DE69501888D1 - Verfahren zur Durchführung einer Polymerisationsreaktion mit incompatiblen Polymerisationskatalysatoren - Google Patents
Verfahren zur Durchführung einer Polymerisationsreaktion mit incompatiblen PolymerisationskatalysatorenInfo
- Publication number
- DE69501888D1 DE69501888D1 DE69501888T DE69501888T DE69501888D1 DE 69501888 D1 DE69501888 D1 DE 69501888D1 DE 69501888 T DE69501888 T DE 69501888T DE 69501888 T DE69501888 T DE 69501888T DE 69501888 D1 DE69501888 D1 DE 69501888D1
- Authority
- DE
- Germany
- Prior art keywords
- carrying
- polymerization
- incompatible
- polymerization reaction
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/218,277 US5442019A (en) | 1994-03-25 | 1994-03-25 | Process for transitioning between incompatible polymerization catalysts |
PCT/US1995/003348 WO1995026370A1 (en) | 1994-03-25 | 1995-03-24 | Process for transitioning between incompatible polymerization catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69501888D1 true DE69501888D1 (de) | 1998-04-30 |
DE69501888T2 DE69501888T2 (de) | 1998-11-12 |
Family
ID=22814463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69501888T Revoked DE69501888T2 (de) | 1994-03-25 | 1995-03-24 | Verfahren zur Durchführung einer Polymerisationsreaktion mit incompatiblen Polymerisationskatalysatoren |
Country Status (9)
Country | Link |
---|---|
US (4) | US5442019A (de) |
EP (1) | EP0751965B1 (de) |
JP (1) | JP2858957B2 (de) |
KR (1) | KR100389180B1 (de) |
CN (2) | CN101117361A (de) |
CA (1) | CA2186400A1 (de) |
DE (1) | DE69501888T2 (de) |
ES (1) | ES2118585T3 (de) |
WO (1) | WO1995026370A1 (de) |
Families Citing this family (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5608019A (en) * | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
US5672666A (en) * | 1995-06-05 | 1997-09-30 | Exxon Chemical Patents Inc. | Process for transitioning between incompatible polymerization catalysts |
US5859303A (en) * | 1995-12-18 | 1999-01-12 | Phillips Petroleum Company | Olefin production |
NO301331B1 (no) * | 1996-03-05 | 1997-10-13 | Borealis As | Fremgangsmåte for skifting av katalysator ved suspensjonspolymerisasjon av olefiner |
US6015779A (en) * | 1996-03-19 | 2000-01-18 | Energy & Environmental International, L.C. | Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents |
US5869570A (en) * | 1996-03-19 | 1999-02-09 | Energy & Environmental International, L.C. | Composition of and process for forming polyalphaolefin drag reducing agents |
US6124412A (en) * | 1997-12-29 | 2000-09-26 | Saudi Basic Industries Corporation | Alumoxane-enhanced, supported ziegler-natta polymerization catalysts, methods of making same, processes of using same and polymers produced therefrom |
US6569964B2 (en) | 1997-12-29 | 2003-05-27 | Saudi Basic Industries Corporation | Alumoxane-enhanced, supported Ziegler-Natta catalysts, methods of making same, processes of using same and polymers produced therefrom |
EP0942011B1 (de) * | 1998-03-09 | 2003-05-14 | Basell Poliolefine Italia S.p.A. | Mehrstufiges Verfahren zur Olefinpolymerisation |
DE69907785T2 (de) | 1998-03-09 | 2004-02-12 | Basell Poliolefine Italia S.P.A. | Mehrstufiges Verfahren zur Olefinpolymerisation |
US6967230B2 (en) * | 1998-12-18 | 2005-11-22 | Chevron Phillips Chemical Company Lp | Process for producing polyolefins |
US6258903B1 (en) | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
