DE69710359D1 - Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen - Google Patents

Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen

Info

Publication number
DE69710359D1
DE69710359D1 DE69710359T DE69710359T DE69710359D1 DE 69710359 D1 DE69710359 D1 DE 69710359D1 DE 69710359 T DE69710359 T DE 69710359T DE 69710359 T DE69710359 T DE 69710359T DE 69710359 D1 DE69710359 D1 DE 69710359D1
Authority
DE
Germany
Prior art keywords
alkylation
organic compounds
alkylatable organic
alkylatable
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69710359T
Other languages
English (en)
Other versions
DE69710359T2 (de
Inventor
Broekhoven Hermanus Van
Cabre Rene Mas
Pieter Bogaard
Gijsbertus Klaver
Marco Vonhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Netherlands BV
Original Assignee
Akzo Nobel NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL1004623A external-priority patent/NL1004623C2/nl
Application filed by Akzo Nobel NV filed Critical Akzo Nobel NV
Publication of DE69710359D1 publication Critical patent/DE69710359D1/de
Application granted granted Critical
Publication of DE69710359T2 publication Critical patent/DE69710359T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • C07C2529/12—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE69710359T 1996-11-27 1997-11-14 Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen Expired - Lifetime DE69710359T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
NL1004623A NL1004623C2 (nl) 1996-11-27 1996-11-27 Werkwijze voor het alkyleren van koolwaterstoffen.
US3154296P 1996-12-02 1996-12-02
EP97202951 1997-09-25
PCT/EP1997/006401 WO1998023560A1 (en) 1996-11-27 1997-11-14 Process for alkylating hydrocarbons

Publications (2)

Publication Number Publication Date
DE69710359D1 true DE69710359D1 (de) 2002-03-21
DE69710359T2 DE69710359T2 (de) 2002-08-14

Family

ID=27238509

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69710359T Expired - Lifetime DE69710359T2 (de) 1996-11-27 1997-11-14 Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen

Country Status (11)

