DE69523070T2 - Extrudierter polymerschaum mit füllstoffteilchen und verfahren - Google Patents
Extrudierter polymerschaum mit füllstoffteilchen und verfahrenInfo
- Publication number
- DE69523070T2 DE69523070T2 DE69523070T DE69523070T DE69523070T2 DE 69523070 T2 DE69523070 T2 DE 69523070T2 DE 69523070 T DE69523070 T DE 69523070T DE 69523070 T DE69523070 T DE 69523070T DE 69523070 T2 DE69523070 T2 DE 69523070T2
- Authority
- DE
- Germany
- Prior art keywords
- extruder
- polyol
- screw
- mixture
- conveyor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/60—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
- B29B7/603—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material in measured doses, e.g. proportioning of several materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/748—Plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/823—Temperature control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/826—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/46—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
- B29C44/50—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying
- B29C44/505—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying extruding the compound through a flat die
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/42—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7404—Mixing devices specially adapted for foamable substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Molding Of Porous Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/144,621 US5424014A (en) | 1992-09-18 | 1993-11-01 | Method for extruding foamable polymer material |
PCT/US1995/000175 WO1996020966A1 (en) | 1993-11-01 | 1995-01-06 | Extruded polymer foam with filler particles and method |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69523070D1 DE69523070D1 (de) | 2001-11-08 |
DE69523070T2 true DE69523070T2 (de) | 2002-07-04 |
Family
ID=26789444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69523070T Expired - Fee Related DE69523070T2 (de) | 1993-11-01 | 1995-01-06 | Extrudierter polymerschaum mit füllstoffteilchen und verfahren |
Country Status (10)
Country | Link |
---|---|
US (1) | US5424014A (de) |
EP (1) | EP0801660B1 (de) |
JP (1) | JP3226927B2 (de) |
AT (1) | ATE206443T1 (de) |
AU (1) | AU1598995A (de) |
CA (1) | CA2209563C (de) |
DE (1) | DE69523070T2 (de) |
ES (1) | ES2164760T3 (de) |
MX (1) | MX9704957A (de) |
WO (1) | WO1996020966A1 (de) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5723506A (en) * | 1992-09-18 | 1998-03-03 | Apache Products Company | Extruded polymer foam with filler particles and method |
USRE37095E1 (en) * | 1992-09-18 | 2001-03-13 | Apache Products Company | Extruded polymer foam with filler particles and method |
US5846461A (en) * | 1996-11-26 | 1998-12-08 | National Foam Cushion Manufacturing, Inc. | Method of manufacturing carpet pads from a polyurethane foam composition |
US5981611A (en) * | 1997-11-24 | 1999-11-09 | Prince Corporation | Thermoformable foam with infrared receptors |
US6022912A (en) * | 1998-09-22 | 2000-02-08 | Bayer Corporation | Expansion of polymeric microspheres insitu in a rigid PUR/PIR foam formulation using a twin screw extruder |
US6403663B1 (en) | 1999-09-20 | 2002-06-11 | North Carolina State University | Method of making foamed materials using surfactants and carbon dioxide |
ATE362012T1 (de) * | 1999-12-20 | 2007-06-15 | Advanced Plastics Technologies | Hydroxy-phenoxyetherpolymere in der papierherstellung |
AU2001249453A1 (en) | 2000-03-27 | 2001-10-08 | Apache Products Company | Fire resistant foam and foam products, method and dispersions for making same |
DE10056251B4 (de) * | 2000-11-14 | 2006-06-08 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Schaumstoffen |