US7005485B2 (en) * | 1998-12-18 | 2006-02-28 | Chevron Phillips Chemical Company Lp | Process for producing polyolefins |
US6111034A (en) * | 1998-12-31 | 2000-08-29 | Union Carbide Chemicals & Plastics Technology Corporation | Static control in olefin polymerization |
WO2000053646A1 (en) * | 1999-03-09 | 2000-09-14 | Basell Technology Company B.V. | Multi-stage process for the (co)polymerization of olefins |
EP1171486A1 (de) * | 1999-03-31 | 2002-01-16 | Chevron Phillips Chemical Company LP | Verfahren zum wechsel zwischen untereinander nicht verträglichen katalysatorsystemen |
KR20010051260A (ko) * | 1999-11-12 | 2001-06-25 | 조셉 에스. 바이크 | 점착성 중합체의 제조를 위한 전이 방법 |
GB0008770D0 (en) * | 2000-04-10 | 2000-05-31 | Bp Chem Int Ltd | Polymerisation process |
US6388027B1 (en) | 2000-10-24 | 2002-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Transition strategy for the production of sticky polymers |
US6815011B2 (en) | 2000-11-27 | 2004-11-09 | Energy & Environmental International, L.C. | Alpha olefin monomer partitioning agents for drag reducing agents and methods of forming drag reducing agents using alpha olefin monomer partitioning agents |
DE60235444D1 (de) | 2001-01-16 | 2010-04-08 | Beta Technologies Ag | Verfahren zur herstellung von amorphen polyolefinen mit ultrahohem molekulargewicht zur strömungbeschleunigung |
US7012046B2 (en) * | 2001-06-08 | 2006-03-14 | Eaton Gerald B | Drag reducing agent slurries having alfol alcohols and processes for forming drag reducing agent slurries having alfol alcohols |
EP1406969A1 (de) * | 2001-07-17 | 2004-04-14 | Basell Polyolefine GmbH | Mehrstufenpolymerisationsverfahren für olefinen |
US6916892B2 (en) * | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
CN100360571C (zh) * | 2002-06-24 | 2008-01-09 | 巴塞尔聚烯烃意大利有限公司 | α-烯烃聚合的液相法 |
US6730751B2 (en) * | 2002-07-16 | 2004-05-04 | Fina Technology, Inc. | Polymerization of polyethylene having high molecular weight |
US6897269B2 (en) * | 2002-12-27 | 2005-05-24 | Univation Technologies, Llc | Processes for transitioning between Ziegler-Natta and alumoxane-based single-site polymerization catalysts |
JP2006512446A (ja) * | 2002-12-27 | 2006-04-13 | ユニベーション・テクノロジーズ・エルエルシー | チーグラー・ナッタ重合触媒とアルモキサンベースのシングルサイト重合触媒との間の移行方法 |
US6858684B2 (en) * | 2002-12-30 | 2005-02-22 | Univation Technologies, Llc | Processes for transitioning between various polymerization catalysts |
CN1302015C (zh) * | 2002-12-30 | 2007-02-28 | 尤尼威蒂恩技术有限责任公司 | 用于在不同聚合催化剂之间转变的方法 |
US6841630B2 (en) * | 2002-12-31 | 2005-01-11 | Univation Technologies, Llc | Processes for transitioning between chrome-based and mixed polymerization catalysts |
CN100335508C (zh) * | 2002-12-31 | 2007-09-05 | 尤尼威蒂恩技术有限责任公司 | 用于在金属茂和齐格勒-纳塔聚合催化剂之间转变的方法 |
US6833417B2 (en) * | 2002-12-31 | 2004-12-21 | Univation Technologies, Llc | Processes for transitioning between chrome-based and mixed polymerization catalysts |
US6867270B2 (en) * | 2002-12-31 | 2005-03-15 | Univation Technologies, Llc | Process for transitioning between incompatible catalysts using a substantially contaminant free seedbed |
US6949612B2 (en) * | 2002-12-31 | 2005-09-27 | Univation Technologies, Llc | Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts |
CN1310966C (zh) * | 2002-12-31 | 2007-04-18 | 尤尼威蒂恩技术有限责任公司 | 在气相反应器中将催化剂转换成不相容催化剂的方法 |