Country Link
US (1) US5986158A (de)
EP (1) EP0941211B1 (de)
JP (1) JP4278067B2 (de)
KR (1) KR100533754B1 (de)
CN (1) CN1088449C (de)
AU (1) AU5750598A (de)
BR (1) BR9713441B1 (de)
CA (1) CA2273333C (de)
DE (1) DE69710359T2 (de)
ES (1) ES2172035T3 (de)
WO (1) WO1998023560A1 (de)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001000310A2 (en) 1999-06-08 2001-01-04 Bechtel Bwxt Idaho, Llc Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas
ES2228888T3 (es) * 2000-05-30 2005-04-16 Albemarle Netherlands B.V. Uso de un catalizador para la alquilacion de hidrocarburos.
US20020013216A1 (en) 2000-05-30 2002-01-31 Broekhoven Emanuel Hermanus Van Novel alkylation catalyst and its use in alkylation
US6579821B1 (en) 2000-06-14 2003-06-17 Bechtel Bwxt Idaho, Llc Method for reactivating solid catalysts used in alkylation reactions
US7407905B2 (en) 2000-06-14 2008-08-05 Battelle Energy Alliance, Llc Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts
US6844479B2 (en) * 2000-10-20 2005-01-18 Abb Lummus Global Inc. Alkylation process
ATE438602T1 (de) * 2001-06-08 2009-08-15 Albemarle Netherlands Bv Verfahren zur katalytischen alkylierung von kohlenwasserstoffen
DK1527035T3 (da) 2001-06-08 2015-06-08 Albemarle Netherlands Bv Kontinuerlig fremgangsmåde til alkyleringen af carbonhydrider
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6924407B2 (en) * 2001-08-27 2005-08-02 The University Of Kansas Pressure-tuned solid catalyzed heterogeneous chemical reactions
ATE519538T1 (de) 2001-11-06 2011-08-15 Albemarle Netherlands Bv Schwefel enthaltender alkylierungskatalysator und dessen verwendung
US7361797B2 (en) * 2002-02-05 2008-04-22 Abb Lummus Global Inc. Hydrocarbon conversion using nanocrystalline zeolite Y
CN1310852C (zh) * 2002-03-18 2007-04-18 阿尔伯麦尔荷兰有限公司 使用级间蒸馏的饱和烃的烷基化
US20040158113A1 (en) * 2003-02-06 2004-08-12 Girish Srinivas Catalysts and process for converting fuel gases to gasoline
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
JP4508617B2 (ja) * 2003-11-28 2010-07-21 薫 藤元 イソパラフィン−オレフィンアルキル化用ゼオライト触媒および該触媒を用いたアルキル化法
JP5016927B2 (ja) 2004-02-09 2012-09-05 アルベマーレ ネザーランズ ビー．ブイ． 固体酸および水素化金属を含む触媒を使用するアルキル化方法
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7592282B2 (en) 2004-11-11 2009-09-22 Battelle Energy Alliance, Llc Enhancement of alkylation catalysts for improved supercritical fluid regeneration
US20060101712A1 (en) * 2004-11-15 2006-05-18 Burnett Don E Small off-road engine green fuel
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
CN101395088B (zh) 2006-02-03 2012-04-04 Grt公司 轻气体与卤素的分离方法
US7875754B2 (en) * 2006-07-27 2011-01-25 Lummus Technology Inc. Method of improving alkylate yield in an alkylation reaction
WO2008048427A1 (en) * 2006-10-17 2008-04-24 Abb Lummus Global, Inc. Bimetallic alkylation catalysts
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
US20100234661A1 (en) * 2007-10-17 2010-09-16 Albemarle Netherlands, BV Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal
WO2009058522A2 (en) * 2007-11-02 2009-05-07 Exxonmobil Chemical Patents Inc. A process for rejuvenating a catalyst composition
WO2009061303A1 (en) * 2007-11-08 2009-05-14 Lummus Technology Inc. Method of improving alkylate yield in an alkylation reaction
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US20110313227A1 (en) 2009-02-11 2011-12-22 Albemarle Europe Sprl Alkylation catalyst and related process
US8791301B2 (en) * 2010-02-04 2014-07-29 University-Industry Cooperation Group Of Kyunghee University Method of preparing secondary amine compound using microflow reactor
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
EP4223730A3 (de) * 2010-12-30 2023-10-04 Virent, Inc. Organokatalytischer biomasseabbau
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9415385B2 (en) 2011-11-21 2016-08-16 Exxonmobil Research And Engineering Company Activation of dual catalyst systems
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
KR102429723B1 (ko) 2014-07-07 2022-08-04 알베마를 유럽 에스피알엘 제올라이트 및 수소화 금속을 함유하는 세륨이 풍부한 희토류를 포함하는 촉매제를 이용한 알킬화 방법
US9963403B2 (en) * 2014-10-27 2018-05-08 Exxonmobil Chemical Patents Inc. Process and apparatus for the conversion of hydrocarbons
EP3733290A3 (de) 2015-06-22 2021-02-17 Exelus, Inc. Verbesserte katalysierte alkylierung, alkylierungskatalysatoren und verfahren zur herstellung von alkylisierungskatalysatoren
CN105195177B (zh) * 2015-09-18 2017-12-26 宁波海越新材料有限公司 一种烷基化汽油催化剂及其制备方法
CN106631656B (zh) * 2015-10-28 2019-09-24 中国石油化工股份有限公司 一种烷基化反应方法
CN106631655B (zh) * 2015-10-28 2019-05-21 中国石油化工股份有限公司 一种烷基化反应方法
RU2637922C2 (ru) * 2016-06-02 2017-12-08 Публичное акционерное общество "Электрогорский институт нефтепереработки" (ПАО "ЭлИНП") Способ алкилирования изобутана в трехфазном реакторе с неподвижным слоем катализатора
WO2018158377A1 (en) 2017-03-01 2018-09-07 Albemarle Europe Sprl Alkylation process with improved octane number
CN109420403B (zh) * 2017-08-31 2022-05-03 中国石油化工股份有限公司 一种重整氢气的利用方法、固体酸催化剂的再生方法和烷基化反应方法
CN110538675A (zh) * 2018-05-28 2019-12-06 中国石油化工股份有限公司 固体酸烷基化催化剂及其制备方法和应用
CN110872529B (zh) * 2018-09-04 2022-06-28 中国石油化工股份有限公司 固体酸烷基化反应方法和反应系统
CN110876854B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 一种低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
CN110876855B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
US11951461B2 (en) 2019-01-25 2024-04-09 China Petroleum & Chemical Corporation Solid acid catalyst, preparation therefor and use thereof
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
WO2021025835A1 (en) * 2019-08-06 2021-02-11 Exxonmobil Research And Engineering Company Catalyst rejuvenation in multistage alkylation of isoparaffin
CN111763130B (zh) 2020-06-22 2023-01-03 南京克米斯璀新能源科技有限公司 一种用于生产长链烷基苯的方法
BR102021007444A2 (pt) * 2021-04-19 2022-10-25 Petróleo Brasileiro S.A. - Petrobras Processo para a obtenção de alquil-naftênicos
CN115678599A (zh) * 2021-07-29 2023-02-03 中国石油化工股份有限公司 一种烷基化方法
US11851386B2 (en) 2021-10-15 2023-12-26 Exelus, Inc. Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents
CN115999617B (zh) * 2021-10-22 2024-07-09 中国石油化工股份有限公司 一种利用重整氢气再生固体酸烷基化反应催化剂的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3549557A (en) * 1968-06-26 1970-12-22 Union Carbide Corp Isoparaffin alkylation process and catalyst for use therein
US3851004A (en) * 1973-09-27 1974-11-26 Union Carbide Corp Hydrocarbon alkylation process using catalyst regeneration
FR2721603B1 (fr) * 1994-06-22 1996-09-20 Inst Francais Du Petrole Procédé de réjuvénation d'un catalyseur solide d'alkylation.
US5489732A (en) * 1994-10-14 1996-02-06 Uop Fluidized solid bed motor fuel alkylation process

