DE69823013T2 - Verfahren zum katalytischen cracken - Google Patents
Verfahren zum katalytischen cracken Download PDFInfo
- Publication number
- DE69823013T2 DE69823013T2 DE69823013T DE69823013T DE69823013T2 DE 69823013 T2 DE69823013 T2 DE 69823013T2 DE 69823013 T DE69823013 T DE 69823013T DE 69823013 T DE69823013 T DE 69823013T DE 69823013 T2 DE69823013 T2 DE 69823013T2
- Authority
- DE
- Germany
- Prior art keywords
- zsm
- zeolite
- catalyst
- phosphorus
- additional component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 238000000034 method Methods 0.000 title claims description 32
- 238000004523 catalytic cracking Methods 0.000 title description 10
- 239000003054 catalyst Substances 0.000 claims description 44
- 239000010457 zeolite Substances 0.000 claims description 42
- 229910021536 Zeolite Inorganic materials 0.000 claims description 38
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 38
- 239000011148 porous material Substances 0.000 claims description 33
- 229910052698 phosphorus Inorganic materials 0.000 claims description 27
- 239000011574 phosphorus Substances 0.000 claims description 27
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 239000013078 crystal Substances 0.000 claims description 20
- 238000005336 cracking Methods 0.000 claims description 18
- 150000002430 hydrocarbons Chemical class 0.000 claims description 17
- 239000002808 molecular sieve Substances 0.000 claims description 15
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 238000004231 fluid catalytic cracking Methods 0.000 claims description 12
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- 230000009849 deactivation Effects 0.000 claims 1
- 239000000463 material Substances 0.000 description 19
- 238000009835 boiling Methods 0.000 description 11
- 239000003921 oil Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- -1 C 3 -C 5 olefins Chemical class 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000004927 clay Substances 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 239000007900 aqueous suspension Substances 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- 241000640882 Condea Species 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 108090000765 processed proteins & peptides Proteins 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 150000003463 sulfur Chemical class 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- BEQVQKJCLJBTKZ-UHFFFAOYSA-N diphenylphosphinic acid Chemical compound C=1C=CC=CC=1P(=O)(O)C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 2
- MNZAKDODWSQONA-UHFFFAOYSA-N 1-dibutylphosphorylbutane Chemical compound CCCCP(=O)(CCCC)CCCC MNZAKDODWSQONA-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical group O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- OOSPDKSZPPFOBR-UHFFFAOYSA-N butyl dihydrogen phosphite Chemical compound CCCCOP(O)O OOSPDKSZPPFOBR-UHFFFAOYSA-N 0.000 description 1
- DLIJPAHLBJIQHE-UHFFFAOYSA-N butylphosphane Chemical compound CCCCP DLIJPAHLBJIQHE-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- KMJJJTCKNZYTEY-UHFFFAOYSA-N chloro-diethoxy-sulfanylidene-$l^{5}-phosphane Chemical compound CCOP(Cl)(=S)OCC KMJJJTCKNZYTEY-UHFFFAOYSA-N 0.000 description 1
- XGRJZXREYAXTGV-UHFFFAOYSA-N chlorodiphenylphosphine Chemical compound C=1C=CC=CC=1P(Cl)C1=CC=CC=C1 XGRJZXREYAXTGV-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- RDXABLXNTVBVML-UHFFFAOYSA-N diethoxyphosphanyl diethyl phosphite Chemical compound CCOP(OCC)OP(OCC)OCC RDXABLXNTVBVML-UHFFFAOYSA-N 0.000 description 1
- KTLIMPGQZDZPSB-UHFFFAOYSA-N diethylphosphinic acid Chemical compound CCP(O)(=O)CC KTLIMPGQZDZPSB-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- VZRHEACAPBMOMA-UHFFFAOYSA-N dioxosilane oxygen(2-) thorium(4+) Chemical compound [O-2].[Th+4].[Si](=O)=O.[O-2] VZRHEACAPBMOMA-UHFFFAOYSA-N 0.000 description 1
