DE69713058T2 - Regeneratives verfahren und zusammensetzung zur entfernung von sulfiden aus gasströmen - Google Patents
Regeneratives verfahren und zusammensetzung zur entfernung von sulfiden aus gasströmenInfo
- Publication number
- DE69713058T2 DE69713058T2 DE69713058T DE69713058T DE69713058T2 DE 69713058 T2 DE69713058 T2 DE 69713058T2 DE 69713058 T DE69713058 T DE 69713058T DE 69713058 T DE69713058 T DE 69713058T DE 69713058 T2 DE69713058 T2 DE 69713058T2
- Authority
- DE
- Germany
- Prior art keywords
- composition
- gas flows
- removing sulfides
- regenerative method
- regenerative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/80—Organic bases or salts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/587,837 US5698171A (en) | 1996-01-10 | 1996-01-10 | Regenerative method for removing sulfides from gas streams |
PCT/US1997/000324 WO1997025126A2 (en) | 1996-01-10 | 1997-01-09 | Regenerative method and composition for removing sulfides from gas streams |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69713058D1 DE69713058D1 (de) | 2002-07-11 |
DE69713058T2 true DE69713058T2 (de) | 2002-09-19 |
Family
ID=24351405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69713058T Expired - Fee Related DE69713058T2 (de) | 1996-01-10 | 1997-01-09 | Regeneratives verfahren und zusammensetzung zur entfernung von sulfiden aus gasströmen |
Country Status (18)
Country | Link |
---|---|
US (1) | US5698171A (de) |
EP (1) | EP0877647B1 (de) |
JP (1) | JP2001508349A (de) |
CN (1) | CN1133483C (de) |
AR (1) | AR005435A1 (de) |
AT (1) | ATE218389T1 (de) |
AU (1) | AU710674B2 (de) |
BR (1) | BR9706952A (de) |
CA (1) | CA2240820C (de) |
DE (1) | DE69713058T2 (de) |
EG (1) | EG21187A (de) |
ES (1) | ES2178751T3 (de) |
ID (1) | ID19812A (de) |
IS (1) | IS2098B (de) |
NO (1) | NO322393B1 (de) |
TR (1) | TR199801285T2 (de) |
WO (1) | WO1997025126A2 (de) |
ZA (1) | ZA97183B (de) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5885538A (en) * | 1997-07-02 | 1999-03-23 | Quaker Chemical Corporation | Method and composition for the regeneration of an aminal compound |
US6063346A (en) * | 1998-06-05 | 2000-05-16 | Intevep, S. A. | Process for scavenging hydrogen sulfide and mercaptan contaminants from a fluid |
CN1086147C (zh) * | 1999-04-14 | 2002-06-12 | 唐山市新世纪环保设计研究所 | 消烟除尘脱硫烟气净化剂 |
CA2445422A1 (en) * | 2001-04-25 | 2002-10-31 | Clearwater International, Llc | Treatment of hydrocarbons containing sulfides |
US8562820B2 (en) | 2001-11-09 | 2013-10-22 | Clearwater International, L.L.C. | Sulfide scavenger |
US7211665B2 (en) * | 2001-11-09 | 2007-05-01 | Clearwater International, L.L.C. | Sulfide scavenger |
US6773582B2 (en) * | 2002-09-25 | 2004-08-10 | Precision Control Technology, Inc. | Drinking water treatment system including hydrogen sulfide scrubber using triazine compound and associated methods |
US7140433B2 (en) * | 2003-12-12 | 2006-11-28 | Clearwater International, Llc | Diamine terminated primary amine-aldehyde sulfur converting compositions and methods for making and using same |
US7077884B2 (en) * | 2004-06-09 | 2006-07-18 | Precision Control Technology, Inc. | Hydrogen sulfide scrubber using polymeric amine and associated methods |
