ES2172035T3 - Procedimiento para alquilar compuestos organicos susceptibles de alquilacion. - Google Patents

Procedimiento para alquilar compuestos organicos susceptibles de alquilacion.

Info

Publication number
ES2172035T3
ES2172035T3 ES97953684T ES97953684T ES2172035T3 ES 2172035 T3 ES2172035 T3 ES 2172035T3 ES 97953684 T ES97953684 T ES 97953684T ES 97953684 T ES97953684 T ES 97953684T ES 2172035 T3 ES2172035 T3 ES 2172035T3
Authority
ES
Spain
Prior art keywords
catalyst
procedure
rental
renting
rent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97953684T
Other languages
English (en)
Inventor
Broekhoven Emanuel Hermanu Van
Cabre Francisco Rene Mas
Pieter Bogaard
Gijsbertus Klaver
Marco Vonhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel NV
Original Assignee
Akzo Nobel NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL1004623A external-priority patent/NL1004623C2/nl
Application filed by Akzo Nobel NV filed Critical Akzo Nobel NV
Application granted granted Critical
Publication of ES2172035T3 publication Critical patent/ES2172035T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • C07C2529/12—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE ALQUILACION DE HIDROCARBUROS EN EL CUAL UN COMPUESTO ORGANICO ALQUILABLE SE HACE REACCIONAR CON UN AGENTE DE ALQUILACION, PARA FORMAR UN ALQUILADO, EN PRESENCIA DE UN CATALIZADOR QUE COMPRENDE UNA FUNCION HIDROGENANTE Y UN CONSTITUYENTE ACIDO SOLIDO. EL CATALIZADOR SE SOMETE INTERMITENTEMENTE A UNA ETAPA DE REGENERACION, MEDIANTE SU PUESTA EN CONTACTO CON UNA CORRIENTE DE ALIMENTACION QUE CONTIENE UN HIDROCARBURO SATURADO E HIDROGENO. DICHA REGENERACION SE LLEVA A CABO AL 90 % O MENOS DEL CICLO ACTIVO DEL CATALIZADOR, DEFINIENDOSE DICHO CICLO ACTIVO COMO EL TIEMPO DESDE EL INICIO DEL SUMINISTRO DEL AGENTE DE ALQUILACION HASTA EL MOMENTO EN EL QUE EL 20 % DEL AGENTE DE ALQUILACION ABANDONA LA SECCION DEL REACTOR QUE CONTIENE EL CATALIZADOR SIN HABER SIDO TRANSFORMADO, SIN TENER EN CUENTA LA ISOMERIZACION EN EL INTERIOR DE LA MOLECULA. EL PROCEDIMIENTO DE LA INVENCION ES ESPECIALMENTE ADECUADO PARA LA ALQUILACION DE ISOBUTANO CON UNO O MAS BUTENOS, PARA FORMAR UN ALQUILADO CON UN RON ELEVADO.
ES97953684T 1996-11-27 1997-11-14 Procedimiento para alquilar compuestos organicos susceptibles de alquilacion. Expired - Lifetime ES2172035T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL1004623A NL1004623C2 (nl) 1996-11-27 1996-11-27 Werkwijze voor het alkyleren van koolwaterstoffen.
US3154296P 1996-12-02 1996-12-02
EP97202951 1997-09-25

Publications (1)

Publication Number Publication Date
ES2172035T3 true ES2172035T3 (es) 2002-09-16

Family

ID=27238509

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97953684T Expired - Lifetime ES2172035T3 (es) 1996-11-27 1997-11-14 Procedimiento para alquilar compuestos organicos susceptibles de alquilacion.

Country Status (11)

Country Link
US (1) US5986158A (es)
EP (1) EP0941211B1 (es)
JP (1) JP4278067B2 (es)
KR (1) KR100533754B1 (es)
CN (1) CN1088449C (es)
AU (1) AU5750598A (es)
BR (1) BR9713441B1 (es)
CA (1) CA2273333C (es)
DE (1) DE69710359T2 (es)
ES (1) ES2172035T3 (es)
WO (1) WO1998023560A1 (es)