US6833416B2 (en) * | 2003-03-21 | 2004-12-21 | Univation Technologies, Llc | Methods of polymerizing olefin monomers with mixed catalyst systems |
US6995216B2 (en) * | 2003-06-16 | 2006-02-07 | Equistar Chemicals, Lp | Process for manufacturing single-site polyolefins |
US6861485B2 (en) * | 2003-06-20 | 2005-03-01 | Equistar Chemicals, Lp | Multi-catalyst system for olefin polymerization |
US7629422B2 (en) * | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
CN101080423B (zh) * | 2004-12-21 | 2011-06-15 | 尤尼威蒂恩技术有限责任公司 | 用于在齐格勒-纳塔基催化剂和铬基催化剂之间转变的方法 |
DE102005035477A1 (de) * | 2005-07-26 | 2007-02-01 | Basell Polyolefine Gmbh | Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren |
RU2008107335A (ru) * | 2005-07-27 | 2009-09-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Способ полимеризации для получения полиолефинов |
US7473745B2 (en) * | 2005-09-02 | 2009-01-06 | Equistar Chemicals, Lp | Preparation of multimodal polyethylene |
EP1767549A1 (de) | 2005-09-20 | 2007-03-28 | Ineos Europe Limited | Polymerisationskatalysatoren |
US8377586B2 (en) | 2005-10-05 | 2013-02-19 | California Institute Of Technology | Fluoride ion electrochemical cell |
US20100221603A1 (en) * | 2006-03-03 | 2010-09-02 | Rachid Yazami | Lithium ion fluoride battery |
DE102005056775A1 (de) * | 2005-11-28 | 2007-05-31 | Basell Polyolefine Gmbh | Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor |
CA2529920C (en) * | 2005-12-13 | 2013-08-20 | Nova Chemicals Corporation | On the fly catalyst transitions |
EP1840141A1 (de) * | 2006-03-31 | 2007-10-03 | Total Petrochemicals Research Feluy | Verfahren zur Beendung einer katalysierten Olefinpolymerization |
EP2167228B1 (de) | 2007-05-09 | 2015-07-08 | California Institute of Technology | Lithiumfluorpolymer und fluororganische batterien |
US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
WO2010009860A1 (en) * | 2008-07-23 | 2010-01-28 | Basell Polyolefine Gmbh | Method for transitioning between incompatible olefin polymerization catalyst systems |
SG171988A1 (en) * | 2008-12-23 | 2011-07-28 | Basell Polyolefine Gmbh | Method for transitioning between incompatible olefin polymerization catalyst systems |
EP2216347A1 (de) | 2009-01-30 | 2010-08-11 | Borealis AG | Verfahren für Katalysatorübergänge in Olefinpolymerisierungen |
SG177344A1 (en) * | 2009-06-29 | 2012-02-28 | Chevron Phillips Chemical Co | The use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor |
MX2012000250A (es) | 2009-06-29 | 2012-01-25 | Chevron Philips Chemical Company Lp | Sistemas catalizadores duales de metaloceno para disminuir el indice de fusion e incrementar las velocidades de produccion de polimero. |
WO2011028178A1 (en) * | 2009-09-07 | 2011-03-10 | Irpc Public Company Limited | Highly active, morphologically-controled ziegler-natta polyethylene catalyst and method of preparing the same |
CN102762606B (zh) | 2009-12-18 | 2014-11-26 | 道达尔研究技术弗吕公司 | 改善乙烯聚合反应的方法 |
EP2383298A1 (de) † | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerisierungsverfahren |
ES2537183T3 (es) * | 2010-07-30 | 2015-06-03 | Total Research & Technology Feluy | Procedimiento de producción de polietileno |
CN103772544B (zh) * | 2012-10-20 | 2016-06-15 | 中国石油化工股份有限公司 | 气相法聚乙烯钛系与铬系催化剂切换工艺 |
SG11201604581PA (en) | 2013-12-23 | 2016-07-28 | Ineos Europe Ag | Scavenger injection |
WO2015181151A1 (en) | 2014-05-27 | 2015-12-03 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
JP6761810B2 (ja) | 2014-12-22 | 2020-09-30 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 非相容性触媒間の移行方法 |
EA034766B1 (ru) | 2014-12-22 | 2020-03-18 | Сабик Глоубл Текнолоджиз Б.В. | Способ перехода между несовместимыми катализаторами |
EP3274374B1 (de) | 2015-03-24 | 2018-10-24 | SABIC Global Technologies B.V. | Verfahren zum übergang zwischen unverträglichen katalysatoren |
US10400049B2 (en) | 2015-04-24 | 2019-09-03 | Univation Technologies, Llc | Methods for operating a polymerization reactor |
KR101885812B1 (ko) | 2015-11-30 | 2018-08-07 | 인디언 오일 코퍼레이션 리미티드 | 마찰저항 감소 폴리머를 제조하는 방법 및 이의 용도 |
CN108699168B (zh) * | 2015-12-22 | 2021-04-27 | Sabic环球技术有限责任公司 | 用于不相容催化剂之间转换的方法 |
KR101758572B1 (ko) | 2016-09-29 | 2017-07-14 | 롯데케미칼 주식회사 | 비혼화성 중합 촉매계 사이의 전환 방법 |
CN114426590A (zh) * | 2020-09-28 | 2022-05-03 | 中国石油化工股份有限公司 | 一种茂金属催化剂与Ziegler-Natta催化剂的在线切换方法 |
CN114624386A (zh) * | 2020-12-10 | 2022-06-14 | 中国石油天然气股份有限公司 | 一种乙烯聚合催化剂的评价方法 |
EP4389783A1 (de) | 2022-12-20 | 2024-06-26 | Borealis AG | Katalysatorübergangsverfahren |
EP4389776A1 (de) | 2022-12-20 | 2024-06-26 | Borealis AG | Verfahren |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4433122A (en) * | 1982-05-03 | 1984-02-21 | Monsanto Company | Stopping/restarting free radical polymerizations |
US4460755A (en) * | 1982-09-30 | 1984-07-17 | Union Carbide Corporation | Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst |
US4883847A (en) * | 1988-10-27 | 1989-11-28 | Amoco Corporation | Process to terminate an olefin polymerization reaction |
DE4241530C2 (de) * | 1992-12-10 | 1999-03-25 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von Polyethylen hoher Dichte |
-
1994
- 1994-03-25 US US08/218,277 patent/US5442019A/en not_active Expired - Lifetime
-
1995
- 1995-03-24 JP JP7525193A patent/JP2858957B2/ja not_active Expired - Fee Related
- 1995-03-24 CN CNA2007101270544A patent/CN101117361A/zh active Pending
- 1995-03-24 KR KR1019960705340A patent/KR100389180B1/ko not_active IP Right Cessation
- 1995-03-24 DE DE69501888T patent/DE69501888T2/de not_active Revoked
- 1995-03-24 CA CA002186400A patent/CA2186400A1/en not_active Abandoned
- 1995-03-24 WO PCT/US1995/003348 patent/WO1995026370A1/en not_active Application Discontinuation
- 1995-03-24 CN CN95192772A patent/CN1157000A/zh active Pending
- 1995-03-24 EP EP95914085A patent/EP0751965B1/de not_active Revoked
- 1995-03-24 ES ES95914085T patent/ES2118585T3/es not_active Expired - Lifetime
- 1995-05-17 US US08/442,590 patent/US5753786A/en not_active Expired - Lifetime
- 1995-05-17 US US08/443,136 patent/US5672665A/en not_active Expired - Lifetime
- 1995-05-19 US US08/444,592 patent/US5747612A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5753786A (en) | 1998-05-19 |
US5747612A (en) | 1998-05-05 |
DE69501888T2 (de) | 1998-11-12 |
ES2118585T3 (es) | 1998-09-16 |
WO1995026370A1 (en) | 1995-10-05 |
US5442019A (en) | 1995-08-15 |
JPH09511006A (ja) | 1997-11-04 |
US5672665A (en) | 1997-09-30 |
JP2858957B2 (ja) | 1999-02-17 |
CN101117361A (zh) | 2008-02-06 |
EP0751965A1 (de) | 1997-01-08 |
KR970702299A (ko) | 1997-05-13 |
KR100389180B1 (ko) | 2004-03-30 |
CA2186400A1 (en) | 1995-10-05 |
EP0751965B1 (de) | 1998-03-25 |
CN1157000A (zh) | 1997-08-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8331 | Complete revocation |