JP4434321B2 - アルカリ金属イオン伝導体の連続相とセラミック酸素イオン伝導体の連続相とを含むセラミック複合体及び当該セラミック複合体の形成方法 - Google Patents
アルカリ金属イオン伝導体の連続相とセラミック酸素イオン伝導体の連続相とを含むセラミック複合体及び当該セラミック複合体の形成方法 Download PDFInfo
- Publication number
- JP4434321B2 JP4434321B2 JP53619699A JP53619699A JP4434321B2 JP 4434321 B2 JP4434321 B2 JP 4434321B2 JP 53619699 A JP53619699 A JP 53619699A JP 53619699 A JP53619699 A JP 53619699A JP 4434321 B2 JP4434321 B2 JP 4434321B2
- Authority
- JP
- Japan
- Prior art keywords
- ceramic
- alkali metal
- alumina
- composite
- oxygen ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000919 ceramic Substances 0.000 title claims description 55
- 239000001301 oxygen Substances 0.000 title claims description 54
- 229910052760 oxygen Inorganic materials 0.000 title claims description 54
- 239000002131 composite material Substances 0.000 title claims description 39
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 35
- 239000010416 ion conductor Substances 0.000 title claims description 32
- 229910001413 alkali metal ion Inorganic materials 0.000 title claims 15
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 46
- 239000011734 sodium Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- 239000003513 alkali Substances 0.000 claims description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 19
- -1 oxygen ion Chemical class 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000012071 phase Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 14
- 238000005245 sintering Methods 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 9
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 9
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims description 5
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 claims description 4
- 241000588731 Hafnia Species 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 claims description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 3
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052701 rubidium Inorganic materials 0.000 claims description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 3
- 241000968352 Scandia <hydrozoan> Species 0.000 claims description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- HJGMWXTVGKLUAQ-UHFFFAOYSA-N oxygen(2-);scandium(3+) Chemical compound [O-2].[O-2].[O-2].[Sc+3].[Sc+3] HJGMWXTVGKLUAQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910018068 Li 2 O Inorganic materials 0.000 claims 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 72
- 238000006243 chemical reaction Methods 0.000 description 35
- RPMPQTVHEJVLCR-UHFFFAOYSA-N pentaaluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3] RPMPQTVHEJVLCR-UHFFFAOYSA-N 0.000 description 20
- 238000009792 diffusion process Methods 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000003792 electrolyte Substances 0.000 description 9
- 239000004020 conductor Substances 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 229910001195 gallium oxide Inorganic materials 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 4
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 229910001948 sodium oxide Inorganic materials 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007723 die pressing method Methods 0.000 description 2
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000879 optical micrograph Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001093 holography Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/111—Fine ceramics
- C04B35/113—Fine ceramics based on beta-aluminium oxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Secondary Cells (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/002,483 US6117807A (en) | 1998-01-02 | 1998-01-02 | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
| US09/002,483 | 1998-01-02 | ||
