DE69801324D1 - Ein katalysator mit palladium und gold abscheidenen auf einen kupferenthaltenden träger zur herstellung des vinylacetats - Google Patents

Ein katalysator mit palladium und gold abscheidenen auf einen kupferenthaltenden träger zur herstellung des vinylacetats

Info

Publication number
DE69801324D1
DE69801324D1 DE69801324T DE69801324T DE69801324D1 DE 69801324 D1 DE69801324 D1 DE 69801324D1 DE 69801324 T DE69801324 T DE 69801324T DE 69801324 T DE69801324 T DE 69801324T DE 69801324 D1 DE69801324 D1 DE 69801324D1
Authority
DE
Germany
Prior art keywords
copper
palladium
catalyst
production
vinyl acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69801324T
Other languages
English (en)
Other versions
DE69801324T2 (de
Inventor
Ioan Nicolau
Adolfo Aguilo
M Colling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese International Corp
Original Assignee
Celanese International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese International Corp filed Critical Celanese International Corp
Publication of DE69801324D1 publication Critical patent/DE69801324D1/de
Application granted granted Critical
Publication of DE69801324T2 publication Critical patent/DE69801324T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926Copper and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69801324T 1997-06-03 1998-05-15 Ein katalysator mit palladium und gold abscheidenen auf einen kupferenthaltenden träger zur herstellung des vinylacetats Expired - Lifetime DE69801324T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/867,911 US5968869A (en) 1997-06-03 1997-06-03 Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
PCT/US1998/009939 WO1998055225A1 (en) 1997-06-03 1998-05-15 Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier

Publications (2)

Publication Number Publication Date
DE69801324D1 true DE69801324D1 (de) 2001-09-13
DE69801324T2 DE69801324T2 (de) 2002-05-23

Family

ID=25350704

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69801324T Expired - Lifetime DE69801324T2 (de) 1997-06-03 1998-05-15 Ein katalysator mit palladium und gold abscheidenen auf einen kupferenthaltenden träger zur herstellung des vinylacetats

Country Status (29)

Country Link
US (2) US5968869A (de)
EP (1) EP0986433B1 (de)
JP (1) JP4165663B2 (de)
KR (1) KR100516259B1 (de)
CN (1) CN1107538C (de)
AR (1) AR012901A1 (de)
AT (1) ATE203930T1 (de)
AU (1) AU724125B2 (de)
BR (1) BR9809715B1 (de)
CA (1) CA2289503C (de)
CZ (1) CZ298593B6 (de)
DE (1) DE69801324T2 (de)
ES (1) ES2161531T3 (de)
HU (1) HUP0003486A2 (de)
ID (1) ID22991A (de)
MY (1) MY117733A (de)
NO (1) NO319763B1 (de)
NZ (1) NZ501439A (de)
PE (1) PE116299A1 (de)
PL (1) PL190979B1 (de)
RU (1) RU2198731C2 (de)
SA (1) SA98190239B1 (de)
SK (1) SK164599A3 (de)
TR (1) TR199903000T2 (de)
TW (1) TW412526B (de)
UA (1) UA57077C2 (de)
WO (1) WO1998055225A1 (de)
YU (1) YU49183B (de)
ZA (1) ZA984729B (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5753542A (en) * 1985-08-02 1998-05-19 Semiconductor Energy Laboratory Co., Ltd. Method for crystallizing semiconductor material without exposing it to air
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6013834A (en) * 1999-03-04 2000-01-11 Celanese International Corporation Production of vinyl acetate in a catalytic reactor equipped with filter and distribution bed
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US20020061277A1 (en) * 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
JP2005507659A (ja) * 2001-10-15 2005-03-24 イミューノメディクス、インコーポレイテッド 直接ターゲッティング結合タンパク質
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
CN100336593C (zh) * 2004-02-19 2007-09-12 中国石油化工股份有限公司 合成醋酸乙烯酯的负载型催化剂的制备方法
UA95442C2 (ru) * 2004-12-20 2011-08-10 Селаниз Интернешнл Корпорейшн Модифицированные материалы носителей для катализаторов
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
KR101017904B1 (ko) * 2006-08-30 2011-03-04 쇼와 덴코 가부시키가이샤 아세트산 알케닐 제조용 촉매의 제조방법
US8507720B2 (en) * 2010-01-29 2013-08-13 Lyondell Chemical Technology, L.P. Titania-alumina supported palladium catalyst
US8329611B2 (en) 2009-12-16 2012-12-11 Lyondell Chemical Technology, L,P. Titania-containing extrudate
US8273682B2 (en) * 2009-12-16 2012-09-25 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalyst
TW202204039A (zh) 2020-06-11 2022-02-01 美商瑟蘭斯國際股份有限公司 用於乙酸乙烯酯製造之催化劑的製備方法
CN114618519A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种负载型双金属催化剂制备丙酸甲酯的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1618391C3 (de) * 1967-03-22 1975-08-14 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Vinylacetat
CH534005A (de) * 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
JPS4837245B1 (de) * 1969-10-02 1973-11-09
JPS514118A (en) * 1974-06-27 1976-01-14 Kuraray Co Sakusanbiniruno seizohoho
GB1571910A (en) * 1975-12-18 1980-07-23 Nat Distillers Chem Corp Vinyl acetate process and catalyst therefor
DE3200483A1 (de) * 1982-01-09 1983-07-21 Bayer Ag, 5090 Leverkusen Kieselsaeurehaltige formkoerper, verfahren zu ihrer herstellung und ihre verwendung
US5274181A (en) * 1991-05-06 1993-12-28 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
US5185308A (en) * 1991-05-06 1993-02-09 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
TW330160B (en) * 1992-04-08 1998-04-21 Hoechst Ag Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
SA97180048B1 (ar) * 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst

Also Published As

Publication number Publication date
NZ501439A (en) 2001-11-30
TR199903000T2 (xx) 2000-05-22
ID22991A (id) 1999-12-23
KR100516259B1 (ko) 2005-09-20
PE116299A1 (es) 1999-11-22
HUP0003486A2 (hu) 2001-02-28
SK164599A3 (en) 2000-05-16
ZA984729B (en) 1999-12-02
AU7488998A (en) 1998-12-21
JP4165663B2 (ja) 2008-10-15
NO995873D0 (no) 1999-12-01
UA57077C2 (uk) 2003-06-16
CN1259060A (zh) 2000-07-05
YU49183B (sh) 2004-07-15
TW412526B (en) 2000-11-21
MY117733A (en) 2004-07-31
NO995873L (no) 1999-12-01
CA2289503C (en) 2007-06-26
YU24698A (en) 1999-11-22
RU2198731C2 (ru) 2003-02-20
CA2289503A1 (en) 1998-12-10
AR012901A1 (es) 2000-11-22
JP2002508703A (ja) 2002-03-19
BR9809715B1 (pt) 2009-01-13
US5968869A (en) 1999-10-19
AU724125B2 (en) 2000-09-14
BR9809715A (pt) 2000-07-11
WO1998055225A1 (en) 1998-12-10
ATE203930T1 (de) 2001-08-15
DE69801324T2 (de) 2002-05-23
PL190979B1 (pl) 2006-02-28
CZ298593B6 (cs) 2007-11-21
EP0986433A1 (de) 2000-03-22
EP0986433B1 (de) 2001-08-08
NO319763B1 (no) 2005-09-12
ES2161531T3 (es) 2001-12-01
SA98190239B1 (ar) 2006-05-01
PL337162A1 (en) 2000-07-31
US6107514A (en) 2000-08-22
CN1107538C (zh) 2003-05-07
CZ436599A3 (cs) 2000-06-14
KR20010013308A (ko) 2001-02-26

Similar Documents

Publication Publication Date Title
DE69801324D1 (de) Ein katalysator mit palladium und gold abscheidenen auf einen kupferenthaltenden träger zur herstellung des vinylacetats
DE59608407D1 (de) Kobaltkatalysatoren
DE69807691D1 (de) Schlammkohlenwasserstoffsynthese mit externer produktfiltrierung
DE68906419D1 (de) Platinkatalysator und verfahren fuer seine herstellung.
DE59506586D1 (de) Wirbelschicht-oxidationsverfahren zur herstellung von polycarboxylaten auf polysaccharid-basis
DE69629164D1 (de) Gerät zur Herzfrequenzklassifizierung, abgeleitet aus der EKG-Wellenform
ATE283112T1 (de) Herstellung eines metallisches palladium, kupfer und gold enthaltenden vinylacetatkatalysators
ATE272443T1 (de) Vinylacetatkatalysator mit metallischem palladium und gold mit kaliumaurat bereitet
ZA993400B (en) Catalyst and use thereof in the production of vinyl acetate.
DE69609149D1 (de) Ungesättigtes Copolymer auf Olefinbasis, seine Herstellung und seine Verwendung
DE69613326D1 (de) Photokatalysatorzusammenstellung und Verfahren für seine Herstellung, Photokatalysatorzusammenstellung verbunden auf einen Träger
DE19880237D2 (de) Deformationselement, Verfahren zu seiner Herstellung und seine Verwendung
DE69618635D1 (de) Katalysator zur herstellung von vinylazetat
DE68905356D1 (de) Rhodiumkolloid, verfahren zur herstellung und verwendung.
ZA9811282B (en) Catalyst process for producing the catalyst and process for preparing vinyl acetate using the catalyst
ATE284271T1 (de) Herstellung eines metallisches palladium, kupfer und gold enthaltenden vinylacetatkatalysators
DE69609354D1 (de) Klebe streifen und reiterblock mit zentralem anfangstreifen.
DE59809572D1 (de) Silber-palladium-legierungen zur herstellung von mit dentalkeramik verblendbarem zahnersatz
PL339811A1 (en) Vinyl acetate production catalyst containing palladium and gold as well as cupric acetate
DE59811249D1 (de) Katalysator auf der basis von palladium, gold, alkali und lanthanoid und verfahren zur herstellung von vinylacetat
DE59811750D1 (de) Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE69613200D1 (de) Beta-Fructofuranosidase, seine Herstellung und Verwendungen
DE59500603D1 (de) Palladium-Trägerkatalysatoren
DE69604327D1 (de) Herstellung von polyalkylierten Cyclopentadienen aus Isobornylcarboxylaten
DE69405519D1 (de) Verwendung von Palladium/Gold Trägerkatalysatoren zur Herstellung von Tertiärbutylalkohol aus Tertiärbutyl

Legal Events

Date Code Title Description
8364 No opposition during term of opposition