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US6579821B1 (en) 2000-06-14 2003-06-17 Bechtel Bwxt Idaho, Llc Method for reactivating solid catalysts used in alkylation reactions
US7407905B2 (en) 2000-06-14 2008-08-05 Battelle Energy Alliance, Llc Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts
US6844479B2 (en) * 2000-10-20 2005-01-18 Abb Lummus Global Inc. Alkylation process
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US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6924407B2 (en) * 2001-08-27 2005-08-02 The University Of Kansas Pressure-tuned solid catalyzed heterogeneous chemical reactions
EP1308207B1 (en) 2001-11-06 2011-08-10 Albemarle Netherlands B.V. Sulfur-containing alkylation catalyst and use thereof
US7361797B2 (en) * 2002-02-05 2008-04-22 Abb Lummus Global Inc. Hydrocarbon conversion using nanocrystalline zeolite Y
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US20040158113A1 (en) * 2003-02-06 2004-08-12 Girish Srinivas Catalysts and process for converting fuel gases to gasoline
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US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
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PL1732866T3 (pl) 2004-02-09 2017-10-31 Albemarle Netherlands Bv Sposób alkilacji z zastosowaniem katalizatora zawierającego stały kwas i uwodorniający metal
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7592282B2 (en) 2004-11-11 2009-09-22 Battelle Energy Alliance, Llc Enhancement of alkylation catalysts for improved supercritical fluid regeneration
US20060101712A1 (en) * 2004-11-15 2006-05-18 Burnett Don E Small off-road engine green fuel
BRPI0707490A2 (pt) 2006-02-03 2011-05-03 Grt Inc separação de gases leves de halogênios
EP2457887A1 (en) 2006-02-03 2012-05-30 GRT, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US7875754B2 (en) * 2006-07-27 2011-01-25 Lummus Technology Inc. Method of improving alkylate yield in an alkylation reaction
WO2008048427A1 (en) * 2006-10-17 2008-04-24 Abb Lummus Global, Inc. Bimetallic alkylation catalysts
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
EP2197817A1 (en) * 2007-10-17 2010-06-23 Albemarle Netherlands B.V. Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal
EP2217374B1 (en) * 2007-11-02 2022-03-09 Badger Licensing, LLC A process for rejuvenating a catalyst composition
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EP2396291A1 (en) 2009-02-11 2011-12-21 Albemarle Europe Sprl. Alkylation catalyst and related process
KR101259708B1 (ko) * 2010-02-04 2013-05-06 경희대학교 산학협력단 마이크로 플로우 리액터를 이용한 2차 아민 화합물을 제조하는 신규한 방법
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
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CN106631656B (zh) * 2015-10-28 2019-09-24 中国石油化工股份有限公司 一种烷基化反应方法
CN106631655B (zh) * 2015-10-28 2019-05-21 中国石油化工股份有限公司 一种烷基化反应方法
RU2637922C2 (ru) * 2016-06-02 2017-12-08 Публичное акционерное общество "Электрогорский институт нефтепереработки" (ПАО "ЭлИНП") Способ алкилирования изобутана в трехфазном реакторе с неподвижным слоем катализатора
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CN110538675A (zh) * 2018-05-28 2019-12-06 中国石油化工股份有限公司 固体酸烷基化催化剂及其制备方法和应用
CN110872529B (zh) * 2018-09-04 2022-06-28 中国石油化工股份有限公司 固体酸烷基化反应方法和反应系统
CN110876854B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 一种低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
CN110876855B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
WO2020151646A1 (zh) * 2019-01-25 2020-07-30 中国石油化工股份有限公司 固体酸催化剂、其制备和应用
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Also Published As

Publication number Publication date
AU5750598A (en) 1998-06-22
EP0941211B1 (en) 2002-02-06
CN1088449C (zh) 2002-07-31
JP4278067B2 (ja) 2009-06-10
CN1238747A (zh) 1999-12-15
JP2001504504A (ja) 2001-04-03
KR20000052722A (ko) 2000-08-25
KR100533754B1 (ko) 2005-12-06
US5986158A (en) 1999-11-16
WO1998023560A1 (en) 1998-06-04
BR9713441A (pt) 2000-02-01
EP0941211A1 (en) 1999-09-15
BR9713441B1 (pt) 2009-01-13
DE69710359T2 (de) 2002-08-14
CA2273333C (en) 2007-05-01
DE69710359D1 (de) 2002-03-21
CA2273333A1 (en) 1998-06-04

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