BR9810488A - Novos catalisadores. - Google Patents
Novos catalisadores.Info
- Publication number
- BR9810488A BR9810488A BR9810488-8A BR9810488A BR9810488A BR 9810488 A BR9810488 A BR 9810488A BR 9810488 A BR9810488 A BR 9810488A BR 9810488 A BR9810488 A BR 9810488A
- Authority
- BR
- Brazil
- Prior art keywords
- new catalysts
- catalysts
- new
- metaphase
- isomerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical group 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000031864 metaphase Effects 0.000 abstract 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH156297 | 1997-06-27 | ||
| PCT/EP1998/003781 WO1999000397A1 (en) | 1997-06-27 | 1998-06-20 | Ruthenium and osmium catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9810488A true BR9810488A (pt) | 2000-09-12 |
Family
ID=4213330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9810488-8A BR9810488A (pt) | 1997-06-27 | 1998-06-20 | Novos catalisadores. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6306987B1 (enExample) |
| EP (1) | EP0993466B1 (enExample) |
| JP (1) | JP2002506455A (enExample) |
| KR (1) | KR100569620B1 (enExample) |
| AU (1) | AU8800498A (enExample) |
| BR (1) | BR9810488A (enExample) |
| CA (1) | CA2289709A1 (enExample) |
| DE (1) | DE69819501T2 (enExample) |
| ES (1) | ES2209185T3 (enExample) |
| MX (1) | MX210210B (enExample) |
| WO (1) | WO1999000397A1 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6900347B2 (en) | 1998-09-01 | 2005-05-31 | Tilliechem, Inc. | Impurity inhibition in olefin metathesis reactions |
| US7507854B2 (en) | 1998-09-01 | 2009-03-24 | Materia, Inc. | Impurity reduction in Olefin metathesis reactions |
| US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
| DE19840107A1 (de) * | 1998-09-03 | 2000-03-09 | Bayer Ag | Verfahren zur Synthese alpha-substituierter Ringsysteme |
| IT1314204B1 (it) * | 1999-10-28 | 2002-12-06 | Sigea Srl | Complessi di rutenio con elevata attivita' antitumorale |
| RU2289568C2 (ru) * | 2001-03-26 | 2006-12-20 | Дау Глобал Текнолоджиз Инк. | Способ метатезиса сложных эфиров ненасыщенных жирных кислот или ненасыщенных жирных кислот с низшими олефинами и композиция гетерогенного катализатора, предназначенная для способа метатезиса |
| CA2458904C (en) * | 2001-08-30 | 2012-07-17 | Materia, Inc. | Infusion of cyclic olefin resins into porous materials |
| JP4138417B2 (ja) * | 2001-09-28 | 2008-08-27 | 積水化学工業株式会社 | 有機金属化合物の合成方法 |
| US6620955B1 (en) * | 2001-11-15 | 2003-09-16 | Richard L. Pederson | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| CN100379716C (zh) | 2002-04-29 | 2008-04-09 | 陶氏环球技术公司 | 关于种子油工业应用的综合化学方法 |
| JP4455318B2 (ja) | 2002-05-06 | 2010-04-21 | ケール コーポレーション | メタセシス反応による硬化性組成物 |
| US7173097B2 (en) * | 2003-05-06 | 2007-02-06 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| US7060770B2 (en) * | 2003-05-06 | 2006-06-13 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| US7683148B2 (en) * | 2003-05-06 | 2010-03-23 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| US7060769B2 (en) | 2003-05-06 | 2006-06-13 | Kerr Corporation | Method of curing composition by metathesis reaction using reaction control agent |
| WO2005040077A2 (en) | 2003-10-09 | 2005-05-06 | Dow Global Technologies Inc. | An improved process for the synthesis of unsaturated alcohols |
| US7109344B2 (en) * | 2003-12-04 | 2006-09-19 | Boehringer Ingelheim International Gmbh | Ruthenium catalyst |
| DE602004019973D1 (de) * | 2003-12-08 | 2009-04-23 | Boehringer Ingelheim Int | Abtrennung von ruthenium-nebenprodukten durch behandlung mit überkritischen flüssigkeiten |
| DE102004002178A1 (de) | 2004-01-15 | 2005-08-11 | Ivoclar Vivadent Ag | Dentalmeterialien auf der Basis von RÖMP-Kompositen |
| AU2011205218B2 (en) * | 2004-03-29 | 2015-12-17 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
| WO2005094345A2 (en) * | 2004-03-29 | 2005-10-13 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand |
| US7625551B2 (en) | 2004-11-15 | 2009-12-01 | Kerr Corporation | Polyether-based dental impression material curable by metathesis reaction |
