DE69720998D1 - Herstellung von para-xylol durch methylierung von toluol - Google Patents

Herstellung von para-xylol durch methylierung von toluol

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Publication number
DE69720998D1
DE69720998D1 DE69720998T DE69720998T DE69720998D1 DE 69720998 D1 DE69720998 D1 DE 69720998D1 DE 69720998 T DE69720998 T DE 69720998T DE 69720998 T DE69720998 T DE 69720998T DE 69720998 D1 DE69720998 D1 DE 69720998D1
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Germany
Prior art keywords
toluol
xylol
methylating
para
production
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Expired - Lifetime
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DE69720998T
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English (en)
Inventor
D Mohr
S Smith
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
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    • B01J29/005Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
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DE69720998T 1996-05-29 1997-05-29 Herstellung von para-xylol durch methylierung von toluol Expired - Lifetime DE69720998D1 (de)

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US1855096P 1996-05-29 1996-05-29
US1854696P 1996-05-29 1996-05-29
US1839096P 1996-05-29 1996-05-29
US1855196P 1996-05-29 1996-05-29
US1858396P 1996-05-29 1996-05-29
US1854796P 1996-05-29 1996-05-29
PCT/US1997/009609 WO1997045387A1 (en) 1996-05-29 1997-05-29 Methylation of toluene to para-xylene