| PCT/US1998/027859 WO1999035104A1 (en) | 1998-01-02 | 1998-12-31 | ALKALI-METAL-β-AND $G(b)''-ALUMINA AND GALLATE POLYCRYSTALLINE CERAMICS AND FABRICATION BY A VAPOR PHASE METHOD |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001515454A JP2001515454A (ja) | 2001-09-18 |
| JP2001515454A5 JP2001515454A5 (enExample) | 2006-04-13 |
| JP4434321B2 true JP4434321B2 (ja) | 2010-03-17 |
Family
ID=21700991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53619699A Expired - Fee Related JP4434321B2 (ja) | 1998-01-02 | 1998-12-31 | アルカリ金属イオン伝導体の連続相とセラミック酸素イオン伝導体の連続相とを含むセラミック複合体及び当該セラミック複合体の形成方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US6117807A (enExample) |
| EP (1) | EP0973700B1 (enExample) |
| JP (1) | JP4434321B2 (enExample) |
| AU (1) | AU2099299A (enExample) |
| DE (1) | DE69834390T2 (enExample) |
| WO (1) | WO1999035104A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6117807A (en) | 1998-01-02 | 2000-09-12 | Materials And Systems Research, Inc. | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
| FR2799194B1 (fr) | 1999-10-05 | 2001-12-14 | Corning Sa | Billes d'un fluorure d'alcalin ou d'alcalino-terreux polycristallin, leur preparation et leur utilisation pour preparer des monocristaux |
| GB2421238A (en) | 2004-12-16 | 2006-06-21 | Basf Ag | Solid polycrystalline potassium ion conductor having beta-alumina structure |
| US20060213772A1 (en) * | 2005-03-22 | 2006-09-28 | Jain Kailash C | Sensing element and method of making |
| US20090233170A1 (en) * | 2006-12-19 | 2009-09-17 | General Electric Company | Energy storage device and method |
| US7632604B2 (en) * | 2006-12-19 | 2009-12-15 | General Electric Company | Energy storage device and method |
| CN102244304A (zh) * | 2006-12-19 | 2011-11-16 | 通用电气公司 | 铜基储能装置和方法 |
| US8110301B2 (en) * | 2006-12-19 | 2012-02-07 | General Electric Company | Energy storage device and cell configuration therefor |
| US20080145746A1 (en) * | 2006-12-19 | 2008-06-19 | General Electric Company | Copper-based energy storage device and method |
| US20090291365A1 (en) * | 2006-12-19 | 2009-11-26 | General Electric Company | Energy storage device and method |
| US9073773B2 (en) | 2011-03-11 | 2015-07-07 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory object, glass overflow forming block, and process for glass object manufacture |
| CN103261118A (zh) | 2011-03-30 | 2013-08-21 | 圣戈本陶瓷及塑料股份有限公司 | 耐火物体、玻璃溢流形成块、以及形成和使用该耐火物体的方法 |
| EP2697177B1 (en) | 2011-04-13 | 2020-11-18 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory object including beta alumina and processes of making and using the same |
| US9634353B2 (en) | 2011-11-08 | 2017-04-25 | Na4B, Llc | Low internal resistance beta—and beta″—alumina electrolyte produced via vapor phase method |
| KR102223591B1 (ko) | 2012-01-11 | 2021-03-08 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 내화체 및 내화체를 이용한 유리판 성형방법 |
| KR101669112B1 (ko) * | 2012-05-08 | 2016-10-25 | 삼성에스디아이 주식회사 | 복합 금속 전구체, 이로부터 형성된 양극 활물질, 이를 포함하는 리튬 이차 전지용 양극 및 이를 구비한 리튬 이차 전지 |
| WO2013177088A1 (en) * | 2012-05-23 | 2013-11-28 | Materials And Systems Research, Inc. | Porous metal supported thin film sodium ion conducting solid state electrolyte |
| JP2014025875A (ja) * | 2012-07-30 | 2014-02-06 | Nippon Steel & Sumitomo Metal | セシウム分圧測定装置及びセシウム分圧測定方法 |
| US9054394B2 (en) * | 2013-06-28 | 2015-06-09 | Dynantis Corporation | Secondary alkali metal/oxygen batteries |
| US20150017490A1 (en) | 2013-07-09 | 2015-01-15 | Material and Systems Research, Inc. | Planar alkali metal-beta battery |
| US11145894B2 (en) | 2014-08-21 | 2021-10-12 | Battelle Memorial Institute | Process for fabrication of enhanced β″-alumina solid electrolytes for energy storage devices and energy applications |
