DE69819501T2 - Ruthenium und osmiumcarbenkatalysatoren - Google Patents

Ruthenium und osmiumcarbenkatalysatoren Download PDF

Info

Publication number
DE69819501T2
DE69819501T2 DE69819501T DE69819501T DE69819501T2 DE 69819501 T2 DE69819501 T2 DE 69819501T2 DE 69819501 T DE69819501 T DE 69819501T DE 69819501 T DE69819501 T DE 69819501T DE 69819501 T2 DE69819501 T2 DE 69819501T2
Authority
DE
Germany
Prior art keywords
tert
butyl
bis
alkyl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69819501T
Other languages
German (de)
English (en)
Other versions
DE69819501D1 (de
Inventor
Adriaan Paul VAN DER SCHAAF
Andreas Hafner
Andreas MÜHLEBACH
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of DE69819501D1 publication Critical patent/DE69819501D1/de
Application granted granted Critical
Publication of DE69819501T2 publication Critical patent/DE69819501T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
DE69819501T 1997-06-27 1998-06-20 Ruthenium und osmiumcarbenkatalysatoren Expired - Fee Related DE69819501T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH156297 1997-06-27
CH156297 1997-06-27
PCT/EP1998/003781 WO1999000397A1 (en) 1997-06-27 1998-06-20 Ruthenium and osmium catalysts

Publications (2)

Publication Number Publication Date
DE69819501D1 DE69819501D1 (de) 2003-12-11
DE69819501T2 true DE69819501T2 (de) 2004-09-23

Family

ID=4213330

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69819501T Expired - Fee Related DE69819501T2 (de) 1997-06-27 1998-06-20 Ruthenium und osmiumcarbenkatalysatoren

Country Status (11)

Country Link
US (1) US6306987B1 (enExample)
EP (1) EP0993466B1 (enExample)
JP (1) JP2002506455A (enExample)
KR (1) KR100569620B1 (enExample)
AU (1) AU8800498A (enExample)
BR (1) BR9810488A (enExample)
CA (1) CA2289709A1 (enExample)
DE (1) DE69819501T2 (enExample)
ES (1) ES2209185T3 (enExample)
MX (1) MX210210B (enExample)
WO (1) WO1999000397A1 (enExample)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6696597B2 (en) 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
US6900347B2 (en) 1998-09-01 2005-05-31 Tilliechem, Inc. Impurity inhibition in olefin metathesis reactions
US7507854B2 (en) 1998-09-01 2009-03-24 Materia, Inc. Impurity reduction in Olefin metathesis reactions
DE19840107A1 (de) * 1998-09-03 2000-03-09 Bayer Ag Verfahren zur Synthese alpha-substituierter Ringsysteme
IT1314204B1 (it) * 1999-10-28 2002-12-06 Sigea Srl Complessi di rutenio con elevata attivita' antitumorale
KR100869981B1 (ko) * 2001-03-26 2008-11-24 다우 글로벌 테크놀로지스 인크. 불포화 지방산 에스테르 또는 불포화 지방산과 저급 올레핀과의 상호교환반응
BRPI0212392B1 (pt) * 2001-08-30 2015-09-15 Materia Inc processo para preparação de um material poroso infundido com poliolefina e artigo manufaturado.
JP4138417B2 (ja) * 2001-09-28 2008-08-27 積水化学工業株式会社 有機金属化合物の合成方法
WO2003044060A2 (en) * 2001-11-15 2003-05-30 Materia, Inc. Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts
CN101172952B (zh) 2002-04-29 2013-03-27 陶氏环球技术有限责任公司 关于种子油工业应用的综合化学方法
WO2003093351A1 (en) * 2002-05-06 2003-11-13 Kerr Corporation Composition curable by metathesis reaction
US7683148B2 (en) 2003-05-06 2010-03-23 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7060770B2 (en) * 2003-05-06 2006-06-13 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7060769B2 (en) * 2003-05-06 2006-06-13 Kerr Corporation Method of curing composition by metathesis reaction using reaction control agent
US7173097B2 (en) 2003-05-06 2007-02-06 Kerr Corporation Metathesis-curable composition with a reaction control agent
DE602004014958D1 (de) 2003-10-09 2008-08-21 Dow Global Technologies Inc Verbessertes verfahren zur synthese ungesättigter alkohole
US7109344B2 (en) * 2003-12-04 2006-09-19 Boehringer Ingelheim International Gmbh Ruthenium catalyst
DE602004019973D1 (de) * 2003-12-08 2009-04-23 Boehringer Ingelheim Int Abtrennung von ruthenium-nebenprodukten durch behandlung mit überkritischen flüssigkeiten
DE102004002178A1 (de) 2004-01-15 2005-08-11 Ivoclar Vivadent Ag Dentalmeterialien auf der Basis von RÖMP-Kompositen
AU2011205218B2 (en) * 2004-03-29 2015-12-17 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
WO2005094345A2 (en) * 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand
US7625551B2 (en) * 2004-11-15 2009-12-01 Kerr Corporation Polyether-based dental impression material curable by metathesis reaction
US7001590B1 (en) 2004-11-15 2006-02-21 Kerr Corporation Metathesis-curable composition
US7645443B2 (en) * 2004-11-15 2010-01-12 Kerr Corporation Polyether-based composition curable by metathesis reaction
WO2006096652A2 (en) 2005-03-08 2006-09-14 Boehringer Ingelheim International Gmbh Process for preparing macrocyclic compounds
ATE510846T1 (de) 2005-09-09 2011-06-15 Boehringer Ingelheim Int Cyclisierendes metatheseverfahren zur herstellung von makrocyclischen peptiden
WO2007054483A1 (en) * 2005-11-09 2007-05-18 Boehringer Ingelheim International Gmbh Preparation of catalysts
CN101365703B (zh) 2005-11-16 2013-11-06 S*Bio私人有限公司 杂烷基连接的嘧啶衍生物
EP1847245A1 (en) 2006-02-21 2007-10-24 Kerr Corporation Method for making alkoxy-siloxane polyether carboxylates terminated with functional olefin groups
PL379879A1 (pl) 2006-06-07 2007-12-10 Umicore Ag & Co.Kg. Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy
EP2044095B1 (en) * 2006-06-30 2009-08-26 F. Hoffmann-Roche AG New ruthenium complexes as catalysts for metathesis reactions
DE102007020694A1 (de) 2007-05-03 2008-11-06 Evonik Degussa Gmbh Schwefelhaltige Metathesekatalysatoren
US8241575B2 (en) 2008-01-28 2012-08-14 The Johns Hopkins University Molecularly imprinted polymer sensor device
JP5365625B2 (ja) * 2008-03-31 2013-12-11 日本ゼオン株式会社 重合性組成物、樹脂成形体、及び架橋樹脂成形体
US8436110B2 (en) 2008-10-31 2013-05-07 Dow Global Technologies Llc Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands
WO2010096445A2 (en) * 2009-02-18 2010-08-26 Henkel Corporation Thermally switchable ruthenium initiators
ES2391340B1 (es) 2010-05-11 2013-09-30 Melchor Daumal Castellón Conjunto soporte multifuncion para columna de direccion
KR101297431B1 (ko) * 2011-04-18 2013-08-19 주식회사 폴리사이언텍 폴리프로필렌계 수지조성물 및 이로부터 제조된 스크래치 자기재생성 성형품
PL220408B1 (pl) * 2011-09-26 2015-10-30 Inst Chemii Organicznej Polskiej Akademii Nauk Kompleks rutentu, sposób jego wytwarzania oraz zastosowanie
US10933409B2 (en) * 2016-02-01 2021-03-02 Seoul National University R&Db Foundation Transition metal complex containing sulfonamide or amide group for olefin metathesis reaction and application thereof
US10792651B2 (en) 2016-10-19 2020-10-06 Umicore Ag & Co. Kg Synthesis and characterization of Ru alkylidene complexes
WO2022045204A1 (ja) * 2020-08-28 2022-03-03 Rimtec株式会社 酸素バリア性シクロオレフィン系樹脂硬化物
JP2024534168A (ja) * 2021-08-31 2024-09-18 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 組成物