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BR (1) BR9709620A (de)
CA (1) CA2255873A1 (de)
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Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0958050A1 (de) * 1996-05-29 1999-11-24 Exxon Chemical Patents Inc. Metallhaltiger zeolith-katalysator, verfahren zu seiner herstellung und dessen verwendung zur umwandlung von kohlenwasserstoffen
WO1999028031A1 (en) * 1997-12-03 1999-06-10 Exxon Chemical Patents Inc. Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion
DE69805003T2 (de) * 1997-12-03 2002-11-14 Exxonmobil Chem Patents Inc Herstellung einer durch eine zeolith von mfi-strukturtyp gebundenen zeolith und ihre verwendung
US6613708B1 (en) 1999-06-07 2003-09-02 Exxonmobil Chemical Patents Inc. Catalyst selectivation
US6459006B1 (en) 1999-05-14 2002-10-01 Exxonmobil Chemical Patents Inc. Selective methylation to para-xylene using fuel syngas
US6388156B1 (en) 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
US6797155B1 (en) * 1999-12-21 2004-09-28 Exxonmobil Research & Engineering Co. Catalytic cracking process using a modified mesoporous aluminophosphate material
AU2001236985A1 (en) * 2000-02-16 2001-08-27 Exxonmobil Chemical Patents Inc Treatment of molecular sieves with silicon containing compounds
TWI281879B (en) * 2002-05-24 2007-06-01 Mitsubishi Gas Chemical Co Crystalline silicoaluminophosphate salt molecular sieve having octaoxygen-membered ring pore, process for producing the same and process for producing methylamine with the molecular sieve as catalyst
US7119239B2 (en) * 2002-06-19 2006-10-10 Exxonmobil Chemical Patents Inc. Manufacture of xylenes using reformate
WO2004000767A1 (en) * 2002-06-19 2003-12-31 Exxonmobil Chemical Patents Inc. Manufacture of xylenes from reformate
EP1523535A1 (de) * 2002-06-19 2005-04-20 Exxonmobil Chemical Patents Inc. Herstellung von xylolen aus einem reformat
US7255849B2 (en) * 2003-06-24 2007-08-14 Exxonmobil Research And Engineering Company EMM-3, new crystalline microporous material
US7453018B2 (en) * 2003-12-31 2008-11-18 Exxonmobil Chemical Patents Inc. Process for aromatic alkylation
US6943131B1 (en) * 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
US7285511B2 (en) 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
KR100598988B1 (ko) * 2005-05-18 2006-07-12 주식회사 하이닉스반도체 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법
US7368410B2 (en) 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
US7563358B2 (en) * 2006-08-24 2009-07-21 Exxonmobil Chemical Patents Inc. Process for the production of benzene, toluene, and xylenes
US7745675B2 (en) * 2006-12-20 2010-06-29 Saudi Basic Industries Corporation Regeneration of platinum-germanium zeolite catalyst
TWI478768B (zh) * 2007-07-18 2015-04-01 China Petro Chemical Technologydevelopment Company Catalysts and methods for the production of light aromatics and light alkanes from hydrocarbon feedstocks
JP5520212B2 (ja) * 2008-03-27 2014-06-11 Jx日鉱日石エネルギー株式会社 パラ置換芳香族炭化水素の製造方法
CN101306974B (zh) * 2008-06-12 2011-03-30 江苏工业学院 一种催化合成对二甲基苯的方法
JP5495531B2 (ja) 2008-10-09 2014-05-21 Jx日鉱日石エネルギー株式会社 パラキシレン製造用合成ゼオライト触媒の製造方法、並びに該方法で製造したパラキシレン製造用触媒を用いた高純度パラキシレンの製造方法
US8846559B2 (en) 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US20120004487A1 (en) 2009-03-16 2012-01-05 Jx Nippon Oil & Energy Corporation Catalyst for producing para-substituted aromatic hydrocarbon and method for producing para-substituted aromatic hydrocarbon using the same
CN101885662B (zh) * 2009-05-13 2013-09-18 中国石油化工股份有限公司 甲苯甲醇烷基化的方法
US8062987B2 (en) 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
JP5485639B2 (ja) * 2009-10-05 2014-05-07 山本化成株式会社 アルキルベンゼン誘導体の製造方法
JP5985139B2 (ja) 2010-03-26 2016-09-06 Jxエネルギー株式会社 パラキシレンを製造するための、ベンゼンのアルキル化反応、或いは、トルエンのアルキル化反応又はトルエンの不均化反応に用いる触媒及びその製造方法、並びにそれを用いたパラキシレンの製造方法
CN102464560B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 甲醇或二甲醚和甲苯生产二甲苯的方法
CN102464561B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 甲醇或二甲醚和甲苯制备二甲苯的方法
CN102464549B (zh) * 2010-11-17 2013-12-25 中国石油化工股份有限公司 生产丙烯和对二甲苯的方法
US9181146B2 (en) 2010-12-10 2015-11-10 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins
SG190307A1 (en) 2010-12-10 2013-06-28 Exxonmobil Chem Patents Inc Method and apparatus for obtaining aromatics from diverse feedstock
CN102875319B (zh) * 2011-07-12 2015-09-09 中国石油化工股份有限公司 芳烃甲基化的移动床催化方法
AU2012347625A1 (en) * 2011-12-08 2014-07-17 Gtc Technology Us, Llc Production of xylenes by methylation of aromatic compounds
KR101663121B1 (ko) 2012-03-30 2016-10-06 제이엑스 에네루기 가부시키가이샤 실리케이트 피복 MFI형 제올라이트와 그 제조 방법 및 그것을 이용한 p-크실렌의 제조 방법
US9181147B2 (en) 2012-05-07 2015-11-10 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
JP6127232B2 (ja) * 2012-07-19 2017-05-17 株式会社 Acr 抗シンタリング触媒
CN103785461A (zh) * 2012-11-01 2014-05-14 中国石油化工股份有限公司 一种甲苯与甲醇烷基化的催化剂及其制备方法和应用