| US7645443B2 (en) | 2004-11-15 | 2010-01-12 | Kerr Corporation | Polyether-based composition curable by metathesis reaction |
| US7001590B1 (en) | 2004-11-15 | 2006-02-21 | Kerr Corporation | Metathesis-curable composition |
| EP2332963A3 (en) | 2005-03-08 | 2011-11-16 | Boehringer Ingelheim International Gmbh | Process for preparing macrocyclic compounds |
| DK1934243T3 (da) | 2005-09-09 | 2011-09-05 | Boehringer Ingelheim Int | Cykliserende metathesefremgangsmåde til fremstilling af makrocykliske peptider |
| DE602006017249D1 (de) * | 2005-11-09 | 2010-11-11 | Boehringer Ingelheim Int | Herstellung von katalysatoren |
| PH12012501003B1 (en) | 2005-11-16 | 2018-04-06 | Cti Biopharma Corp | Oxygen linked pyrimidine derivatives |
| US7625991B2 (en) | 2006-02-21 | 2009-12-01 | Kerr Corporation | Method for making alkoxy-siloxane polyether carboxylates terminated with functional olefin groups |
| PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
| JP5323691B2 (ja) * | 2006-06-30 | 2013-10-23 | エフ.ホフマン−ラ ロシュ アーゲー | メタセシス反応用触媒としての新規ルテニウム錯体 |
| DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
| US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
| WO2009123209A1 (ja) * | 2008-03-31 | 2009-10-08 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| EP2350159A1 (en) | 2008-10-31 | 2011-08-03 | Dow Global Technologies LLC | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
| EP2398814A4 (en) | 2009-02-18 | 2013-02-20 | Henkel Corp | THERMALLY SWITCHED RUTHENIUM INITIATORS |
| ES2391340B1 (es) | 2010-05-11 | 2013-09-30 | Melchor Daumal Castellón | Conjunto soporte multifuncion para columna de direccion |
| KR101297431B1 (ko) * | 2011-04-18 | 2013-08-19 | 주식회사 폴리사이언텍 | 폴리프로필렌계 수지조성물 및 이로부터 제조된 스크래치 자기재생성 성형품 |
| PL220408B1 (pl) * | 2011-09-26 | 2015-10-30 | Inst Chemii Organicznej Polskiej Akademii Nauk | Kompleks rutentu, sposób jego wytwarzania oraz zastosowanie |
| US10933409B2 (en) * | 2016-02-01 | 2021-03-02 | Seoul National University R&Db Foundation | Transition metal complex containing sulfonamide or amide group for olefin metathesis reaction and application thereof |
| EP3528942B1 (en) * | 2016-10-19 | 2021-04-28 | Umicore Ag & Co. Kg | Synthesis and characterization of ru alkylidene complexes |
| WO2022045204A1 (ja) * | 2020-08-28 | 2022-03-03 | Rimtec株式会社 | 酸素バリア性シクロオレフィン系樹脂硬化物 |
| US20240352181A1 (en) * | 2021-08-31 | 2024-10-24 | Merck Patent Gmbh | Composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU691645B2 (en) * | 1992-04-03 | 1998-05-21 | California Institute Of Technology | High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof |
-
1998
- 1998-06-20 WO PCT/EP1998/003781 patent/WO1999000397A1/en not_active Ceased
- 1998-06-20 DE DE69819501T patent/DE69819501T2/de not_active Expired - Fee Related
- 1998-06-20 JP JP50526299A patent/JP2002506455A/ja not_active Withdrawn
- 1998-06-20 AU AU88004/98A patent/AU8800498A/en not_active Abandoned
- 1998-06-20 MX MX9911931A patent/MX210210B/es not_active IP Right Cessation
- 1998-06-20 KR KR19997012334A patent/KR100569620B1/ko not_active Expired - Fee Related
- 1998-06-20 CA CA002289709A patent/CA2289709A1/en not_active Abandoned
- 1998-06-20 US US09/446,052 patent/US6306987B1/en not_active Expired - Lifetime
- 1998-06-20 EP EP98939522A patent/EP0993466B1/en not_active Expired - Lifetime
- 1998-06-20 BR BR9810488-8A patent/BR9810488A/pt not_active Application Discontinuation
- 1998-06-20 ES ES98939522T patent/ES2209185T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6306987B1 (en) | 2001-10-23 |
| CA2289709A1 (en) | 1999-01-07 |
| JP2002506455A (ja) | 2002-02-26 |
| AU8800498A (en) | 1999-01-19 |
| ES2209185T3 (es) | 2004-06-16 |
| MX210210B (es) | 2002-09-06 |
| EP0993466B1 (en) | 2003-11-05 |
| WO1999000397A1 (en) | 1999-01-07 |
| EP0993466A1 (en) | 2000-04-19 |
| DE69819501D1 (de) | 2003-12-11 |
| DE69819501T2 (de) | 2004-09-23 |
| KR20010014234A (ko) | 2001-02-26 |
| KR100569620B1 (ko) | 2006-04-11 |
| MX9911931A (es) | 2000-03-31 |
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