type alumina bodies using alpha-alumina encapsulation |
| US4294898A (en) * | 1980-05-05 | 1981-10-13 | International Business Machines Corporation | Solid state battery |
| US4358516A (en) * | 1981-10-16 | 1982-11-09 | Rockwell International Corporation | Sodium ion conductor, solid electrolyte strengthened with zirconia |
| GB2131410A (en) * | 1982-12-06 | 1984-06-20 | Chloride Silent Power Ltd | Beta-alumina material |
| AU570018B2 (en) * | 1982-12-06 | 1988-03-03 | Chloride Silent Power Ltd. | Sodium beta alumina electrolyte element |
| US5137853A (en) * | 1990-08-13 | 1992-08-11 | Ngk Insulators, Ltd. | Beta alumina sintered body and method of manufacturing the same |
| US5137852A (en) * | 1991-01-11 | 1992-08-11 | Rockwell International Corp. | High temperature ceramic composites |
| JPH0526841A (ja) * | 1991-07-03 | 1993-02-02 | Toray Ind Inc | ナトリウム・硫黄センサ |
| JPH05208863A (ja) * | 1991-12-06 | 1993-08-20 | Sumitomo Chem Co Ltd | 固体電解質用高密度焼結体の製造方法 |
| US5415127A (en) * | 1993-07-07 | 1995-05-16 | Ontario Centre For Materials Research | Method of forming a single crystal film of sodium-beta "-alumina |
| US6117807A (en) * | 1998-01-02 | 2000-09-12 | Materials And Systems Research, Inc. | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
-
1998
- 1998-01-02 US US09/002,483 patent/US6117807A/en not_active Expired - Lifetime
- 1998-12-31 JP JP53619699A patent/JP4434321B2/ja not_active Expired - Fee Related
- 1998-12-31 AU AU20992/99A patent/AU2099299A/en not_active Abandoned
- 1998-12-31 DE DE69834390T patent/DE69834390T2/de not_active Expired - Lifetime
- 1998-12-31 WO PCT/US1998/027859 patent/WO1999035104A1/en not_active Ceased
- 1998-12-31 EP EP98965549A patent/EP0973700B1/en not_active Expired - Lifetime
-
2000
- 2000-08-10 US US09/636,157 patent/US6537940B1/en not_active Expired - Lifetime
-
2002
- 2002-12-02 US US10/308,652 patent/US6632763B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0973700A4 (en) | 2003-01-02 |
| AU2099299A (en) | 1999-07-26 |
| US20030087752A1 (en) | 2003-05-08 |
| EP0973700B1 (en) | 2006-05-03 |
| US6632763B2 (en) | 2003-10-14 |
| DE69834390D1 (de) | 2006-06-08 |
| EP0973700A1 (en) | 2000-01-26 |
| JP4434321B2 (ja) | 2010-03-17 |
| US6537940B1 (en) | 2003-03-25 |
| JP2001515454A (ja) | 2001-09-18 |
| US6117807A (en) | 2000-09-12 |
| WO1999035104A1 (en) | 1999-07-15 |
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