US9919984B2 (en) 2013-08-23 2018-03-20 Hindustan Petroleum Corporation Limited Process for the preparation of isomers of xylene
US10196329B2 (en) 2014-11-21 2019-02-05 Exxonmobil Chemical Patents Inc. Process for making para-xylene
EP3280530B1 (de) * 2015-04-09 2022-03-16 BASF Corporation Zsm-5-katalysator
KR102231925B1 (ko) 2016-03-25 2021-03-25 엑손모빌 케미칼 패턴츠 인코포레이티드 파라-크실렌의 제조 방법 및 촉매
JP6743173B2 (ja) * 2016-03-25 2020-08-19 エクソンモービル・ケミカル・パテンツ・インク パラキシレンの製造用触媒およびプロセス
CN106902868B (zh) * 2017-03-09 2020-07-28 中国科学院山西煤炭化学研究所 一种改性催化剂及其制备方法和应用
EP3632547A4 (de) 2017-05-31 2020-12-16 Furukawa Electric Co., Ltd. Katalysatorstruktur zum katalytischen cracken oder zur hydrodesulfurierung, vorrichtung zum katalytischen cracken und hydrodesulfurierungsvorrichtung unter verwendung der besagten katalysatorstruktur und herstellungsverfahren für katalysatorstruktur zum katalytischen cracken oder zur hydrodesulfurierung
CN110709165A (zh) 2017-05-31 2020-01-17 国立大学法人北海道大学 功能性结构体以及功能性结构体的制造方法
EP3632542A4 (de) 2017-05-31 2021-01-06 Furukawa Electric Co., Ltd. Co-shift- oder reverse-shift-katalysatorstruktur und herstellungsverfahren dafür, co-shift- oder reverse-shift-reaktionsvorrichtung, herstellungsverfahren von kohlendioxid und wasserstoff und herstellungsverfahren von kohlenmonoxid und wasser
CN110730688A (zh) * 2017-05-31 2020-01-24 古河电气工业株式会社 芳香族烃制造用催化剂结构体、具备该芳香族烃制造用催化剂结构体的芳香族烃制造装置、芳香族烃制造用催化剂结构体的制造方法以及芳香族烃的制造方法
CN110678263A (zh) 2017-05-31 2020-01-10 古河电气工业株式会社 加氢脱硫用催化剂结构体、具备该催化剂结构体的加氢脱硫装置、以及加氢脱硫用催化剂结构体的制造方法
JP7382827B2 (ja) 2017-05-31 2023-11-17 古河電気工業株式会社 排気ガス浄化用酸化触媒構造体及びその製造方法、自動車の排気ガス処理装置、触媒成形体、並びに気体浄化方法
CN110691645A (zh) 2017-05-31 2020-01-14 国立大学法人北海道大学 功能性结构体以及功能性结构体的制造方法
US11161101B2 (en) 2017-05-31 2021-11-02 Furukawa Electric Co., Ltd. Catalyst structure and method for producing the catalyst structure
AU2018276617B2 (en) 2017-05-31 2021-03-25 Furukawa Electric Co., Ltd. Functional structure and production method for functional structure
WO2018221706A1 (ja) 2017-05-31 2018-12-06 古河電気工業株式会社 メタノール改質触媒構造体、メタノール改質用装置、メタノール改質触媒構造体の製造方法及びオレフィンまたは芳香族炭化水素の少なくとも一方の製造方法
US10450240B2 (en) 2017-11-10 2019-10-22 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
CN114425422B (zh) * 2020-09-23 2024-01-30 中国石油化工股份有限公司 复合分子筛催化剂、制备方法及其应用
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures
WO2023244394A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization and separation thereof
WO2023244389A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization in the presence of c9+ aromatic hydrocarbons and separation thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4002697A (en) * 1973-12-03 1977-01-11 Mobil Oil Corporation Selective production of para-xylene
US4100215A (en) * 1974-09-25 1978-07-11 Mobil Oil Corporation Selective production of para-xylene
US3965207A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Selective production of para-xylene
US4358395A (en) * 1978-09-11 1982-11-09 Mobil Oil Corporation Hydrogen regeneration of coke-selectivated crystalline aluminosilicate catalyst
US4289607A (en) * 1979-04-09 1981-09-15 Mobil Oil Corporation Catalytic conversion with crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
DE2924116A1 (de) * 1979-06-15 1980-12-18 Interatom Vorrichtung zum veraendern eines fluessigmetallstromes in einen kanal
US4358362A (en) * 1981-01-15 1982-11-09 Mobil Oil Corporation Method for enhancing catalytic activity
US4670616A (en) * 1985-11-25 1987-06-02 Amoco Corporation AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene methylation
FR2600557B1 (fr) * 1986-06-24 1993-03-19 Elf France Systemes zeolitiques binaires, leur synthese et leur utilisation
US4746763A (en) * 1987-04-22 1988-05-24 Uop Inc. Process for producing aromatic compounds from C2 -C6 aliphatic hydrocarbons
GB9101456D0 (en) * 1991-01-23 1991-03-06 Exxon Chemical Patents Inc Process for producing substantially binder-free zeolite
US5349113A (en) * 1993-02-25 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversion over pre-selectivated, activated catalyst
AU4737896A (en) * 1994-11-23 1996-06-17 Exxon Chemical Patents Inc. Hydrocarbon conversion process using a zeolite bound zeolite catalyst
ZA978671B (en) * 1996-10-02 1999-03-26 Mobil Oil Corp Selective para-xylene production by toluene methylation

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BR9709620A (pt) 1999-08-10
EA199801061A1 (ru) 1999-06-24
EP0912473B1 (de) 2003-04-16
CA2255873A1 (en) 1997-12-04
US5994603A (en) 1999-11-30
AU3228997A (en) 1998-01-05
EA002376B1 (ru) 2002-04-25
EP0912473A1 (de) 1999-05-06
CN1083412C (zh) 2002-04-24
JP2001504084A (ja) 2001-03-27
WO1997045387A1 (en) 1997-12-04
AU737003B2 (en) 2001-08-09
CN1224408A (zh) 1999-07-28

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