Also Published As

Publication number Publication date
WO1998023560A1 (en) 1998-06-04
BR9713441A (pt) 2000-02-01
DE69710359T2 (de) 2002-08-14
KR100533754B1 (ko) 2005-12-06
EP0941211A1 (de) 1999-09-15
US5986158A (en) 1999-11-16
AU5750598A (en) 1998-06-22
JP4278067B2 (ja) 2009-06-10
CN1088449C (zh) 2002-07-31
ES2172035T3 (es) 2002-09-16
CA2273333C (en) 2007-05-01
BR9713441B1 (pt) 2009-01-13
CN1238747A (zh) 1999-12-15
EP0941211B1 (de) 2002-02-06
CA2273333A1 (en) 1998-06-04
JP2001504504A (ja) 2001-04-03
KR20000052722A (ko) 2000-08-25

Similar Documents

Publication Publication Date Title
DE69710359D1 (de) Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen
DE60004938D1 (de) Verfahren zur Alkylierung von Isoparaffinen mit Olefinen
DE59510656D1 (de) Verfahren zur Dinitrierung von aromatischen Verbindungen
DE69731450D1 (de) Katalytische Zusammensetzung und Verfahren zur Alkylierung bzw. Transalkylierung aromatischer Verbindungen
DE69529936T2 (de) Verfahren zur Quantifizierung von spezifischen Verbindungen
DE50015014D1 (de) Verfahren zur Hydroformylierung von Olefinen
DE69406478D1 (de) Verfahren zur Entfernung von festen organischen Stoffen
DE59900390D1 (de) Verfahren zur Herstellung von Olefinen
DE69611028D1 (de) Verfahren zur Isomerisierung von Olefinen
DE59901861D1 (de) Verfahren zur katalytischen zersetzung von n 2?o
DE69836155D1 (de) Verfahren zur Alkylierung von Benzol
DE69802581D1 (de) Verfahren zur Züchtung von Einkristallen
DE69733883D1 (de) Verfahren zur zugabe von borverbindungen
DE69606689D1 (de) Verfahren zur Hydroformylierung von olefinischen Verbindungen
DE69934948D1 (de) Verfahren zur cooxidation von organischen verbindungen
DE60018648D1 (de) Verfahren zur Alkylierung von aromatichen Verbindungen in der Gasphase
DE69938067D1 (de) Verfahren zur Entfernung von organischen Verbindungen mittels Verbrennungskatalysatoren
DE69302973D1 (de) Verfahren zur Alkylierung von Paraffinen
DE69911677D1 (de) Verfahren zur Alkylierung von aromatischen Verbindungen oder zur Herstellung von monoalkylierten aromatischen Verbindungen
DE69817978D1 (de) Verfahren zur Oxidation von aromatischen Verbindungen zu aromatischen Hydroxyverbindungen
DE69901644D1 (de) Verfahren zur Hydration von Olefinen
DE69811598D1 (de) Verfahren zur Herstellung von Triphendioxazinverbindungen
DE69313411D1 (de) Verfahren zur O-Alkylierung von phenolischen Verbindungen
DE69900321D1 (de) Verfahren zur Alkylierug von gehinderten Sulfonamiden
DE69509941D1 (de) Verfahren zur Wiedergewinnung von Alkylierungskatalysator

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: ALBEMARLE NETHERLANDS B.V., AMERSFOORT, NL