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773948A4 (en) * 1992-04-03 1998-09-02 California Inst Of Techn HIGHLY ACTIVE RUTHENIUM OR OSMIUM METAL CARBEN COMPLEXES FOR OLEFIN METHETHESE REACTIONS AND THEIR SYNTHESIS

Also Published As

Publication number Publication date
KR100569620B1 (ko) 2006-04-11
DE69819501D1 (de) 2003-12-11
MX210210B (es) 2002-09-06
JP2002506455A (ja) 2002-02-26
WO1999000397A1 (en) 1999-01-07
AU8800498A (en) 1999-01-19
CA2289709A1 (en) 1999-01-07
ES2209185T3 (es) 2004-06-16
US6306987B1 (en) 2001-10-23
KR20010014234A (ko) 2001-02-26
EP0993466B1 (en) 2003-11-05
EP0993466A1 (en) 2000-04-19
BR9810488A (pt) 2000-09-12
MX9911931A (es) 2000-03-31

Similar Documents

Publication Publication Date Title
DE69819501T2 (de) Ruthenium und osmiumcarbenkatalysatoren
DE69818240T2 (de) Neue katalysatoren
DE69809552T2 (de) Ruthenium und osmiumcarbenkatalysatoren
DE69806634T9 (de) Ruthenium- und osmiumkatalysatoren mit heterocyclischem liganden
EP1070091B1 (en) Ruthenium and osmium carbene carbonyl catalysts
JP2003524019A (ja) オリゴマー性紫外線吸収剤を有するｒｏｍｐ
CA2375340A1 (en) Romp with alkoxy ether groups
DE69630801T2 (de) Polymerisierbare zusammensetzung und verfahren zum polymerisieren
EP1241196A2 (en) ROMP with alkoxy ether groups

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: CIBA HOLDING INC., BASEL, CH

8339 Ceased/non-payment of the annual fee