DE69811131T2 - Optische-aktive Phosphin-Derivate mindestens zwei Vinyl-Gruppen enthaltend, davon abgeleitete Polymere und deren Übergangsmetallkomplexe - Google Patents

Optische-aktive Phosphin-Derivate mindestens zwei Vinyl-Gruppen enthaltend, davon abgeleitete Polymere und deren Übergangsmetallkomplexe

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Publication number
DE69811131T2
DE69811131T2 DE69811131T DE69811131T DE69811131T2 DE 69811131 T2 DE69811131 T2 DE 69811131T2 DE 69811131 T DE69811131 T DE 69811131T DE 69811131 T DE69811131 T DE 69811131T DE 69811131 T2 DE69811131 T2 DE 69811131T2
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DE
Germany
Prior art keywords
optical
transition metal
metal complexes
vinyl groups
derivatives containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69811131T
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English (en)
Other versions
DE69811131D1 (de
Inventor
Kyoko Tamao
Yohei Itoi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago Perfumery Industry Co
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Filing date
Publication date
Application filed by Takasago Perfumery Industry Co filed Critical Takasago Perfumery Industry Co
Publication of DE69811131D1 publication Critical patent/DE69811131D1/de
Application granted granted Critical
Publication of DE69811131T2 publication Critical patent/DE69811131T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2495—Ligands comprising a phosphine-P atom and one or more further complexing phosphorus atoms covered by groups B01J31/1845 - B01J31/1885, e.g. phosphine/phosphinate or phospholyl/phosphonate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F12/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
DE69811131T 1997-03-11 1998-03-10 Optische-aktive Phosphin-Derivate mindestens zwei Vinyl-Gruppen enthaltend, davon abgeleitete Polymere und deren Übergangsmetallkomplexe Expired - Fee Related DE69811131T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP07281797A JP3892931B2 (ja) 1997-03-11 1997-03-11 ２個のビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体

Publications (2)

Publication Number Publication Date
DE69811131D1 DE69811131D1 (de) 2003-03-13
DE69811131T2 true DE69811131T2 (de) 2003-07-24

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DE69811131T Expired - Fee Related DE69811131T2 (de) 1997-03-11 1998-03-10 Optische-aktive Phosphin-Derivate mindestens zwei Vinyl-Gruppen enthaltend, davon abgeleitete Polymere und deren Übergangsmetallkomplexe

Country Status (4)

Country Link
US (2) US6143834A (de)
EP (1) EP0864577B1 (de)
JP (1) JP3892931B2 (de)
DE (1) DE69811131T2 (de)

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US6229052B1 (en) * 1998-05-29 2001-05-08 E. I. Du Pont De Nemours And Company Hydroformylation of olefins using supported bis(phosphorus) ligands
US6307087B1 (en) * 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
US7223879B2 (en) 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
JP4275795B2 (ja) 1999-03-30 2009-06-10 高砂香料工業株式会社 ビニル基を有するホスフィン誘導体、それをモノマーとするポリマー及びそれらの遷移金属錯体
JP2001139691A (ja) * 1999-11-16 2001-05-22 Mitsubishi Chemicals Corp ３価リン含有重合体触媒によるアルデヒド類の製造方法および新規なホスファイト含有重合体
JP2002060727A (ja) * 2000-08-21 2002-02-26 Nippon Polyurethane Ind Co Ltd 天蓋パッキン用組成物及び該組成物を用いた天蓋パッキンの製造方法
KR100342659B1 (en) * 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
US20030135014A1 (en) * 2001-11-26 2003-07-17 Radu Nora S. Polymeric, phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
US6660876B2 (en) 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
JP4148702B2 (ja) * 2002-06-04 2008-09-10 高砂香料工業株式会社 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
JP4576584B2 (ja) * 2005-01-31 2010-11-10 独立行政法人科学技術振興機構 リン含有高分子固定化パラジウム触媒およびその使用
JP2007302859A (ja) * 2006-04-12 2007-11-22 Hokko Chem Ind Co Ltd ｐ−ホスフィン基含有スチレン−スチレン系共重合体を配位子とする新規なポリマー担持遷移金属錯体及び該錯体からなる触媒
JP4020155B2 (ja) * 2006-07-31 2007-12-12 三菱化学株式会社 有機二リン基架橋型重合体
JP4701195B2 (ja) * 2007-03-09 2011-06-15 独立行政法人科学技術振興機構 高分子固定化パラジウム触媒、及びその製造方法、並びに前記触媒を用いた反応方法
CN104667977B (zh) * 2013-11-29 2017-09-29 中国科学院大连化学物理研究所 一种丙烯氢甲酰化制丁醛的催化剂体系及使用其的方法
CN104667976B (zh) * 2013-11-29 2017-07-18 中国科学院大连化学物理研究所 一种乙烯氢甲酰化制丙醛的多相催化剂及使用其的方法
WO2015085504A1 (zh) * 2013-12-11 2015-06-18 中国科学院大连化学物理研究所 一种利用烯烃氢甲酰化反应生产高碳醛的方法
CN104707660B (zh) * 2013-12-11 2017-03-08 中国科学院大连化学物理研究所 一种用于烯烃氢甲酰化反应的固体多相催化剂及其制备方法和应用
CN104710289B (zh) * 2013-12-11 2017-04-19 中国科学院大连化学物理研究所 一种采用固体多相催化剂的用于烯烃氢甲酰化反应的方法
CN104707663B (zh) * 2013-12-11 2017-07-18 中国科学院大连化学物理研究所 一种有机配体聚合物载体及其制备方法
CN104710288B (zh) * 2013-12-11 2016-08-24 中国科学院大连化学物理研究所 一种利用烯烃氢甲酰化反应生产高碳醛的方法
CN106140302B (zh) * 2015-04-03 2018-11-27 中国科学院大连化学物理研究所 一种含膦有机混聚物-金属多相催化剂及其方法和应用
CN106140303B (zh) * 2015-04-03 2018-11-27 中国科学院大连化学物理研究所 一种含膦有机混聚物-金属多相催化剂及其制备和应用
CN106140301B (zh) * 2015-04-03 2018-11-27 中国科学院大连化学物理研究所 含膦有机混聚物-金属多相催化剂及其制备方法和应用
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WO2023125073A1 (zh) * 2021-12-31 2023-07-06 中国石油天然气股份有限公司 有机膦配体聚合物及二齿膦配体共聚物催化剂的制备方法

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JP3789508B2 (ja) 1995-03-14 2006-06-28 高砂香料工業株式会社 光学活性非対称ジホスフィン及び該化合物の存在下にて光学活性体を得る方法
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JP3892932B2 (ja) 1997-03-11 2007-03-14 高砂香料工業株式会社 ビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体

Also Published As

Publication number Publication date
JPH10251282A (ja) 1998-09-22
EP0864577A2 (de) 1998-09-16
DE69811131D1 (de) 2003-03-13
US6248848B1 (en) 2001-06-19
US6143834A (en) 2000-11-07
EP0864577B1 (de) 2003-02-05
EP0864577A3 (de) 1999-08-25
JP3892931B2 (ja) 2007-03-14

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