DE69529507T2 - Verfahren zur Herstellung eines klebenden Schaumgegenstandes - Google Patents
Verfahren zur Herstellung eines klebenden SchaumgegenstandesInfo
- Publication number
- DE69529507T2 DE69529507T2 DE69529507T DE69529507T DE69529507T2 DE 69529507 T2 DE69529507 T2 DE 69529507T2 DE 69529507 T DE69529507 T DE 69529507T DE 69529507 T DE69529507 T DE 69529507T DE 69529507 T2 DE69529507 T2 DE 69529507T2
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- foamable composition
- hollow component
- parts
- acrylate copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 11
- 239000000853 adhesive Substances 0.000 title claims description 9
- 230000001070 adhesive effect Effects 0.000 title claims description 9
- 239000006260 foam Substances 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims description 50
- 238000005187 foaming Methods 0.000 claims description 23
- 239000004840 adhesive resin Substances 0.000 claims description 19
- 229920006223 adhesive resin Polymers 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 15
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 13
- 239000004971 Cross linker Substances 0.000 claims description 10
- 229920001684 low density polyethylene Polymers 0.000 claims description 10
- 239000004702 low-density polyethylene Substances 0.000 claims description 10
- 239000004604 Blowing Agent Substances 0.000 claims description 9
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 8
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 6
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 5
- 229920002959 polymer blend Polymers 0.000 claims description 5
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 4
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000013585 weight reducing agent Substances 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013016 damping Methods 0.000 description 3
- KINULKKPVJYRON-PVNXHVEDSA-N n-[(e)-[10-[(e)-(4,5-dihydro-1h-imidazol-2-ylhydrazinylidene)methyl]anthracen-9-yl]methylideneamino]-4,5-dihydro-1h-imidazol-2-amine;hydron;dichloride Chemical compound Cl.Cl.N1CCN=C1N\N=C\C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1\C=N\NC1=NCCN1 KINULKKPVJYRON-PVNXHVEDSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- UOYIYWCAYFTQLH-UHFFFAOYSA-N 3,7-dinitro-1,3,5,7-tetrazabicyclo[3.3.1]nonane Chemical compound C1N2CN([N+](=O)[O-])CN1CN([N+]([O-])=O)C2 UOYIYWCAYFTQLH-UHFFFAOYSA-N 0.000 description 1
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/18—Filling preformed cavities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/08—Insulating elements, e.g. for sound insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Acoustics & Sound (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26391194 | 1994-10-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69529507D1 DE69529507D1 (de) | 2003-03-06 |
| DE69529507T2 true DE69529507T2 (de) | 2003-09-04 |
Family
ID=17395983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69529507T Expired - Fee Related DE69529507T2 (de) | 1994-10-27 | 1995-10-27 | Verfahren zur Herstellung eines klebenden Schaumgegenstandes |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US5708042A (enExample) |
| EP (1) | EP0710696B1 (enExample) |
| DE (1) | DE69529507T2 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103152A (en) | 1998-07-31 | 2000-08-15 | 3M Innovative Properties Co. | Articles that include a polymer foam and method for preparing same |
| JP3386730B2 (ja) | 1998-11-30 | 2003-03-17 | 株式会社ネオックスラボ | 中空構造物における遮断・補強具 |
| US6482340B1 (en) * | 1999-03-30 | 2002-11-19 | Lear Corporation | Sprayed-on foam wire harness |
| US6403668B1 (en) | 1999-05-28 | 2002-06-11 | Neo-Ex Lab, Inc. | Foam materials and foam precursor materials |
| US6630531B1 (en) | 2000-02-02 | 2003-10-07 | 3M Innovative Properties Company | Adhesive for bonding to low surface energy surfaces |
| US20030211308A1 (en) | 2001-02-02 | 2003-11-13 | Khandpur Ashish K | Adhesive for bonding to low surface energy surfaces |
| WO2003093064A1 (en) * | 2002-05-02 | 2003-11-13 | Dow Global Technologies, Inc. | Vehicle body cavity filler |
| US7249415B2 (en) | 2003-06-26 | 2007-07-31 | Zephyros, Inc. | Method of forming members for sealing or baffling |
| JP3771567B2 (ja) | 2003-09-02 | 2006-04-26 | 日東電工株式会社 | 充填発泡用組成物、充填発泡部材および充填用発泡体 |
| US7316985B2 (en) * | 2004-04-16 | 2008-01-08 | Frank Tien | Breathable and waterproof lining structure for footwear and garment |
| EP1772480B1 (en) * | 2005-10-06 | 2013-12-04 | Henkel AG & Co. KGaA | Reduction of transfer of vibrations |