| WO2016138111A1 (en) | 2015-02-24 | 2016-09-01 | Saint-Gobain Ceramics & Plastics, Inc. | Refractory article and method of making |
| WO2018031689A1 (en) * | 2016-08-10 | 2018-02-15 | The Board Of Trustees Of The Leland Stanford Junior University | Near ambient temperature, high potential secondary battery with liquid electrode materials separated by a solid electrolyte |
| JP6959788B2 (ja) * | 2017-08-03 | 2021-11-05 | 東京窯業株式会社 | ガスセンサ |
| KR102191515B1 (ko) * | 2018-12-28 | 2020-12-15 | 경상대학교산학협력단 | 나트륨 이차 전지용 고체 전해질, 이의 제조 방법 및 이를 포함하는 나트륨 이차 전지 |
| US11515564B2 (en) | 2019-09-04 | 2022-11-29 | The Regents Of The University Of Michigan | Surface treatment of a solid electrolyte to lower the interfacial resistance between the solid electrolyte and an electrode |
| KR102836793B1 (ko) * | 2023-02-21 | 2025-07-18 | 건국대학교 산학협력단 | 기상 전환법에 의한 나트륨 고체 전해질의 제조 방법, 나트륨 고체 전해질 및 나트륨 고체 전해질 제조용 적층체 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS502607B1 (enExample) * | 1968-08-10 | 1975-01-28 | ||
| US3707589A (en) * | 1971-04-13 | 1972-12-26 | Toyoda Chuo Kenkyusho Kk | Reheating a beta-alumina article in an alkali metal atmosphere to improve its permeability |
| US4263381A (en) * | 1978-10-27 | 1981-04-21 | The United States Of America As Represented By The United States Department Of Energy | Sintering of beta-type alumina bodies using alpha-alumina encapsulation |
| US4294898A (en) * | 1980-05-05 | 1981-10-13 | International Business Machines Corporation | Solid state battery |
| US4358516A (en) * | 1981-10-16 | 1982-11-09 | Rockwell International Corporation | Sodium ion conductor, solid electrolyte strengthened with zirconia |
| GB2131410A (en) * | 1982-12-06 | 1984-06-20 | Chloride Silent Power Ltd | Beta-alumina material |
| AU570018B2 (en) * | 1982-12-06 | 1988-03-03 | Chloride Silent Power Ltd. | Sodium beta alumina electrolyte element |
| US5137853A (en) * | 1990-08-13 | 1992-08-11 | Ngk Insulators, Ltd. | Beta alumina sintered body and method of manufacturing the same |
| US5137852A (en) * | 1991-01-11 | 1992-08-11 | Rockwell International Corp. | High temperature ceramic composites |
| JPH0526841A (ja) * | 1991-07-03 | 1993-02-02 | Toray Ind Inc | ナトリウム・硫黄センサ |
| JPH05208863A (ja) * | 1991-12-06 | 1993-08-20 | Sumitomo Chem Co Ltd | 固体電解質用高密度焼結体の製造方法 |
| US5415127A (en) * | 1993-07-07 | 1995-05-16 | Ontario Centre For Materials Research | Method of forming a single crystal film of sodium-beta "-alumina |
| US6117807A (en) * | 1998-01-02 | 2000-09-12 | Materials And Systems Research, Inc. | Alkali-metal-β- and β"-alumina and gallate polycrystalline ceramics and fabrication by a vapor phase method |
-
1998
- 1998-01-02 US US09/002,483 patent/US6117807A/en not_active Expired - Lifetime
- 1998-12-31 JP JP53619699A patent/JP4434321B2/ja not_active Expired - Fee Related
- 1998-12-31 AU AU20992/99A patent/AU2099299A/en not_active Abandoned
- 1998-12-31 DE DE69834390T patent/DE69834390T2/de not_active Expired - Lifetime
- 1998-12-31 WO PCT/US1998/027859 patent/WO1999035104A1/en not_active Ceased
- 1998-12-31 EP EP98965549A patent/EP0973700B1/en not_active Expired - Lifetime
-
2000
- 2000-08-10 US US09/636,157 patent/US6537940B1/en not_active Expired - Lifetime
-
2002
- 2002-12-02 US US10/308,652 patent/US6632763B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0973700A4 (en) | 2003-01-02 |
| AU2099299A (en) | 1999-07-26 |
| US20030087752A1 (en) | 2003-05-08 |
| EP0973700B1 (en) | 2006-05-03 |
| DE69834390T2 (de) | 2006-09-07 |
| US6632763B2 (en) | 2003-10-14 |
| DE69834390D1 (de) | 2006-06-08 |
| EP0973700A1 (en) | 2000-01-26 |
| US6537940B1 (en) | 2003-03-25 |
| JP2001515454A (ja) | 2001-09-18 |
| US6117807A (en) | 2000-09-12 |
| WO1999035104A1 (en) | 1999-07-15 |
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