- AZRCNKIZGKJWOA-UHFFFAOYSA-N dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4].O=[Si]=O AZRCNKIZGKJWOA-UHFFFAOYSA-N 0.000 description 1
- TVUBDAUPRIFHFN-UHFFFAOYSA-N dioxosilane;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4].O=[Si]=O TVUBDAUPRIFHFN-UHFFFAOYSA-N 0.000 description 1
- NFORZJQPTUSMRL-UHFFFAOYSA-N dipropan-2-yl hydrogen phosphite Chemical compound CC(C)OP(O)OC(C)C NFORZJQPTUSMRL-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- OJLGDNQSVQHXJH-UHFFFAOYSA-N magnesium dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[Zr+4].[Mg+2].[Si](=O)=O.[O-2].[O-2] OJLGDNQSVQHXJH-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- WSANLGASBHUYGD-UHFFFAOYSA-N sulfidophosphanium Chemical group S=[PH3] WSANLGASBHUYGD-UHFFFAOYSA-N 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/819,900 US5888378A (en) | 1997-03-18 | 1997-03-18 | Catalytic cracking process |
| US819900 | 1997-03-18 | ||
| PCT/US1998/003057 WO1998041595A1 (en) | 1997-03-18 | 1998-02-18 | Catalytic cracking process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69823013D1 DE69823013D1 (de) | 2004-05-13 |
| DE69823013T2 true DE69823013T2 (de) | 2004-08-12 |
Family
ID=25229381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69823013T Revoked DE69823013T2 (de) | 1997-03-18 | 1998-02-18 | Verfahren zum katalytischen cracken |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5888378A (enExample) |
| EP (1) | EP0968256B1 (enExample) |
| JP (1) | JP2001517255A (enExample) |
| AU (1) | AU741417B2 (enExample) |
| CA (1) | CA2281534C (enExample) |
| DE (1) | DE69823013T2 (enExample) |
| ES (1) | ES2215291T3 (enExample) |
| WO (1) | WO1998041595A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6294081B1 (en) | 1998-05-26 | 2001-09-25 | Exxonmobil Chemical Patents, Inc. | Hydroprocessing with catalytic silicoaluminophosphates having an AEL structure |
| US6180550B1 (en) | 1998-12-22 | 2001-01-30 | Mobile Oil Corporation | Small crystal ZSM-5, its synthesis and use |
| US20020003103A1 (en) * | 1998-12-30 | 2002-01-10 | B. Erik Henry | Fluid cat cracking with high olefins prouduction |
| US20020049133A1 (en) * | 1999-03-02 | 2002-04-25 | Michael S. Ziebarth | High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith |
| US6153089A (en) * | 1999-03-29 | 2000-11-28 | Indian Oil Corporation Limited | Upgradation of undesirable olefinic liquid hydrocarbon streams |
| FR2794116B1 (fr) * | 1999-05-11 | 2001-07-20 | Inst Francais Du Petrole | Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique |
| IT1314190B1 (it) | 1999-10-18 | 2002-12-06 | Eni Spa | Processo per preparare 2,6-dimetilnaftalene |
| EP1116775A1 (en) | 2000-01-12 | 2001-07-18 | Akzo Nobel N.V. | Catalyst composition with high efficiency for the production of light olefins |
| US6797155B1 (en) * | 1999-12-21 | 2004-09-28 | Exxonmobil Research & Engineering Co. | Catalytic cracking process using a modified mesoporous aluminophosphate material |
| US6884744B2 (en) | 2001-04-13 | 2005-04-26 | W. R. Grace & Co.-Conn. | Zeolite based catalyst of ultra-high kinetic conversion activity |
| CN1248994C (zh) * | 2001-07-02 | 2006-04-05 | 埃克森美孚化学专利公司 | 在烯烃生产中抑制催化剂焦炭形成 |
| US7425258B2 (en) * | 2003-02-28 | 2008-09-16 | Exxonmobil Research And Engineering Company | C6 recycle for propylene generation in a fluid catalytic cracking unit |
| US7267759B2 (en) * | 2003-02-28 | 2007-09-11 | Exxonmobil Research And Engineering Company | Fractionating and further cracking a C6 fraction from a naphtha feed for propylene generation |
| US7375048B2 (en) * | 2004-04-29 | 2008-05-20 | Basf Catalysts Llc | ZSM-5 additive |
| WO2006020547A1 (en) | 2004-08-10 | 2006-02-23 | Shell Internationale Research Maatschappij B.V. | Method and apparatus for making a middle distillate product and lower olefins from a hydrocarbon feedstock |
| US7582203B2 (en) | 2004-08-10 | 2009-09-01 | Shell Oil Company | Hydrocarbon cracking process for converting gas oil preferentially to middle distillate and lower olefins |
| AR052122A1 (es) | 2004-11-05 | 2007-03-07 | Grace W R & Co | Catalizadores para olefinas livianas y glp gas licuado de petroleo en unidades de craqueo catalitico fluidizado |
| CN100363465C (zh) * | 2004-12-28 | 2008-01-23 | 中国石油化工股份有限公司 | 一种提高液化气中丙烯浓度的催化裂化方法 |
| CN100351345C (zh) * | 2004-12-28 | 2007-11-28 | 中国石油化工股份有限公司 | 一种石油烃催化裂化方法 |
| CN100363466C (zh) * | 2004-12-28 | 2008-01-23 | 中国石油化工股份有限公司 | 一种催化裂化助剂 |
| US20090192125A1 (en) * | 2007-02-08 | 2009-07-30 | Dermworx Incorporated | Local anti-infective agent for treatment of nail fungal infections |
| US8920630B2 (en) * | 2007-04-13 | 2014-12-30 | Shell Oil Company | Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock |
| US20100200460A1 (en) * | 2007-04-30 | 2010-08-12 | Shell Oil Company | Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock |
| BRPI0705179B1 (pt) | 2007-10-10 | 2016-10-11 | Petróleo Brasileiro S A Petrobras | aditivo para maximizar olefinas leves em fcc e processo para preparação do mesmo |
| RU2474606C2 (ru) * | 2007-10-10 | 2013-02-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Системы и способы получения средних дистиллятов и низших олефинов из углеводородного сырья |
| BRPI0704422A2 (pt) | 2007-10-29 | 2009-06-23 | Petroleo Brasileiro Sa | sistema catalìtico e aditivo para maximização de olefinas leves em unidades de craqueamento catalìtico fluido em operações de baixa severidade |
| EP2696979B8 (en) * | 2011-04-13 | 2021-06-16 | Mard, Inc. | Improved catalyst for thermocatalytic conversion of biomass to liquid fuels and chemicals |
| BR112014001453A2 (pt) | 2011-07-21 | 2017-02-21 | Reliance Ind Ltd | aditivo catalizador e método de preparação do mesmo |
| US9227181B2 (en) | 2011-09-13 | 2016-01-05 | Basf Corporation | Catalyst to increase propylene yields from a fluid catalytic cracking unit |
| US20130131412A1 (en) * | 2011-11-18 | 2013-05-23 | Uop Llc | Resid catalytic cracker and catalyst for increased propylene yield |
| SG11201407659XA (en) | 2012-05-25 | 2014-12-30 | Saudi Arabian Oil Co | Catalyst for enhanced propylene in fluidized catalytic cracking |
| CA2897015C (en) * | 2013-01-23 | 2021-02-02 | Basf Corporation | Zsm-5 additive activity enhancement by improved zeolite and phosphorus interaction |
| WO2017015597A1 (en) | 2015-07-23 | 2017-01-26 | Albemarle Corporation | Fcc catalyst additive and binder |
| BR112018076987B1 (pt) | 2016-06-24 | 2022-05-03 | Albemarle Corporation | Zsm-22 mesoporoso para aumento da produção de propileno |
| US11964256B2 (en) | 2017-03-17 | 2024-04-23 | Ketjen Limited Liability Company | FCC catalyst additive with mixed alumina |
| US12168223B2 (en) | 2019-08-01 | 2024-12-17 | King Abdullah University Of Science And Technology | Metal carbide based catalyst and method of making |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4512875A (en) * | 1983-05-02 | 1985-04-23 | Union Carbide Corporation | Cracking of crude oils with carbon-hydrogen fragmentation compounds over non-zeolitic catalysts |
| US4828679A (en) * | 1984-03-12 | 1989-05-09 | Mobil Oil Corporation | Octane improvement with large size ZSM-5 catalytic cracking |
| US4601993A (en) * | 1984-05-25 | 1986-07-22 | Mobil Oil Corporation | Catalyst composition dewaxing of lubricating oils |
| GB9026775D0 (en) * | 1990-12-10 | 1991-01-30 | Shell Int Research | Process for the preparation of an olefins-containing mixture of hydrocarbons |
| US5110776A (en) * | 1991-03-12 | 1992-05-05 | Mobil Oil Corp. | Cracking catalysts containing phosphate treated zeolites, and method of preparing the same |