AU2002257127A1 (en) | 2001-04-04 | 2002-10-21 | Advanced Plastics Technologies, Ltd. | Process for coating paper, paperboard, and molded fiber with a water-dispersible polyester polymer |
DE10123002C1 (de) * | 2001-05-11 | 2002-08-08 | Basf Ag | Reaktionsapparat zur Herstellung von Reaktions-Kunststoffen |
US7363244B2 (en) * | 2002-11-08 | 2008-04-22 | Palo Alto Research Center Incorporated | Methods, apparatus, and program products for inferring service usage |
US20040102830A1 (en) * | 2002-11-22 | 2004-05-27 | Williams Terrell M. | System for coupling an implanatable medical device to an epicardial site |
WO2004065092A1 (en) * | 2003-01-22 | 2004-08-05 | Wellstream International Limited | Process for manufacturing a flexible tubular pipe having extruded layers made of crosslinked polyethylene |
US7763341B2 (en) | 2004-01-23 | 2010-07-27 | Century-Board Usa, Llc | Filled polymer composite and synthetic building material compositions |
AU2005267399A1 (en) | 2004-06-24 | 2006-02-02 | Century-Board Usa, Llc | Continuous forming apparatus for three-dimensional foamed products |
US7794224B2 (en) | 2004-09-28 | 2010-09-14 | Woodbridge Corporation | Apparatus for the continuous production of plastic composites |
US7329374B2 (en) * | 2004-12-15 | 2008-02-12 | Lung-Wen Chou | Method for manufacturing resing films |
JP4694191B2 (ja) * | 2004-12-17 | 2011-06-08 | 住化バイエルウレタン株式会社 | ポリウレタンフォーム成形品の製造法 |
US20070222105A1 (en) | 2006-03-24 | 2007-09-27 | Century-Board Usa, Llc | Extrusion of polyurethane composite materials |
ES2429171T3 (es) * | 2007-12-19 | 2013-11-13 | Sika Technology Ag | Espuma polímera monocomponente que se endurece con la humedad |
CN101952335B (zh) * | 2007-12-28 | 2015-08-05 | 波士胶公司 | 一种用于生产湿固化聚氨酯密封剂和粘合剂的连续工艺 |
US8846776B2 (en) | 2009-08-14 | 2014-09-30 | Boral Ip Holdings Llc | Filled polyurethane composites and methods of making same |
US9481759B2 (en) | 2009-08-14 | 2016-11-01 | Boral Ip Holdings Llc | Polyurethanes derived from highly reactive reactants and coal ash |
JP2013072038A (ja) * | 2011-09-28 | 2013-04-22 | Nitto Denko Corp | 熱可塑性樹脂発泡体の製造方法 |
WO2013052732A1 (en) | 2011-10-07 | 2013-04-11 | Boral Industries Inc. | Inorganic polymer/organic polymer composites and methods of making same |
WO2014168633A1 (en) | 2013-04-12 | 2014-10-16 | Boral Ip Holdings (Australia) Pty Limited | Composites formed from an absorptive filler and a polyurethane |
TWI667285B (zh) | 2013-10-18 | 2019-08-01 | 德商巴斯夫歐洲公司 | 膨脹熱塑性彈性體之製造 |
JP6321404B2 (ja) * | 2014-02-26 | 2018-05-09 | 株式会社ジェイテクト | 蓄電材料の製造装置および製造方法 |
US10138341B2 (en) | 2014-07-28 | 2018-11-27 | Boral Ip Holdings (Australia) Pty Limited | Use of evaporative coolants to manufacture filled polyurethane composites |
WO2016022103A1 (en) | 2014-08-05 | 2016-02-11 | Amitabha Kumar | Filled polymeric composites including short length fibers |
WO2016118141A1 (en) | 2015-01-22 | 2016-07-28 | Boral Ip Holdings (Australia) Pty Limited | Highly filled polyurethane composites |
WO2016195717A1 (en) | 2015-06-05 | 2016-12-08 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with lightweight fillers |
US20170267585A1 (en) | 2015-11-12 | 2017-09-21 | Amitabha Kumar | Filled polyurethane composites with size-graded fillers |
KR102154867B1 (ko) * | 2020-02-07 | 2020-09-10 | 최규술 | 폴리우레탄 발포폼 및 그 제조방법 |
EP4001335A1 (de) | 2020-11-18 | 2022-05-25 | Covestro Deutschland AG | Verfahren zur herstellung von polyurethan-schaumstoffen |
JP2022159929A (ja) * | 2021-04-05 | 2022-10-18 | 積水化学工業株式会社 | ポリオール組成物、ポリウレタン樹脂組成物、及びポリウレタンフォーム |