| US8475694B2 (en) * | 2005-10-25 | 2013-07-02 | Zephyros, Inc. | Shaped expandable material |
| BRPI0709476A2 (pt) * | 2006-04-06 | 2011-07-19 | Dow Global Technologies Inc | método para aplicar uma composição poliolefìnica expansìvel termicamente e composição poliolefinica sólida expansìvel termicamente |
| CN101535394B (zh) * | 2006-09-20 | 2013-02-27 | 汉高两合股份公司 | 固态可膨胀组合物 |
| DE102007038659A1 (de) * | 2007-08-15 | 2009-02-19 | Henkel Ag & Co. Kgaa | Expandierbares, extrudiertes Formteil und Verfahren zu seiner Herstellung |
| EP2262664A4 (en) | 2008-03-07 | 2012-05-09 | Henkel Corp | ACOUSTIC SCREEN ASSEMBLY |
| GB0806434D0 (en) * | 2008-04-09 | 2008-05-14 | Zephyros Inc | Improvements in or relating to structural adhesives |
| GB0818498D0 (en) * | 2008-10-09 | 2008-11-19 | Zephyros Inc | Provision of inserts |
| GB0916205D0 (en) | 2009-09-15 | 2009-10-28 | Zephyros Inc | Improvements in or relating to cavity filling |
| CN103153604B (zh) | 2010-03-04 | 2016-04-13 | 泽菲罗斯公司 | 结构复合层压板 |
| GB201016530D0 (en) | 2010-09-30 | 2010-11-17 | Zephyros Inc | Improvements in or relating to adhesives |
| BR112013013989B1 (pt) | 2010-12-08 | 2022-02-08 | Zephyros, Inc | Dispositivo de vedação para uma cavidade e método para vedar uma cavidade |
| BR112013031193A2 (pt) | 2011-06-10 | 2017-08-08 | Henkel Ag & Co Kgaa | amortecimento de vibração eficaz através de uma ampla faixa de temperatura |
| US8967327B2 (en) | 2012-03-20 | 2015-03-03 | Zephyros, Inc. | Baffle assembly |
| EP3483046A1 (en) | 2012-06-08 | 2019-05-15 | Zephyros Inc. | Baffle with expanding material |
| US9701093B2 (en) | 2013-04-30 | 2017-07-11 | Zephyros, Inc. | Surface conforming activatable adhesive bodies and methods of making same |
| EP3024903B1 (en) | 2013-07-26 | 2021-09-08 | Zephyros Inc. | Improvements in or relating to thermosetting adhesive films |
| EP3052298B1 (en) | 2013-10-04 | 2023-09-20 | Zephyros Inc. | Method and apparatus for adhesion of inserts |
| KR101378517B1 (ko) * | 2013-10-31 | 2014-03-27 | 주식회사 금양 | Ｅｖａ 발포체 제조를 위한 수지 개질제 |
| US9796891B2 (en) | 2014-08-11 | 2017-10-24 | Zephyros, Inc. | Panel edge enclosures |
| EP4140733A1 (en) | 2014-08-14 | 2023-03-01 | Zephyros Inc. | Reformable epoxy resin for composites |
| GB201417985D0 (en) | 2014-10-10 | 2014-11-26 | Zephyros Inc | Improvements in or relating to structural adhesives |
| CN114312602B (zh) | 2015-04-30 | 2024-08-30 | 泽菲罗斯有限公司 | 用于密封、隔挡或加固的构件 |
| US10780672B2 (en) | 2015-05-14 | 2020-09-22 | Zephyros, Inc. | Localized panel stiffener |
| US11155673B2 (en) | 2015-11-12 | 2021-10-26 | Zephyros, Inc. | Controlled glass transition polymeric material and method |
| USD879701S1 (en) | 2018-05-14 | 2020-03-31 | Zephyros, Inc. | Sealing device |
| USD879007S1 (en) | 2018-05-14 | 2020-03-24 | Zephyros, Inc. | Sealing device |
| USD938887S1 (en) | 2018-06-21 | 2021-12-21 | Zephyros, Inc. | Sealing device |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3965054A (en) * | 1973-04-10 | 1976-06-22 | The Furukawa Electric Co., Ltd. | Foamable polyolefin composition and method for manufacturing foamed polyolefin |
| US4424181A (en) * | 1982-10-13 | 1984-01-03 | Nippon Unicar Company | Process and composition for producing open-cell cross linked polyolefin foam |
| US4659746A (en) * | 1984-12-21 | 1987-04-21 | Union Carbide Corporation | Olefin polymer foams |
| US4607060A (en) * | 1985-09-30 | 1986-08-19 | Pennwalt Corporation | Foaming and crosslinking of elastomeric and/or thermoplastic polymers |
| US4755402A (en) * | 1987-03-03 | 1988-07-05 | W. R. Grace & Co., Cryovac Div. | Thermoplastic multi-layer barrier packaging film and bags made therefrom |
| GB8903211D0 (en) * | 1989-02-13 | 1989-03-30 | Exxon Chemical Patents Inc | Thermoplastic foamable compositions and car body inserts made from such composition |
| US5077317A (en) * | 1991-03-08 | 1991-12-31 | Yi Shyu Horng | Electrically conductive closed cell foam of ethylene vinyl acetate copolymer and method of making |
| US5631304A (en) * | 1994-10-27 | 1997-05-20 | Hasegawa; Itsuro | Method of manufacturing rigid foamed product |
-
1995
- 1995-10-26 US US08/548,612 patent/US5708042A/en not_active Expired - Fee Related
- 1995-10-27 DE DE69529507T patent/DE69529507T2/de not_active Expired - Fee Related
- 1995-10-27 EP EP95307661A patent/EP0710696B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5708042A (en) | 1998-01-13 |
| DE69529507D1 (de) | 2003-03-06 |
| EP0710696A2 (en) | 1996-05-08 |
| EP0710696A3 (enExample) | 1996-05-22 |
| EP0710696B1 (en) | 2003-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |