DE69720070T2 - Verfahren zur phyto-extraktion von nickel, kobalt und anderen metallen aus dem erdreich - Google Patents
Verfahren zur phyto-extraktion von nickel, kobalt und anderen metallen aus dem erdreichInfo
- Publication number
- DE69720070T2 DE69720070T2 DE69720070T DE69720070T DE69720070T2 DE 69720070 T2 DE69720070 T2 DE 69720070T2 DE 69720070 T DE69720070 T DE 69720070T DE 69720070 T DE69720070 T DE 69720070T DE 69720070 T2 DE69720070 T2 DE 69720070T2
- Authority
- DE
- Germany
- Prior art keywords
- soil
- nickel
- alyssum
- metals
- plants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 62
- 239000002184 metal Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims description 28
- 150000002739 metals Chemical class 0.000 title abstract description 34
- 229910017052 cobalt Inorganic materials 0.000 title abstract description 23
- 239000010941 cobalt Substances 0.000 title abstract description 23
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract description 23
- 238000000605 extraction Methods 0.000 title description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 94
- 239000002689 soil Substances 0.000 claims abstract description 76
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 41
- 241000430521 Alyssum Species 0.000 claims abstract description 31
- 239000011575 calcium Substances 0.000 claims abstract description 21
- 239000002738 chelating agent Substances 0.000 claims abstract description 14
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003337 fertilizer Substances 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 9
- 230000001143 conditioned effect Effects 0.000 claims abstract description 7
- 238000009825 accumulation Methods 0.000 claims abstract description 4
- 239000011368 organic material Substances 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 3
- 238000003306 harvesting Methods 0.000 claims abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000002028 Biomass Substances 0.000 claims description 5
- 241000303945 Alyssum murale Species 0.000 claims description 4
- 241000303816 Alyssum pintodasilvae Species 0.000 claims description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 4
- 241000303930 Alyssum fallacinum Species 0.000 claims description 3
- 241000303955 Alyssum lesbiacum Species 0.000 claims description 3
- 241000303954 Alyssum malacitanum Species 0.000 claims description 3
- 241000303815 Alyssum tenium Species 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- GXVUZYLYWKWJIM-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanamine Chemical compound NCCOCCN GXVUZYLYWKWJIM-UHFFFAOYSA-N 0.000 claims description 2
- 241000751643 Alyssum bertolonii Species 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 42
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract description 14
- 238000011084 recovery Methods 0.000 abstract description 14
- 229910052697 platinum Inorganic materials 0.000 abstract description 9
- 229910052763 palladium Inorganic materials 0.000 abstract description 8
- 241000219193 Brassicaceae Species 0.000 abstract description 5
- 238000003723 Smelting Methods 0.000 abstract description 2
- 210000001519 tissue Anatomy 0.000 description 11
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 7
- 241000894007 species Species 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 4
- 230000008635 plant growth Effects 0.000 description 4
- 239000002364 soil amendment Substances 0.000 description 4
- 235000019738 Limestone Nutrition 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- 231100000350 mutagenesis Toxicity 0.000 description 3
- 229910052762 osmium Inorganic materials 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000722118 Thlaspi Species 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002703 mutagenesis Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 230000005945 translocation Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 241000303939 Alyssum argenteum Species 0.000 description 1
- 241000303823 Alyssum serpyllifolium Species 0.000 description 1
- 244000178993 Brassica juncea Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical class NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- 241000219823 Medicago Species 0.000 description 1
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 1
- 241001529597 Noccaea caerulescens Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000012364 cultivation method Methods 0.000 description 1
- 210000000805 cytoplasm Anatomy 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 238000012239 gene modification Methods 0.000 description 1
- 230000005017 genetic modification Effects 0.000 description 1
- 235000013617 genetically modified food Nutrition 0.000 description 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- -1 palladium metals Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/18—Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Microbiology (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Fertilizers (AREA)
- Processing Of Solid Wastes (AREA)
- Cultivation Of Plants (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1997/009806 WO1998059080A1 (en) | 1997-06-20 | 1997-06-20 | Method for phytomining of nickel, cobalt and other metals from soil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69720070D1 DE69720070D1 (de) | 2003-04-24 |
| DE69720070T2 true DE69720070T2 (de) | 2003-12-24 |
Family
ID=22261034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69720070T Expired - Fee Related DE69720070T2 (de) | 1997-06-20 | 1997-06-20 | Verfahren zur phyto-extraktion von nickel, kobalt und anderen metallen aus dem erdreich |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0993510B1 (enExample) |
| JP (1) | JP4837153B2 (enExample) |
| AT (1) | ATE234940T1 (enExample) |
| AU (1) | AU744810B2 (enExample) |
| BG (1) | BG64218B1 (enExample) |
| BR (1) | BR9714799A (enExample) |
| CA (1) | CA2296116C (enExample) |
| DE (1) | DE69720070T2 (enExample) |
| EA (1) | EA001697B1 (enExample) |
| ES (1) | ES2195154T3 (enExample) |
| PT (1) | PT993510E (enExample) |
| TR (1) | TR199903145T2 (enExample) |
| WO (1) | WO1998059080A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE452997T1 (de) * | 1998-11-10 | 2010-01-15 | Univ Sheffield | Gewinnung von metallen aus erdreich |
| DE10261705A1 (de) * | 2002-12-31 | 2004-07-08 | Bothe, Hermann, Prof. Dr. | Verfahren zur Anreicherung von Schwermetallen aus metallhaltigen Böden sowie zur Sanierung metall-kontaminierter Böden |
| JP5852002B2 (ja) * | 2009-11-26 | 2016-02-03 | サントル ナショナル ドゥ ラ ルシェルシュ シアンティフィク | 化学反応を実行するための金属集積植物の使用 |
| CA2731457A1 (fr) * | 2011-02-04 | 2012-08-04 | Institut National De La Recherche Scientifique (Inrs) | Procede de production d'un sel de sulfate double de nickel et d'ammonium a partir de plantes hyperaccumulatrices |
| DE102020210948A1 (de) | 2020-08-31 | 2022-03-03 | Volkswagen Aktiengesellschaft | Verfahren zur Rückgewinnung von Stoffen aus gebrauchten Batteriezellen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5320663A (en) * | 1992-07-02 | 1994-06-14 | E. I. Du Pont De Nemours And Company | Method of obtaining lead and organolead from contaminated media using metal accumulating plants |
| US5364451A (en) * | 1993-06-04 | 1994-11-15 | Phytotech, Inc. | Phytoremediation of metals |
| US5711784A (en) * | 1995-06-06 | 1998-01-27 | University Of Maryland At College Park | Method for phytomining of nickel, cobalt and other metals from soil |
| GB9518599D0 (en) * | 1995-09-12 | 1995-11-15 | Isis Innovation | Hyperaccumulation of metals in plants |
| EP0888197A1 (en) * | 1996-03-21 | 1999-01-07 | Phytotech, Inc. | Method for hyperaccumulation of metals in plant shoots |
| WO1998008991A1 (en) * | 1996-08-30 | 1998-03-05 | University Of Maryland College Park | Method for phytomining of nickel, cobalt and other metals from soil |
-
1997
- 1997-06-20 BR BR9714799-0A patent/BR9714799A/pt not_active IP Right Cessation
- 1997-06-20 AU AU34787/97A patent/AU744810B2/en not_active Expired
- 1997-06-20 EA EA200000055A patent/EA001697B1/ru not_active IP Right Cessation
- 1997-06-20 PT PT97931061T patent/PT993510E/pt unknown
- 1997-06-20 WO PCT/US1997/009806 patent/WO1998059080A1/en not_active Ceased
- 1997-06-20 DE DE69720070T patent/DE69720070T2/de not_active Expired - Fee Related
- 1997-06-20 EP EP97931061A patent/EP0993510B1/en not_active Expired - Lifetime
- 1997-06-20 JP JP50433499A patent/JP4837153B2/ja not_active Expired - Lifetime
- 1997-06-20 CA CA002296116A patent/CA2296116C/en not_active Expired - Lifetime
- 1997-06-20 AT AT97931061T patent/ATE234940T1/de not_active IP Right Cessation
- 1997-06-20 ES ES97931061T patent/ES2195154T3/es not_active Expired - Lifetime
- 1997-06-20 TR TR1999/03145T patent/TR199903145T2/xx unknown
-
1999
- 1999-12-09 BG BG103975A patent/BG64218B1/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR9714799A (pt) | 2000-10-10 |
| DE69720070D1 (de) | 2003-04-24 |
| CA2296116A1 (en) | 1998-12-30 |
| ES2195154T3 (es) | 2003-12-01 |
| JP4837153B2 (ja) | 2011-12-14 |
| EP0993510A4 (en) | 2000-08-23 |
| EA001697B1 (ru) | 2001-06-25 |
| EP0993510B1 (en) | 2003-03-19 |
| PT993510E (pt) | 2003-07-31 |
| CA2296116C (en) | 2008-12-09 |
| EP0993510A1 (en) | 2000-04-19 |
| ATE234940T1 (de) | 2003-04-15 |
| BG103975A (en) | 2000-08-31 |
| WO1998059080A1 (en) | 1998-12-30 |
| BG64218B1 (bg) | 2004-05-31 |
| EA200000055A1 (ru) | 2000-06-26 |
| JP2002511904A (ja) | 2002-04-16 |
| TR199903145T2 (xx) | 2002-12-23 |
| AU3478797A (en) | 1999-01-04 |
| AU744810B2 (en) | 2002-03-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8339 | Ceased/non-payment of the annual fee |