DE69430234T2 - Epoxidierungsverfahren und Katalysator dafür - Google Patents

Epoxidierungsverfahren und Katalysator dafür

Info

Publication number
DE69430234T2
DE69430234T2 DE69430234T DE69430234T DE69430234T2 DE 69430234 T2 DE69430234 T2 DE 69430234T2 DE 69430234 T DE69430234 T DE 69430234T DE 69430234 T DE69430234 T DE 69430234T DE 69430234 T2 DE69430234 T2 DE 69430234T2
Authority
DE
Germany
Prior art keywords
mixture
molecular sieve
epoxidation process
containing molecular
framework
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69430234T
Other languages
English (en)
Other versions
DE69430234D1 (de
Inventor
Robert J Saxton
Guy L Crocco
John G Zajacek
Kanthi S Wijesekera
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/172,405 external-priority patent/US5374747A/en
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Application granted granted Critical
Publication of DE69430234D1 publication Critical patent/DE69430234D1/de
Publication of DE69430234T2 publication Critical patent/DE69430234T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D211/26—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/27—Beta, e.g. NU-2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE69430234T 1993-12-23 1994-12-16 Epoxidierungsverfahren und Katalysator dafür Expired - Fee Related DE69430234T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/172,405 US5374747A (en) 1993-12-23 1993-12-23 Epoxidation process and catalyst therefore
US30255494A 1994-09-08 1994-09-08
US08/329,732 US5453511A (en) 1993-12-23 1994-10-26 Bis-piperidinium compounds

Publications (2)

Publication Number Publication Date
DE69430234D1 DE69430234D1 (de) 2002-05-02
DE69430234T2 true DE69430234T2 (de) 2002-10-17

Family

ID=27390135

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69430234T Expired - Fee Related DE69430234T2 (de) 1993-12-23 1994-12-16 Epoxidierungsverfahren und Katalysator dafür

Country Status (10)

Country Link
US (3) US5453511A (de)
EP (2) EP1151999A2 (de)
JP (1) JPH07242649A (de)
KR (1) KR100339284B1 (de)
AT (1) ATE215051T1 (de)
CA (1) CA2138840A1 (de)
DE (1) DE69430234T2 (de)
ES (1) ES2170766T3 (de)
SG (1) SG50357A1 (de)
TW (1) TW426641B (de)

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DE19528219A1 (de) * 1995-08-01 1997-02-06 Degussa Verfahren zur Herstellung von Epoxiden aus Olefinen
US5591875A (en) * 1995-08-02 1997-01-07 Chang; Te Epoxidation Process
FR2737482B1 (fr) * 1995-08-02 1997-09-19 Elf Aquitaine Procede d'obtention de zeolithes au titane insere dans le reseau et application
US5741749A (en) * 1996-02-13 1998-04-21 Arco Chemical Technology, L.P. Regeneration of a titanium-containing molecular sieve
WO1997029991A1 (es) * 1996-02-16 1997-08-21 Consejo Superior Investigaciones Cientificas PROCEDIMIENTO DE PREPARACION DE ZEOLITA BETA CONTENIENDO Ti, Y SIN Al
US5663384A (en) * 1996-03-06 1997-09-02 Arco Chemical Technology, L.P. Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide
ES2126485B1 (es) * 1996-05-16 1999-12-01 Univ Valencia Politecnica Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos.
DE19623608A1 (de) * 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden
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BE1010716A3 (fr) 1996-10-25 1998-12-01 Solvay Procede de regeneration de catalyseurs de type silicalite au titane.
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BE1011577A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur.
JP2001509821A (ja) * 1998-03-26 2001-07-24 レプソル キミカ，ソシエダ アノニマ 溶媒の存在下での過酸化水素によるオレフィン性化合物のエポキシ化方法
US6008388A (en) * 1998-04-16 1999-12-28 Arco Chemical Technology, L.P. Epoxidation process
SG82626A1 (en) 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
US5906954A (en) * 1998-10-13 1999-05-25 Engelhard Corporation Removal of titanium atoms from titanium silicate molecular sieves
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FR2918050B1 (fr) * 2007-06-29 2011-05-06 Inst Francais Du Petrole Solide cristallise izm-2 et son procede de preparation
KR101345560B1 (ko) 2011-12-06 2014-01-10 한국화학연구원 디시클로펜타디엔다이머의 에폭시화 반응용 고활성 촉매 및 이의 제조방법
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WO2019082995A1 (ja) 2017-10-25 2019-05-02 三井金属鉱業株式会社 ベータ型ゼオライト及びその製造方法並びに触媒
CN109438393A (zh) * 2018-10-29 2019-03-08 辽宁石油化工大学 一种环氧增塑剂合成方法
CN113371729B (zh) * 2021-07-09 2022-01-04 中国矿业大学 一种含有三元环的全硅Beta分子筛的改性方法

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Also Published As

Publication number Publication date
ATE215051T1 (de) 2002-04-15
KR950016874A (ko) 1995-07-20
US5527520A (en) 1996-06-18
KR100339284B1 (ko) 2002-11-27
SG50357A1 (en) 1998-07-20
JPH07242649A (ja) 1995-09-19
ES2170766T3 (es) 2002-08-16
US5453511A (en) 1995-09-26
TW426641B (en) 2001-03-21
US5621122A (en) 1997-04-15
CA2138840A1 (en) 1995-06-24
DE69430234D1 (de) 2002-05-02
EP1151999A2 (de) 2001-11-07
EP0659685B1 (de) 2002-03-27
EP0659685A1 (de) 1995-06-28

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