| US5308475A (en) * | 1992-11-23 | 1994-05-03 | Mobil Oil Corporation | Use of ZSM-12 in catalytic cracking for gasoline octane improvement and co-production of light olefins |
| US5470810A (en) * | 1994-02-02 | 1995-11-28 | Mobil Oil Corporation | Catalyst and method of manufacture |
| US5472594A (en) * | 1994-07-18 | 1995-12-05 | Texaco Inc. | FCC process for producing enhanced yields of C4 /C5 olefins |
-
1997
- 1997-03-18 US US08/819,900 patent/US5888378A/en not_active Expired - Lifetime
-
1998
- 1998-02-18 JP JP54050398A patent/JP2001517255A/ja not_active Ceased
- 1998-02-18 WO PCT/US1998/003057 patent/WO1998041595A1/en not_active Ceased
- 1998-02-18 CA CA002281534A patent/CA2281534C/en not_active Expired - Lifetime
- 1998-02-18 AU AU61714/98A patent/AU741417B2/en not_active Ceased
- 1998-02-18 ES ES98906504T patent/ES2215291T3/es not_active Expired - Lifetime
- 1998-02-18 DE DE69823013T patent/DE69823013T2/de not_active Revoked
- 1998-02-18 EP EP98906504A patent/EP0968256B1/en not_active Revoked
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998041595A1 (en) | 1998-09-24 |
| JP2001517255A (ja) | 2001-10-02 |
| US5888378A (en) | 1999-03-30 |
| EP0968256B1 (en) | 2004-04-07 |
| CA2281534A1 (en) | 1998-09-24 |
| ES2215291T3 (es) | 2004-10-01 |
| EP0968256A1 (en) | 2000-01-05 |
| AU6171498A (en) | 1998-10-12 |
| CA2281534C (en) | 2007-06-19 |
| DE69823013D1 (de) | 2004-05-13 |
| AU741417B2 (en) | 2001-11-29 |
| EP0968256A4 (en) | 2000-05-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69823013T2 (de) | Verfahren zum katalytischen cracken | |
| DE60013376T2 (de) | Katalysator mit hohem zeolith-anteil und hohem abreibungswiderstand, herstellungsverfahren und katalytische anwendungen | |
| US7615143B2 (en) | Hydrothermally stable catalyst and its use in catalytic cracking | |
| DE69201648T2 (de) | Katalysatorzusammensetzungen. | |
| US5456821A (en) | Catalytic conversion with improved catalyst | |
| US5366948A (en) | Catalyst and catalytic conversion therewith | |
| DE60021593T2 (de) | Reduktion des gasolin-schwefelgehaltes in einem katalytischen fluidkrackverfahren | |
| DE68905478T2 (de) | Verfahren zur herstellung eines zeolith-beta-kohlenwasserstoffumwandlungskatalysators. | |
| DE69904027T2 (de) | Erhöhung der wirkung eines zeolitischen katalysators mit aluminiumphosphat und phosphor | |
| RU2427424C2 (ru) | Композиция катализа, предназначенная для переработки тяжелого исходного сырья | |
| DE69816114T2 (de) | Herstellung von olefinen | |
| DE69734206T2 (de) | Selektive herstellung von p-xylol durch methylierung von toluol | |
| JP6133989B2 (ja) | 流動接触分解ユニットからプロピレン収率を増加するための新規触媒 | |
| DE2808103C3 (de) | Katalytisches Crackverfahren | |
| DE69828199T2 (de) | Verfahren zur herstellung eines molekularsieb enthaltenden katalysators | |
| KR101734633B1 (ko) | 유동상 접촉 분해에서 향상된 프로필렌용 촉매 | |
| DE69203254T2 (de) | Herstellung von Crackkatalysatoren und Crackverfahren mit diesen. | |
| DE19941319A1 (de) | Verringerung des Schwefelgehaltes von Benzin beim Fliessbettkracken | |
| DE4114874B4 (de) | Verfahren zum katalytischen Kracken in Anwesenheit eines Katalysators, der einen Zeolithen ZSM mit intermediären Porenöffnungen beinhaltet | |
| DE102011013908A1 (de) | Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen | |
| DE60020882T2 (de) | Verfahren zur Herstellung eines hitzebeständigen, mesoporösen Aluminophosphats mit hoher spezifischer Oberfläche | |
| DE69530492T2 (de) | Katalytisches krackverfahren mit mcm-49 | |
| EP0708807B1 (en) | Catalyst system and process for catalytic cracking | |
| DE69323325T2 (de) | Krackverfahren und dazu hergestellter zsm-5-katalysator | |
| KR20220025897A (ko) | 올레핀 수율을 증가시키기 위한 유동 분해 방법 및 이를 위한 촉매 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8331 | Complete revocation |