CN113563555A (zh) * | 2021-08-17 | 2021-10-29 | 长虹美菱股份有限公司 | 一种聚氨酯发泡料及其发泡工艺 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3466705A (en) * | 1966-03-07 | 1969-09-16 | Owens Illinois Inc | Apparatus for extruding foamable plastic materials in tubular form |
DE2649996A1 (de) * | 1976-10-30 | 1978-05-03 | Bayer Ag | Verfahren und vorrichtung zum herstellen eines fuellstoffhaltigen reaktionsgemisches aus mindestens zwei fliessfaehigen komponenten, insbesondere zum erzeugen von polyurethan |
DE2707026A1 (de) * | 1977-02-18 | 1978-08-24 | Bayer Ag | Verfahren und vorrichtung zum kontinuierlichen extrudieren von kunststoffprofilen aus polyurethan-rohstoffen |
DE2828506C2 (de) * | 1978-06-29 | 1980-04-17 | Bayer Ag, 5090 Leverkusen | Verfahren und Vorrichtung zum Herstellen eines schäumfähigen Gemisches aus mindestens zwei fließfähigen, schaumstoffbildenden Reaktionskomponenten und Zuschlagstoffen |
DE2854409A1 (de) * | 1978-12-16 | 1980-06-26 | Bayer Ag | Verfahren zur herstellung von thermoplastischen chemiewerkstoffen |
DE2854406A1 (de) * | 1978-12-16 | 1980-06-26 | Bayer Ag | Thermoplastische chemiewerkstoffe und verfahren zu ihrer herstellung |
US4395214A (en) * | 1981-08-27 | 1983-07-26 | U.C. Industries | Foam extrusion apparatus having downstream upper and lower hinged shaping means and side restraining means |
DE3224324A1 (de) * | 1982-06-30 | 1984-01-05 | Basf Ag, 6700 Ludwigshafen | Zweistufenverfahren zur herstellung von thermoplastischen polyurethan-elastomeren |
DK157908C (da) * | 1982-12-22 | 1990-09-03 | John Schmidt | Byggemateriale til byggeelementer samt fremgangsmaade og anlaeg til fremstilling heraf. |
US4496625A (en) * | 1983-10-12 | 1985-01-29 | The Celotex Corporation | Alkoxylated aromatic amine-aromatic polyester polyol blend and polyisocyanurate foam therefrom |
US4795763A (en) * | 1988-04-18 | 1989-01-03 | The Celotex Corporation | Carbon black-filled foam |
US4948859A (en) * | 1988-10-28 | 1990-08-14 | Minnesota Mining And Manufacturing Company | Extruder polymerization of polyurethanes |
US5192607A (en) * | 1991-08-28 | 1993-03-09 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5149722A (en) * | 1991-08-28 | 1992-09-22 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5137930A (en) * | 1991-08-28 | 1992-08-11 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5373026A (en) * | 1992-12-15 | 1994-12-13 | The Dow Chemical Company | Methods of insulating with plastic structures containing thermal grade carbon black |
-
1993
- 1993-11-01 US US08/144,621 patent/US5424014A/en not_active Expired - Lifetime
-
1995
- 1995-01-06 DE DE69523070T patent/DE69523070T2/de not_active Expired - Fee Related
- 1995-01-06 ES ES95907992T patent/ES2164760T3/es not_active Expired - Lifetime
- 1995-01-06 AT AT95907992T patent/ATE206443T1/de not_active IP Right Cessation
- 1995-01-06 JP JP52092396A patent/JP3226927B2/ja not_active Expired - Fee Related
- 1995-01-06 WO PCT/US1995/000175 patent/WO1996020966A1/en active IP Right Grant
- 1995-01-06 MX MX9704957A patent/MX9704957A/es not_active IP Right Cessation
- 1995-01-06 EP EP95907992A patent/EP0801660B1/de not_active Expired - Lifetime
- 1995-01-06 CA CA002209563A patent/CA2209563C/en not_active Expired - Fee Related
- 1995-01-06 AU AU15989/95A patent/AU1598995A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CA2209563C (en) | 2002-06-25 |
ATE206443T1 (de) | 2001-10-15 |
EP0801660A4 (de) | 1998-04-08 |
ES2164760T3 (es) | 2002-03-01 |
JPH10502415A (ja) | 1998-03-03 |
EP0801660B1 (de) | 2001-10-04 |
WO1996020966A1 (en) | 1996-07-11 |
DE69523070D1 (de) | 2001-11-08 |
MX9704957A (es) | 1998-02-28 |
CA2209563A1 (en) | 1996-07-11 |
US5424014A (en) | 1995-06-13 |
EP0801660A1 (de) | 1997-10-22 |
AU1598995A (en) | 1996-07-24 |
JP3226927B2 (ja) | 2001-11-12 |
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