US7438877B2 (en) * | 2006-09-01 | 2008-10-21 | Baker Hughes Incorporated | Fast, high capacity hydrogen sulfide scavengers |
US7985881B2 (en) * | 2007-09-12 | 2011-07-26 | Guard Products Llc | Aromatic imine compounds for use as sulfide scavengers |
TWI383837B (zh) * | 2007-12-26 | 2013-02-01 | Ind Tech Res Inst | 還原性氣體污染物的處理方法 |
US7931882B1 (en) | 2008-12-19 | 2011-04-26 | Syneco Systems Inc | Sulfide scavenging media and associated methods |
FR2942802B1 (fr) * | 2009-03-03 | 2012-06-01 | Total Raffinage Marketing | Composition reticulante sous forme de granule pour preparer des compositions bitume/elastomere reticulees |
CN101538478A (zh) * | 2009-04-01 | 2009-09-23 | 孙文村 | 一种脱硫化氢试剂的制作方法 |
EP2430213A1 (de) * | 2009-05-14 | 2012-03-21 | Basf Se | Verfahren zur elektrolytischen spaltung von schwefelwasserstoff |
US20120012505A1 (en) * | 2010-07-14 | 2012-01-19 | Compton Dennis R | Use of alpha-amino ethers for the removal of mercaptans from hydrocarbons |
US8409535B2 (en) | 2010-11-03 | 2013-04-02 | Calpine Corporation | System and method for removing a contaminant from a gas stream |
KR101961343B1 (ko) * | 2010-11-22 | 2019-03-25 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 탄화수소 스트림에서 황화수소 소거용 첨가제 조성물 및 소거 방법 |
US9052289B2 (en) * | 2010-12-13 | 2015-06-09 | Schlumberger Technology Corporation | Hydrogen sulfide (H2S) detection using functionalized nanoparticles |
US9394396B2 (en) * | 2011-06-21 | 2016-07-19 | Baker Hughes Incorporated | Hydrogen sulfide scavenger for use in hydrocarbons |
US9463989B2 (en) | 2011-06-29 | 2016-10-11 | Baker Hughes Incorporated | Synergistic method for enhanced H2S/mercaptan scavenging |
KR101349973B1 (ko) * | 2011-08-03 | 2014-01-23 | 주식회사 그린솔루스 | 가스상 황화수소 처리 장치 |
US9278307B2 (en) | 2012-05-29 | 2016-03-08 | Baker Hughes Incorporated | Synergistic H2 S scavengers |
US9327211B2 (en) | 2013-06-18 | 2016-05-03 | Uop Llc | Process for removing carbonyl sulfide in a gas phase hydrocarbon stream and apparatus relating thereto |
US9790313B2 (en) | 2014-08-21 | 2017-10-17 | Hexion Inc. | Curing compositions and methods of preparing |
US20160060520A1 (en) * | 2014-09-03 | 2016-03-03 | Baker Hughes Incorporated | Scavengers for sulfur species and/or phosphorus containing compounds |
US10655232B2 (en) | 2014-09-03 | 2020-05-19 | Baker Hughes, A Ge Company, Llc | Additives to control hydrogen sulfide release of sulfur containing and/or phosphorus containing corrosion inhibitors |
BR112018013492B1 (pt) * | 2016-01-05 | 2023-01-10 | Dorf Ketal Chemicals (India) Private Limited | Composição de aditivo sequestrante de sulfeto de hidrogênio, método para sequestrar sulfeto de hidrogênio e uso da composição de aditivo sequestrante de sulfeto de hidrogênio |
MY187429A (en) * | 2016-01-08 | 2021-09-22 | Dorf Ketal Chemicals India Private Ltd | Nitrogen based hydrogen sulfide scavengers and method of use thereof |
US20190184383A1 (en) * | 2016-04-25 | 2019-06-20 | Liudmila Aleksandrovna TYURINA | Catalyst intended for desulfurization/demercaptanization/dehydration of gaseous hydrocarbons |
CN106076092A (zh) * | 2016-07-05 | 2016-11-09 | 西安赫立盖斯新能源科技有限公司 | 一种适用于液相氧化工艺的螯合稳定剂 |
DE102016113930A1 (de) | 2016-07-28 | 2018-02-01 | Schülke & Mayr GmbH | Kondensationsprodukt aus 1-Aminopropan-2-ol und Formaldehyd und dessen Verwendung zur Verminderung der Menge von Schwefelwasserstoff in Flüssigkeiten und Gasen |
CN106281406A (zh) * | 2016-08-30 | 2017-01-04 | 句容宁武高新技术发展有限公司 | 油田脱硫剂及其制备方法 |
CN106554804B (zh) * | 2016-11-18 | 2018-06-26 | 中国海洋石油总公司 | 一种油田防垢脱硫剂及其制备方法 |
MX2019005907A (es) | 2016-11-22 | 2019-08-22 | Kuraray Co | Composicion para eliminacion de compuesto que contiene azufre. |
US10513662B2 (en) | 2017-02-02 | 2019-12-24 | Baker Hughes, A Ge Company, Llc | Functionalized aldehydes as H2S and mercaptan scavengers |
EA039258B1 (ru) * | 2017-06-21 | 2021-12-23 | Курарей Ко., Лтд. | Композиция для удаления серосодержащего соединения |
WO2019139910A1 (en) * | 2018-01-12 | 2019-07-18 | Baker Hughes, A Ge Company, Llc | Additives to control hydrogen sulfide release of sulfur containing and/or phosphorus containing corrosion inhibitors |
EA202091782A1 (ru) * | 2018-02-28 | 2020-11-10 | Курарей Ко., Лтд. | Композиция для удаления серосодержащих соединений |
US11198828B2 (en) * | 2018-03-28 | 2021-12-14 | Bionomic Industries Inc. | Process for hydrogen sulfide scrubbing and method for ferric ion regeneration |
CN109092277B (zh) * | 2018-09-19 | 2021-07-16 | 上海交通大学 | 一种对金属硫化物除汞吸附剂的活化与再生方法 |
EP3891262A1 (de) * | 2018-12-04 | 2021-10-13 | Total Marketing Services | Schwefelwasserstoff- und mercaptanenabsorbierende zusammensetzungen |
CN109603487B (zh) * | 2019-01-28 | 2021-09-21 | 烟台新瑞环保科技有限公司 | 一种液相氧化脱硫工艺中螯合铁催化剂的稳定剂及包含其的脱硫剂 |
US11946008B2 (en) | 2022-05-04 | 2024-04-02 | Nexgen Oilfield Chemicals, Llc | Compositions and methods for scavenging hydrogen sulfide |
CN115893625B (zh) * | 2022-10-26 | 2023-09-15 | 中国石油化工股份有限公司 | 一种用于压返液中有机硫去除的生物脱硫剂及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2776870A (en) * | 1953-11-27 | 1957-01-08 | Union Oil Co | Corrosion prevention in gas recovery systems |
US3622273A (en) * | 1970-02-06 | 1971-11-23 | Nalco Chemical Co | Method for the removal of hydrogen sulfide from gaseous streams |
JPS5092294A (de) * | 1973-12-18 | 1975-07-23 | ||
AU506199B2 (en) * | 1975-06-26 | 1979-12-20 | Exxon Research And Engineering Company | Absorbtion of co2 from gaseous feeds |
US4076621A (en) * | 1976-03-15 | 1978-02-28 | Air Resources, Inc. | Chelate oxidation of hydrogen sulfide in sour water |
SU1237241A1 (ru) * | 1980-10-29 | 1986-06-15 | Всесоюзный научно-исследовательский институт углеводородного сырья | Абсорбент дл очистки газов от сероводорода |
US4414194A (en) * | 1981-05-26 | 1983-11-08 | Shell Oil Company | Extraction process |
CA1205276A (en) * | 1981-06-15 | 1986-06-03 | Malcolm W. Mcewan | Process for the removal of co.sub.2 and, if present h.sub.2s from a gas mixture |
US4455287A (en) * | 1982-03-15 | 1984-06-19 | Ari Technologies, Inc. | Method of stabilizing chelated polyvalent metal solutions |
DE3219762A1 (de) * | 1982-05-26 | 1983-12-01 | Linde Ag, 6200 Wiesbaden | Verfahren zur verhinderung der thiosulfatbildung bei oxidativen schwefelwasserstoffwaeschen |
US4436714A (en) * | 1982-09-30 | 1984-03-13 | Shell Oil Company | Method of removing hydrogen sulfide from gases utilizing a polyvalent metal chelate of nitrilotriacetic acid and electrolytically regenerating the solution |
US4647397A (en) * | 1984-01-23 | 1987-03-03 | Chevron Research Company | Composition for removing sulfides from industrial gas |
US4624838A (en) * | 1985-04-29 | 1986-11-25 | Exxon Research And Engineering Company | Process for removing acidic gases from gaseous mixtures using aqueous scrubbing solutions containing heterocyclic nitrogen compounds |
US4775519A (en) * | 1985-10-31 | 1988-10-04 | Texaco Inc. | Removal of acid gases from gas streams |
US4978512B1 (en) * | 1988-12-23 | 1993-06-15 | Composition and method for sweetening hydrocarbons | |
US5273734A (en) * | 1990-01-12 | 1993-12-28 | The Texas A&M University System | Conversion of H2 to sulfur |
US5128049A (en) * | 1991-01-22 | 1992-07-07 | Gatlin Larry W | Hydrogen sulfide removal process |
JPH04290547A (ja) * | 1991-03-15 | 1992-10-15 | Kuraray Chem Corp | 吸水性脱臭剤 |
US5160714A (en) * | 1991-04-08 | 1992-11-03 | Ari Technologies, Inc. | Continuous autocirculation, multiple zone mass transfer apparatus and method |
US5347003A (en) * | 1993-03-05 | 1994-09-13 | Quaker Chemical Corporation | Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction |
-
1996
- 1996-01-10 US US08/587,837 patent/US5698171A/en not_active Expired - Lifetime
-
1997
- 1997-01-09 AU AU16943/97A patent/AU710674B2/en not_active Ceased
- 1997-01-09 JP JP52539297A patent/JP2001508349A/ja not_active Ceased
- 1997-01-09 ZA ZA9700183A patent/ZA97183B/xx unknown
- 1997-01-09 BR BR9706952-3A patent/BR9706952A/pt not_active IP Right Cessation
- 1997-01-09 CN CNB971916365A patent/CN1133483C/zh not_active Expired - Fee Related
- 1997-01-09 CA CA002240820A patent/CA2240820C/en not_active Expired - Fee Related
- 1997-01-09 ES ES97902872T patent/ES2178751T3/es not_active Expired - Lifetime
- 1997-01-09 EP EP97902872A patent/EP0877647B1/de not_active Expired - Lifetime
- 1997-01-09 DE DE69713058T patent/DE69713058T2/de not_active Expired - Fee Related
- 1997-01-09 EG EG2397A patent/EG21187A/xx active
- 1997-01-09 AT AT97902872T patent/ATE218389T1/de not_active IP Right Cessation
- 1997-01-09 WO PCT/US1997/000324 patent/WO1997025126A2/en active IP Right Grant
- 1997-01-09 TR TR1998/01285T patent/TR199801285T2/xx unknown
- 1997-01-10 ID IDP970053A patent/ID19812A/id unknown
- 1997-01-10 AR ARP970100107A patent/AR005435A1/es unknown
-
1998
- 1998-06-29 IS IS4786A patent/IS2098B/is unknown
- 1998-07-09 NO NO19983168A patent/NO322393B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
EP0877647A2 (de) | 1998-11-18 |
EP0877647B1 (de) | 2002-06-05 |
CA2240820A1 (en) | 1997-07-17 |
AU1694397A (en) | 1997-08-01 |
ATE218389T1 (de) | 2002-06-15 |
JP2001508349A (ja) | 2001-06-26 |
US5698171A (en) | 1997-12-16 |
DE69713058D1 (de) | 2002-07-11 |
WO1997025126A2 (en) | 1997-07-17 |
EG21187A (en) | 2000-12-31 |
CN1207052A (zh) | 1999-02-03 |
NO983168L (no) | 1998-07-10 |
AU710674B2 (en) | 1999-09-30 |
CN1133483C (zh) | 2004-01-07 |
TR199801285T2 (xx) | 1998-10-21 |
WO1997025126A3 (en) | 1997-12-04 |
NO322393B1 (no) | 2006-10-02 |
CA2240820C (en) | 2002-03-19 |
IS4786A (is) | 1998-06-29 |
IS2098B (is) | 2006-04-12 |
ES2178751T3 (es) | 2003-01-01 |
ID19812A (id) | 1998-08-06 |
BR9706952A (pt) | 2000-01-04 |
AR005435A1 (es) | 1999-06-23 |
ZA97183B (en) | 1997-08-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |